CN107927901A - It is a kind of that the method for tobacco aromaticss and its application in the quick-fried pearl of cigarette are prepared using Glycerin, mixed triester with caprylic acid capric acid - Google Patents
It is a kind of that the method for tobacco aromaticss and its application in the quick-fried pearl of cigarette are prepared using Glycerin, mixed triester with caprylic acid capric acid Download PDFInfo
- Publication number
- CN107927901A CN107927901A CN201711173594.6A CN201711173594A CN107927901A CN 107927901 A CN107927901 A CN 107927901A CN 201711173594 A CN201711173594 A CN 201711173594A CN 107927901 A CN107927901 A CN 107927901A
- Authority
- CN
- China
- Prior art keywords
- quick
- cigarette
- glycerin
- tobacco aromaticss
- capric acid
- Prior art date
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Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 title claims abstract description 58
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 41
- 235000002637 Nicotiana tabacum Nutrition 0.000 title claims abstract description 30
- 235000011187 glycerol Nutrition 0.000 title claims abstract description 29
- 241000208125 Nicotiana Species 0.000 title claims abstract description 26
- NXMUXTAGFPJGTQ-UHFFFAOYSA-N decanoic acid;octanoic acid Chemical compound CCCCCCCC(O)=O.CCCCCCCCCC(O)=O NXMUXTAGFPJGTQ-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 150000005691 triesters Chemical class 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 20
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000001914 filtration Methods 0.000 claims abstract description 17
- 241000196324 Embryophyta Species 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 15
- 239000000843 powder Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 229930003427 Vitamin E Natural products 0.000 claims abstract description 10
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229940046009 vitamin E Drugs 0.000 claims abstract description 10
- 235000019165 vitamin E Nutrition 0.000 claims abstract description 10
- 239000011709 vitamin E Substances 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 8
- 239000012535 impurity Substances 0.000 claims abstract description 8
- 239000012982 microporous membrane Substances 0.000 claims abstract description 8
- 238000010992 reflux Methods 0.000 claims abstract description 8
- 239000007787 solid Substances 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 6
- 238000007873 sieving Methods 0.000 claims abstract description 5
- 239000000341 volatile oil Substances 0.000 claims description 15
- 239000003921 oil Substances 0.000 claims description 13
- 239000000796 flavoring agent Substances 0.000 claims description 10
- 235000019634 flavors Nutrition 0.000 claims description 10
- 238000013019 agitation Methods 0.000 claims description 7
- 241001165494 Rhodiola Species 0.000 claims description 6
- 241000533293 Sesbania emerus Species 0.000 claims description 6
- 239000001359 coriandrum sativum l. oleoresin Substances 0.000 claims description 6
- 235000005881 Calendula officinalis Nutrition 0.000 claims description 5
- 240000000785 Tagetes erecta Species 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- 244000178870 Lavandula angustifolia Species 0.000 claims description 4
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 4
- 244000061176 Nicotiana tabacum Species 0.000 claims description 4
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 4
- 239000001102 lavandula vera Substances 0.000 claims description 4
- 235000018219 lavender Nutrition 0.000 claims description 4
- 239000002304 perfume Substances 0.000 claims description 4
- 239000006187 pill Substances 0.000 claims description 4
- 244000223014 Syzygium aromaticum Species 0.000 claims description 3
- 235000016639 Syzygium aromaticum Nutrition 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 239000012528 membrane Substances 0.000 claims description 3
- 241000207199 Citrus Species 0.000 claims description 2
- 241000233855 Orchidaceae Species 0.000 claims description 2
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 2
- 244000299461 Theobroma cacao Species 0.000 claims description 2
- 235000009470 Theobroma cacao Nutrition 0.000 claims description 2
- 239000001387 apium graveolens Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 235000020971 citrus fruits Nutrition 0.000 claims description 2
- 235000013399 edible fruits Nutrition 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 238000003860 storage Methods 0.000 claims description 2
- 239000004568 cement Substances 0.000 claims 1
- 210000003739 neck Anatomy 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 15
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 8
- 239000003546 flue gas Substances 0.000 abstract description 8
- 239000003205 fragrance Substances 0.000 abstract description 8
- 238000000605 extraction Methods 0.000 abstract description 6
- 239000011162 core material Substances 0.000 abstract description 5
- 230000008569 process Effects 0.000 abstract description 5
- 238000000465 moulding Methods 0.000 abstract description 4
- 239000011324 bead Substances 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 abstract 2
