CN109914106B - Shrink-proof finishing method for low strength loss of wool fabric - Google Patents
Shrink-proof finishing method for low strength loss of wool fabric Download PDFInfo
- Publication number
- CN109914106B CN109914106B CN201910196792.7A CN201910196792A CN109914106B CN 109914106 B CN109914106 B CN 109914106B CN 201910196792 A CN201910196792 A CN 201910196792A CN 109914106 B CN109914106 B CN 109914106B
- Authority
- CN
- China
- Prior art keywords
- wool
- solution
- fabric
- wool fabric
- low strength
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 210000002268 wool Anatomy 0.000 title claims abstract description 146
- 239000004744 fabric Substances 0.000 title claims abstract description 118
- 238000000034 method Methods 0.000 title claims abstract description 54
- 206010003549 asthenia Diseases 0.000 title claims abstract description 7
- 229920001661 Chitosan Polymers 0.000 claims abstract description 31
- 239000001913 cellulose Substances 0.000 claims abstract description 30
- 229920002678 cellulose Polymers 0.000 claims abstract description 30
- 238000011282 treatment Methods 0.000 claims abstract description 14
- 239000002159 nanocrystal Substances 0.000 claims abstract description 10
- 239000000243 solution Substances 0.000 claims description 77
- 239000000835 fiber Substances 0.000 claims description 31
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 claims description 25
- 238000010006 anti-felting Methods 0.000 claims description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 10
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- 239000003638 chemical reducing agent Substances 0.000 claims description 8
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000012670 alkaline solution Substances 0.000 claims description 7
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 239000001509 sodium citrate Substances 0.000 claims description 4
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 4
- 235000010265 sodium sulphite Nutrition 0.000 claims description 4
- 238000007598 dipping method Methods 0.000 claims description 3
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 3
- 238000005660 chlorination reaction Methods 0.000 abstract description 14
- 238000004043 dyeing Methods 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 description 30
- 238000005406 washing Methods 0.000 description 30
- 238000002791 soaking Methods 0.000 description 26
- 238000001035 drying Methods 0.000 description 12
- 238000006386 neutralization reaction Methods 0.000 description 12
- 238000009950 felting Methods 0.000 description 11
- 230000000382 dechlorinating effect Effects 0.000 description 10
- 238000001338 self-assembly Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 239000004753 textile Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 230000006378 damage Effects 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 3
- 230000000149 penetrating effect Effects 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000006298 dechlorination reaction Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000004546 feltproofing Methods 0.000 description 2
- 238000000707 layer-by-layer assembly Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920005615 natural polymer Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- YSULOORXQBDPCU-UHFFFAOYSA-N 2-(trimethylazaniumyl)ethanehydrazonate;hydrochloride Chemical compound [Cl-].C[N+](C)(C)CC(=O)NN YSULOORXQBDPCU-UHFFFAOYSA-N 0.000 description 1
- WNTGHAZFHMDMCZ-UHFFFAOYSA-N ClC12NC(NC1(NC(N(C2=O)[N+]#[C-])=O)Cl)=O Chemical compound ClC12NC(NC1(NC(N(C2=O)[N+]#[C-])=O)Cl)=O WNTGHAZFHMDMCZ-UHFFFAOYSA-N 0.000 description 1
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108010029541 Laccase Proteins 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229960003067 cystine Drugs 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methyl-cyclopentane Natural products CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- -1 scales Chemical compound 0.000 description 1
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 238000011410 subtraction method Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 125000001493 tyrosinyl group Chemical group [H]OC1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])(N([H])[H])C(*)=O 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
本发明公开了一种羊毛织物低强力损失的防缩整理方法，属于毛织物染整加工技术领域。本发明首先采用DCCA对羊毛织物进行氯化防缩处理，再将羊毛织物依次浸渍在壳聚糖整理液和纤维素纳米晶溶液中，并进行组装10～20次，处理的羊毛织物的防毡缩性能明显提高，此处，也大大降低了织物的强力损失，且羊毛织物的手感较好。The invention discloses a shrink-proof finishing method for wool fabrics with low strength loss, belonging to the technical field of wool fabric dyeing and finishing. In the present invention, DCCA is used to first perform chlorination and anti-shrinkage treatment on wool fabrics, and then the wool fabrics are immersed in a chitosan finishing solution and a cellulose nanocrystal solution in turn, and are assembled for 10 to 20 times. The shrinkage performance is significantly improved, and the strength loss of the fabric is also greatly reduced here, and the hand feeling of the wool fabric is better.
