CN105648780A - Preparation method of mercerized wool air-layer composite fabric - Google Patents

Preparation method of mercerized wool air-layer composite fabric Download PDF

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Publication number
CN105648780A
CN105648780A CN201511008911.XA CN201511008911A CN105648780A CN 105648780 A CN105648780 A CN 105648780A CN 201511008911 A CN201511008911 A CN 201511008911A CN 105648780 A CN105648780 A CN 105648780A
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wool
preparation
air layer
fabric
layer composite
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CN105648780B (en
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赵军伟
林红
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SHANDONG LIANG HUA GARMENT Co.,Ltd.
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Jiangyin Changjing Garden Wool Textile Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00Producing multi-layer textile fabrics
    • D06M17/04Producing multi-layer textile fabrics by applying synthetic resins as adhesives
    • D06M17/10Polyurethanes polyurea
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/54Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur dioxide; with sulfurous acid or its salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325Amines
    • D06M13/342Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/395Isocyanates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46Compounds containing quaternary nitrogen atoms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/647Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00Producing multi-layer textile fabrics
    • D06M17/04Producing multi-layer textile fabrics by applying synthetic resins as adhesives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/10Animal fibres
    • D06M2101/12Keratin fibres or silk
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

Abstract

The invention discloses a preparation method of mercerized wool air-layer composite fabric. The preparation method comprises the following steps: chlorination, enzymatic reduction, enzymatic hydrolysis, softening, bonding compounding, digital-printing and the like. According to the chlorine enzymic mercerization technology, a substrate lysine and a catalyst horseradish peroxidase which can rapidly react with wool color-developing lysine residues are added into a treating fluid during the reduction step. By the characteristic of fast enzymatic reaction rate, residual chlorine obtained after chlorination scale-stripping is prevented from undergoing an oxidation reaction with tyrosine residues on the wool surface. By applying the above mercerized wool in production of air-layer fabric, it is guaranteed that yellowing of the mercerized wool layer is small and the fabric obtained after digital printing has bright color. According to the invention, reaction process is not increased, and yellowing protection and free chlorine reduction are combined. The preparation method has simple steps and is convenient to operate.

Description

A kind of preparation method of mercerized wool air layer composite material
Technical field
The present invention relates to fabric technical field, the preparation method being specifically related to a kind of mercerized wool air layer composite material.
Background technology
Scale layer is the distinctive structure of wool fiber, and it makes Pilus Caprae seu Ovis have special gloss and felting property, also leads to morphological stability difference and prodding and itching feeling when wearing when woolen dyed difficulty, washing simultaneously. Scale layer is to be passed through cell membrane complexes by cornified flat cell. The mercerising principle of Pilus Caprae seu Ovis is exactly adopt suitable physics, chemical method that the scale of Pilus Caprae seu Ovis is carried out softening degraded, the scale making Pilus Caprae seu Ovis sustains damage, partially or completely divest, thus improving the surface configuration of wool fiber so that it is have the feel as cashmere and gloss. In prior art, the method for physics has resin increasing method, chemical method conventional refinement Subtraction method. It is refinement Subtraction method currently for the method that wool fabric is conventional. Subtraction method includes chloridising, oxidizing process and protease Subtraction method. Chloridising needs to produce substantial amounts of water lotion, and the enzymatic activity of protease method needs strict reaction condition, and the technical scheme of improvement adopts the chlorine enzyme process that chloridising and protease method combine, and the method releases chlorine agent makes consumption few, and the water lotion produced is less. In chlorine enzyme process mercerized wool technique, owing to after chloridized, wool fiber still remains a small amount of chlorine, if not being carried out dechlorination, this residual chlorine may proceed to and the tyrosine residue compound generation slow oxidative reaction in Pilus Caprae seu Ovis, cause Pilus Caprae seu Ovis yellowing, the problem such as strength damage. Above-mentioned Yellowing can make mercerized wool fabric yellowing when Pilus Caprae seu Ovis dye light color. Prior art can avoid above-mentioned phenomenon by selection hydrogen peroxide oxidation method, but damage is also inevitably caused in the surface of wool fiber by hydrogen peroxide oxidation method.
