CN107927151A - A kind of natural long-acting fruit and vegetable fresh-keeping agent and preparation method thereof - Google Patents
A kind of natural long-acting fruit and vegetable fresh-keeping agent and preparation method thereof Download PDFInfo
- Publication number
- CN107927151A CN107927151A CN201711294733.0A CN201711294733A CN107927151A CN 107927151 A CN107927151 A CN 107927151A CN 201711294733 A CN201711294733 A CN 201711294733A CN 107927151 A CN107927151 A CN 107927151A
- Authority
- CN
- China
- Prior art keywords
- parts
- distilled water
- leaf
- tealeaves
- keeping
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000012055 fruits and vegetables Nutrition 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 235000002732 Allium cepa var. cepa Nutrition 0.000 claims abstract description 18
- 239000012153 distilled water Substances 0.000 claims abstract description 17
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 15
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 15
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 15
- 239000011425 bamboo Substances 0.000 claims abstract description 15
- 229920002752 Konjac Polymers 0.000 claims abstract description 14
- 241000218231 Moraceae Species 0.000 claims abstract description 14
- 235000008708 Morus alba Nutrition 0.000 claims abstract description 14
- 240000002853 Nelumbo nucifera Species 0.000 claims abstract description 14
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims abstract description 14
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims abstract description 14
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 claims abstract description 13
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920002581 Glucomannan Polymers 0.000 claims abstract description 13
- 229940046240 glucomannan Drugs 0.000 claims abstract description 13
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 12
- 244000163122 Curcuma domestica Species 0.000 claims abstract description 12
- 235000003392 Curcuma domestica Nutrition 0.000 claims abstract description 12
- 239000001110 calcium chloride Substances 0.000 claims abstract description 12
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 12
- 235000003373 curcuma longa Nutrition 0.000 claims abstract description 12
- 235000013976 turmeric Nutrition 0.000 claims abstract description 12
- 244000062241 Kaempferia galanga Species 0.000 claims abstract description 10
- 235000013421 Kaempferia galanga Nutrition 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 244000291564 Allium cepa Species 0.000 claims abstract 5
- 240000000560 Citrus x paradisi Species 0.000 claims abstract 4
- 244000082204 Phyllostachys viridis Species 0.000 claims abstract 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 30
- 235000013311 vegetables Nutrition 0.000 claims description 10
- 238000007654 immersion Methods 0.000 claims description 7
- 235000013399 edible fruits Nutrition 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 5
- 239000003814 drug Substances 0.000 claims description 3
- 241000411851 herbal medicine Species 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 2
- 239000003509 long acting drug Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 11
- 241000894006 Bacteria Species 0.000 abstract description 7
- 230000003647 oxidation Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 241000196324 Embryophyta Species 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 241000234282 Allium Species 0.000 description 13
- 241001330002 Bambuseae Species 0.000 description 11
- 230000000844 anti-bacterial effect Effects 0.000 description 9
- 244000276331 Citrus maxima Species 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- 239000003963 antioxidant agent Substances 0.000 description 6
- 235000006708 antioxidants Nutrition 0.000 description 6
- 238000004321 preservation Methods 0.000 description 6
- 230000003064 anti-oxidating effect Effects 0.000 description 5
- 230000003078 antioxidant effect Effects 0.000 description 5
- 229930003935 flavonoid Natural products 0.000 description 5
- 235000017173 flavonoids Nutrition 0.000 description 5
- 150000002215 flavonoids Chemical class 0.000 description 5
- 235000021022 fresh fruits Nutrition 0.000 description 5
- IYRMWMYZSQPJKC-UHFFFAOYSA-N kaempferol Chemical compound C1=CC(O)=CC=C1C1=C(O)C(=O)C2=C(O)C=C(O)C=C2O1 IYRMWMYZSQPJKC-UHFFFAOYSA-N 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 230000001143 conditioned effect Effects 0.000 description 3
- 238000005138 cryopreservation Methods 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 230000004060 metabolic process Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000001717 pathogenic effect Effects 0.000 description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- 241000193830 Bacillus <bacterium> Species 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- 235000002566 Capsicum Nutrition 0.000 description 2
- 240000008574 Capsicum frutescens Species 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UBSCDKPKWHYZNX-UHFFFAOYSA-N Demethoxycapillarisin Natural products C1=CC(O)=CC=C1OC1=CC(=O)C2=C(O)C=C(O)C=C2O1 UBSCDKPKWHYZNX-UHFFFAOYSA-N 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 2
