CN103981694A - Method for finishing wool fabric by compositing chitosan/TiO2 - Google Patents
Method for finishing wool fabric by compositing chitosan/TiO2 Download PDFInfo
- Publication number
- CN103981694A CN103981694A CN201410164116.9A CN201410164116A CN103981694A CN 103981694 A CN103981694 A CN 103981694A CN 201410164116 A CN201410164116 A CN 201410164116A CN 103981694 A CN103981694 A CN 103981694A
- Authority
- CN
- China
- Prior art keywords
- wool fabric
- tio
- fabric
- finishing
- composite finishing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 57
- 210000002268 wool Anatomy 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims abstract description 23
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title abstract 10
- 229920001661 Chitosan Polymers 0.000 title abstract 4
- 239000002131 composite material Substances 0.000 claims abstract description 24
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000005406 washing Methods 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 4
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 7
- 229940043237 diethanolamine Drugs 0.000 claims description 6
- 239000001488 sodium phosphate Substances 0.000 claims description 5
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 5
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 4
- 239000003431 cross linking reagent Substances 0.000 claims description 4
- 238000010992 reflux Methods 0.000 claims description 3
- 230000006750 UV protection Effects 0.000 abstract 1
- 230000003115 biocidal effect Effects 0.000 abstract 1
- 238000007598 dipping method Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- SDVHRXOTTYYKRY-UHFFFAOYSA-J tetrasodium;dioxido-oxo-phosphonato-$l^{5}-phosphane Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)P([O-])([O-])=O SDVHRXOTTYYKRY-UHFFFAOYSA-J 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000004546 feltproofing Methods 0.000 description 1
- 108010025899 gelatin film Proteins 0.000 description 1
- 238000006552 photochemical reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention provides a method for finishing wool fabric by compositing chitosan/TiO2, which comprises the following steps: A)pretreating fabric; B)preparing composite finishing liquor, taking butyl titanate and dissolving in ethanol, adding diethanolamine, uniformly stirring and adding mixed liquor mixed by ethanol and water, heating, stirring under a backflow state to form nano TiO2 sol; adding chitosan, citric acid and sodium hypophosphate in the nano TiO2 sol, uniformly stirring to obtain the composite finishing liquor; C)finishing wool fabric, placing wool fabric in the composite finishing liquor, dipping and padding twice, wherein mangle expression is 85% and padding temperature is 50-65%; D)predrying; E)baking; F)washing; and G)drying. According to the finishing method, chitosan and nano TiO2 sol are employed as the composite finishing liquor, the finished wool fabric has good antibiosis, shrinkproof, ultraviolet resistance and anti-insolation performances; the finishing method generates no pollution on human body and environment, and the finished wool fabric has good hand feeling.
Description
Technical field
The present invention relates to a kind of method for sorting of wool fabric, especially relate to a kind of with shitosan/TiO
2the method of composite finishing wool fabric.
Background technology
Along with light and thin type fabric is being widely used of summer, problem that person pays close attention to that the deodorization of wool fabric, antibacterial, uvioresistant and sun-resistant performance etc. have become spinstry.Wool fabric irradiates through long-time ultraviolet ray, can make the dye molecule absorption photon on fabric become excitation state, thereby cause dyestuff generation photochemical reaction, the light fastness that reduces fabric, uvioresistant and the sun-resistant performance of therefore taking wool fabric summer just become the key factor that affects product quality and class.
Nano-TiO
2with its remarkable chemical stability, high efficiency, selectively, the advantage such as not soluble and safe, inexpensive, pollution-free, be acknowledged as one of focus of tech Textiles application study.Nano-TiO
2in the mixed emulsion finishing agent that powder is made, because nano particle has very strong adsorptivity, can make finishing agent be adsorbed on securely wool surfaces, be conducive to finishing agent and be coated on fully fiber epicuticula comprehensively, thereby weaken rubbing effect, reduce the frictional resistance of fiber surface, give wool fabric lasting, long-acting shrinkproof performance, reach the finishing effect of felt proofing, keep the good style of wool fabric, color and luster, gas permeability and feel, meet machine washing, the requirement of anti-fuzz balls, simultaneously, this method for sorting technological process is short, harmless to human body when processing, the waste water environmentally safe producing, and the fabric feeling after arranging is better.
