CN107954637A - A kind of ceramic tile marble binding agent of superpower water resistance - Google Patents
A kind of ceramic tile marble binding agent of superpower water resistance Download PDFInfo
- Publication number
- CN107954637A CN107954637A CN201711386971.4A CN201711386971A CN107954637A CN 107954637 A CN107954637 A CN 107954637A CN 201711386971 A CN201711386971 A CN 201711386971A CN 107954637 A CN107954637 A CN 107954637A
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- China
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- binding agent
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- ceramic tile
- marble
- water resistance
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention relates to ceramic tile marble binding agent research and development technology field,Disclose a kind of ceramic tile marble binding agent of superpower water resistance,Ensure the enough densifications of total to keep out the infiltration of hydrone,With absorption and reduce by ceramic tile,The ability of the difference and the issuable stress of basic unit's displacement of marble and basic unit's thermal expansion,The polymer of addition will greatly change the flexibility of binding agent,Moisture between polymer beads agglomerated together is gradually all absorbed in the chemical bonding water of hydration process,Final polymer beads are merged completely with basal plane,Form continuous polymeric web structure,Suppress the cracking of binding agent,It can adapt to various environmental tests,With superpower waterproof and adhesive property,Dosage is few,It is easy to use,Anti-high and low-temp performance is strong,Tack coat has toughness,And long lifespan,Safety and environmental protection,It can be used after the outdoor alternating temperature temperature difference as excellent as before for number decades.
Description
Technical field
The invention belongs to ceramic tile marble binding agent research and development technology field, and in particular to a kind of porcelain of superpower water resistance
Brick marble binding agent.
Background technology
World's development of real estate is rapid in recent years so that the production and consumption of world's ceramic tile all obtains larger hair
Exhibition, since Chinese tile product designs and varieties are more, quantity is big, quality is good, low- medium- high level product is complete, choice is big and price
Suitably, Chinese tile product is favored in world many countries and area very much, and proportion of the Chinese ceramic tile in international market increasingly expands
Greatly.The general physical property of marble is relatively soft, this is for granite.In fitting up indoors, television set table top, window
Platform, flooring etc. are suitable to use marble.Marble is trade name, not petrology definition.Marble is naturally to build
The one of decorative stone is main kind of, refers generally to decoration functions, can be processed into going bad or not for building stone or craftwork
Rotten carbonate rock.It is obtained by the produced stone material with gorgeous color and luster and decorative pattern of Chinese yunnan Dali Dian Cang Mountain
Name.Marble refers to the skarns and griotte that griotte, limestone, dolomite and carbonate rock are formed through different alterations
Deng.It is very beautiful after marble polishing, be mainly used for being processed into various shape materials, plate, make the metope of building, ground, platform,
Column, is also commonly used for the material of monumental building such as upright stone tablet, tower, statue etc..Marble can also be engraved as workmanship, text
The practical artworks such as tool, lamps and lanterns, vessel.
Ceramic tile and marble are quite varied in the application of building field, and it is in use, can be corroded be subject to environment,
There is hollowing to come off and the problems such as wall leakage, existing binding agent also influenced for water resistance be subject to environmental change and
It is very unstable.
The content of the invention
The purpose of the present invention is for it is existing the problem of, there is provided the ceramic tile marble of superpower water resistance a kind of bonds
Agent, has superpower waterproof and adhesive property, and dosage is few, easy to use, and anti-high and low-temp performance is strong, and tack coat has toughness, and
Long lifespan, safety and environmental protection.
The present invention is achieved by the following technical solutions：
A kind of ceramic tile marble binding agent of superpower water resistance, it is made according to parts by weight of following component：Organosilicon changes
35-45 parts of styrene-acrylic emulsion of property, 10-12 parts of polyvinyl alcohol, 8-10 parts of polypropylene phthalein amine, 2.5-3.0 parts of anhydrous calcium chloride, sodium sulphate
1.2-1.4 parts, 0.5-0.8 parts of filler, 0.30-0.35 parts of methyl cellulose ether, 0.25-0.35 parts of starch ether, polypropylene monofilament
0.15-0.18 parts of fiber, 0.10-0.12 parts of triethanolamine；The binding agent is used cooperatively with modified kraft cement, according to modification
The 1.0-1.2% of sulfate cement quality carries out dispensing, and the viscosity for adjusting mortar is 7-9 centimetres.
As further improvement of these options, the methyl cellulose ether viscosity is 40000-43000mpas, carefully
Spend for 150-180 mesh.
As further improvement of these options, the polypropylene monofilament fibre length is between 8-10 millimeters.