- 235000019198 oils Nutrition 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- 230000001953 sensory effect Effects 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000002775 capsule Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 235000010410 calcium alginate Nutrition 0.000 description 3
- 239000000648 calcium alginate Substances 0.000 description 3
- 229960002681 calcium alginate Drugs 0.000 description 3
- OKHHGHGGPDJQHR-YMOPUZKJSA-L calcium;(2s,3s,4s,5s,6r)-6-[(2r,3s,4r,5s,6r)-2-carboxy-6-[(2r,3s,4r,5s,6r)-2-carboxylato-4,5,6-trihydroxyoxan-3-yl]oxy-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate Chemical compound [Ca+2].O[C@@H]1[C@H](O)[C@H](O)O[C@@H](C([O-])=O)[C@H]1O[C@H]1[C@@H](O)[C@@H](O)[C@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@H](O2)C([O-])=O)O)[C@H](C(O)=O)O1 OKHHGHGGPDJQHR-YMOPUZKJSA-L 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 235000013599 spices Nutrition 0.000 description 3
- 206010011732 Cyst Diseases 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 208000031513 cyst Diseases 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- 230000000391 smoking effect Effects 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 238000004435 EPR spectroscopy Methods 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000002262 Litsea cubeba Species 0.000 description 1
- 235000012854 Litsea cubeba Nutrition 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 150000004667 medium chain fatty acids Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 239000008601 oleoresin Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000005180 public health Effects 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 235000019505 tobacco product Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/24—Treatment of tobacco products or tobacco substitutes by extraction; Tobacco extracts
- A24B15/241—Extraction of specific substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/02—Manufacture of tobacco smoke filters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/022—Refining
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/025—Recovery by solvent extraction
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/02—Recovery or refining of essential oils from raw materials
- C11B9/027—Recovery of volatiles by distillation or stripping
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The method of tobacco aromaticss is prepared using Glycerin, mixed triester with caprylic acid capric acid and its application in the quick-fried pearl of cigarette, the preparation method mainly include the following steps the present invention provides a kind of：(1) solid powder will be made after natural plant raw material drying, crushing, sieving.(2) by after natural plants solid powder and Glycerin, mixed triester with caprylic acid capric acid and vitamin E heating and refluxing extraction, then gauze coarse filtration, filtering with microporous membrane is reused, removes impurity and a small amount of insoluble matter, up to tobacco aromaticss of the present invention.Present invention process is simple, easily controllable, and cost of material is low；The fragrance product of preparation has nature, pure, coordination odor characteristic, natural sense is stronger, product quality is stablized, it may be directly applied to as oil-soluble content in the quick-fried bead core material of cigarette, the quick-fried online molding effect of pearl is stablized, while the free-radical contents in having effects that removing cigarette mainstream flue gas during cigarette is burnt and sucked.
Description
Technical field
The present invention relates to cigarette flavors field, specifically one kind prepares tobacco aromaticss using Glycerin, mixed triester with caprylic acid capric acid
Method and its application in the quick-fried pearl of cigarette.
Background technology
By coriander seed, rhodiola root, cloves, coffee bean etc. rich in oil soluble flavors natural plants by steam distillation,
The processing methods such as solvent extraction, can obtain essential oil or oleoresin.Under prior art conditions, the fragrance of essential oil product is past
It is past not pure enough, comfortable, lack natural sense；Due to the residual of organic solvent, also there is certain chemical breath in portioned product.For
Effective solution above technical problem, the characteristic Study on extraction of carrying out fat soluble flavor seem increasingly important.
Quick-fried pearl cigarette is pre-filled with one or more flavored capsules, smoker in filter tip and can be selected in sucking process
Property by capsule pinch it is quick-fried, release fragrance.Quick-fried pearl is that cigarette assigns fragrant, the technology new way of flavouring humectation, and spices can be avoided to participate in combustion
Burn, be effectively ensured that fragrance is pure and aroma strength, it is excellent with incomparable technology in terms of cigarette brand style and features are strengthened
Gesture, its personalized sensory experience are favored by consumers.Cigarette is similar with capsule for medicine, edible capsule with quick-fried pearl, and wall material is
The hydrophilic compositions such as gelatin, natural plant gum, polysaccharide, therefore core liquid must select oil-soluble ingredients, to avoid wall material is destroyed.