Summary of the invention
The object of this invention is to provide a kind of shitosan/TiO
2the method of composite finishing wool fabric.
What the present invention will solve is the defects such as the finishing effect existing in existing wool fabric method for sorting is not good, arranging process is numerous and diverse, dressing liquid is big for environment pollution.
Technical scheme of the present invention is: a kind of shitosan/TiO
2the method of composite finishing wool fabric, described method at least comprises the steps: the preliminary treatment of a. fabric: wool fabric is cleaned and is placed in warm water, and the ultrasonic wave that is 30～40KHz by frequency is processed 30～60 minutes; B. composite finishing liquid preparation: get in the ethanol that a certain amount of butyl titanate is dissolved in certain volume, add a certain amount of diethanol amine, after stirring, add the mixed liquor of the second alcohol and water of certain volume, continue to stir a period of time, then the temperature that raises, forms nano-TiO after stirring a period of time under reflux state
2colloidal sol; To nano-TiO
2in colloidal sol, add a certain amount of shitosan, crosslinking agent citric acid and catalyst inferior sodium phosphate, stir, obtain composite finishing liquid; C. wool fabric arranges: pretreated wool fabric is placed in to composite finishing liquid, and described arrangement is two to soak two and roll, and pick-up rate is 85%, and padding temperature is 50～65 DEG C; D. preliminary drying: the wool fabric after arranging is dried 3～5 minutes at 70～80 DEG C; E. cure: pre-baked wool fabric is baked to 2～5 minutes at 140～170 DEG C; F: washing: with the hot wash fabric of 60 DEG C; G: dry: wool fabric is dried at 70～80 DEG C.
The nano-TiO of described preparation
2the concentration of colloidal sol is 0.3～0.5mol/L; The consumption of described shitosan is 0.5～1.2% owf; The consumption of described citric acid is 2～4% owf; The consumption of described inferior sodium phosphate is 1～3% owf.
Described nano-TiO
2in the preparation process of colloidal sol, the mol ratio of butyl titanate, diethanol amine, second alcohol and water is 1:0.7～0.9:20:0.5～0.6.
The beneficial effect that the present invention produces is: compared with prior art, composite finishing method provided by the invention, adopts shitosan and nano-TiO
2the mixture of colloidal sol is as composite finishing agent, nano-TiO
2colloidal sol is not only conducive to improve the graft reaction efficiency of shitosan, and nano-TiO
2colloidal sol itself is adsorbed on after wool surface, can form fine and close gel film through curing; Wool fabric after arrangement has the functions such as extraordinary antibacterial, shrinkproof, uvioresistant, anti-Japanese solarization.Method for sorting is harmless to human body, the waste water environmentally safe of generation, and the fabric feeling after arrangement is better.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
A kind of shitosan/TiO
2the method of composite finishing wool fabric, described method at least comprises the steps: the preliminary treatment of a. fabric: wool fabric is cleaned and is placed in warm water, and the ultrasonic wave that is 30～40KHz by frequency is processed 30 minutes; B. composite finishing liquid preparation: get in the ethanol that a certain amount of butyl titanate is dissolved in certain volume, add a certain amount of diethanol amine, after stirring, add the mixed liquor of the second alcohol and water of certain volume, continue to stir a period of time, then the temperature that raises, forms the nano-TiO that concentration is 0.4mol/L after stirring a period of time under reflux state
2colloidal sol, the mol ratio of described butyl titanate, diethanol amine, second alcohol and water is 1:0.8:20:0.6; To nano-TiO
2in colloidal sol, add 1.0% owf shitosan, 3.5% owf crosslinking agent citric acid and 1.5% owf catalyst inferior sodium phosphate, stir, obtain composite finishing liquid; C. wool fabric arranges: pretreated wool fabric is placed in to composite finishing liquid, and described arrangement is two to soak two and roll, and pick-up rate is 85%, and padding temperature is 50～65 DEG C; D. preliminary drying: the wool fabric after arranging is dried 3 minutes at 80 DEG C; E. cure: pre-baked wool fabric is baked to 3 minutes at 155 DEG C; F: washing: with the hot wash fabric of 60 DEG C; G: dry: wool fabric is dried at 80 DEG C.