As further improvement of these options, the filler is consisted of the following compositions according to mass percent meter：Sulphur
Sour magnesium accounts for 10-12%, manganese dioxide accounts for 13-15%, titanium dioxide accounts for 15-18%, montmorillonite powder accounts for 20-30%, remaining as calcium carbonate.
As further improvement of these options, the preparation method of the modified kraft cement is：By sulfuric acid brine
Mud is added in mortar agitated kettle, adds granule size in the fine sand of 0.2-0.6 millimeters of scopes, additive amount is cement quality fraction
20-25%, stirring at low speed is uniformly mixed raw material in 30-40 seconds, adds quick stirring 90-100 seconds after water, adds mass fraction
The land plaster of 4-6% is accounted for, lasting stirring.
As further improvement of these options, the binding agent is with modified kraft cement mixing mode：On one side
Stirring slowly adds binding agent on one side, and control machinery mixer mixing speed is 400-500 revs/min, uniform stirring, directly
To uniform rubber cement of the generation without caking.
The present invention has the following advantages compared with prior art：In order to solve existing ceramic tile, marble binding agent water proofing property
Can be unstable, durability is poor the problem of, the present invention provides a kind of ceramic tile marble binding agent of superpower water resistance, ensures
The enough densifications of total have to keep out the infiltration of hydrone and absorb and reduce by ceramic tile, marble and basic unit's thermal expansion
Different and the issuable stress of basic unit's displacement ability, the polymer of addition will greatly change the flexibility of binding agent,
Moisture between polymer beads agglomerated together is gradually all absorbed in the chemical bonding water of hydration process, most
Final polymerization composition granule is merged completely with basal plane, is formed continuous polymeric web structure, is suppressed the cracking of binding agent, can
Various environmental tests are adapted to, there is superpower waterproof and adhesive property, dosage is few, easy to use, and anti-high and low-temp performance is strong, bonds
Layer has toughness, and long lifespan, and safety and environmental protection, can use as excellent as before for number decades after the outdoor alternating temperature temperature difference.
Embodiment
With reference to specific embodiment, the invention will be further described.
Embodiment 1
A kind of ceramic tile marble binding agent of superpower water resistance, it is made according to parts by weight of following component：Organosilicon changes
35 parts of styrene-acrylic emulsion of property, 10 parts of polyvinyl alcohol, 8 parts of polypropylene phthalein amine, 2.5 parts of anhydrous calcium chloride, 1.2 parts of sodium sulphate, filler 0.5
Part, 0.30 part of methyl cellulose ether, 0.25 part of starch ether, 0.15 part of polypropylene monofilament fiber, 0.10 part of triethanolamine；The bonding
Agent is used cooperatively with modified kraft cement, is carried out dispensing according to the 1.0% of modified kraft cement quality, is adjusted the viscous of mortar
Spend for 7 centimetres.
As further improvement of these options, the methyl cellulose ether viscosity is 40000-mpas, and fineness is
150 mesh.
As further improvement of these options, the polypropylene monofilament fibre length is between 8-10 millimeters.
As further improvement of these options, the filler is consisted of the following compositions according to mass percent meter：Sulphur
Sour magnesium, which accounts for 10%, manganese dioxide and accounts for 13%, titanium dioxide and account for 15%, montmorillonite powder, accounts for 20%, remaining as calcium carbonate.
As further improvement of these options, the preparation method of the modified kraft cement is：By sulfuric acid brine
Mud is added in mortar agitated kettle, adds granule size in the fine sand of 0.2-0.6 millimeters of scopes, additive amount is cement quality fraction
20%, stirring at low speed is uniformly mixed raw material in 30 seconds, adds quick stirring 90 seconds after water, adds the gypsum that mass fraction accounts for 4%
Powder, lasting stirring.
As further improvement of these options, the binding agent is with modified kraft cement mixing mode：On one side
Stirring slowly adds binding agent on one side, and control machinery mixer mixing speed is 400 revs/min, uniform stirring, Zhi Daosheng
Into the uniform rubber cement of no caking.
Embodiment 2
A kind of ceramic tile marble binding agent of superpower water resistance, it is made according to parts by weight of following component：Organosilicon changes
40 parts of styrene-acrylic emulsion of property, 11 parts of polyvinyl alcohol, 9 parts of polypropylene phthalein amine, 2.8 parts of anhydrous calcium chloride, 1.3 parts of sodium sulphate, filler 0.6
Part, 0.33 part of methyl cellulose ether, 0.30 part of starch ether, 0.16 part of polypropylene monofilament fiber, 0.11 part of triethanolamine；The bonding
Agent is used cooperatively with modified kraft cement, is carried out dispensing according to the 1.1% of modified kraft cement quality, is adjusted the viscous of mortar
Spend for 8 centimetres.