In recent years, effect of the natural plant pefume in terms of improving cigarette comfort and highlighting cigarette style characteristic obtains
Tobacco scientific and technical personnel and consumer's is widely recognized as.Traditional essence spice for cigarette obtained after natural products is processed, mostly
It is obtained by extraction using organic solvents such as propane diols, glycerine, ethanol, due to the particular/special requirement of quick-fried pearl oiliness core, it is impossible to
Directly addition uses in quick-fried pearl essential oil modulated process.For example, the core that the polar solvent miscible with water such as propane diols, glycerine is prepared
Capsule can not be processed into, the ethanol of too high amount also can give the processing of quick-fried pearl to bring difficulty.
Glycerin, mixed triester with caprylic acid capric acid is using greases such as coconut oil, palm-kernel oil, litsea citrate oils as raw material, through hydrolyzing, being fractionated, cutting
Cut, obtain octanoic acid, capric acid and glycerine esterification, then depickling, dehydration, medium chain fatty acid made from decoloration.As a kind of special
Esters food additives, Glycerin, mixed triester with caprylic acid capric acid meet natural, nutrition, multi-functional direction, are ratified by the Ministry of Public Health within 1996 available
In various food, and dosage is unrestricted.Since Off-Shoot-O glyceride colorless and odorless, viscosity are low, its viscosity is general plant
The half of oil, without interference with the fragrance of essence, can be used as base-material, solvent, diluent, stabilizer to make in essence production process
With.In addition, Glycerin, mixed triester with caprylic acid capric acid have cost of material is low, stability is good, high temperature resistant, it is not oxidizable the advantages that, boil for a long time fried
Viscosity is almost unchanged afterwards.
The present inventor has found in experimentation：Simply by the obtained extracted form natural plant of extraction technique
Thing, since extraction temperature is higher, oxygenolysis easily occurs for part aroma substance (effumability such as phenols, esters component), leads
The characteristic perfume style unobvious of raw material are caused, the natural sense of fragrance is weaker, sometimes because the introducing generation of chemical reagent is undesirable
Chemical breath, being added in cigarette has different degrees of negative effect, can not meet the use as additive of tobacco product
It is required that.
The content of the invention
The purpose of the present invention is insufficient according to prior art, there is provided Glycerin, mixed triester with caprylic acid capric acid and vitamin E are molten as extracting
Agent prepares the method for tobacco aromaticss and its application in the quick-fried pearl of cigarette, and characteristic tobacco aromaticss prepared by the present invention have raw material
Characteristic perfume style, fragrance is natural, pure, coordination, and no adverse chemical breath, natural sense is stronger, without organic solvent, product matter
Amount is stablized, and as additive application in the quick-fried pearl of cigarette, online molding effect is stablized, and personalized note feature is bright after pinching brokenly
Aobvious, aromatic flavour is full, pure comfortable, and pleasant impression is totally comfortable, the soft exquisiteness of flue gas；Have at the same time during cigarette is burnt and sucked clear
Except in cigarette mainstream flue gas the effect of free-radical contents.
To achieve the above object, a kind of method that tobacco aromaticss are prepared using Glycerin, mixed triester with caprylic acid capric acid provided by the invention, it
Include the following steps：
(1) solid powder will be made after natural plant raw material drying, crushing, sieving.
(2) it is 1 in mass ratio by natural plants solid powder and Glycerin, mixed triester with caprylic acid capric acid:15-20 is put into three-neck flask, is added
Enter to account for the vitamin E of system weight 0.05-0.1%, connect reflux condensing tube, start oil bath heating equipment, controlled at 110
DEG C -150 DEG C, handle under constant agitation 2-4 it is small when, after cooled to room temperature.
(3) after step (2) resulting material first being used gauze coarse filtration, reuse filtering with microporous membrane, remove impurity and a small amount of
Insoluble matter, up to tobacco aromaticss of the present invention.