Description
Technical Field
The invention relates to a shrink-proof finishing method for low strength loss of wool fabric, belonging to the technical field of dyeing and finishing of wool fabric.
Background
Wool is a natural protein fiber, and is highly popular with consumers due to the characteristics of softness, heat preservation, stiffness and low possibility of being stained. However, due to the structural particularity of wool, namely, the surface of the fiber is provided with the scale layer, when the wool is rubbed, the friction resistance in the direction opposite to the scale is larger than that in the direction along the scale, so that the directional friction effect is generated; in addition, the wool has excellent elasticity and crimpability, so that the wool fabric can generate felting phenomenon due to the action of external force in the washing process, the style and the dimensional stability of the fabric are influenced, the hand feeling of the wool fabric becomes rough, and the wearability is obviously reduced.
In order to effectively improve the anti-felting performance of wool, a large number of documents report various modification researches for wool at home and abroad, and the basic principle of the research is how to reduce the directional friction effect. At present, the shrink-proof finishing method for wool fabric can be divided into subtraction method and addition method. Among them, the subtraction process based on chlorination technique has better anti-felting effect, and the common chlorination technique reagents in the current industrial production include NaClO and DCCA (dichloroisocyanurate). In a solution with a proper pH value, the compounds can be converted into HClO to promote the scale layer to be oxidized and hydrolyzed, so that the scale layer is damaged to prevent shrinkage. However, the cortex of wool fibers also contains a large amount of cystine (-S-S-) and tyrosine residues, which can react with HClO like scales, resulting in the destruction of the fur-like layer of wool, and the deterioration of the physical and mechanical properties of wool. Besides chlorination-process anti-felting finishing, various oxidants such as potassium permanganate and hydrogen peroxide are also used for wool anti-felting, but the problems of great fabric strength damage after finishing exist.
The addition anti-felting process mainly applies various polymers to the surface of wool, so that on one hand, the effects of covering a wool scale layer and reducing the directional friction effect are achieved; on the other hand, the fibers are bonded together by the polymer film and cannot move freely, so that the anti-felting effect is obtained. The additive anti-felting treatment applies the polymer on the fiber surface by padding or dipping and solidifies to form a film, often forms a thicker coating on the fiber surface, seriously influences the hand feeling of wool, and has certain influence on the style, anti-contamination property, waterproofness, color and the like of wool fabric.
Disclosure of Invention
[ problem ] to
Solves the problem of great strength damage of the finished fabric in the chlorination shrink-proof processing.
[ solution ]
The invention provides a low-strength-loss anti-felting finishing process for wool fabrics based on self-assembly chitosan-cellulose nanocrystal combined reinforcement, and aims to improve the anti-felting performance of the wool fabrics, reduce the strength damage to the fabrics and improve the hand feeling and the wetting performance of the fabrics.
Specifically, the invention provides a shrink-proof finishing method for low strength loss of wool fabric, which comprises the following steps:
soaking the wool fabric or the wool fiber after chlorination felt proofing treatment in 5-10g/L chitosan finishing liquid for 1-5min, then washing the wool fabric or the wool fiber with water, soaking in 1-5g/L cellulose nanocrystalline solution for 1-5min, then washing the wool fabric or the wool fiber with water, then sequentially repeating the processes of soaking in the chitosan finishing liquid and the cellulose nanocrystalline solution respectively, repeating the self-assembly procedure for 10-20 times, taking out, washing the wool fabric or the wool fiber with water, and drying.
In one embodiment of the invention, the wool fabric or wool fiber is immersed in the chitosan finishing liquor or the cellulose nanocrystal solution at a bath ratio of 1:25 to 1: 50.
In one embodiment of the invention, the chlorination felting prevention treatment method comprises the following steps: placing the wool fabric or the wool fiber in a chlorination solution containing 1-5wt% of Dichloroisocyanurate (DCCA) and 1-3g/L of penetrating agent JFC, performing chlorination treatment at room temperature for 20-40min, placing the wool fabric or the wool fiber in a reducing agent solution with the concentration of 4-8 wt% for dechlorination at 30-50 ℃ for 10-30min, and finally placing the wool fabric in an alkaline solution with the pH value of 8-9, and performing neutralization at 30-50 ℃ for 10-30 min.
In one embodiment of the present invention, the chlorination solution has a pH of 3 to 6.