Air layer face fabric is generally composited by surface layer fabric and air layer adjuvant, in order to ensure the novel design of air layer face fabric, prior art adopts digit printing more, but the wool fabric xanthochromia after mercerization finish is big, the purpose bright-coloured in order to reach pattern color, need to increase blanching step, production process increases, complex operation, and bleaching also can damage fiber further and cause fabric decrease in strength, accordingly, it would be desirable to the surface layer fabric mercerising process of air layer face fabric is improved.
Summary of the invention
It is an object of the invention to overcome the defect existed in prior art, it is provided that the preparation method of a kind of mercerization finish post yellowing and the less mercerized wool air layer composite material of strength damage.
For realizing above-mentioned technique effect, the preparation method that the technical scheme is that a kind of mercerized wool air layer composite material, it is characterised in that comprise the steps:
S1: be placed in the aqueous solution that pH value is 3.5��4.5 by the wool fabric after fluffy process, adds chloride stripping squama agent in aqueous solution, reacts 30��40min, then taken out by wool fabric under room temperature;
S2: be impregnated in reduction treatment liquid by the wool fabric with liquid, is warming up to 33��38 DEG C, insulation reaction 5��8h, then heats to 80��90 DEG C of insulation 10��20min;
S3: be placed in the hydrolysis process liquid containing protease and peptidase by S2 gained wool fabric, after 42��50 DEG C of immersion 20��30min, with the cleaning mixture washing that pH value is 5��6 dehydration, repeated washing dehydrating operations 2��3 times;
S4: soft, is placed in S3 gained Pilus Caprae seu Ovis in the aqueous solution containing softening agent and cleans, dry, obtains the wool fabric after mercerization finish;
S5: bonding compound, carries out one side cropping process, and by adhesive by the cropping face of wool fabric and air layer face fabric compound, to wool fabric surface digit printing, obtains mercerized wool air layer composite material S4 gained wool fabric;
Wherein, reduction treatment liquid mainly comprise as TYR, horseradish peroxidase, pH value regulator, reducing agent and water; The pH value of reduction treatment liquid is 7.5��9.5; The pH value of hydrolysis process liquid is 6��8.
Chloride dichlorisocyanurate oxydrolysis makes the disulfide bond in wool scale layer and peptide bond fission, unnecessary free chlorine is scattered in treatment fluid, the TYR residue that wool surfaces generates after chloridized, S2 is increased between stripping squama and reduction treatment, TYR under the catalytic action of horseradish peroxidase with the TYR residue cross-linking reaction on wool fabric surface, form two TYR keys or different two TYR keys, TYR residue is formed protective effect, the chlorine remained after stoping chlorination stripping squama and the TYR residue generation oxidation reaction of wool surfaces, simultaneously, reducing agent and free chlorine react and generate stable chloride ion, 3rd step adopt protease to the peptide chain catalyzing hydrolysis after chloridized, two TYR keys or different two TYR key hydrolysis. utilizing TYR to be cross-linked to form dimer protection wool surfaces and affect the tyrosine residual bond of color, compared with the mercerized wool that chlorine enzyme process of the prior art obtains, xanthochromia is little, and the feel of Pilus Caprae seu Ovis and color are good.
PH value in order to ensure enzymatic reaction system is relatively stable, it is preferred that technical scheme is, pH value regulator is right for buffering, described buffering to be selected from boric acid-Borax buffering to, Glycine-NaOH buffering to the one with sodium carbonate-bicarbonate buffering centering. Boric acid and sodium hydroxide all can go deep into inside Pilus Caprae seu Ovis, damage wool intensity, and preferred technical scheme adopts sodium carbonate-bicarbonate buffering right.