As further improvement of these options, the methyl cellulose ether viscosity is 42000mpas, and fineness is
160 mesh.
As further improvement of these options, the polypropylene monofilament fibre length is between 8-10 millimeters.
As further improvement of these options, the filler is consisted of the following compositions according to mass percent meter：Sulphur
Sour magnesium, which accounts for 11%, manganese dioxide and accounts for 14%, titanium dioxide and account for 16%, montmorillonite powder, accounts for 25%, remaining as calcium carbonate.
As further improvement of these options, the preparation method of the modified kraft cement is：By sulfuric acid brine
Mud is added in mortar agitated kettle, adds granule size in the fine sand of 0.2-0.6 millimeters of scopes, additive amount is cement quality fraction
22%, stirring at low speed is uniformly mixed raw material in 35 seconds, adds quick stirring 95 seconds after water, adds the gypsum that mass fraction accounts for 5%
Powder, lasting stirring.
As further improvement of these options, the binding agent is with modified kraft cement mixing mode：On one side
Stirring slowly adds binding agent on one side, and control machinery mixer mixing speed is 450 revs/min, uniform stirring, Zhi Daosheng
Into the uniform rubber cement of no caking.
Embodiment 3
A kind of ceramic tile marble binding agent of superpower water resistance, it is made according to parts by weight of following component：Organosilicon changes
45 parts of styrene-acrylic emulsion of property, 12 parts of polyvinyl alcohol, 10 parts of polypropylene phthalein amine, 3.0 parts of anhydrous calcium chloride, 1.4 parts of sodium sulphate, filler
0.8 part, 0.35 part of methyl cellulose ether, 0.35 part of starch ether, 0.18 part of polypropylene monofilament fiber, 0.12 part of triethanolamine；Should
Binding agent is used cooperatively with modified kraft cement, is carried out dispensing according to the 1.2% of modified kraft cement quality, is adjusted mortar
Viscosity be 9 centimetres.
As further improvement of these options, the methyl cellulose ether viscosity is 43000mpas, and fineness is
180 mesh.
As further improvement of these options, the polypropylene monofilament fibre length is between 8-10 millimeters.
As further improvement of these options, the filler is consisted of the following compositions according to mass percent meter：Sulphur
Sour magnesium, which accounts for 12%, manganese dioxide and accounts for 15%, titanium dioxide and account for 18%, montmorillonite powder, accounts for 30%, remaining as calcium carbonate.
As further improvement of these options, the preparation method of the modified kraft cement is：By sulfuric acid brine
Mud is added in mortar agitated kettle, adds granule size in the fine sand of 0.2-0.6 millimeters of scopes, additive amount is cement quality fraction
25%, stirring at low speed is uniformly mixed raw material in 40 seconds, adds quick stirring 100 seconds after water, adds the gypsum that mass fraction accounts for 6%
Powder, lasting stirring.
As further improvement of these options, the binding agent is with modified kraft cement mixing mode：On one side
Stirring slowly adds binding agent on one side, and control machinery mixer mixing speed is 500 revs/min, uniform stirring, Zhi Daosheng
Into the uniform rubber cement of no caking.
Contrast experiment
Method processing and fabricating ceramic tile, the marble binding agent of embodiment 1-3 is used respectively, while with existing poly vinyl acetate emulsion
Liquid type binding agent carries out adhesion test, keeps each group irrelevant variable consistent, be tested for the property after bonding 28 days as control
As a result it is as shown in the table：
As can be seen here：Binding agent prepared by the present invention has superpower waterproof and adhesive property, and dosage is few, easy to use, anti-height
Cryogenic property is strong, and tack coat has toughness, and long lifespan, safety and environmental protection.
Claims (6)
1. the ceramic tile marble binding agent of a kind of superpower water resistance, it is characterised in that according to parts by weight by following component system
Into：35-45 parts of silicone modified styrene-acrylate emulsion, 10-12 parts of polyvinyl alcohol, 8-10 parts of polypropylene phthalein amine, anhydrous calcium chloride 2.5-
3.0 parts, 1.2-1.4 parts of sodium sulphate, 0.5-0.8 parts of filler, 0.30-0.35 parts of methyl cellulose ether, starch ether 0.25-0.35
Part, 0.15-0.18 parts of polypropylene monofilament fiber, 0.10-0.12 parts of triethanolamine；The binding agent coordinates with modified kraft cement
Use, carry out dispensing according to the 1.0-1.2% of modified kraft cement quality, the viscosity for adjusting mortar is 7-9 centimetres.
