CN107892957B - 一种醇基液体燃料及其制备方法 - Google Patents

一种醇基液体燃料及其制备方法 Download PDF

Info

Publication number
CN107892957B
CN107892957B CN201711374327.5A CN201711374327A CN107892957B CN 107892957 B CN107892957 B CN 107892957B CN 201711374327 A CN201711374327 A CN 201711374327A CN 107892957 B CN107892957 B CN 107892957B
Authority
CN
China
Prior art keywords
parts
alcohol
based liquid
liquid fuel
additive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201711374327.5A
Other languages
English (en)
Other versions
CN107892957A (zh
Inventor
车春玲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Linyi Xinghuo Intellectual Property Service Co.,Ltd.
Original Assignee
Shandong Lianxing Energy Group Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Lianxing Energy Group Co ltd filed Critical Shandong Lianxing Energy Group Co ltd
Priority to CN201711374327.5A priority Critical patent/CN107892957B/zh
Publication of CN107892957A publication Critical patent/CN107892957A/zh
Application granted granted Critical
Publication of CN107892957B publication Critical patent/CN107892957B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1608—Well defined compounds, e.g. hexane, benzene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C10L1/1832—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852—Ethers; Acetals; Ketals; Orthoesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/1915—Esters ester radical containing compounds; ester ethers; carbonic acid esters complex esters (at least 3 ester bonds)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/20—Organic compounds containing halogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/08—Inhibitors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/08—Inhibitors
    • C10L2230/088—Inhibitors for inhibiting or avoiding odor
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

本发明属于液体燃料技术领域，具体涉及一种高热值醇基液体燃料及其制备方法，包括以下重量份的原料：甲醇85‑90份、C12燃料油10‑15份、辛醇5‑10份、甲缩醛15‑20份、除臭剂1‑4份、添加剂10‑15份，所述添加剂包括以下重量份的原料：乙醇5‑10份、三乙酸甘油酯3‑5份、阳离子氟碳表面活性剂4‑7份、二戊铁3‑5份、烃类化合物10‑15份、助燃剂10‑15份、稳定剂3‑5份、抗爆剂3‑5份。本发明所述的高热值醇基液体燃料各组分相互配合，燃烧充分彻底、燃烧热值高、无积碳现象产生，且与汽油具有较好的互溶性和抗腐蚀性能，具有较好的汽化性和正效加和性。

