CN106758259A - A kind of wool tops is without chlorine shiinkproof finish technique - Google Patents

A kind of wool tops is without chlorine shiinkproof finish technique Download PDF

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Publication number
CN106758259A
CN106758259A CN201710031141.3A CN201710031141A CN106758259A CN 106758259 A CN106758259 A CN 106758259A CN 201710031141 A CN201710031141 A CN 201710031141A CN 106758259 A CN106758259 A CN 106758259A
Authority
CN
China
Prior art keywords
wool tops
shrinking
biology enzyme
wool
chlorine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710031141.3A
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Chinese (zh)
Inventor
瞿建德
瞿韬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGSHU XINGUANG WOOL TOP SPECIALIST PROCESSOR Co Ltd
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CHANGSHU XINGUANG WOOL TOP SPECIALIST PROCESSOR Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHANGSHU XINGUANG WOOL TOP SPECIALIST PROCESSOR Co Ltd filed Critical CHANGSHU XINGUANG WOOL TOP SPECIALIST PROCESSOR Co Ltd
Priority to CN201710031141.3A priority Critical patent/CN106758259A/en
Publication of CN106758259A publication Critical patent/CN106758259A/en
Pending legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/54—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur dioxide; with sulfurous acid or its salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/45—Shrinking resistance, anti-felting properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses a kind of wool tops without chlorine shiinkproof finish technique, comprise the following steps：1）Washing：Wool tops is carried out into water-washing pre-treatment, the impurity in removal wool tops；2）Biology enzyme anti-shrinking：Wool tops after washing process is impregnated into biology enzyme anti-shrinking liquid, carries out padding treatment, wherein, the biology enzyme anti-shrinking liquid includes the following ingredients for constituting by mass percentage：Hydrogen peroxide 1% 3%, sodium hydrogensulfite 2% 5%, compound protease B 15% 20%, organic siliconresin 35% 40%, bleeding agent 7% 10%, acrylic resin 29% 33%；3）Drying：To be dried by the wool tops of biology enzyme anti-shrinking, obtained with shrinkproof, anti-pilling property wool tops finished product.Through the above way, present invention reduces technological process, the wool tops after treatment is made to reach traditional chlorinated machine washable shrinkproof result, and anti-pilling is also improved, and do not produce AOX to pollute during arrangement, energy-conserving and environment-protective.