Preferred technical scheme is, in reduction treatment liquid, the percentage by weight of TYR is 5��10%. Horseradish peroxidase is not only sufficient to the tyrosine residue of catalysis wool surfaces and free tyrosine generation cross-linking reaction, it is also possible to promoting the tyrosine cross-links dissociated, therefore the tyrosine in reduction treatment liquid need to be excessive.
In order to optimize the catalysis activity of horseradish peroxidase further, accelerate the response speed of tyrosine cross-links, the chlorine in treatment fluid is made to keep free zero-valent state and reducing agent generation redox reaction, preferred technical scheme is, the consumption of horseradish peroxidase and TYR weight ratio are (5��9) �� Kat/1g.
Preferred technical scheme is, stripping squama agent is the dichloroisocyanuric acid sodium that slow release processes. The used in amounts of stripping squama agent to be reacted the hypochlorous amount of generation according to concrete material and water and to be determined. Preferred technical scheme can select the stripping squama agent after slow corrosion treatment.
Preferred technical scheme is, described reducing agent is sodium sulfite or sodium pyrosulfite, and the content of reducing agent is in wool fabric the 5��8% of wool content.
Preferred technical scheme is, softening agent is at least one in block polyether amino-modified silicone oil softening agent and ester based quaternary ammonium salt softening agent. There is strong anion hole in the wool surfaces after chlorine enzyme process mercerization finish, therefore wool surfaces is negative, ester based quaternary ammonium salt softening agent belongs to cationic surfactant, the Pilus Caprae seu Ovis on softening agent cation and negative surface adsorbs, and the carboxyl condensation of the amino of block polyether amino-modified silicone oil softening agent and wool surfaces amino acid residue, two kinds of softening agents all can be firmly attached to wool surfaces, be the wool fabric high resilience after mercerization finish and feel smooth.
Preferred technical scheme is, softening agent is formed by block polyether amino-modified silicone oil softening agent and ester based quaternary ammonium salt formulation of softener, and block polyether amino-modified silicone oil softening agent accounts for the 60��80% of softening agent total amount, and the pH value of water solution containing softening agent is 5��6. Composite softening agent based on amino-modified silicone oil has excellent composite stability and emulsifiability, can form the aqueous solution of high degree of dispersion at low temperatures, can optimize the yellowing-resistant performance being used alone block polyether amino-modified silicone oil softening agent further.
It is preferred that technical scheme be, it is characterised in that the consumption that makes of peptidase is 12��20 �� Kat/1g with the ratio of wool content in wool fabric. Peptidase makes the excessive meeting of consumption promote the acid hydrolysis on the protein peptide chain of wool surfaces, damages wool surface further, is unfavorable for forming the wool fabric surface that feel is smooth.
Preferred technical scheme can also be, described adhesive is PUR PUR.
Advantages of the present invention and having the beneficial effects that:
Chlorine enzyme process mercerization process of the present invention by adding can develop the color group lysine residue rapid-action substrate lysine and catalyst horseradish peroxidase with Pilus Caprae seu Ovis in the treatment fluid of reduction step, utilize the feature that enzyme ' s reaction speeding is fast, the chlorine remained after stoping chlorination stripping squama and the TYR residue generation oxidation reaction of wool surfaces, above-mentioned mercerized wool is used for the production of air layer face fabric, ensureing that the xanthochromia of mercerized wool layer is little, the shade fabric after digit printing is bright-coloured;
The present invention does not increase reaction process, yellow protection is combined with reduction free chlorine, and step is simple, easy to operate.
Detailed description of the invention
Below in conjunction with embodiment, the specific embodiment of the present invention is further described. Following example are only for clearly illustrating technical scheme, and can not limit the scope of the invention with this.