- 244000070406 Malus silvestris Species 0.000 description 2
- 241000588769 Proteus <enterobacteria> Species 0.000 description 2
- 235000014443 Pyrus communis Nutrition 0.000 description 2
- 241000607764 Shigella dysenteriae Species 0.000 description 2
- 240000003768 Solanum lycopersicum Species 0.000 description 2
- 241000191940 Staphylococcus Species 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 239000001390 capsicum minimum Substances 0.000 description 2
- 210000004027 cell Anatomy 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- VFLDPWHFBUODDF-FCXRPNKRSA-N curcumin Chemical compound C1=C(O)C(OC)=CC(\C=C\C(=O)CC(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-FCXRPNKRSA-N 0.000 description 2
- 229930003944 flavone Natural products 0.000 description 2
- 235000011949 flavones Nutrition 0.000 description 2
- 150000002213 flavones Chemical class 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- MWDZOUNAPSSOEL-UHFFFAOYSA-N kaempferol Natural products OC1=C(C(=O)c2cc(O)cc(O)c2O1)c3ccc(O)cc3 MWDZOUNAPSSOEL-UHFFFAOYSA-N 0.000 description 2
- 235000008777 kaempferol Nutrition 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- UXOUKMQIEVGVLY-UHFFFAOYSA-N morin Natural products OC1=CC(O)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)O)=C1 UXOUKMQIEVGVLY-UHFFFAOYSA-N 0.000 description 2
- 244000052769 pathogen Species 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 229940007046 shigella dysenteriae Drugs 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 229920001864 tannin Chemical class 0.000 description 2
- 235000018553 tannin Nutrition 0.000 description 2
- 239000001648 tannin Chemical class 0.000 description 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 1
- 241000193738 Bacillus anthracis Species 0.000 description 1
- 235000001759 Citrus maxima Nutrition 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- 239000000232 Lipid Bilayer Substances 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 241000194017 Streptococcus Species 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 208000037386 Typhoid Diseases 0.000 description 1
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 229930013930 alkaloid Chemical class 0.000 description 1
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 235000012754 curcumin Nutrition 0.000 description 1
- 229940109262 curcumin Drugs 0.000 description 1
- 239000004148 curcumin Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- VFLDPWHFBUODDF-UHFFFAOYSA-N diferuloylmethane Natural products C1=C(O)C(OC)=CC(C=CC(=O)CC(=O)C=CC=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 210000004602 germ cell Anatomy 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 206010020718 hyperplasia Diseases 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 235000010485 konjac Nutrition 0.000 description 1
- -1 linoleic acid, myristic acid, leukotrienes Chemical class 0.000 description 1
- 238000005360 mashing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000002703 mutagenesis Methods 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 201000008297 typhoid fever Diseases 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/14—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
- A23B7/153—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
- A23B7/154—Organic compounds; Microorganisms; Enzymes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/14—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
- A23B7/153—Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
- A23B7/157—Inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B7/00—Preservation or chemical ripening of fruit or vegetables
- A23B7/16—Coating with a protective layer; Compositions or apparatus therefor
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Zoology (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Microbiology (AREA)
- Preparation Of Fruits And Vegetables (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
The invention discloses a kind of natural long-acting fruit and vegetable fresh-keeping agent and preparation method thereof, it is related to antistaling agent technical field, which is prepared from the following raw materials in parts by weight:4~8 parts of chinese bulbous onion, 4~10 parts of tealeaves, 2~6 parts of radix scutellariae, 2~6 parts of mulberries, 8~14 parts of leaf of Herba Apii graveolentis, 2~6 parts of kaempferia galanga root, 6~12 parts of pomelo peel, 4~10 parts of Fructus Corni, 2~8 parts of turmeric, 2~8 parts of bamboo extractive, 2~8 parts of Lotus Leafextract, 6~14 parts of konjaku glucomannan, 3~6 parts of ethanol, 0.5~2 part of calcium chloride, 0.5~2.5 part of lauric monoglyceride, 60~120 parts of distilled water;The growth that can effectively inhibit bacteria of antistaling agent of the present invention, prevents that fruits and vegetables are corrupt, also has oxidation resistant effect fresh-keeping while.The present invention is gone out using natural plant component proportioning, nontoxic, safe to use, it is only necessary to can be removed by clear water cleaning.