Description

A kind of wool tops is without chlorine shiinkproof finish technique
Technical field
The present invention relates to wool tops processing technology field, more particularly to a kind of wool tops is without chlorine shiinkproof finish technique.
Background technology
Wool surface has the scale layer of special construction, and under the rubbing action of external force, scale layer produces orientation to move It is dynamic, there is felting phenomenon, therefore, it is necessary to carry out arrangement processing to wool fiber bar, the machine specified with reaching International Wool Secretariat can Standard is washed, while Final finishing processing can improve the comfortable feel of wool fiber bar.
For a long time, enterprise mostly carries out Final finishing processing using oxidizer containing chlorine to wool fiber bar, to reach Good anti-felting effect, but, oxidizer containing chlorine can produce substantial amounts of AOX in process is arranged（Adsorbable is organic Halide）, severe contamination environment is damaged to human body, while complex process, operating process is long, and energy resource consumption is big, Er Qiehui Wool fiber bar is set to produce yellowing phenomenon.
The content of the invention
The present invention solves the technical problem of a kind of wool tops is provided without chlorine shiinkproof finish technique, can solve the problem that existing The defect that wool tops handling process is present.
In order to solve the above technical problems, one aspect of the present invention is：There is provided a kind of wool tops shrinkproof without chlorine Finishing technique, comprises the following steps：
1）Washing：Wool tops is carried out into water-washing pre-treatment, the impurity in removal wool tops；
2）Biology enzyme anti-shrinking：Wool tops after washing process is impregnated into biology enzyme anti-shrinking liquid, carries out padding place Reason, wherein, the biology enzyme anti-shrinking liquid includes the following ingredients for constituting by mass percentage：Hydrogen peroxide 1%-3%, sulfurous acid Hydrogen sodium 2%-5%, compound protease B 15%-20%, organic siliconresin 35%-40%, bleeding agent 7%-10%, acrylic resin 29%- 33%；
3）Drying：To be dried by the wool tops of biology enzyme anti-shrinking, obtained with shrinkproof, anti-pilling property wool Bar finished product.
In a preferred embodiment of the present invention, the step 2）In, the condition of padding is：Bath raio：1:10-12, pressure Liquid rate 95-120%.
In a preferred embodiment of the present invention, the step 2）In, the temperature of biology enzyme anti-shrinking liquid is 60-80 ℃。
The beneficial effects of the invention are as follows：The present invention by optimizing the composition and proportioning of biology enzyme anti-shrinking liquid, make it is shrinkproof, The bath of anti pilling treatment one is completed, and shortens technological process, the wool tops after treatment is reached the shrinkproof effect of traditional chlorinated machine washable Really, and anti-pilling is also improved, and during arranging AOX is not produced to pollute, energy-conserving and environment-protective.
Specific embodiment
Presently preferred embodiments of the present invention is described in detail below so that advantages and features of the invention can be easier to by It will be appreciated by those skilled in the art that apparent clearly being defined so as to be made to protection scope of the present invention.
The embodiment of the present invention includes：
Embodiment one：
A kind of wool tops comprises the following steps without chlorine shiinkproof finish technique：
1）Washing：Wool tops is carried out into water-washing pre-treatment, the impurity in removal wool tops；
2）Biology enzyme anti-shrinking：Wool tops after washing process is impregnated into the biology enzyme anti-shrinking liquid that temperature is 60 DEG C In, carrying out padding treatment, wherein dipping bath ratio is 1:10, hydraulic fluid rate is 95%,
The biology enzyme anti-shrinking liquid includes the following ingredients for constituting by mass percentage：Hydrogen peroxide 1%, sodium hydrogensulfite 5%, Compound protease B 18%, organic siliconresin 38%, bleeding agent 9%, acrylic resin 29%；
3）Drying：To be dried by the wool tops of biology enzyme anti-shrinking, obtained with shrinkproof, anti-pilling property wool Bar finished product.
Embodiment two：
A kind of wool tops comprises the following steps without chlorine shiinkproof finish technique：
1）Washing：Wool tops is carried out into water-washing pre-treatment, the impurity in removal wool tops；
2）Biology enzyme anti-shrinking：Wool tops after washing process is impregnated into the biology enzyme anti-shrinking liquid that temperature is 70 DEG C In, carrying out padding treatment, wherein dipping bath ratio is 1:12, hydraulic fluid rate is 100%,
The biology enzyme anti-shrinking liquid includes the following ingredients for constituting by mass percentage：Hydrogen peroxide 2%, sodium hydrogensulfite 4%, Compound protease B 20%, organic siliconresin 35%, bleeding agent 10%, acrylic resin 29%；
3）Drying：To be dried by the wool tops of biology enzyme anti-shrinking, obtained with shrinkproof, anti-pilling property wool Bar finished product.
Embodiment three：
A kind of wool tops comprises the following steps without chlorine shiinkproof finish technique：
1）Washing：Wool tops is carried out into water-washing pre-treatment, the impurity in removal wool tops；
2）Biology enzyme anti-shrinking：Wool tops after washing process is impregnated into the biology enzyme anti-shrinking liquid that temperature is 80 DEG C In, carrying out padding treatment, wherein dipping bath ratio is 1:12, hydraulic fluid rate is 120%,
The biology enzyme anti-shrinking liquid includes the following ingredients for constituting by mass percentage：Hydrogen peroxide 3%, sodium hydrogensulfite 2%, Compound protease B 15%, organic siliconresin 40%, bleeding agent 7%, acrylic resin 33%；
3）Drying：To be dried by the wool tops of biology enzyme anti-shrinking, obtained with shrinkproof, anti-pilling property wool Bar finished product.
Present invention is disclosed a kind of wool tops without chlorine shiinkproof finish technique, by the composition for optimizing biology enzyme anti-shrinking liquid And proportioning, the shrinkproof, bath of anti pilling treatment one is completed, technological process is shortened, reach the wool tops after treatment traditional chlorinated Machine washable shrinkproof result, and anti-pilling is also improved, and do not produce AOX to pollute during arranging, energy-conserving and environment-protective.
Embodiments of the invention are the foregoing is only, the scope of the claims of the invention is not thereby limited, it is every to utilize this hair Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks Domain, is included within the scope of the present invention.