A kind of 2. ceramic tile marble binding agent of superpower water resistance as claimed in claim 1, it is characterised in that
The methyl cellulose ether viscosity is 40000-43000mpas, and fineness is 150-180 mesh.
A kind of 3. ceramic tile marble binding agent of superpower water resistance as claimed in claim 1, it is characterised in that
The polypropylene monofilament fibre length is between 8-10 millimeters.
A kind of 4. ceramic tile marble binding agent of superpower water resistance as claimed in claim 1, it is characterised in that
The filler is consisted of the following compositions according to mass percent meter：Magnesium sulfate accounts for 10-12%, manganese dioxide accounts for 13-15%, titanium
White powder accounts for 15-18%, montmorillonite powder accounts for 20-30%, remaining as calcium carbonate.
A kind of 5. ceramic tile marble binding agent of superpower water resistance as claimed in claim 1, it is characterised in that
The preparation method of the modified kraft cement is：Sulfate cement is added in mortar agitated kettle, it is big to add granularity
The small fine sand in 0.2-0.6 millimeters of scopes, additive amount are the 20-25% of cement quality fraction, and stirring at low speed makes raw material in 30-40 seconds
It is uniformly mixed, is quickly stirred 90-100 seconds after adding water, add the land plaster that mass fraction accounts for 4-6%, lasting stirring.
6. the ceramic tile marble binding agent of a kind of superpower water resistance as claimed in claim 1, it is characterised in that described viscous
Tie agent is with modified kraft cement mixing mode：Stir while slowly adding binding agent, control machinery mixer stirs
It is 400-500 revs/min to mix speed, uniform stirring, until generating the uniform rubber cement without caking.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711386971.4A CN107954637A (en) | 2017-12-20 | 2017-12-20 | A kind of ceramic tile marble binding agent of superpower water resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711386971.4A CN107954637A (en) | 2017-12-20 | 2017-12-20 | A kind of ceramic tile marble binding agent of superpower water resistance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107954637A true CN107954637A (en) | 2018-04-24 |
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ID=61956355
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711386971.4A Pending CN107954637A (en) | 2017-12-20 | 2017-12-20 | A kind of ceramic tile marble binding agent of superpower water resistance |
Country Status (1)
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108658551A (en) * | 2018-06-05 | 2018-10-16 | 唐林元 | A kind of marble special-purpose water-proof adhesive |
| CN110723943A (en) * | 2019-10-24 | 2020-01-24 | 常树高 | Adhesive formula for ceramic tiles and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1132770A (en) * | 1995-04-04 | 1996-10-09 | 楼文星 | Powdered adhesive for building |
| CN1260369A (en) * | 1999-01-12 | 2000-07-19 | 常大勇 | Putty for plastering |
| CN104446251A (en) * | 2014-11-27 | 2015-03-25 | 久筑节能科技（天津）有限公司 | Adhesion agent as well as preparation method and application thereof |
| CN104804674A (en) * | 2015-04-10 | 2015-07-29 | 无锡市全发化工有限公司 | Environment-friendly building adhesive and preparation method thereof |
| CN105777027A (en) * | 2016-03-31 | 2016-07-20 | 济南维高建材技术有限公司 | Early strength two-component polymer emulsion modified cement tile binder and using method thereof |
-
2017
- 2017-12-20 CN CN201711386971.4A patent/CN107954637A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1132770A (en) * | 1995-04-04 | 1996-10-09 | 楼文星 | Powdered adhesive for building |
| CN1260369A (en) * | 1999-01-12 | 2000-07-19 | 常大勇 | Putty for plastering |
| CN104446251A (en) * | 2014-11-27 | 2015-03-25 | 久筑节能科技（天津）有限公司 | Adhesion agent as well as preparation method and application thereof |
| CN104804674A (en) * | 2015-04-10 | 2015-07-29 | 无锡市全发化工有限公司 | Environment-friendly building adhesive and preparation method thereof |
| CN105777027A (en) * | 2016-03-31 | 2016-07-20 | 济南维高建材技术有限公司 | Early strength two-component polymer emulsion modified cement tile binder and using method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108658551A (en) * | 2018-06-05 | 2018-10-16 | 唐林元 | A kind of marble special-purpose water-proof adhesive |
| CN110723943A (en) * | 2019-10-24 | 2020-01-24 | 常树高 | Adhesive formula for ceramic tiles and preparation method thereof |
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Application publication date: 20180424 |
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