Nano-TiO
2composite finishing liquid with shitosan composition, wool fabric is in the time padding processing, because nano particle has very strong adsorptivity, shitosan, crosslinking agent and catalyst can be wrapped up and be adsorbed on wool surface, greatly accelerate speed and the efficiency of shitosan at the graft reaction of wool surfaces, made wool fabric after treatment there is well shrinkproof and anti-microbial property.In addition, for nano-TiO
2itself, it is coated on fiber epicuticula, can weaken rubbing effect, reduces the frictional resistance of fiber surface, gives wool fabric lasting, long-acting shrinkproof performance and anti-ultraviolet property, keeps good style, color and luster, gas permeability and the feel of wool fabric.The waste water environmentally safe that described method for sorting is harmless to human body, produce, and fabric feeling after arranging is better.
Claims (3)
1. a shitosan/TiO
2the method of composite finishing wool fabric, is characterized in that described method at least comprises the steps: the preliminary treatment of a. fabric: wool fabric is cleaned and is placed in warm water, and the ultrasonic wave that is 30～40KHz by frequency is processed 30～60 minutes; B. composite finishing liquid preparation: get in the ethanol that a certain amount of butyl titanate is dissolved in certain volume, add a certain amount of diethanol amine, after stirring, add the mixed liquor of the second alcohol and water of certain volume, continue to stir a period of time, then the temperature that raises, forms nano-TiO after stirring a period of time under reflux state
2colloidal sol; To nano-TiO
2in colloidal sol, add a certain amount of shitosan, crosslinking agent citric acid and catalyst inferior sodium phosphate, stir, obtain composite finishing liquid; C. wool fabric arranges: pretreated wool fabric is placed in to composite finishing liquid, and described arrangement is two to soak two and roll, and pick-up rate is 85%, and padding temperature is 50～65 DEG C; D. preliminary drying: the wool fabric after arranging is dried 3～5 minutes at 70～80 DEG C; E. cure: pre-baked wool fabric is baked to 2～5 minutes at 140～170 DEG C; F. washing: with the hot wash fabric of 60 DEG C; G. dry: wool fabric is dried at 70～80 DEG C.
2. a kind of shitosan/TiO as claimed in claim 1
2the method of composite finishing wool fabric, is characterized in that the nano-TiO of described preparation
2the concentration of colloidal sol is 0.3～0.5mol/L; The consumption of described shitosan is 0.5～1.2% owf; The consumption of described citric acid is 2～4% owf; The consumption of described inferior sodium phosphate is 1～3% owf.