Description
Technical field
A kind of antistaling agent technical field of the present invention, and in particular to natural long-acting fruit and vegetable fresh-keeping agent and preparation method thereof.
Background technology
At present, the technological means used both at home and abroad in preserving fruit and vegetable utilizing field mainly has physics and chemical two major classes, generally all
It is to be regulated and controled by following three big principles, is to control its ageing process first;Secondly, microorganism is controlled, mainly by corruption
The control for losing bacterium is realized;3rd internal moisture evaporation in order to control, mainly passes through the control to envionmental humidity and iuntercellular water
Point structuring realize.
One of China is vegetables big producer, and kind and yield occupy first place in the world, be the pillar industries of the national economy, but
For a long time, China's agricultural production is only paid attention to managing in antenatal, production, but ignores the antistaling storing in postpartum, causes greatly to pass through
Ji loss.Needed with the improvement of people ' s living standards with the quality requirement high to food, vegetables in the case of more complicated
More permanently keep fresh, and keep its flavor and nutriment, in the prior art frequently with cryopreservation, air conditioned storage or
Chemical preservation.
Although what cryopreservation, air conditioned storage can reduce fresh fruits and vegetables to varying degrees adopts rear metabolism degree, delay
The process of its quality deterioration, extends its freshness date.But during cryopreservation, still can there are some psychrophiles such as monokaryon is thin
Raised growth and the breeding under refrigerated conditions such as born of the same parents Liszt's hyperplasia bacterium and pseudomonas, ultimately results in vegetables and corruption change occurs
Matter.And often disposably input is big, operating cost is high for air conditioned storage, the cost of fresh fruits and vegetables is not only increased, and to storage
The requirement of administrative skill is higher, and grasp is bad to will also result in heavy losses.Using chemical preservation antistaling agent to fresh fruits and vegetables into
Row Preservation Treatment, although positive effect, can significantly adjust the metabolism degree of fresh fruits and vegetables, suppress the breeding of surface microorganism, drop
The postharvest decay loss of low fresh fruits and vegetables.But the security of many chemical preservation antistaling agents is relatively low, often exist in various degree
Toxic side effect or residue problem.Therefore there is an urgent need for study natural antistaling agent a kind of of good preservation effect and safe.
The content of the invention
The technical problems to be solved by the invention are the shortcomings that overcoming the above prior art:There is provided it is a kind of it is of good preservation effect,
And safe natural long-acting fruit and vegetable fresh-keeping agent and preparation method thereof.
The technical solution of the present invention is as follows:
A kind of natural long-acting fruit and vegetable fresh-keeping agent, is prepared from the following raw materials in parts by weight:4~8 parts of chinese bulbous onion, tealeaves 4~10
Part, 2~6 parts of radix scutellariae, 2~6 parts of mulberries, 8~14 parts of leaf of Herba Apii graveolentis, 2~6 parts of kaempferia galanga root, 6~12 parts of pomelo peel, Fructus Corni 4~10
Part, 2~8 parts of turmeric, 2~8 parts of bamboo extractive, 2~8 parts of Lotus Leafextract, 6~14 parts of konjaku glucomannan, ethanol 3~6
Part, 0.5~2 part of calcium chloride, 0.5~2.5 part of lauric monoglyceride, 60~120 parts of distilled water.