Embodiment 1:
The preparation method of embodiment 1 mercerized wool air layer composite material, comprises the steps:
S1: be placed in the aqueous solution that pH value is 3.5 by the wool fabric after fluffy process, adds chloride stripping squama agent TCCA (Trichloroisocyanuric acid) sodium in aqueous solution, reacts 30min, then taken out by wool fabric under room temperature;
S2: be impregnated in reduction treatment liquid by the wool fabric with liquid, is warming up to 33 DEG C, insulation reaction 5h, then heats to 80 DEG C of insulation 10min;
S3: S2 gained wool fabric is placed in the hydrolysis process liquid containing protease and peptidase, after 42��DEG C immersion 20min, with the cleaning mixture washing that pH value is 5 dehydration, repeated washing dehydrating operations 2 times, pH value acetic acid regulates;
S4: soft, is placed in S3 gained Pilus Caprae seu Ovis in the aqueous solution containing softening agent and cleans, dry, obtains the wool fabric after mercerization finish;
S5: bonding compound, carries out one side cropping process, and by adhesive by the cropping face of wool fabric and air layer face fabric compound, to wool fabric surface digit printing, obtains mercerized wool air layer composite material S4 gained wool fabric;
Wherein, reduction treatment liquid mainly comprise as TYR, horseradish peroxidase, pH value regulator, reducing agent sodium sulfite and water, the consumption of horseradish peroxidase and TYR weight ratio are 10 �� Kat/1g, in reduction treatment liquid, the percentage by weight of TYR is 3%, and the content of reducing agent is in wool fabric the 4% of wool content; The pH value of reduction treatment liquid is 9.5, regulates pH value with boric acid-Borax; The pH value of hydrolysis process liquid is 6.
In hydrolysis process liquid, the consumption that makes of peptidase is 10 �� Kat/1g with the ratio of wool content in wool fabric, and the consumption that makes of protease is 40 �� Kat/1g with the ratio of wool content in wool fabric.
The adhesive of embodiment 1 is acrylate adhesive.
Embodiment 2
The step of the preparation method of embodiment 2 mercerized wool air layer composite material includes:
S1: be placed in the aqueous solution that pH value is 4.5 by the wool fabric after fluffy process, adds chloride stripping squama agent TCCA (Trichloroisocyanuric acid) sodium in aqueous solution, reacts 40min, then taken out by wool fabric under room temperature, and stripping squama agent is the dichloroisocyanuric acid sodium that slow release processes;
S2: be impregnated in reduction treatment liquid by the wool fabric with liquid, is warming up to 38 DEG C, insulation reaction 8h, then heats to 90 DEG C of insulation 20min;
S3: S2 gained wool fabric is placed in the hydrolysis process liquid containing protease and peptidase, after 50 DEG C of immersion 30min, with the cleaning mixture washing that pH value is 6 dehydration, repeated washing dehydrating operations 3 times, pH value acetic acid regulates;
S4: soft, is placed in S3 gained Pilus Caprae seu Ovis in the aqueous solution containing softening agent and cleans, dry, obtains the wool fabric after mercerization finish;
S5: bonding compound, carries out one side cropping process, and by adhesive by the cropping face of wool fabric and air layer face fabric compound, to wool fabric surface digit printing, obtains mercerized wool air layer composite material S4 gained wool fabric;
Wherein, reduction treatment liquid mainly comprise as TYR, horseradish peroxidase, pH value regulator, reducing agent sodium pyrosulfite and water, the consumption of horseradish peroxidase and TYR weight ratio are 5 �� Kat/1g, in reduction treatment liquid, the percentage by weight of TYR is 5%, and the content of reducing agent is in wool fabric the 8% of wool content; The pH value of reduction treatment liquid is 8.5, regulates pH value with Glycine-NaOH; The pH value of hydrolysis process liquid is 8.
The consumption that makes of peptidase is 12 �� Kat/1g with the ratio of wool content in wool fabric, and the consumption that makes of protease is 50 �� Kat/1g with the ratio of wool content in wool fabric.
The adhesive of embodiment 2 is PUR PUR.