Description

一种醇基液体燃料及其制备方法
技术领域
本发明属于液体燃料技术领域，具体涉及一种醇基液体燃料及其制备方法。
背景技术
在世界能源紧张的大背景下，各国都在投入人力物力大力开发替代能源。其中醇基燃料是新发展起来的一种新型能源，它比煤更环保，比石油基燃料油更加经济，由于醇基自身含氧，因此燃烧时需氧量少，且能充分燃烧，具有清洁卫生、安全环保、使用方便、廉价等优点，因此醇基燃料是未来最具有潜力的新型代替再生资源，属于国家“十一五”期间鼓励发展的生物清洁能源。现有的技术中醇基燃料存在以下缺点：甲醇与汽油互不相溶，燃烧不充分，动力小、油耗大，容易产生爆震，容易对金属形成腐蚀，长期使用会对燃烧设备的使用寿命造成严重影响。
发明内容
本发明要解决的技术问题是研制出一种醇基液体燃料，具体技术方案如下：
一种醇基液体燃料，包括以下重量份的原料：甲醇85-90份、C12燃料油10-15份、辛醇5-10份、甲缩醛15-20份、除臭剂1-4份、添加剂10-15份，所述添加剂包括以下重量份的原料：乙醇5-10份、三乙酸甘油酯3-5份、阳离子氟碳表面活性剂4-7份、二戊铁3-5份、烃类化合物10-15份、助燃剂10-15份、稳定剂3-5份、抗爆剂3-5份。
作为优选，所述醇基液体燃料，包括以下重量份的原料：甲醇85份、C12燃料油15份、辛醇10份、甲缩醛15份、除臭剂1份、添加剂10份，所述添加剂包括以下重量份的原料：乙醇5份、三乙酸甘油酯5份、阳离子氟碳表面活性剂4份、二戊铁5份、烃类化合物10份、助燃剂15份、稳定剂3份、抗爆剂3份。
作为优选，所述醇基液体燃料，包括以下重量份的原料：甲醇90份、C12燃料油10份、辛醇5份、甲缩醛20份、除臭剂4份、添加剂15份，所述添加剂包括以下重量份的原料：乙醇10份、三乙酸甘油酯3份、阳离子氟碳表面活性剂7份、二戊铁3份、烃类化合物15份、助燃剂10份、稳定剂5份、抗爆剂5份。
作为优选，所述烃类化合物包括重量比为3:1:5的戊烷、己烷、异辛烷。
作为优选，所述助燃剂包括重量比为4:2:1的二甲醚、异丙醚、甲基叔丁基醚。
作为优选，所述稳定剂为重量比为3:5的二叔丁基对甲酚和异丁胺。
作为优选，所述抗爆剂为甲基环二烯三羰基锰。
作为优选，所述除臭剂为工业香精或除味樟脑。
本发明还公开了上述醇基液体燃料的制备方法，采用如下技术方案：
一种醇基液体燃料的制备方法，包括：
(1)制备添加剂：在常温常压条件下，先将乙醇、三乙酸甘油酯、烃类化合物和助燃剂加入配置器中混合均匀；然后再将阳离子氟碳表面活性剂、稳定剂、抗爆剂、二戊铁依次加入配置器中混合均匀；将上述混好的试剂通过防爆离心泵循环混合3-5h，然后静置1h，即得到所述添加剂，备用；
(2)先将甲醇、C12燃料油、辛醇、甲缩醛加入配置器中，混合均匀，备用；
(3)再向配置器中加入除臭剂、添加剂，混合均匀，即得到所述醇基液体燃料。
本发明的有益效果
(1)本发明所述的醇基液体燃料采用甲醇作为主燃组分，燃烧完全彻底，无三废产生，有效的保护了环境；采用C12燃料油作为热值提高组分，显著的提高燃料的热值；辛醇、甲缩醛作为助溶剂加入，可以使甲醇与其他组分互溶，而且还可使醇基液体燃料与传统汽油混合使用，互溶性好；加入除臭剂可去除燃料中的异味。
(2)添加了高效的添加剂，添加剂中乙醇作为点火剂；二茂铁是一种橙黄色固体，它不溶于水，溶于汽、柴油、甲醇的有机金属化合物，化学性质稳定，具有抗癌活性，在本发明中用于节能消烟剂和阳离子氟碳表面活性剂配成热值提高剂；三乙酸甘油酯除了可与其他原料配伍，提高燃料的闪点外，还能够在金属的表面形成保护膜，隔离了腐蚀物质与金属表面的接触，从而可以起到防止燃烧对金属的腐蚀，增强了醇基液体燃料的抗腐蚀性能；烃类化合物、助燃剂的加入，可以大大提高燃料的热值；加入稳定剂可保证燃料在使用过程中的质量稳定；抗爆剂的主要作用是抗爆，可大幅提高燃料的安全性。
(3)本发明所述的醇基液体燃料各组分相互配合，燃烧充分彻底、燃烧热值高、无积碳现象产生，燃料热值可达28000kJ/kg。且与汽油具有较好的互溶性和抗腐蚀性能，具有较好的汽化性和正效加和性，因此本发明提供的醇基液体燃料作为高效、环保的替代燃料具有较大的发展潜力和重要的经济效益、社会价值。本发明所述的醇基液体燃料的制备方法，制作工艺简单，易于操作。
具体实施方式
实施例1
一种醇基液体燃料，包括以下重量份的原料：甲醇85份、C12燃料油15份、辛醇10份、甲缩醛15份、除臭剂1份、添加剂10份，所述添加剂包括以下重量份的原料：乙醇5份、三乙酸甘油酯5份、阳离子氟碳表面活性剂4份、二戊铁5份、烃类化合物10份、助燃剂15份、稳定剂3份、抗爆剂3份。
作为优选，所述烃类化合物包括重量比为3:1:5的戊烷、己烷、异辛烷。
作为优选，所述助燃剂包括重量比为4:2:1的二甲醚、异丙醚、甲基叔丁基醚。
作为优选，所述稳定剂为重量比为3:5的二叔丁基对甲酚和异丁胺。
作为优选，所述抗爆剂为甲基环二烯三羰基锰。
作为优选，所述除臭剂为工业香精或除味樟脑。
实施例2
一种醇基液体燃料，包括以下重量份的原料：甲醇90份、C12燃料油10份、辛醇5份、甲缩醛20份、除臭剂4份、添加剂15份，所述添加剂包括以下重量份的原料：乙醇10份、三乙酸甘油酯3份、阳离子氟碳表面活性剂7份、二戊铁3份、烃类化合物15份、助燃剂10份、稳定剂5份、抗爆剂5份。
作为优选，所述烃类化合物包括重量比为3:1:5的戊烷、己烷、异辛烷。
作为优选，所述助燃剂包括重量比为4:2:1的二甲醚、异丙醚、甲基叔丁基醚。
作为优选，所述稳定剂为重量比为3:5的二叔丁基对甲酚和异丁胺。
作为优选，所述抗爆剂为甲基环二烯三羰基锰。
作为优选，所述除臭剂为工业香精或除味樟脑。
实施例3
一种醇基液体燃料，其特征在于，包括以下重量份的原料：甲醇88份、C12燃料油12份、辛醇8份、甲缩醛16份、除臭剂3份、添加剂13份，所述添加剂包括以下重量份的原料：乙醇8份、三乙酸甘油酯4份、阳离子氟碳表面活性剂5份、二戊铁4份、烃类化合物12份、助燃剂14份、稳定剂4份、抗爆剂4份。
作为优选，所述烃类化合物包括重量比为3:1:5的戊烷、己烷、异辛烷。
作为优选，所述助燃剂包括重量比为4:2:1的二甲醚、异丙醚、甲基叔丁基醚。
作为优选，所述稳定剂为重量比为3:5的二叔丁基对甲酚和异丁胺。
作为优选，所述抗爆剂为甲基环二烯三羰基锰。
作为优选，所述除臭剂为工业香精或除味樟脑。
实施例4
一种醇基液体燃料，包括以下重量份的原料：甲醇86份、C12燃料油14份、辛醇7份、甲缩醛19份、除臭剂2份、添加剂12份，所述添加剂包括以下重量份的原料：乙醇7份、三乙酸甘油酯3份、阳离子氟碳表面活性剂6份、二戊铁4份、烃类化合物12份、助燃剂11份、稳定剂3份、抗爆剂5份。
作为优选，所述烃类化合物包括重量比为3:1:5的戊烷、己烷、异辛烷。
作为优选，所述助燃剂包括重量比为4:2:1的二甲醚、异丙醚、甲基叔丁基醚。
作为优选，所述稳定剂为重量比为3:5的二叔丁基对甲酚和异丁胺。
作为优选，所述抗爆剂为甲基环二烯三羰基锰。
作为优选，所述除臭剂为工业香精或除味樟脑。
本发明还公开了上述醇基液体燃料的制备方法，采用如下技术方案：
实施例5
一种醇基液体燃料的制备方法，包括：
(1)制备添加剂：在常温常压条件下，先将乙醇、三乙酸甘油酯、烃类化合物和助燃剂加入配置器中混合均匀；然后再将阳离子氟碳表面活性剂、稳定剂、抗爆剂、二戊铁依次加入配置器中混合均匀；将上述混好的试剂通过防爆离心泵循环混合3-5h，然后静置1h，即得到所述添加剂，备用；
(2)先将甲醇、C12燃料油、辛醇、甲缩醛加入配置器中，混合均匀，备用；
(3)再向配置器中加入除臭剂、添加剂，混合均匀，即得到所述醇基液体燃料。
经过测设，本发明所述醇基液体燃料的优异性能如下表1所示。
表1.本发明所述醇基液体燃料的性能
Figure GDA0002456308690000051
Figure GDA0002456308690000061