3. a kind of shitosan/TiO as claimed in claim 1
2the method of composite finishing wool fabric, is characterized in that described nano-TiO
2in the preparation process of colloidal sol, the mol ratio of butyl titanate, diethanol amine, second alcohol and water is 1:0.7～0.9:20:0.5～0.6.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410164116.9A CN103981694B (en) | 2014-04-23 | 2014-04-23 | A kind of shitosan/TiO 2the method of composite finishing wool fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410164116.9A CN103981694B (en) | 2014-04-23 | 2014-04-23 | A kind of shitosan/TiO 2the method of composite finishing wool fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103981694A true CN103981694A (en) | 2014-08-13 |
| CN103981694B CN103981694B (en) | 2015-10-28 |
Family
ID=51273850
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410164116.9A Expired - Fee Related CN103981694B (en) | 2014-04-23 | 2014-04-23 | A kind of shitosan/TiO 2the method of composite finishing wool fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103981694B (en) |
Cited By (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104631117A (en) * | 2015-02-03 | 2015-05-20 | 湖州市菱湖重兆金辉丝织厂 | Antibiotic finishing method of wool fabric |
| CN105056632A (en) * | 2015-07-30 | 2015-11-18 | 安徽凤凰滤清器股份有限公司 | Kapok fiber composite filter material for filtering oil-smoke in air and preparation method thereof |
| CN105056628A (en) * | 2015-07-30 | 2015-11-18 | 安徽凤凰滤清器股份有限公司 | Silver fiber containing filtering material for oil-smoke air and preparation method thereof |
| CN105056631A (en) * | 2015-07-30 | 2015-11-18 | 安徽凤凰滤清器股份有限公司 | Antistatic filtering material for oil-smoke air and preparation method thereof |
| CN105056633A (en) * | 2015-07-30 | 2015-11-18 | 安徽凤凰滤清器股份有限公司 | Polytetrafluoroethylene fiber filter material for filtering oil and smoke in air and preparation method thereof |
| CN105056629A (en) * | 2015-07-30 | 2015-11-18 | 安徽凤凰滤清器股份有限公司 | Flame-retardant filter material for filtering oil smoke in air and preparation method thereof |
| CN105056630A (en) * | 2015-07-30 | 2015-11-18 | 安徽凤凰滤清器股份有限公司 | Glass-fiber composite material for filtering oil smoke in air and preparation method thereof |
| CN105080215A (en) * | 2015-07-30 | 2015-11-25 | 安徽凤凰滤清器股份有限公司 | Pineapple leaf fiber composite lampblack air filtration material and preparation method thereof |
| CN105080213A (en) * | 2015-07-30 | 2015-11-25 | 安徽凤凰滤清器股份有限公司 | Mildew-proof and anti-microbial composite oil fume air filter material and preparation method thereof |
| CN105080214A (en) * | 2015-07-30 | 2015-11-25 | 安徽凤凰滤清器股份有限公司 | Composite cooking fume air filter material made of China hemp fibers and preparation method thereof |
| CN105080217A (en) * | 2015-07-30 | 2015-11-25 | 安徽凤凰滤清器股份有限公司 | Polylactic acid fiber composite oil-fume air filtration material and preparation method thereof |
| CN105107269A (en) * | 2015-07-30 | 2015-12-02 | 安徽凤凰滤清器股份有限公司 | High-strength oil fume air filtering material and preparation method therefor |
| CN105107263A (en) * | 2015-07-30 | 2015-12-02 | 安徽凤凰滤清器股份有限公司 | Filtering material for sterilizing and disinfecting air with oil smoke and preparation method thereof |
| CN105126445A (en) * | 2015-07-30 | 2015-12-09 | 安徽凤凰滤清器股份有限公司 | Corrosion-resistant oil smoke-polluted air filtering material and preparation method thereof |
| CN105126446A (en) * | 2015-07-30 | 2015-12-09 | 安徽凤凰滤清器股份有限公司 | Deodorizing oil smoke-containing air filtering material and preparation method thereof |
| CN105126447A (en) * | 2015-07-30 | 2015-12-09 | 安徽凤凰滤清器股份有限公司 | High temperature-resistant oil smoke-polluted air filtering material and preparation method thereof |