Embodiment 3
Embodiment 3 and embodiment 2 are distinctive in that technological parameter:
S1: be placed in the aqueous solution that pH value is 4 by the wool fabric after fluffy process, adds chloride stripping squama agent TCCA (Trichloroisocyanuric acid) sodium in aqueous solution, reacts 35min, then taken out by wool fabric under room temperature, and stripping squama agent is the dichloroisocyanuric acid sodium that slow release processes;
S2: be impregnated in reduction treatment liquid by the wool fabric with liquid, is warming up to 25 DEG C, insulation reaction 6.5h, then heats to 85 DEG C of insulation 15min;
S3: S2 gained wool fabric is placed in the hydrolysis process liquid containing protease and peptidase, after 46 DEG C of immersion 25min, with the cleaning mixture washing that pH value is 5.5 dehydration, repeated washing dehydrating operations 3 times, pH value acetic acid regulates;
S4: soft, is placed in S3 gained Pilus Caprae seu Ovis in the aqueous solution containing softening agent and cleans, dry, obtains the wool fabric after mercerization finish;
S5: bonding compound, carries out one side cropping process, and by adhesive by the cropping face of wool fabric and air layer face fabric compound, to wool fabric surface digit printing, obtains mercerized wool air layer composite material S4 gained wool fabric;
Wherein, reduction treatment liquid mainly comprise as TYR, horseradish peroxidase, pH value regulator, reducing agent sodium pyrosulfite and water, the consumption of horseradish peroxidase and TYR weight ratio are 9 �� Kat/1g, in reduction treatment liquid, the percentage by weight of TYR is 10%, and the content of reducing agent is in wool fabric the 5% of wool content; The pH value of reduction treatment liquid is 9.5, regulates pH value with sodium carbonate-bicarbonate; The pH value of hydrolysis process liquid is 7.
The consumption that makes of peptidase is 20 �� Kat/1g with the ratio of wool content in wool fabric.
Embodiment 4
Embodiment 4 and embodiment 3 are distinctive in that, reduction treatment liquid mainly comprise as TYR, horseradish peroxidase, pH value regulator, reducing agent sodium pyrosulfite and water, the consumption of horseradish peroxidase and TYR weight ratio are 7 �� Kat/1g, in reduction treatment liquid, the percentage by weight of TYR is 7.5%, and the content of reducing agent is in wool fabric the 6.5% of wool content.
The consumption that makes of peptidase is 16 �� Kat/1g with the ratio of wool content in wool fabric.
Embodiment 5
Embodiment 5 is in that from the different of embodiment 4, and softening agent is formed by block polyether amino-modified silicone oil softening agent and ester based quaternary ammonium salt formulation of softener, and block polyether amino-modified silicone oil softening agent accounts for the 60% of softening agent total amount.
Embodiment 6-7
Embodiment 6-7 and embodiment 5 are distinctive in that: block polyether amino-modified silicone oil softening agent accounts for the 80% and 70% of softening agent total amount.
Comparative example: without TYR and horseradish peroxidase in the reduction treatment liquid of comparative example.
With embodiment, comparative example products obtained therefrom, source textile is carried out the digit printing that pattern is identical, printing technology parameter is identical process.
Embodiment and the detection of comparative example sample:
1, adopt Pilus Caprae seu Ovis Baidu tester that the whiteness of wool fabric is detected;
2, adopt wool fabric feel instrument that the feel of wool fabric detects (I��V grade, I grade of pliability optimum);
3, randomly draw the wool fiber in 10 wool fabrics, adopt electronic mono-fiber strength machine that its brute force is detected, average.
Sample detected value is shown in following table:
Reducing agent, chlorinating agent excessive interpolation be all likely to result in wool fabric xanthochromia.
Air layer face fabric after contrast digit printing process, degree bright in colour is corresponding with the wool fabric whiteness in upper table, and whiteness is more high, and digit printing color is more bright-coloured, and source textile is owing to without mercerization finish, dye-uptake is low.
Adhesive in the present invention can be selected for any adhesive that can be used on garment material of the prior art.
The above is only the preferred embodiment of the present invention; it should be pointed out that, for those skilled in the art, under the premise without departing from the technology of the present invention principle; can also making some improvements and modifications, these improvements and modifications also should be regarded as protection scope of the present invention.