Claims (3)

1. a kind of wool tops is without chlorine shiinkproof finish technique, it is characterised in that comprise the following steps：
1）Washing：Wool tops is carried out into water-washing pre-treatment, the impurity in removal wool tops；
2）Biology enzyme anti-shrinking：Wool tops after washing process is impregnated into biology enzyme anti-shrinking liquid, carries out padding place Reason, wherein, the biology enzyme anti-shrinking liquid includes the following ingredients for constituting by mass percentage：Hydrogen peroxide 1%-3%, sulfurous acid Hydrogen sodium 2%-5%, compound protease B 15%-20%, organic siliconresin 35%-40%, bleeding agent 7%-10%, acrylic resin 29%- 33%；
3）Drying：To be dried by the wool tops of biology enzyme anti-shrinking, obtained with shrinkproof, anti-pilling property wool Bar finished product.
2. wool tops according to claim 1 is without chlorine shiinkproof finish technique, it is characterised in that the step 2）In, it is described The condition of padding is：Bath raio：1:10-12, hydraulic fluid rate 95-120%.
3. wool tops according to claim 1 is without chlorine shiinkproof finish technique, it is characterised in that the step 2）In, it is biological The temperature of enzyme anti-shrinking liquid is 60-80 DEG C.
CN201710031141.3A 2017-01-17 2017-01-17 A kind of wool tops is without chlorine shiinkproof finish technique Pending CN106758259A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107858835A (en) * 2017-12-08 2018-03-30 常熟市沪联印染有限公司 A kind of wool fabric dyeing pre-treating technology
CN107956106A (en) * 2017-11-30 2018-04-24 安徽中福毛纺制帽有限公司 A kind of antibacterial felt-proofing finishing method of wool cap
CN109023620A (en) * 2018-08-09 2018-12-18 合肥五凡工程设计有限公司 A kind of flexible cored cashmere yarn of antistatic
CN110306348A (en) * 2019-07-12 2019-10-08 常熟市新光毛条处理有限公司 A kind of shrinkproof anti-sticking mixed processing method of wool top
CN110468594A (en) * 2019-08-29 2019-11-19 江苏阳光股份有限公司 A kind of feld proofing technique of woolen fabric
CN111395005A (en) * 2020-05-15 2020-07-10 嘉兴市菲尔欣制衣股份有限公司 Production process of mothproof and bacteriostatic woolen sweater

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Publication number Priority date Publication date Assignee Title
CN1693575A (en) * 2005-05-18 2005-11-09 陕西省科学院酶工程研究所 Finishing method for preventing felting and shrinking of wood fabric
CN103924439A (en) * 2014-04-25 2014-07-16 江南大学 Method for protease-method wool felt-proofing treatment by using ultrasonic technology
CN104611935A (en) * 2015-02-03 2015-05-13 湖州市菱湖重兆金辉丝织厂 Felt proofing method for wool fabrics
CN104631127A (en) * 2013-11-11 2015-05-20 青岛鑫益发工贸有限公司 Textile anti-pilling finishing method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1693575A (en) * 2005-05-18 2005-11-09 陕西省科学院酶工程研究所 Finishing method for preventing felting and shrinking of wood fabric
CN104631127A (en) * 2013-11-11 2015-05-20 青岛鑫益发工贸有限公司 Textile anti-pilling finishing method
CN103924439A (en) * 2014-04-25 2014-07-16 江南大学 Method for protease-method wool felt-proofing treatment by using ultrasonic technology
CN104611935A (en) * 2015-02-03 2015-05-13 湖州市菱湖重兆金辉丝织厂 Felt proofing method for wool fabrics

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王杰等: ""羊毛生物酶防毡缩整理"", 《印染》 *
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107956106A (en) * 2017-11-30 2018-04-24 安徽中福毛纺制帽有限公司 A kind of antibacterial felt-proofing finishing method of wool cap
CN107858835A (en) * 2017-12-08 2018-03-30 常熟市沪联印染有限公司 A kind of wool fabric dyeing pre-treating technology
CN109023620A (en) * 2018-08-09 2018-12-18 合肥五凡工程设计有限公司 A kind of flexible cored cashmere yarn of antistatic
CN110306348A (en) * 2019-07-12 2019-10-08 常熟市新光毛条处理有限公司 A kind of shrinkproof anti-sticking mixed processing method of wool top
CN110468594A (en) * 2019-08-29 2019-11-19 江苏阳光股份有限公司 A kind of feld proofing technique of woolen fabric
CN111395005A (en) * 2020-05-15 2020-07-10 嘉兴市菲尔欣制衣股份有限公司 Production process of mothproof and bacteriostatic woolen sweater

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Application publication date: 20170531