Natural plant raw material in the step (1) is celery seed, coriander seed, marigold, bitter citrus immature flower, white orchid, smokes clothing
Grass, rhodiola root, cloves, coffee bean, cocoa bean etc. are rich in the plant perfume of oil-soluble flavor component.
Sieving sieve mesh number used is preferably 20-40 mesh in the step (1).
The aperture of miillpore filter is 0.8 μm in the step (3).
It is specific as follows the invention also discloses application of the above-mentioned characteristic tobacco aromaticss in the quick-fried pearl of cigarette：By institute of the present invention
After the tobacco aromaticss stated use Glycerin, mixed triester with caprylic acid capric acid to dilute 5-10 times as solvent, the 0.2%-0.4% of system gross weight is added
Span-80 as surfactant, referring next to the production technology of the quick-fried pearl of cigarette, above-mentioned essential oil smaple is existed as content
Online forming experiment is carried out on pill dripping machine, cigarette is made after quick-fried pearl finished product is inserted filter stick, spices is determined by sensory evaluating smoking
Practical application effect.
The raw material such as Glycerin, mixed triester with caprylic acid capric acid, vitamin E is commercial product in the present invention.
The advantage of the invention is that：
(1) Extraction solvent used in the present invention is Glycerin, mixed triester with caprylic acid capric acid, has low cost of material, colorless and odorless, viscosity
A little, viscosity is almost unchanged after long-time heating processing for low, high temperature resistant, not oxidizable etc..In leaching process, without interference with day
The oil-soluble flavor component of right plant, and vitamin E has certain inoxidizability as a small amount of additive, can be effective
Ground prevents aroma substance from aoxidizing and decomposing during high-temp extracting, preferably retains the characteristic flavor on basis component of raw material, fragrance is certainly
So, pure, coordination, no adverse chemical breath, natural sense is stronger, and without organic solvent, product quality is stablized.
(2) tobacco aromaticss of the present invention can be used as oil-soluble content to be applied in the quick-fried bead core material of cigarette, quick-fried pearl
Online molding effect is stablized, and personalized note feature is obvious after pinching brokenly, and aromatic flavour is full, pure comfortable, and pleasant impression is totally comfortable,
The soft exquisiteness of flue gas；The free-radical contents in there is removing cigarette mainstream flue gas during cigarette is burnt and sucked at the same time.
(3) the method for the present invention prepares cigarette with quick-fried pearl, after calcium alginate pearl is initially formed, then is dipped into oxidant respectively
In aqueous solution and water-soluble polymer solution, water soluble polymer can be made to be evenly distributed on calcium alginate surface, play raising
Cyst wall air-tightness, strengthens the effect of cyst wall intensity, achievees the purpose that inclusion and prevents essence from volatilizing.
(4) present invention has the characteristics that easy to operate, easily controllable, cost of material is low, is suitable for actual production conversion, fits
Cooperate to be promoted and applied for a kind of method for preparing characteristic tobacco aromaticss.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment one
By coriander seed raw material, after drying, crushing, coriander seed powder-product is made after crossing 40 mesh sieve nets.Weigh coriander seed
Powder 0.1kg, Glycerin, mixed triester with caprylic acid capric acid 1.5kg, 0.8g vitamin E, is put into three-neck flask, connects reflux condensing tube, starts oil
Bathe heating equipment, controlled at 120 DEG C, under constant agitation handle 3 it is small when, after cooled to room temperature.Will
After resulting material first uses gauze coarse filtration, 0.8 μm of filtering with microporous membrane is reused, impurity and a small amount of insoluble matter are removed, up to this hair
The bright tobacco aromaticss.
Embodiment two
By marigold petal, after drying, crushing, marigold powder-product is made after crossing 20 mesh sieve nets.Weigh marigold
Powder 0.1kg, Glycerin, mixed triester with caprylic acid capric acid 1.6kg, is put into three-neck flask, 1.3g vitamin Es, connects reflux condensing tube, starts oil
Bathe heating equipment, controlled at 110 DEG C, under constant agitation handle 2 it is small when, after cooled to room temperature.Will
After resulting material first uses gauze coarse filtration, 0.8 μm of filtering with microporous membrane is reused, impurity and a small amount of insoluble matter are removed, up to this hair
The bright tobacco aromaticss.