Preferably, the natural agent keeping vegetable fresh is prepared from the following raw materials in parts by weight:5~7 parts of chinese bulbous onion, tealeaves 6
~8 parts, 3~5 parts of radix scutellariae, 3~5 parts of mulberries, 10~12 parts of leaf of Herba Apii graveolentis, 3~5 parts of kaempferia galanga root, 8~10 parts of pomelo peel, Fructus Corni 6
~8 parts, 3~7 parts of turmeric, 3~7 parts of bamboo extractive, 4~6 parts of Lotus Leafextract, 8~12 parts of konjaku glucomannan, ethanol 4
~5 parts, 1~3 part of citric acid, 1~1.5 part of calcium chloride, 1~2 part of lauric monoglyceride, 80~100 parts of distilled water.
The preparation method of the natural long-acting fruit and vegetable fresh-keeping agent, comprises the following steps:
(1) chinese bulbous onion, tealeaves, citric acid are mixed, adds distilled water not have 20~30min of immersion, be put into beater
Mashing, 10~20min is heated at 70~80 DEG C, is filtered to get filtrate;
(2) leaf of Herba Apii graveolentis is crushed, is then mixed with ethanol, 40~60min is reacted at 80~100 DEG C, with step
Suddenly (1) obtains chinese bulbous onion, tealeaves, the filtrate of citric acid are mixed;
(3) radix scutellariae, mulberries, leaf of Herba Apii graveolentis, kaempferia galanga root, pomelo peel, Fructus Corni, turmeric are added in medicinal herb grinder, powder
200~400 mesh are broken to, adds distilled water not have 30~50min of immersion, is added in decocting for Chinese herbal medicine tank, after boiling with high heat, changes text
Fire continues 30~40min of decoction, filters to obtain Chinese medicine extract;
(4) solution made from step (2), step (3) is mixed, adds bamboo extractive, Lotus Leafextract, heating
To 80~100 DEG C, it is uniformly mixed, then adds konjaku glucomannan, calcium chloride, lauric monoglyceride, remaining steaming
Distilled water, is uniformly mixed, up to the antistaling agent of the present invention.
The present invention is acted synergistically using a variety of antioxidants and antiseptic, and the tealeaves in the present invention has very strong anti-oxidant
And antibacterial action;Bamboo-leaves flavones in the bamboo extractive of the present invention have very strong antioxidation;Bamboo extractive at the same time
Also there is broad spectrum antibacterial, strong inhibitory action is respectively provided with to bacterium, yeast and mold.In the Lotus Leafextract of the present invention
Containing flavonoids, alkaloids and tannin class, therefore there is antioxidation;The apiolin that contains is in the leaf of Herba Apii graveolentis of the present invention
A kind of Flavonoid substances, have antioxidation, and apiolin has hypotoxicity, without mutagenesis compared with other Flavonoid substances
Feature;Contain Kaempferol in kaempferia galanga root, Kaempferol has the function that anti-oxidant, antibacterial.The radix scutellariae of the present invention contains flavonoid
Thing, has stronger inhibitory action to shigella dysenteriae, paratyphosum Bacterium, Escherichia coli, proteus, staphylococcus etc.;In mulberries
Containing tannic acid, malic acid, linoleic acid, myristic acid, leukotrienes etc., there is anti-oxidant, antibacterial.Contain in the fruit of medicinal cornel
The component such as physiological activity stronger saponin raw sugar, polysaccharide, malic acid, tartaric acid, gallic acid, tannin and vitamin A, C, has
Antibacterial and antioxidation.Curcumin in turmeric has resisting pathogenic microbes effect and antioxidation.The shaddock of the present invention
The flavones and Flavonoid substances that sub- skin contains are to gram-positive cocci, such as staphylococcus, streptococcus, Diplococcus pneumopniae, anthrax bar
Bacterium etc., and gram-Negative bacillus, such as Escherichia coli, shigella dysenteriae, typhoid bacillus, proteus have inhibitory action.This
The good synergistic effect that tealeaves, chinese bulbous onion, the citric acid of invention have, chinese bulbous onion can increase the dissolubility of active ingredient in tealeaves;Tea
The good synergistic effect that tea polyphenols in leaf have with citric acid, improves oxidation resistance.Therefore cooperateed with and made by above-mentioned raw materials
With improving the anti-oxidant and antibacterial effect of antistaling agent.