| CN105506949A (en) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | Preparation method of single-side-antifelting wool plus material |
| CN105506951A (en) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | Breathable light and thin double-sided hollowed-out fabric |
| CN105506963A (en) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | Preparation method of sandwich type anti-felting double-faced woolen cloth |
| CN105506977A (en) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | Crease-resistant finishing fluid composition for cotton fabric |
| CN105506954A (en) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | Preparation method of wool laser punched hollow fabric |
| CN105544205A (en) * | 2015-12-30 | 2016-05-04 | 江阴市长泾花园毛纺织有限公司 | Breathable and warm air layer fabric |
| CN105568665A (en) * | 2015-12-30 | 2016-05-11 | 江阴市长泾花园毛纺织有限公司 | Production method of dirt repelling and felting resisting wool fabric |
| CN105803577A (en) * | 2016-04-08 | 2016-07-27 | 江南大学 | Preparation method of taxus chinensis fibers with high antibacterial activity |
| CN106012547A (en) * | 2016-05-23 | 2016-10-12 | 江苏顺远新材料科技股份有限公司 | Functional wool fabric finishing agent and functional wool fabric finishing method |
| CN106087435A (en) * | 2016-06-12 | 2016-11-09 | 合肥市再德高分子材料有限公司 | A kind of preparation method of heat-accumulation temperature-adjustment fabric |
| CN106801338A (en) * | 2017-01-17 | 2017-06-06 | 常熟市新光毛条处理有限公司 | A kind of wool tops is without the shrinkproof Anti-Pilling Finishes technique of chlorine |
| CN106884313A (en) * | 2017-02-24 | 2017-06-23 | 东华大学 | A kind of worsted fabric sol-gal process water-repellent finishing method |
| CN106884312A (en) * | 2017-03-17 | 2017-06-23 | 富思特新材料科技发展股份有限公司 | The preparation method of Uvr Protective Fabric |
| CN107119445A (en) * | 2017-06-23 | 2017-09-01 | 沙洲职业工学院 | A kind of worsted fabric shiinkproof finish method |
| CN107326650A (en) * | 2017-07-25 | 2017-11-07 | 西安工程大学 | A kind of method of modifying of terylene supatex fabric |
| CN107829295A (en) * | 2017-11-30 | 2018-03-23 | 安徽中福毛纺制帽有限公司 | A kind of special antibacterial and mouldproof finishing agent of wool cap |
| CN107938342A (en) * | 2017-11-30 | 2018-04-20 | 安徽中福毛纺制帽有限公司 | A kind of finishing technique of wool cap |
| CN107974828A (en) * | 2017-11-30 | 2018-05-01 | 安徽中福毛纺制帽有限公司 | A kind of preparation method of the special antibacterial wool fiber of wool cap |
| CN108797101A (en) * | 2018-07-09 | 2018-11-13 | 江苏阳光股份有限公司 | A kind of preparation method of the warming dressing liquid of wool fabric |
| CN109137475A (en) * | 2018-08-09 | 2019-01-04 | 合肥五凡工程设计有限公司 | A kind of preparation process of waterproof and dampproof wool fiber |
| CN109914106A (en) * | 2019-03-15 | 2019-06-21 | 江南大学 | A kind of shiinkproof finish method of wool fabric low strength loss |
| CN111005207A (en) * | 2019-11-28 | 2020-04-14 | 江苏品创纺织科技有限公司 | Preparation method of intelligent heat-storage temperature-regulating fabric |
| CN111877010A (en) * | 2020-07-21 | 2020-11-03 | 康赛妮集团有限公司 | Antibacterial fiber, antibacterial cashmere yarn and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481874A (en) * | 2009-01-23 | 2009-07-15 | 东华大学 | Nano metal titanium dioxide sol negative oxygen ion finishing method for fabric |
| CN102912634A (en) * | 2012-10-18 | 2013-02-06 | 西安工程大学 | Method for modifying surfaces of wool fibers by using tetrabutyl titanate and chitosan |
| CN103726319A (en) * | 2013-12-09 | 2014-04-16 | 科凯精细化工（上海）有限公司 | Nano-TiO2 loaded chitosan compound and preparation method thereof |
-
2014