In one embodiment of the invention, in the chlorination anti-felting treatment, the bath ratio in the chlorination, dechlorination or neutralization process is 1: 25-1:50.
In one embodiment of the invention, the chlorinated solution is preferably treated with DCCA at a concentration of 3 wt% and the penetrant JFC at 1g/L at pH 4 for 20-40min at room temperature.
In one embodiment of the invention, the reducing agent is NaHSO3And reducing agents such as sodium sulfite and sodium dithionite, and the concentration of the reducing agent is preferably 6 wt%.
In one embodiment of the present invention, the alkaline solution is one or more of a sodium bicarbonate solution, a sodium carbonate solution, a sodium hydroxide solution or a sodium citrate solution.
In one embodiment of the invention, the chitosan finish has a pH of 5 to 6.
In one embodiment of the invention, the concentration of chitosan in the chitosan finishing liquor is preferably 5 g/L.
In one embodiment of the present invention, the concentration of the cellulose nanocrystal solution is preferably 2 g/L.
In one embodiment of the present invention, the cellulose nanocrystals have a length of 50 to 200nm and a diameter of 5 to 20 nm.
In one embodiment of the invention, the number of self-assembly is preferably 10 to 15
In one embodiment of the invention, the drying temperature is 80-100 ℃, and the drying time is 10-20 min.
The invention also provides a low-strength-loss anti-felting finishing liquid for wool, which comprises a liquid A, a liquid B, a liquid C, a liquid D and a liquid E, wherein the liquid A is a chlorinated solution containing 1-5wt% of dichloroisocyanurate DCCA and 1-3g/L of penetrating agent JFC, the liquid B is a reducing agent solution with the concentration of 4-8 wt%, the liquid C is an alkaline solution with the pH of 8-9, the liquid D is a chitosan finishing liquid of 5-10g/L, and the liquid E is a cellulose nanocrystalline solution of 1-5 g/L; the reducing agent is one or more of sodium bisulfite, sodium sulfite or sodium hydrosulfite, and the alkaline solution is one or more of sodium bicarbonate solution, sodium carbonate solution, sodium hydroxide solution or sodium citrate solution.
The invention also provides a using method of the low-strength-loss anti-felting finishing liquid for wool, which is characterized by comprising the following steps: placing wool fabrics or wool fibers in the solution A for treatment for 20-40min, dechlorinating the wool fabrics or the wool fibers in the solution B at 30-50 ℃ for 10-30min, placing the wool fabrics or the wool fibers in the solution C for neutralization at 30-50 ℃ for 10-30min, soaking the wool fabrics or the wool fibers subjected to chlorination felt-proofing treatment in the solution D for 1-5min, washing, soaking in the solution E for 1-5min, washing, repeating the soaking in the solution D and the solution E for 10-20 times, and drying after washing.
In one embodiment of the invention, the wool fabric or wool fiber is immersed in the A-E liquid at a bath ratio of 1:25 to 1: 50.
The invention has the following beneficial effects:
(1) the anti-felting performance is improved: on one hand, HClO generated in chlorination anti-felting treatment can hydrolyze the scale layer and the outer hydrophobic lipoid structure thereof, so as to achieve the purpose of destroying the scale layer to a certain degree; on the other hand, the chitosan with positive electricity and the cellulose nanocrystalline with negative electricity can form a natural polymer thin layer on the surface of wool fibers through layer-by-layer electrostatic self-assembly treatment, so that relative slippage between the fibers is limited, and the felting rate of the fabric can also be reduced. In addition, the thin layer has small polymer application amount and less influence on the fabric hand compared with the traditional polymer coating by a dipping or padding method.
(2) "repair" of fabric strength damage: on one hand, the invention firstly carries out chlorination subtraction anti-felting treatment to destroy the surface scale of the wool to a certain extent, and although the anti-felting performance is improved, the strength of the fabric is reduced. On the other hand, the cellulose nanocrystal has the characteristics of high crystallinity, high elastic modulus, high strength and the like, is a polyhydroxy reinforced filler, can be negatively charged due to generation of sulfonic acid groups in the preparation process by a sulfuric acid hydrolysis method, and can form a natural polymer thin layer with better toughness on the surface of wool fibers through electrostatic self-assembly with chitosan with positive charges; in addition, the cellulose nanocrystal with a large specific surface area and a large amount of hydroxyl on the surface can form a three-dimensional network structure with chitosan molecules through hydrogen bonds, and the film forming property and the strength of chitosan on the wool fiber matrix material are further enhanced in a layer-by-layer self-assembly mode, so that the strong damage effect of the fabric is compensated.