Embodiment three
By lavender after drying, crushing, lavender powder product is made after crossing 40 mesh sieve nets.Weigh lavender powder
0.1kg, Glycerin, mixed triester with caprylic acid capric acid 1.8kg, 1.8g vitamin E, is put into three-neck flask, connects reflux condensing tube, starts oil bath and adds
Hot equipment, controlled at 130 DEG C, under constant agitation handle 2.5 it is small when, after cooled to room temperature.By institute
Material is obtained first with after gauze coarse filtration, is reused 0.8 μm of filtering with microporous membrane, is removed impurity and a small amount of insoluble matter, up to the present invention
The tobacco aromaticss.
Example IV
By rhodiola root after drying, crushing, rhodiola root powder-product is made after crossing 20 mesh sieve nets.Weigh rhodiola root powder
0.1kg, Glycerin, mixed triester with caprylic acid capric acid 2.0kg, 1.3g vitamin E, is put into three-neck flask, connects reflux condensing tube, starts oil bath and adds
Hot equipment, controlled at 150 DEG C, under constant agitation handle 2 it is small when, after cooled to room temperature.By gained
After material first uses gauze coarse filtration, 0.8 μm of filtering with microporous membrane is reused, removes impurity and a small amount of insoluble matter, up to institute of the present invention
State tobacco aromaticss.
Embodiment five
By coffee bean after drying, crushing, coffee bean powder-product is made after crossing 40 mesh sieve nets.Weigh coffee bean powder
0.1kg, Glycerin, mixed triester with caprylic acid capric acid 1.7kg, 1.2g vitamin E, is put into three-neck flask, connects reflux condensing tube, starts oil bath and adds
Hot equipment, controlled at 135 DEG C, under constant agitation handle 3 it is small when, after cooled to room temperature.By gained
After material first uses gauze coarse filtration, 0.8 μm of filtering with microporous membrane is reused, removes impurity and a small amount of insoluble matter, up to institute of the present invention
State tobacco aromaticss.
Application experiment:
After tobacco aromaticss of the present invention are diluted 5-10 times using oil solvent based on Glycerin, mixed triester with caprylic acid capric acid, addition
The Span-80 of system gross weight 0.2%-0.4%, stirring at normal temperature 1.0-2.0h is to molten under the conditions of rotating speed is 200-300r/min
Liquid clear, is quick-fried pearl essence after 100nm ceramic membranes (pressure 0.10-0.20MPa, temperature are 25-30 DEG C) filtering
Oil.By quick-fried pearl essential oil after Fruit storage 10-20min, peristaltic pump is used to control the flow velocity of quick-fried pearl essential oil as 2mL/
Min, quick-fried pearl essential oil is directly added drop-wise in the sodium alginate aqueous solution of mass fraction 2% by orifice, and quick-fried pearl essential oil is in seaweed
Stopped 20 minutes in acid sodium solution and obtain calcium alginate pearl；Pearl is taken out and is washed with distilled water, is then placed in mass fraction
To be soaked 10 minutes in 6% SODIUM PERCARBONATE aqueous solution；After the taking-up of gained pearl is washed with distilled water, it is dense that quality is dipped into again
20 minutes are spent in the polyvinylpyrrolidonesolution solution for 5%；Gained pearl is taken out again after being washed with distilled water, be less than in temperature
Naturally dry in 30 degree of environment, is prepared cigarette with quick-fried pearl.The positioning of quick-fried pearl is applied to filter in filter tow forming process
In rod, cigarette is then made.
Tobacco aromaticss prepared by embodiment 1-5 are modulated into essential oil according to following proportioning：Tobacco aromaticss 12.75%, the pungent last of the ten Heavenly stems
Acid glyceride 87%, Span-80 surfactants 0.25%, by being stirred, after degassing process, carry out quick-fried on pill dripping machine
Pearl is molded online, and then the positioning of quick-fried pearl is applied in cigarette filter rod, quick-fried pearl cigarette is made.The result shows that：Quick-fried pearl essential oil conduct
Oil-soluble content, has good compatibility, the quick-fried online molding effect of pearl is stablized, and product qualification rate reaches with quick-fried pearl wall material
More than 98%, the abnormal phenomenon such as solid pearl, permeability, bias, rupture is less.