- 2014-04-23 CN CN201410164116.9A patent/CN103981694B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481874A (en) * | 2009-01-23 | 2009-07-15 | 东华大学 | Nano metal titanium dioxide sol negative oxygen ion finishing method for fabric |
| CN102912634A (en) * | 2012-10-18 | 2013-02-06 | 西安工程大学 | Method for modifying surfaces of wool fibers by using tetrabutyl titanate and chitosan |
| CN103726319A (en) * | 2013-12-09 | 2014-04-16 | 科凯精细化工（上海）有限公司 | Nano-TiO2 loaded chitosan compound and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 张辉等: ""壳聚糖/TiO2复合整理羊毛织物性能研究"", 《天津工业大学学报》 * |
| 郭凤芝等: ""用壳聚糖/纳米TiO2对毛针织物进行功能性整理"", 《毛纺科技》 * |
Cited By (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104631117A (en) * | 2015-02-03 | 2015-05-20 | 湖州市菱湖重兆金辉丝织厂 | Antibiotic finishing method of wool fabric |
| CN105056632A (en) * | 2015-07-30 | 2015-11-18 | 安徽凤凰滤清器股份有限公司 | Kapok fiber composite filter material for filtering oil-smoke in air and preparation method thereof |
| CN105056628A (en) * | 2015-07-30 | 2015-11-18 | 安徽凤凰滤清器股份有限公司 | Silver fiber containing filtering material for oil-smoke air and preparation method thereof |
| CN105056631A (en) * | 2015-07-30 | 2015-11-18 | 安徽凤凰滤清器股份有限公司 | Antistatic filtering material for oil-smoke air and preparation method thereof |
| CN105056633A (en) * | 2015-07-30 | 2015-11-18 | 安徽凤凰滤清器股份有限公司 | Polytetrafluoroethylene fiber filter material for filtering oil and smoke in air and preparation method thereof |
| CN105056629A (en) * | 2015-07-30 | 2015-11-18 | 安徽凤凰滤清器股份有限公司 | Flame-retardant filter material for filtering oil smoke in air and preparation method thereof |
| CN105056630A (en) * | 2015-07-30 | 2015-11-18 | 安徽凤凰滤清器股份有限公司 | Glass-fiber composite material for filtering oil smoke in air and preparation method thereof |
| CN105080215A (en) * | 2015-07-30 | 2015-11-25 | 安徽凤凰滤清器股份有限公司 | Pineapple leaf fiber composite lampblack air filtration material and preparation method thereof |
| CN105080213A (en) * | 2015-07-30 | 2015-11-25 | 安徽凤凰滤清器股份有限公司 | Mildew-proof and anti-microbial composite oil fume air filter material and preparation method thereof |
| CN105080214A (en) * | 2015-07-30 | 2015-11-25 | 安徽凤凰滤清器股份有限公司 | Composite cooking fume air filter material made of China hemp fibers and preparation method thereof |
| CN105080217A (en) * | 2015-07-30 | 2015-11-25 | 安徽凤凰滤清器股份有限公司 | Polylactic acid fiber composite oil-fume air filtration material and preparation method thereof |
| CN105107269A (en) * | 2015-07-30 | 2015-12-02 | 安徽凤凰滤清器股份有限公司 | High-strength oil fume air filtering material and preparation method therefor |
| CN105107263A (en) * | 2015-07-30 | 2015-12-02 | 安徽凤凰滤清器股份有限公司 | Filtering material for sterilizing and disinfecting air with oil smoke and preparation method thereof |
| CN105126445A (en) * | 2015-07-30 | 2015-12-09 | 安徽凤凰滤清器股份有限公司 | Corrosion-resistant oil smoke-polluted air filtering material and preparation method thereof |
| CN105126446A (en) * | 2015-07-30 | 2015-12-09 | 安徽凤凰滤清器股份有限公司 | Deodorizing oil smoke-containing air filtering material and preparation method thereof |
| CN105126447A (en) * | 2015-07-30 | 2015-12-09 | 安徽凤凰滤清器股份有限公司 | High temperature-resistant oil smoke-polluted air filtering material and preparation method thereof |
| CN105544205B (en) * | 2015-12-30 | 2018-04-20 | 江阴市长泾花园毛纺织有限公司 | A kind of breathable heat insulating air layer face fabric |
| CN105506963B (en) * | 2015-12-30 | 2017-07-21 | 江阴市长泾花园毛纺织有限公司 | A kind of two-sided preparation method of sandwich type felt proofing |
| CN105506963A (en) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | Preparation method of sandwich type anti-felting double-faced woolen cloth |