Claims (10)

1. the preparation method of a mercerized wool air layer composite material, it is characterised in that comprise the steps:
S1: be placed in the aqueous solution that pH value is 3.5��4.5 by the wool fabric after fluffy process, adds chloride stripping squama agent in aqueous solution, reacts 30��40min, then taken out by wool fabric under room temperature;
S2: be impregnated in reduction treatment liquid by the wool fabric with liquid, is warming up to 33��38 DEG C, insulation reaction 5��8h, then heats to 80��90 DEG C of insulation 10��20min;
S3: be placed in the hydrolysis process liquid containing protease and peptidase by S2 gained wool fabric, after 42��50 DEG C of immersion 20��30min, with the cleaning mixture washing that pH value is 5��6 dehydration, repeated washing dehydrating operations 2��3 times;
S4: soft, is placed in S3 gained Pilus Caprae seu Ovis in the aqueous solution containing softening agent and cleans, dry, obtains the wool fabric after mercerization finish;
S5: bonding compound, carries out one side cropping process, and by adhesive by the cropping face of wool fabric and air layer face fabric compound, to wool fabric surface digit printing, obtains mercerized wool air layer composite material S4 gained wool fabric;
Wherein, reduction treatment liquid mainly comprise as TYR, horseradish peroxidase, pH value regulator, reducing agent and water; The pH value of reduction treatment liquid is 7.5��9.5; The pH value of hydrolysis process liquid is 6��8.
2. the preparation method of mercerized wool air layer composite material according to claim 1, it is characterized in that, pH value regulator is right for buffering, described buffering to be selected from boric acid-Borax buffering to, Glycine-NaOH buffering to the one with sodium carbonate-bicarbonate buffering centering.
3. the preparation method of mercerized wool air layer composite material according to claim 1, it is characterised in that in reduction treatment liquid, the percentage by weight of TYR is 5��10%.
4. the preparation method of mercerized wool air layer composite material according to claim 1, it is characterised in that the consumption of horseradish peroxidase and TYR weight ratio are (5��9) �� Kat/1g.
5. the preparation method of mercerized wool air layer composite material according to claim 1, it is characterised in that stripping squama agent is the dichloroisocyanuric acid sodium that slow release processes.
6. the preparation method of mercerized wool air layer composite material according to claim 1, it is characterised in that described reducing agent is sodium sulfite or sodium pyrosulfite, the content of reducing agent is in wool fabric the 5��8% of wool content.
7. the preparation method of mercerized wool air layer composite material according to claim 1, it is characterised in that softening agent is at least one in block polyether amino-modified silicone oil softening agent and ester based quaternary ammonium salt softening agent.
8. the preparation method of mercerized wool air layer composite material according to claim 7, it is characterized in that, softening agent is formed by block polyether amino-modified silicone oil softening agent and ester based quaternary ammonium salt formulation of softener, block polyether amino-modified silicone oil softening agent accounts for the 60��80% of softening agent total amount, and the pH value of water solution containing softening agent is 5��6.
9. the preparation method of mercerized wool air layer composite material according to claim 1, it is characterised in that the consumption that makes of peptidase is 12��20 �� Kat/1g with the ratio of wool content in wool fabric.
10. the preparation method of mercerized wool air layer composite material according to claim 1, it is characterised in that described adhesive is PUR PUR.
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CN108611864A (en) * 2018-05-24 2018-10-02 江苏阳光股份有限公司 A kind of yellowing-proof finish technique of wool-silk blended yarn weaved fabric
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CN108755194A (en) * 2018-05-23 2018-11-06 江苏阳光股份有限公司 A kind of preparation process imitating old wool fabric
CN108611864A (en) * 2018-05-24 2018-10-02 江苏阳光股份有限公司 A kind of yellowing-proof finish technique of wool-silk blended yarn weaved fabric
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CN110528211A (en) * 2019-09-06 2019-12-03 江苏阳光股份有限公司 A kind of preparation method of cashmere imitating with wool fabric

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