The present invention konjaku glucomannan be dissolved in water after, formed gelatinous solution, fruits and vegetables after konjaku glucomannan film,
The pellicle of one layer of water white transparency is formed on surface, can effectively stop O2Into inside fruit, slow down by fruits and vegetables respiration
The CO of generation2It is fresh-keeping so as to effectively have the function that to external diffusion;In addition, the lauric monoglyceride of the present invention is not only
Safe and efficient wide-spectrum bactericide, while the hydrophilic radical of lauric monoglyceride and hydrophobic grouping can also be with the phosphorus of cell membrane
Lipid bilayer is mutually dissolved, and increases germ membrane passage, antimicrobial component is smoothly entered in pathogen cells, is carried
High antibacterial effect.The releasable calcium ion of calcium chloride of the present invention, calcium ion are contacted with germ cell membrane phospholipid bilayer, changed
Become permeability of cell membrane, antimicrobial component is smoothly entered in pathogen cells, improve the effect of bactericidal.
Therefore, above-mentioned antioxidant, antiseptic etc. are formed one layer by the present invention by konjaku glucomannan in fruit and vegetable surfaces
Relatively compact protective film, completely cuts off most of air, while protection film layer has permeability, water preventing ability, can be to various gases
Molecule increases penetration resistance, forms a kind of micro- controlled atmosphere environment, increases the carbon dioxide content in fruits and vegetables tissue, oxygen content
Reduce, it is suppressed that the respiratory metabolism of fruits and vegetables.
The growth that can effectively inhibit bacteria of antistaling agent of the present invention, prevents that fruits and vegetables are corrupt, also has fresh-keeping while anti-
The effect of oxidation.The present invention is gone out using natural plant component proportioning, nontoxic, safe to use, it is only necessary to pass through clear water
Cleaning can remove, noresidue, safe to people and environmental-friendly, not influence the mouthfeel of fruits and vegetables.
Embodiment
The present invention is described in further details with specific embodiment below, but the present invention is not only limited in detail below in fact
Apply example.
Embodiment one
Weigh the raw material of following weight proportion:4 parts of chinese bulbous onion, 4 parts of tealeaves, 2 parts of radix scutellariae, 2 parts of mulberries, 8 parts of leaf of Herba Apii graveolentis, kaempferia galanga
2 parts of root, 6 parts of pomelo peel, 4 parts of Fructus Corni, 2 parts of turmeric, 2 parts of bamboo extractive, 2 parts of Lotus Leafextract, konjaku glucomannan 6
Part, 3 parts of ethanol, 0.5 part of calcium chloride, 0.5 part of lauric monoglyceride, 60 parts of distilled water.
Prepare in accordance with the following methods:
(4) chinese bulbous onion, tealeaves, citric acid are mixed, add distilled water not have immersion 30min, be put into beater and be beaten,
Filter to get filtrate;
(5) leaf of Herba Apii graveolentis is crushed, is then mixed with ethanol, reacted 50min at 90 DEG C, obtained with step (1)
Chinese bulbous onion, tealeaves, the filtrate of citric acid mixed;
(6) radix scutellariae, mulberries, leaf of Herba Apii graveolentis, kaempferia galanga root, pomelo peel, Fructus Corni, turmeric are added in medicinal herb grinder, powder
300 mesh are broken to, add distilled water not have immersion 40min, are added in decocting for Chinese herbal medicine tank, after boiling with high heat, changes slow boiling and continues to decoct
40min is boiled, filters to obtain Chinese medicine extract;
(4) solution made from step (2), step (3) is mixed, adds bamboo extractive, Lotus Leafextract, heating
To 80, it is uniformly mixed, then adds konjaku glucomannan, calcium chloride, lauric monoglyceride, remaining distilled water, stir
Mix it is uniformly mixed, up to the present invention antistaling agent.