| CN105506977A (en) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | Crease-resistant finishing fluid composition for cotton fabric |
| CN105506954A (en) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | Preparation method of wool laser punched hollow fabric |
| CN105544205A (en) * | 2015-12-30 | 2016-05-04 | 江阴市长泾花园毛纺织有限公司 | Breathable and warm air layer fabric |
| CN105568665A (en) * | 2015-12-30 | 2016-05-11 | 江阴市长泾花园毛纺织有限公司 | Production method of dirt repelling and felting resisting wool fabric |
| CN105506951A (en) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | Breathable light and thin double-sided hollowed-out fabric |
| CN105506954B (en) * | 2015-12-30 | 2018-04-20 | 江阴市长泾花园毛纺织有限公司 | A kind of preparation method of wool laser punching hollow-out fabric |
| CN105506949A (en) * | 2015-12-30 | 2016-04-20 | 江阴市长泾花园毛纺织有限公司 | Preparation method of single-side-antifelting wool plus material |
| CN105568665B (en) * | 2015-12-30 | 2017-08-25 | 江阴市长泾花园毛纺织有限公司 | A kind of production method for refusing dirty felt proofing wool fabric |
| CN105506949B (en) * | 2015-12-30 | 2017-07-25 | 江阴市长泾花园毛纺织有限公司 | A kind of preparation method of one side felt proofing wool fabric |
| CN105803577A (en) * | 2016-04-08 | 2016-07-27 | 江南大学 | Preparation method of taxus chinensis fibers with high antibacterial activity |
| CN106012547A (en) * | 2016-05-23 | 2016-10-12 | 江苏顺远新材料科技股份有限公司 | Functional wool fabric finishing agent and functional wool fabric finishing method |
| CN106012547B (en) * | 2016-05-23 | 2018-12-07 | 江苏顺远新材料科技股份有限公司 | A kind of wool fabric functional finish and functional treatment method |
| CN106087435B (en) * | 2016-06-12 | 2018-12-07 | 合肥市再德高分子材料有限公司 | A kind of preparation method of heat-accumulation temperature-adjustment fabric |
| CN106087435A (en) * | 2016-06-12 | 2016-11-09 | 合肥市再德高分子材料有限公司 | A kind of preparation method of heat-accumulation temperature-adjustment fabric |
| CN106801338A (en) * | 2017-01-17 | 2017-06-06 | 常熟市新光毛条处理有限公司 | A kind of wool tops is without the shrinkproof Anti-Pilling Finishes technique of chlorine |
| CN106884313A (en) * | 2017-02-24 | 2017-06-23 | 东华大学 | A kind of worsted fabric sol-gal process water-repellent finishing method |
| CN106884312A (en) * | 2017-03-17 | 2017-06-23 | 富思特新材料科技发展股份有限公司 | The preparation method of Uvr Protective Fabric |
| CN107119445A (en) * | 2017-06-23 | 2017-09-01 | 沙洲职业工学院 | A kind of worsted fabric shiinkproof finish method |
| CN107326650A (en) * | 2017-07-25 | 2017-11-07 | 西安工程大学 | A kind of method of modifying of terylene supatex fabric |
| CN107326650B (en) * | 2017-07-25 | 2020-06-19 | 西安工程大学 | Modification method of polyester non-woven fabric |
| CN107974828A (en) * | 2017-11-30 | 2018-05-01 | 安徽中福毛纺制帽有限公司 | A kind of preparation method of the special antibacterial wool fiber of wool cap |
| CN107938342A (en) * | 2017-11-30 | 2018-04-20 | 安徽中福毛纺制帽有限公司 | A kind of finishing technique of wool cap |
| CN107829295A (en) * | 2017-11-30 | 2018-03-23 | 安徽中福毛纺制帽有限公司 | A kind of special antibacterial and mouldproof finishing agent of wool cap |
| CN108797101A (en) * | 2018-07-09 | 2018-11-13 | 江苏阳光股份有限公司 | A kind of preparation method of the warming dressing liquid of wool fabric |
| CN109137475A (en) * | 2018-08-09 | 2019-01-04 | 合肥五凡工程设计有限公司 | A kind of preparation process of waterproof and dampproof wool fiber |
| CN109914106A (en) * | 2019-03-15 | 2019-06-21 | 江南大学 | A kind of shiinkproof finish method of wool fabric low strength loss |
| CN109914106B (en) * | 2019-03-15 | 2020-05-08 | 江南大学 | Shrink-proof finishing method for low strength loss of wool fabric |