Detailed Description
Embodiments of the present invention are further illustrated with reference to examples. The following are merely further embodiments of the present invention, which includes but is not limited to the following.
The raw wool fabric used in the examples was worsted wool fabric. Wherein the fabric felt shrinkage is 22.9 percent, and the warp-wise tensile breaking strength is 405N.
Example 1
A low-strength-loss shrink-proof finishing method for wool fabrics comprises the following steps:
(1) the wool fabric is mixed at a bath ratio of 1:25 placing the mixture in a mixing tank containing 3 wt% of Dichloroisocyanurate (DCCA), 1g/L of penetrating agent JFC and a bath ratio of 1:25 (pH 4) for 30min at room temperature, and then the fabric was treated at a bath ratio of 1:25 to 6% by weight of sodium hydrogen sulfite (NaHSO)3) Dechlorinating the wool fabric in the solution for 20min at 40 ℃, and finally placing the wool fabric in NaHCO with the pH of 8-93In solution, neutralization was carried out at 40 ℃ for 20 min.
(2) Soaking the wool fabric treated in the step (1) in 5g/L of chitosan finishing liquid (bath ratio of 1: 50) for 5min, washing, soaking in 1g/L of cellulose nanocrystalline solution (bath ratio of 1: 50) for 5min, washing, sequentially repeating the soaking process in the chitosan finishing liquid and the cellulose nanocrystalline solution, repeating the self-assembly procedure for 10 times totally, and drying at 100 ℃ for 10 min.
When the concentration of the cellulose nanocrystal solution in the step (2) is 3g/L or 5g/L respectively, finishing the wool fabric according to the same method.
The felting rate and tensile breaking strength of the finished fabric were tested according to the international wool agency TM31 wool textile product washing standard and standard GB/T3923.1-2013, with the test results shown in table 1.
Example 2
A low-strength-loss shrink-proof finishing method for wool fabrics comprises the following steps:
(1) placing the wool fabric in a mixture of 3 wt% of Dichloroisocyanurate (DCCA), 1g/L of penetrant JFC and a bath ratio of 1:25 for 30min at room temperature, and then the fabric was treated with 6 wt% sodium bisulfite (NaHSO)3) In solution (bath ratio 1: 25) dechlorinating for 20min at 40 ℃, and finally placing the wool fabric in NaHCO with pH of 8-93In solution, neutralization was carried out at 40 ℃ for 20 min.
(2) Soaking the wool fabric treated in the step (1) in 5g/L of chitosan finishing liquid (bath ratio of 1: 50) for 5min, washing, soaking in 2g/L of cellulose nanocrystalline solution (bath ratio of 1: 50) for 5min, washing, sequentially repeating the soaking process in the chitosan finishing liquid and the cellulose nanocrystalline solution, repeating the self-assembly process for 1, 5, 10, 15 and 20 times, and drying at 100 ℃ for 10 min.
The felting rate and tensile breaking strength of the finished fabric were tested according to the international wool agency TM31 wool textile product washing standard and standard GB/T3923.1-2013, with the test results shown in table 1.
Example 3
A low-strength-loss shrink-proof finishing method for wool fabrics comprises the following steps:
(1) placing the wool fabric in 3 wt% of dichloroisocyanuric acidSalt (DCCA), 1g/L penetrant JFC, bath ratio 1:25 for 30min at room temperature, and then the fabric was treated with 6 wt% sodium bisulfite (NaHSO)3) In solution (bath ratio 1: 25) dechlorinating for 20min at 40 ℃, and finally placing the wool fabric in NaHCO with pH of 8-93In solution, neutralization was carried out at 40 ℃ for 20 min.
(2) Soaking the wool fabric treated in the step (1) in 10g/L of chitosan finishing liquid (bath ratio of 1: 50) for 5min, washing, soaking in 2g/L of cellulose nanocrystalline solution (bath ratio of 1: 50) for 5min, washing, sequentially repeating the soaking process in the chitosan finishing liquid and the cellulose nanocrystalline solution, repeating the self-assembly procedure for 10 times totally, and drying at 100 ℃ for 10 min.
The felting rate and tensile breaking strength of the finished fabric were tested according to the international wool agency TM31 wool textile product washing standard and standard GB/T3923.1-2013, with the test results shown in table 1.