Embodiment two
Weigh the raw material of following weight proportion:6 parts of chinese bulbous onion, 7 parts of tealeaves, 4 parts of radix scutellariae, 4 parts of mulberries, 11 parts of leaf of Herba Apii graveolentis, mountain
4 parts of a kind of apple root, 9 parts of pomelo peel, 7 parts of Fructus Corni, 5 parts of turmeric, 5 parts of bamboo extractive, 5 parts of Lotus Leafextract, konjaku glucomannan
10 parts, 4 parts of ethanol, 1.5 parts of calcium chloride, 1.5 parts of lauric monoglyceride, 90 parts of distilled water.
Preparation method is the same as embodiment one.
Embodiment three
Weigh the raw material of following weight proportion:8 parts of chinese bulbous onion, 10 parts of tealeaves, 6 parts of radix scutellariae, 6 parts of mulberries, 14 parts of leaf of Herba Apii graveolentis, mountain
6 parts of a kind of apple root, 12 parts of pomelo peel, 10 parts of Fructus Corni, 8 parts of turmeric, 8 parts of bamboo extractive, 8 parts of Lotus Leafextract, konjak portuguese gansu polyose
14 parts of sugar, 6 parts of ethanol, 2 parts of calcium chloride, 2.5 parts of lauric monoglyceride, 120 parts of distilled water.
Preparation method is the same as embodiment one.
Embodiment effect:
Take fresh capsicum, tomato, orange, pear, except prevent or cure a disease, part that is blue or green, small and having mechanical damage, ensure fruit
Fresh, uniformity, every kind of fruit every group 50.
A groups use the fruit and vegetable fresh-keeping agent in embodiment two to soak fresh-keeping 3min, are subsequently placed at 10 DEG C at dry and preserve;
B groups using without chinese bulbous onion, mulberries, leaf of Herba Apii graveolentis, Fructus Corni, bamboo extractive, Lotus Leafextract, it is other with implementation
The identical fruit and vegetable fresh-keeping agent of example 2 soaks fresh-keeping 3min, is subsequently placed at 10 DEG C at dry and preserves;
C groups are fresh-keeping using the antistaling disinfectant immersion of Bing Ze Environmental Protection Technology Co., Ltd of the Shenzhen production of in the market purchase
3min, is subsequently placed at 10 DEG C at dry and preserves;
D groups are blank group, soak fresh-keeping 3min using clear water, are subsequently placed at 10 DEG C at dry and preserve;
Different antistaling agents are as shown in the table to the fresh-keeping effect of capsicum, tomato, orange, pear:
As can be seen from the above table:Antistaling agent and only fresh-keeping with clear water, fruit and vegetable fresh-keeping agent effect of the present invention on relative market
Fruit is notable, while chinese bulbous onion, mulberries, leaf of Herba Apii graveolentis, Fructus Corni, bamboo extractive, Lotus Leafextract have significantly guarantor in the present invention
Fresh effect.
It the above is only the feature implementation example of the present invention, the scope of the present invention be not limited in any way.It is all to use together
The technical solution formed Deng exchange or equivalence replacement, all falls within rights protection scope of the present invention.
Claims (3)
- A kind of 1. natural long-acting fruit and vegetable fresh-keeping agent, it is characterised in that:It is prepared from the following raw materials in parts by weight:4~8 parts of chinese bulbous onion, 4~10 parts of tealeaves, 2~6 parts of radix scutellariae, 2~6 parts of mulberries, 8~14 parts of leaf of Herba Apii graveolentis, 2~6 parts of kaempferia galanga root, 6~12 parts of pomelo peel, mountain 4~10 parts of the fruit of medicinal cornel, 2~8 parts of turmeric, 2~8 parts of bamboo extractive, 2~8 parts of Lotus Leafextract, 6~14 parts of konjaku glucomannan, 3~6 parts of ethanol, 0.5~2 part of calcium chloride, 0.5~2.5 part of lauric monoglyceride, 30~60 parts of distilled water.