| CN111005207A (en) * | 2019-11-28 | 2020-04-14 | 江苏品创纺织科技有限公司 | Preparation method of intelligent heat-storage temperature-regulating fabric |
| CN111877010A (en) * | 2020-07-21 | 2020-11-03 | 康赛妮集团有限公司 | Antibacterial fiber, antibacterial cashmere yarn and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103981694B (en) | 2015-10-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103981694B (en) | A kind of shitosan/TiO 2the method of composite finishing wool fabric | |
| CN103981702A (en) | Compound finishing method of wool fabric | |
| CN101446036B (en) | Method for adhering sericin and nanometer material on real silk fabric | |
| CN103409984B (en) | A kind of method at surface of cotton fabric low-temperature growth anatase titanium dioxide film | |
| CN107336314A (en) | A kind of method of vegetalitas black dyes rattan dyeing | |
| CN103397513A (en) | Nano-titanium dioxide sol finishing agent prepared at low temperature and application thereof | |
| CN104878587A (en) | Pretreatment of supercritical fluid nano silver textile fabric and microwave preparation method of supercritical fluid nano silver textile fabric | |
| CN110983755A (en) | Antibacterial nano after-finishing reagent for knitted fabric and preparation method thereof | |
| CN105908514A (en) | Treatment method of machine washable down feather | |
| CN105773782A (en) | Furniture making-replica method | |
| WO2018233125A1 (en) | Process for finishing knitted fabric | |
| CN104233783A (en) | Ultraviolet-proof finishing method of fabric for umbrellas | |
| CN103243587B (en) | A kind of technique for tibet lamp dyeing | |
| CN101270548A (en) | Deodorizing colloidal sol-gel rubber finishing agent, preparation method and application thereof | |
| CN103882711A (en) | Silk wrinkle-resistant finishing method | |
| CN103696266A (en) | Antibacterial finishing process of fabric | |
| CN103924442B (en) | Butyl titanate and dyestuff are to polyester cotton modification of and coloration composite finishing method | |
| CN107558202A (en) | Rayon fabric finishing agent and preparation method thereof | |
| CN111519426A (en) | Finishing process of far infrared and negative ion woolen sweater | |
| CN109162092A (en) | A kind of production technology of anti-ultraviolet functional dacron | |
| CN103174019B (en) | A kind of scouringing and bleaching for polyester cotton to be dyeed with terylene component with bathing the multifunctional chemical system of processing | |
| CN102787487B (en) | Application of nano transparent thermal insulation coating on textile fabrics | |
| KR101167527B1 (en) | Functional wallpaper | |
| CN104441151A (en) | Wood plate antique finishing method | |
| CN114953075A (en) | Preparation method of high-color-fastness recombined decorative veneer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160614 Address after: 314500 Zhejiang city of Tongxiang province Puyuan sweater City Industrial Park Patentee after: ZHEJIANG ZHONGXIN DYEING & FINISHING CO.,LTD. Address before: 314500 Zhejiang city of Tongxiang province Puyuan town of Yuen Road Industrial Park Office Patentee before: Tongxiang Puyuan Woolen Knitting Technology Service Center |
|
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: Jiaxing City, Zhejiang province 314500 Tongxiang Puyuan sweater City Industrial Park Patentee after: Zhejiang Zhongxin dyeing and Finishing Technology Co.,Ltd. Address before: 314500 Zhejiang city of Tongxiang province Puyuan sweater City Industrial Park Patentee before: ZHEJIANG ZHONGXIN DYEING & FINISHING CO.,LTD. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151028 |