Example 4
A low-strength-loss shrink-proof finishing method for wool fabrics comprises the following steps:
(1) placing the wool fabric in a mixture of 3 wt% of Dichloroisocyanurate (DCCA), 1g/L of penetrant JFC and a bath ratio of 1:25 for 30min at room temperature, and then the fabric was treated with 6 wt% sodium bisulfite (NaHSO)3) In solution (bath ratio 1: 25) dechlorinating for 20min at 40 ℃, and finally placing the wool fabric in NaHCO with pH of 8-93In solution, neutralization was carried out at 40 ℃ for 20 min.
(2) Soaking the wool fabric treated in the step (1) in 5g/L of chitosan finishing liquid (bath ratio of 1: 50) for 5min, washing, soaking in 3g/L of cellulose nanocrystalline solution (bath ratio of 1: 50) for 5min, washing, sequentially repeating the soaking process in the chitosan finishing liquid and the cellulose nanocrystalline solution, repeating the self-assembly procedure for 15 times, and drying at 100 ℃ for 10 min.
The felting rate and tensile breaking strength of the finished fabric were tested according to the international wool agency TM31 wool textile product washing standard and standard GB/T3923.1-2013, with the test results shown in table 1.
Example 5
A low-strength-loss shrink-proof finishing method for wool fabrics comprises the following steps:
(1) placing the wool fabric in a mixture of 3 wt% of Dichloroisocyanurate (DCCA), 1g/L of penetrant JFC and a bath ratio of 1:25 for 30min at room temperature, and then the fabric was treated with 6 wt% sodium bisulfite (NaHSO)3) In solution (bath ratio 1: 25) dechlorinating for 20min at 40 ℃, and finally placing the wool fabric in NaHCO with pH of 8-93In solution, neutralization was carried out at 40 ℃ for 20 min.
(2) Soaking the wool fabric treated in the step (1) in 5g/L of chitosan finishing liquid (bath ratio is 1: 50) for 5min, washing, soaking in 5g/L of cellulose nanocrystalline solution for 5min, washing, sequentially repeating the soaking process in the chitosan finishing liquid and the cellulose nanocrystalline solution, repeating the self-assembly procedure for 20 times totally, and drying at 100 ℃ for 10 min.
The felting rate and tensile breaking strength of the finished fabric were tested according to the international wool agency TM31 wool textile product washing standard and standard GB/T3923.1-2013, with the test results shown in table 1.
Example 6
A low-strength-loss shrink-proof finishing method for wool fabrics comprises the following steps:
(1) placing the wool fabric in a mixture of 5wt% of Dichloroisocyanurate (DCCA), 3g/L of penetrant JFC and a bath ratio of 1:25 (pH 4) for 20min at room temperature, dechlorinating the fabric in 8 wt% sodium sulfite solution (bath ratio 1: 25) at 40 deg.C for 20min, and placing the wool fabric in NaHCO at pH 8-93In solution, neutralization was carried out at 40 ℃ for 20 min.
(2) Soaking the wool fabric treated in the step (1) in 5g/L of chitosan finishing liquid (bath ratio is 1: 50) for 5min, washing, soaking in 2g/L of cellulose nanocrystalline solution for 5min, washing, sequentially repeating the soaking process in the chitosan finishing liquid and the cellulose nanocrystalline solution, repeating the self-assembly procedure for 10 times totally, and drying at 100 ℃ for 10 min.
The felting rate and tensile breaking strength of the finished fabric were tested according to the international wool agency TM31 wool textile product washing standard and standard GB/T3923.1-2013, with the test results shown in table 1.
Comparative example 1
A low-strength-loss shrink-proof finishing method for wool fabrics comprises the following steps:
placing the wool fabric in a mixture of 3 wt% of Dichloroisocyanurate (DCCA), 1g/L of penetrant JFC and a bath ratio of 1:25 for 30min at room temperature, and then the fabric was treated with 6 wt% sodium bisulfite (NaHSO)3) In solution (bath ratio 1: 25) dechlorinating for 20min at 40 ℃, and finally placing the wool fabric in NaHCO with pH of 8-93In solution, neutralization was carried out at 40 ℃ for 20 min. And the felt shrinkage and tensile breaking strength of the finished fabric are tested according to the washing standard and the standard GB/T3923.1-2013 of the International wool agency TM31 wool textile product, and the test results are shown in Table 1.