Claims (4)

1.一种醇基液体燃料，其特征在于，包括以下重量份的原料：甲醇85-90份、C12燃料油10-15份、辛醇5-10份、甲缩醛15-20份、除臭剂1-4份、添加剂10-15份，所述添加剂包括以下重量份的原料：乙醇5-10份、三乙酸甘油酯3-5份、阳离子氟碳表面活性剂4-7份、二戊铁3-5份、烃类化合物10-15份、助燃剂10-15份、稳定剂3-5份、抗爆剂3-5份；
所述助燃剂包括重量比为4:2:1的二甲醚、异丙醚、甲基叔丁基醚；
所述稳定剂为重量比为3:5的二叔丁基对甲酚和异丁胺；
所述烃类化合物包括重量比为3:1:5的戊烷、己烷、异辛烷；
所述抗爆剂为甲基环二烯三羰基锰；
所述醇基液体燃料的制备方法，包括：
制备添加剂：在常温常压条件下，先将乙醇、三乙酸甘油酯、烃类化合物和助燃剂加入配置器中混合均匀；然后再将阳离子氟碳表面活性剂、稳定剂、抗爆剂、二戊铁依次加入配置器中混合均匀；将上述混好的试剂通过防爆离心泵循环混合3-5h，然后静置1h，即得到所述添加剂，备用；
先将甲醇、C12燃料油、辛醇、甲缩醛加入配置器中，混合均匀，备用；
再向配置器中加入除臭剂、添加剂，混合均匀，即得到所述醇基液体燃料。
2.根据权利要求1所述醇基液体燃料，其特征在于，包括以下重量份的原料：甲醇85份、C12燃料油15份、辛醇10份、甲缩醛15份、除臭剂1份、添加剂10份，所述添加剂包括以下重量份的原料：乙醇5份、三乙酸甘油酯5份、阳离子氟碳表面活性剂4份、二戊铁5份、烃类化合物10份、助燃剂15份、稳定剂3份、抗爆剂3份。
3.根据权利要求1所述醇基液体燃料，其特征在于，包括以下重量份的原料：甲醇90份、C12燃料油10份、辛醇5份、甲缩醛20份、除臭剂4份、添加剂15份，所述添加剂包括以下重量份的原料：乙醇10份、三乙酸甘油酯3份、阳离子氟碳表面活性剂7份、二戊铁3份、烃类化合物15份、助燃剂10份、稳定剂5份、抗爆剂5份。
4.根据权利要求1所述醇基液体燃料，其特征在于：所述除臭剂为工业香精或除味樟脑。
CN201711374327.5A 2017-12-19 2017-12-19 一种醇基液体燃料及其制备方法 Active CN107892957B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711374327.5A CN107892957B (zh) 2017-12-19 2017-12-19 一种醇基液体燃料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711374327.5A CN107892957B (zh) 2017-12-19 2017-12-19 一种醇基液体燃料及其制备方法

Publications (2)

Publication Number Publication Date
CN107892957A CN107892957A (zh) 2018-04-10
CN107892957B true CN107892957B (zh) 2020-07-31

Family

ID=61806759

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711374327.5A Active CN107892957B (zh) 2017-12-19 2017-12-19 一种醇基液体燃料及其制备方法

Country Status (1)

Country Link
CN (1) CN107892957B (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109097115A (zh) * 2018-09-07 2018-12-28 苟春 一种醇基燃料添加剂配方以及燃料
CN109628172A (zh) * 2019-01-16 2019-04-16 宁夏拓森环保能源有限公司 一种环保型燃料及其制备方法
CN113265276A (zh) * 2021-03-26 2021-08-17 叁久国际新能源科技有限公司 一种锅炉清洁燃料

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101412933A (zh) * 2007-10-15 2009-04-22 李隆梅 一种广谱环保醇基液体燃料及其制备方法
CN103173253A (zh) * 2013-02-28 2013-06-26 鲁书华 一种车用醇基复合燃料
CN103710055B (zh) * 2013-11-27 2015-03-25 湖北力瑞新能源科技有限公司 一种醇基液体燃料及其制作方法
CN105885967A (zh) * 2016-04-20 2016-08-24 上海千茂化工科技有限公司 一种高热值醇基液体燃料
CN106350128B (zh) * 2016-11-09 2017-11-07 黑龙江省能源环境研究院 一种醇基液体燃料及其添加剂

Also Published As

Publication number Publication date
CN107892957A (zh) 2018-04-10

Similar Documents

Publication Publication Date Title
CN107892957B (zh) 一种醇基液体燃料及其制备方法
CN103320186B (zh) 生物基甲醇汽油动力增强剂及其制备方法
CN104479764A (zh) 一种非金属纳米量子点复合添加剂及其改性高效环保甲醇燃料
CN103060032B (zh) 一种耐温微乳化甲醇柴油及其制备方法
CN105331398A (zh) 一种甲醇燃料
CN104650996B (zh) 一种燃料油及其制备方法
CN102504890A (zh) 一种复合型甲醇柴油及其制备方法
CN102559300A (zh) 一种车用醇醚柴油燃料及其配制方法
CN104726149A (zh) 一种生物基甲醇汽油复合助剂及生物基高比例甲醇汽油
CN104650994A (zh) 醇基清洁燃料
CN104263429A (zh) 一种醇基车用燃料
CN103695050B (zh) 一种车用甲醇汽油复合添加剂
CN102827654A (zh) 清洁车用燃料
CN102559294B (zh) 一种醇醚柴油
CN104232180A (zh) 甲醇柴油
CN103773519B (zh) 一种甲醇直馏汽油助溶剂
CN105505486A (zh) 汽车燃油组成物
CN104263436A (zh) 一种汽车燃料功能助剂
CN107841357A (zh) 一种军用高能醇基燃料添加剂及其制备方法
CN102443447B (zh) 柴油组合物和提高生物柴油氧化安定性的方法
CN102533357B (zh) 一种甲醇柴油
CN110724568A (zh) 一种甲醇基体混合清洁液体燃料及其制备方法
CN101275089B (zh) 提高生物柴油氧化安定性的方法
CN104263431A (zh) 一种汽车燃料组合物
CN104059700A (zh) 一种高效液体燃料添加剂及含有此添加剂的液体燃料

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20211123

Address after: Room 608, 6 / F, Zhongxing business enterprise development center, Pingshang Town, Lingang Economic Development Zone, Linyi City, Shandong Province

Patentee after: Linyi Xinghuo Intellectual Property Service Co.,Ltd.

Address before: 250101 comprehensive building a506, University Science Park, 750 Shunhua Road, high tech Zone, Jinan City, Shandong Province

Patentee before: SHANDONG LIANXING ENERGY GROUP Co.,Ltd.

TR01 Transfer of patent right