- 2. natural long-acting agent keeping vegetable fresh according to claim 1, it is characterised in that:By the raw material of following parts by weight It is made:5~7 parts of chinese bulbous onion, 6~8 parts of tealeaves, 3~5 parts of radix scutellariae, 3~5 parts of mulberries, 10~12 parts of leaf of Herba Apii graveolentis, 3~5 parts of kaempferia galanga root, 8~10 parts of pomelo peel, 6~8 parts of Fructus Corni, 3~7 parts of turmeric, 3~7 parts of bamboo extractive, 4~6 parts of Lotus Leafextract, konjaku 8~12 parts of Glucomannan, 4~5 parts of ethanol, 1~3 part of citric acid, 1~1.5 part of calcium chloride, 1~2 part of lauric monoglyceride, 40~50 parts of distilled water.
- A kind of 3. preparation method of natural long-acting fruit and vegetable fresh-keeping agent, it is characterised in that:Comprise the following steps:(1) chinese bulbous onion, tealeaves, citric acid are mixed, add distilled water not have 20~30min of immersion, be put into beater and be beaten, Filter to get filtrate;(2) leaf of Herba Apii graveolentis is crushed, is then mixed with ethanol, 40~60min is reacted at 80~100 DEG C, with step (1) Obtained chinese bulbous onion, tealeaves, the filtrate of citric acid are mixed;(3) radix scutellariae, mulberries, leaf of Herba Apii graveolentis, kaempferia galanga root, pomelo peel, Fructus Corni, turmeric are added in medicinal herb grinder, are crushed to 200~400 mesh, add distilled water do not had immersion 30~50min, be added in decocting for Chinese herbal medicine tank, after boiling with high heat, change slow boiling after It is continuous to decoct 30~40min, filter to obtain Chinese medicine extract;(4) solution made from step (2), step (3) is mixed, adds bamboo extractive, Lotus Leafextract, be heated to 80 ~100 DEG C, it is uniformly mixed, then adds konjaku glucomannan, calcium chloride, lauric monoglyceride, remaining distilled water, It is uniformly mixed, up to the antistaling agent of the present invention.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201711294733.0A CN107927151A (en) | 2017-12-08 | 2017-12-08 | A kind of natural long-acting fruit and vegetable fresh-keeping agent and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201711294733.0A CN107927151A (en) | 2017-12-08 | 2017-12-08 | A kind of natural long-acting fruit and vegetable fresh-keeping agent and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN107927151A true CN107927151A (en) | 2018-04-20 |
Family
ID=61946195
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201711294733.0A Pending CN107927151A (en) | 2017-12-08 | 2017-12-08 | A kind of natural long-acting fruit and vegetable fresh-keeping agent and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107927151A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108966826A (en) * | 2018-07-04 | 2018-12-11 | 江苏省农业科学院 | A kind of leaf vegetables browning inhibition collecting method and device |
CN109090228A (en) * | 2018-08-23 | 2018-12-28 | 吉林农业科技学院 | A method of it is stored for apple fresh-keeping |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103766481A (en) * | 2014-01-08 | 2014-05-07 | 杨凌农科大无公害农药研究服务中心 | Plant-source fresh medlar preservative and preparation method thereof |
CN105594845A (en) * | 2015-11-13 | 2016-05-25 | 中国热带农业科学院热带作物品种资源研究所 | Novel cassava color-protection fresh-keeping agent, and fresh keeping method |
CN106720242A (en) * | 2016-11-24 | 2017-05-31 | 兴业县恩民农业科技有限公司 | A kind of antistaling agent of red heart dragon fruit and preparation method thereof |
CN107047741A (en) * | 2017-03-30 | 2017-08-18 | 合肥金同维低温科技有限公司 | A kind of fruit antistaling agent and preparation method thereof |
-
2017