Comparative example 2
A low-strength-loss shrink-proof finishing method for wool fabrics comprises the following steps:
(1) placing the wool fabric in a mixture of 3% Dichloroisocyanurate (DCCA), 1g/L penetrant JFC and a bath ratio of 1:25 for 30min at room temperature, and then the fabric was treated with 6% sodium bisulfite (NaHSO)4) In solution (bath ratio 1: 25) dechlorinating for 20min at 40 ℃, and finally placing the wool fabric in NaHCO with pH of 8-93In solution, neutralization was carried out at 40 ℃ for 20 min.
(2) Soaking the wool fabric treated in the step (1) in 5g/L chitosan finishing liquid (bath ratio is 1: 50) for 50min, washing with water, and drying at 100 ℃ for 10 min.
The felting rate and tensile breaking strength of the finished fabric were tested according to the international wool agency TM31 wool textile product washing standard and standard GB/T3923.1-2013, with the test results shown in table 1.
Comparative example 3
A low-strength-loss shrink-proof finishing method for wool fabrics comprises the following steps:
(1) placing the wool fabric in a mixture of 3% Dichloroisocyanurate (DCCA), 1g/L penetrant JFC and a bath ratio of 1:25 for 30min at room temperature, and then the fabric was treated with 6% sodium bisulfite (NaHSO)4) In solution (bath ratio 1: 25) dechlorinating for 20min at 40 ℃, and finally placing the wool fabric in NaHCO with pH of 8-93In solution, neutralization was carried out at 40 ℃ for 20 min.
(2) Treating the wool fabric treated in the step (1) at a bath ratio of 1:50 soaking in 5g/L chitosan and 2g/L modified cellulose nanocrystalline finishing liquid for 50min, washing with water, and drying at 100 ℃ for 10 min.
The modified cellulose nanocrystalline is prepared by modifying the cellulose nanocrystalline by an enzyme method in a laccase/TEMPO system and then reacting the modified cellulose nanocrystalline with a Girard reagent T.
The felting rate and tensile breaking strength of the finished fabric were tested according to the international wool agency TM31 wool textile product washing standard and standard GB/T3923.1-2013, with the test results shown in table 1.
TABLE 1 Properties of wool fabrics after different anti-felting treatments
Although the present invention has been described with reference to the preferred embodiments, it should be understood that various changes and modifications can be made therein by those skilled in the art without departing from the spirit and scope of the invention as defined in the appended claims.
Claims (11)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910196792.7A CN109914106B (en) | 2019-03-15 | 2019-03-15 | Shrink-proof finishing method for low strength loss of wool fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910196792.7A CN109914106B (en) | 2019-03-15 | 2019-03-15 | Shrink-proof finishing method for low strength loss of wool fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN109914106A CN109914106A (en) | 2019-06-21 |
| CN109914106B true CN109914106B (en) | 2020-05-08 |
Family
ID=66965034
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910196792.7A Active CN109914106B (en) | 2019-03-15 | 2019-03-15 | Shrink-proof finishing method for low strength loss of wool fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109914106B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111155222A (en) * | 2019-12-27 | 2020-05-15 | 杭州圣玛特毛绒有限公司 | Production method of pure wool fabric |
| CN111411508A (en) * | 2020-05-21 | 2020-07-14 | 中国农业科学院兰州畜牧与兽药研究所 | A kind of scoured wool with strong anti-felt shrinkage and its manufacturing method |
| CN115679680B (en) * | 2022-11-11 | 2024-08-27 | 江南大学 | Preparation method of high-whiteness shrink-proof wool fabric |
| CN116024760B (en) * | 2023-02-02 | 2025-03-14 | 上海嘉麟杰纺织科技有限公司 | Auxiliary tool for tie-dyeing of bamboo joint patterns of ready-made wool clothing and tie-dyeing method of bamboo joint patterns of ready-made wool clothing |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418515A (en) * | 2008-11-27 | 2009-04-29 | 浙江雀屏纺织化工股份有限公司 | Mercerization and shrinkproof finishing method for woven fabric |