Quick-fried pearl is pinched brokenly in aspiration procedure, is evaluated with reference to State Bureau's standard of smokeing panel test.Group smoke panel test by 13 cigarette senses
Official evaluates expert's composition, and using secretly commenting mode to carry out sensory evaluation and giving a mark, Analyses Methods for Sensory Evaluation Results is as shown in table 1.
The quick-fried pearl cigarette sensory effects evaluation result of table 1
| Sample | Blank | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Mean scores | 75.0 | 84.3 | 85.0 | 85.4 | 84.8 | 85.7 |
Using fFlue gas collector and electron spin resonance, analysis detects quick-fried pearl and pinches brokenly rear essential oil to cigarette main flue
The elimination effect of gas free-radical contents, the results are shown in Table 2.
Elimination effect of 2 essential oil of table to cigarette mainstream flue gas free-radical contents
Note：+, free-radical contents rise；-, free-radical contents reduce
Quick-fried pearl prepared by using above-mentioned essential oil, after being pinched brokenly during cigarette smoking, sensory effects evaluation score is obvious
Improve, application effect is more notable, and personalized note protrudes, and aromatic flavour is full, pure comfortable, and lasting is lasting, and pleasant impression is clean
Comfortably, the soft exquisiteness of flue gas, and perfuming effect is stablized；At the same time in there is removing cigarette mainstream flue gas during cigarette is burnt and sucked certainly
The effect of by base content.
The foregoing is merely the detailed description of specific embodiments of the present invention, does not limit the present invention with this, all at this
All any modification, equivalent and improvement made in the mentality of designing of invention etc., should be included in protection scope of the present invention it
It is interior.
Claims (6)
- A kind of 1. method that tobacco aromaticss are prepared using Glycerin, mixed triester with caprylic acid capric acid, it is characterised in that include the following steps：(1) solid powder will be made after natural plant raw material drying, crushing, sieving；(2) it is 1 in mass ratio by the natural plants solid powder obtained by step (1) and Glycerin, mixed triester with caprylic acid capric acid:15-20 is put into three necks In flask, the vitamin E for the 0.05-0.1% for accounting for system weight is added, connects reflux condensing tube, starts oil bath heating equipment, Controlled at 110 DEG C -150 DEG C, under constant agitation handle 2-4 it is small when, after cooled to room temperature；(3) after step (2) resulting material first being used gauze coarse filtration, reuse filtering with microporous membrane, remove impurity and a small amount of insoluble Thing, up to tobacco aromaticss of the present invention.
- A kind of 2. method that tobacco aromaticss are prepared using Glycerin, mixed triester with caprylic acid capric acid according to claim 1, it is characterised in that：Institute State natural plant raw material in step (1) for celery seed, coriander seed, marigold, bitter citrus immature flower, white orchid, lavender, rhodiola root, Cloves, coffee bean or cocoa bean are rich in the plant perfume of oil-soluble flavor component.
- A kind of 3. method that tobacco aromaticss are prepared using Glycerin, mixed triester with caprylic acid capric acid according to claim 1, it is characterised in that：Institute It is 20-40 mesh to state the sieve mesh number that sieving is used in step (1).
- A kind of 4. method that tobacco aromaticss are prepared using Glycerin, mixed triester with caprylic acid capric acid according to claim 1, it is characterised in that：Institute The aperture for stating miillpore filter in step (3) is 0.8 μm.
- 5. according to application of the claim 1-4 any one of them tobacco aromaticss in the quick-fried pearl of cigarette, it is characterised in that：It will obtain Tobacco aromaticss use Glycerin, mixed triester with caprylic acid capric acid based on oil solvent dilute 5-10 times after, addition system gross weight 0.2%- 0.4% Span-80, stirring at normal temperature 1.0-2.0h is passed through to solution clear under the conditions of rotating speed is 200-300r/min It is quick-fried pearl essential oil after 100nm ceramic membrane filters；By quick-fried pearl essential oil after Fruit storage 10-20min, with being placed in dripping pill Dripping pill lapping in machine rubber cement tank and it is placed in the curing agent contained in ball device cigarette is made with quick-fried pearl.
- 6. application of the tobacco aromaticss according to claim 5 in the quick-fried pearl of cigarette, it is characterised in that：The ceramic membrane filter When pressure be 0.10-0.20MPa, temperature is 25-30 DEG C.
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