- 2017-12-08 CN CN201711294733.0A patent/CN107927151A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103766481A (en) * | 2014-01-08 | 2014-05-07 | 杨凌农科大无公害农药研究服务中心 | Plant-source fresh medlar preservative and preparation method thereof |
CN105594845A (en) * | 2015-11-13 | 2016-05-25 | 中国热带农业科学院热带作物品种资源研究所 | Novel cassava color-protection fresh-keeping agent, and fresh keeping method |
CN106720242A (en) * | 2016-11-24 | 2017-05-31 | 兴业县恩民农业科技有限公司 | A kind of antistaling agent of red heart dragon fruit and preparation method thereof |
CN107047741A (en) * | 2017-03-30 | 2017-08-18 | 合肥金同维低温科技有限公司 | A kind of fruit antistaling agent and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
吴圣彬等: "植物性天然食品防腐剂的研究进展 ", 《广东农业科学》 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108966826A (en) * | 2018-07-04 | 2018-12-11 | 江苏省农业科学院 | A kind of leaf vegetables browning inhibition collecting method and device |
CN108966826B (en) * | 2018-07-04 | 2020-06-02 | 江苏省农业科学院 | Leaf vegetable browning inhibition harvesting method and device |
CN109090228A (en) * | 2018-08-23 | 2018-12-28 | 吉林农业科技学院 | A method of it is stored for apple fresh-keeping |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN104664318B (en) | Fresh flower sauce and preparation method thereof | |
CN103519209B (en) | Production method of instant pork chops | |
CN107927150A (en) | A kind of natural composite antistaling agent for vegetables and preparation method thereof | |
CN105211274A (en) | A kind of fruits and vegetables bacteriostasis, preservation agent and preparation method thereof | |
CN105211880A (en) | A kind of preparation method of fig ferment | |
CN107969481A (en) | A kind of bio-preservative for fruits and vegetables and preparation method thereof | |
Yadav et al. | Effect of storage time on Aloe vera beverage | |
CN107197940B (en) | Biological preservative, preparation method thereof and application thereof in loquat preservation | |
CN107927151A (en) | A kind of natural long-acting fruit and vegetable fresh-keeping agent and preparation method thereof | |
KR102289438B1 (en) | health food composition manufacturing method including Hovenia dulcis, Sorbus commixta, Alnus Japonica and kudzu vine, health food composition manufactured by the same | |
KR101917822B1 (en) | Production method of cirsimaritin fortified thistle concentrate using Lactobacillus plantarum KCCM 11322 strain | |
KR20160097936A (en) | Platy codon beverage and manufacture process thereof | |
CN107594410A (en) | One kind is without sulphur dried persimmon and preparation method thereof | |
CN107410466A (en) | A kind of natural strawberry antistaling agent and its application method | |
KR102313373B1 (en) | Composition comprising fermented Poncirus trifoliata extract with both of antimicrobial and antifungal activity and methods of preparation thereof | |
KR102151573B1 (en) | Herb vinegar and manufacturing method thereof | |
KR101535896B1 (en) | Method of preparing eriobotrya japonica tea beverage | |
CN107853388A (en) | A kind of natural bio-preservative and preparation method thereof | |
CN106262308A (en) | A kind of processing method of flexible package Herba corydalis edulis | |
CN103141567A (en) | Litchi chinensis preservative based on Chinese medicinal herbs and preparation method thereof | |
CN105211871B (en) | A kind of preparation method of Moringa cauline leaf deep processed product | |
CN107347983A (en) | A kind of Kiwi berry fresh-keeping liquid, its preparation method and preservation method | |
CN107668184A (en) | A kind of Chinese herbal medicine extraction antistaling agent of egg and preparation method thereof | |
Archana et al. | Studies on preparation and storage of tamarind squash | |
CN106927942A (en) | A kind of small watermelon plantation fertilizer special for organic and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180420 |