| CN101725045A (en) * | 2009-09-14 | 2010-06-09 | 陕西科技大学 | Ecological anti-felting finishing method for wools |
| CN103981708A (en) * | 2014-04-23 | 2014-08-13 | 桐乡市濮院毛针织技术服务中心 | Shrinkproof finishing method for wool fabric |
| CN103981694A (en) * | 2014-04-23 | 2014-08-13 | 桐乡市濮院毛针织技术服务中心 | Method for finishing wool fabric by compositing chitosan/TiO2 |
| CN107044051A (en) * | 2017-05-11 | 2017-08-15 | 江苏苏沃尚新材料科技有限公司 | A kind of fragrant mothproof finish technique of wool fabric |
| CN109137499A (en) * | 2018-08-21 | 2019-01-04 | 江南大学 | A kind of cotton fabric crease-resistant finishing liquid and application of crease-resistant finishing liquid |
| CN109137513A (en) * | 2018-08-09 | 2019-01-04 | 合肥五凡工程设计有限公司 | A kind of preparation method of modified felt proofing wool fiber |
-
2019
- 2019-03-15 CN CN201910196792.7A patent/CN109914106B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101418515A (en) * | 2008-11-27 | 2009-04-29 | 浙江雀屏纺织化工股份有限公司 | Mercerization and shrinkproof finishing method for woven fabric |
| CN101725045A (en) * | 2009-09-14 | 2010-06-09 | 陕西科技大学 | Ecological anti-felting finishing method for wools |
| CN103981708A (en) * | 2014-04-23 | 2014-08-13 | 桐乡市濮院毛针织技术服务中心 | Shrinkproof finishing method for wool fabric |
| CN103981694A (en) * | 2014-04-23 | 2014-08-13 | 桐乡市濮院毛针织技术服务中心 | Method for finishing wool fabric by compositing chitosan/TiO2 |
| CN107044051A (en) * | 2017-05-11 | 2017-08-15 | 江苏苏沃尚新材料科技有限公司 | A kind of fragrant mothproof finish technique of wool fabric |
| CN109137513A (en) * | 2018-08-09 | 2019-01-04 | 合肥五凡工程设计有限公司 | A kind of preparation method of modified felt proofing wool fiber |
| CN109137499A (en) * | 2018-08-21 | 2019-01-04 | 江南大学 | A kind of cotton fabric crease-resistant finishing liquid and application of crease-resistant finishing liquid |
Also Published As
| Publication number | Publication date |
|---|---|
| CN109914106A (en) | 2019-06-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN109914106B (en) | Shrink-proof finishing method for low strength loss of wool fabric | |
| EP0134267B1 (en) | The process for modifying animal fibers | |
| Ammayappan | Eco-friendly surface modifications of wool fiber for its improved functionality: an overview | |
| CN108729231B (en) | Colored uvioresistant hydrophobic fabric and preparation method thereof | |
| CN105019250A (en) | Low-temperature dyeing and finishing technology for bamboo fiber fabric | |
| CN105063998A (en) | Dyeing and finishing process for linen and cotton blended fiber fabric | |
| CN112647285B (en) | Preparation process of anti-static high-strength polyester fabric | |
| CN105544222A (en) | Chitosan and polyester-polyether copolymer hydrophilic finishing method of dacron fabric | |
| CN104153195B (en) | A kind of method for sorting that makes wool fabric there is felt proofing function | |
| CN105544201A (en) | Production method of mercerized wool air layer fabric | |
| KR100378232B1 (en) | How to modify keratin fiber | |
| Wang et al. | Surface modification of textiles by aqueous solutions | |
| CN114737385A (en) | Preparation method of durable uvioresistant polyester simulated silk fabric | |
| CN112921653B (en) | Crease-resistant finishing method for high-hydrophilicity retention of cellulose fiber fabric | |
| CN109989268B (en) | Slightly soluble felt-proofing finishing method for wool fabric surface | |
| CN105648780A (en) | Preparation method of mercerized wool air-layer composite fabric | |
| JP3683879B2 (en) | Partially oxidized animal hair fibers and fiber products obtained therefrom | |
| CN101238250B (en) | Improvements in and relating to wool treatment | |
| US2923596A (en) | Method of rendering wool unshrinkable and non-felting | |
| CN109097977B (en) | A kind of finishing method of machine-washable wool fabric | |
| JP3627411B2 (en) | Textile structure and manufacturing method thereof | |
| CN115679680B (en) | Preparation method of high-whiteness shrink-proof wool fabric | |
| JPH0578983A (en) | Shrink proofing method of wool | |
| JP3014318B2 (en) | Shrink-proof wool fiber | |
| CN109853248A (en) | A kind of biological enzyme synergistic supersonic wave anti-felting method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |