CN107892477A - A kind of frost shield and preparation method thereof - Google Patents
A kind of frost shield and preparation method thereof Download PDFInfo
- Publication number
- CN107892477A CN107892477A CN201711051875.4A CN201711051875A CN107892477A CN 107892477 A CN107892477 A CN 107892477A CN 201711051875 A CN201711051875 A CN 201711051875A CN 107892477 A CN107892477 A CN 107892477A
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- CN
- China
- Prior art keywords
- parts
- glass
- frost shield
- shield according
- frost
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B15/00—Drawing glass upwardly from the melt
- C03B15/14—Drawing tubes, cylinders, or rods from the melt
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
Abstract
This application discloses a kind of frost shield and preparation method thereof, include in parts by weight, 5 25 parts of 340 425 parts of cullet, 54 86 parts of quartz sand, 32 74 parts of soda ash, 10 20 parts of cerium oxide, 165 190 parts of aluminium hydroxide, 210 263 parts of prodan, 30 80 parts of kaolin, 72 104 parts of fluorite, 112 152 parts of barium sulfate, 23 41 parts of sodium nitrate, 12 37 parts of calcite, 20 50 parts of zinc oxide and magnesium sulfate.Thus, glass structure of the invention is simple, reasonable in design, is splashed after can effectively preventing glass breaking, moreover it is possible to adjusts temperature to control frost mist, its good sealing effect, service life length, has a wide range of application.
Description
Technical field
The present invention relates to glass, more particularly to a kind of frost shield and preparation method thereof.
Background technology
Glass：A kind of transparent semisolid, semiliquid material, contiguous network structure is formed in melting, in cooling procedure
Viscosity gradually increases and hardened and non crystallized silicates nonmetallic materials.The composition of simple glass chemical oxide
(Na2O·CaO·6SiO2), main component is silica.It is widely used in building, for every wind printing opacity, belonging to mixing
Thing.Separately there are the oxide for being mixed into some metals or salt and show the coloured glass of color, and pass through specific process system
Safety glass obtained etc..Sometimes some transparent plastics (such as polymethyl methacrylate) are also referred to as lucite.
Glass is a kind of non-crystalline solids of random structure (from microcosmic, glass is also a kind of liquid), its molecule
There is the arrangement of long-range order unlike crystal in space, and be similar to liquid has shortrange order like that.Glass is as solid
Specific profile is equally kept, is flowed unlike liquid with Action of Gravity Field.
Glass state material is usually quickly to be cooled down by molten mass and obtained, cooled during from molten state to glassy transition
Viscosity increased dramatically in journey, and particle has little time to do regular arrangement and form crystal, does not disengage latent heat, therefore, glass
State material contains higher interior energy than crystalline state material, and its energy belongs to metastable state between molten state and crystalline state.From
Mechanics viewpoint sees that glass is a kind of unstable upper state, for example the trend of low-energy state conversion be present, that is, has crystallization to incline
To, so, glass is a kind of metastable solids material.
The primary raw material of glass production has glass former, glass adjustment thing and glass intermediate, and remaining is auxiliary material.
Primary raw material guides oxide, intermediate oxide and the network external oxidation thing that network is formed into glass；Auxiliary material includes clear
Clear agent, fluxing agent, opacifiers, colouring agent, decolorising agent, Oxidizing and Reducing Agents etc..
Traditional Glass breadks easily and not antifog, many fields are very inconvenient when in use, and some manufacturers are on the two sides of glass
The film layer of anti-crushing is added, is disorderly flown after glass breaking can be prevented, reduction casualty rate, but the service life of this glass
Short, outer membrane is easily corroded.
The content of the invention
It is an object of the invention to provide a kind of frost shield and preparation method thereof, solves one in above-mentioned prior art problem
It is or multiple.
According to an aspect of the present invention, there is provided a kind of frost shield, include in parts by weight, cullet 340-425 parts,
Quartz sand 54-86 parts, soda ash 32-74 parts, cerium oxide 10-20 parts, aluminium hydroxide 165-190 parts, prodan 210-263 parts,
Kaolin 30-80 parts, fluorite 72-104 parts, barium sulfate 112-152 parts, sodium nitrate 23-41 parts, calcite 12-37 parts, oxidation
Zinc 20-50 parts and magnesium sulfate 5-25 parts.
In some embodiments：Include in parts by weight, 340 parts of cullet, 54 parts of quartz sand, 32 parts of soda ash, oxidation
10 parts of cerium, 165 parts of aluminium hydroxide, 210 parts of prodan, 30 parts of kaolin, 72 parts of fluorite, 112 parts of barium sulfate, sodium nitrate 23
Part, 12 parts of calcite, 20 parts of zinc oxide and 5 parts of magnesium sulfate.
In some embodiments：Include in parts by weight, 380 parts of cullet, 70 parts of quartz sand, 55 parts of soda ash, oxidation
15 parts of cerium, 177 parts of aluminium hydroxide, 235 parts of prodan, 66 parts of kaolin, 85 parts of fluorite, 128 parts of barium sulfate, sodium nitrate 35
Part, 30 parts of calcite, 35 parts of zinc oxide and 15 parts of magnesium sulfate.
In some embodiments：Include in parts by weight, 425 parts of cullet, 86 parts of quartz sand, 74 parts of soda ash, oxidation
20 parts of cerium, 190 parts of aluminium hydroxide, 263 parts of prodan, 80 parts of kaolin, 104 parts of fluorite, 152 parts of barium sulfate, sodium nitrate 41
Part, 37 parts of calcite, 50 parts of zinc oxide and 25 parts of magnesium sulfate.
In some embodiments：Cullet are flint glass.
Present invention also offers a kind of preparation method of above-mentioned frost shield, comprise the following steps:
Step 1：Among above-mentioned raw materials are positioned over into respective material container, the aniseed for loading dispensing is entered after being stirred
In pipe or feed bin；
Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed
The glass metal of predetermined viscosity, then be homogenized, clarify, discharge bubble, form flowable molten mass, viscosity is 102 Pa Secs
Clarification, exhaust bubble technological temperature are 1250 DEG C -1430 DEG C；
Step 3：Use trombone slide moulding process：Glass is drawn into through tube-pulling apparatus to the melten glass body formed in step 2
Manage and be molded, annealed, cooling, you can glass is made.
In some embodiments：Exhaust bubble technological temperature is 1250 DEG C.
In some embodiments：Exhaust bubble technological temperature is 1300 DEG C.
In some embodiments：Exhaust bubble technological temperature is 1430 DEG C.
In some embodiments：Chemical tempering or physical toughened processing are carried out to prepared glass.
The glass structure of the present invention is simple, reasonable in design, is splashed after can effectively preventing glass breaking, moreover it is possible to adjusts temperature
Frost mist is controlled, its good sealing effect, service life length, is had a wide range of application.
Embodiment
The present invention is described in further detail below by embodiment.
Embodiment 1：
Frost shield, include in parts by weight, 340 parts of cullet, 54 parts of quartz sand, 32 parts of soda ash, 10 parts of cerium oxide,
165 parts of aluminium hydroxide, 210 parts of prodan, 30 parts of kaolin, 72 parts of fluorite, 112 parts of barium sulfate, 23 parts of sodium nitrate, calcite
5 parts of 12 parts, 20 parts of zinc oxide and magnesium sulfate.
The preparation method of frost shield of the present invention：Comprise the following steps:
Step 1：Among above-mentioned raw materials are positioned over into respective material container, the aniseed for loading dispensing is entered after being stirred
In pipe or feed bin；
Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed
The glass metal of predetermined viscosity, then be homogenized, clarify, discharge bubble, form flowable molten mass, viscosity is 102 Pa Secs
Clarification, exhaust bubble technological temperature are 1250 DEG C；
Step 3：Use trombone slide moulding process：Glass is drawn into through tube-pulling apparatus to the melten glass body formed in step 2
Manage and be molded, annealed, cooling, you can glass is made.
In some embodiments：Chemical tempering or physical toughened processing are carried out to prepared glass.
Embodiment 2：
Frost shield, include in parts by weight, 380 parts of cullet, 70 parts of quartz sand, 55 parts of soda ash, 15 parts of cerium oxide,
177 parts of aluminium hydroxide, 235 parts of prodan, 66 parts of kaolin, 85 parts of fluorite, 128 parts of barium sulfate, 35 parts of sodium nitrate, calcite
15 parts of 30 parts, 35 parts of zinc oxide and magnesium sulfate.
The preparation method of frost shield of the present invention：Comprise the following steps:
Step 1：Among above-mentioned raw materials are positioned over into respective material container, the aniseed for loading dispensing is entered after being stirred
In pipe or feed bin；
Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed
The glass metal of predetermined viscosity, then be homogenized, clarify, discharge bubble, form flowable molten mass, viscosity is 102 Pa Secs
Clarification, exhaust bubble technological temperature are 1300 DEG C；
Step 3：Use trombone slide moulding process：Glass is drawn into through tube-pulling apparatus to the melten glass body formed in step 2
Manage and be molded, annealed, cooling, you can glass is made.
In some embodiments：Chemical tempering or physical toughened processing are carried out to prepared glass.
Embodiment 3：
Frost shield, include in parts by weight, 425 parts of cullet, 86 parts of quartz sand, 74 parts of soda ash, 20 parts of cerium oxide,
190 parts of aluminium hydroxide, 263 parts of prodan, 80 parts of kaolin, 104 parts of fluorite, 152 parts of barium sulfate, 41 parts of sodium nitrate, Fang Xie
25 parts of 37 parts of stone, 50 parts of zinc oxide and magnesium sulfate.
The preparation method of frost shield of the present invention：Comprise the following steps:
Step 1：Among above-mentioned raw materials are positioned over into respective material container, the aniseed for loading dispensing is entered after being stirred
In pipe or feed bin；
Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed
The glass metal of predetermined viscosity, then be homogenized, clarify, discharge bubble, form flowable molten mass, viscosity is 102 Pa Secs
Clarification, exhaust bubble technological temperature are 1430 DEG C；
Step 3：Use trombone slide moulding process：Glass is drawn into through tube-pulling apparatus to the melten glass body formed in step 2
Manage and be molded, annealed, cooling, you can glass is made.
In some embodiments：Chemical tempering or physical toughened processing are carried out to prepared glass.
In summary, glass structure of the invention is simple, reasonable in design, is splashed after can effectively preventing glass breaking, moreover it is possible to
Temperature is adjusted to control frost mist, its good sealing effect, service life length, is had a wide range of application.
Described above is only one embodiment of the present invention, it is noted that to those skilled in the art,
Without departing from the concept of the premise of the invention, some similar modification and improvement can also be made, these also should be regarded as this
Within the protection domain of invention.
Claims (10)
- A kind of 1. frost shield, it is characterised in that：Include in parts by weight, it is cullet 340-425 parts, quartz sand 54-86 parts, pure Alkali 32-74 parts, cerium oxide 10-20 parts, aluminium hydroxide 165-190 parts, prodan 210-263 parts, kaolin 30-80 parts, firefly Stone 72-104 parts, barium sulfate 112-152 parts, sodium nitrate 23-41 parts, calcite 12-37 parts, zinc oxide 20-50 parts and magnesium sulfate 5-25 parts.
- A kind of 2. frost shield according to claim 1, it is characterised in that：Include in parts by weight, 340 parts of cullet, 54 parts of quartz sand, 32 parts of soda ash, 10 parts of cerium oxide, 165 parts of aluminium hydroxide, 210 parts of prodan, 30 parts of kaolin, fluorite 72 Part, 112 parts of barium sulfate, 23 parts of sodium nitrate, 12 parts of calcite, 20 parts of zinc oxide and 5 parts of magnesium sulfate.
- A kind of 3. frost shield according to claim 2, it is characterised in that：Include in parts by weight, 380 parts of cullet, 70 parts of quartz sand, 55 parts of soda ash, 15 parts of cerium oxide, 177 parts of aluminium hydroxide, 235 parts of prodan, 66 parts of kaolin, fluorite 85 Part, 128 parts of barium sulfate, 35 parts of sodium nitrate, 30 parts of calcite, 35 parts of zinc oxide and 15 parts of magnesium sulfate.
- A kind of 4. frost shield according to claim 1, it is characterised in that：Include in parts by weight, 425 parts of cullet, 86 parts of quartz sand, 74 parts of soda ash, 20 parts of cerium oxide, 190 parts of aluminium hydroxide, 263 parts of prodan, 80 parts of kaolin, fluorite 104 Part, 152 parts of barium sulfate, 41 parts of sodium nitrate, 37 parts of calcite, 50 parts of zinc oxide and 25 parts of magnesium sulfate.
- A kind of 5. frost shield according to claim 1, it is characterised in that：The cullet are flint glass.
- A kind of 6. method for preparing any one of the claim 1-5 frost shields, it is characterised in that, comprise the following steps:Step 1：Among above-mentioned raw materials are positioned over into respective material container, after being stirred enter load dispensing big expects pipe or In feed bin；Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed predetermined Viscosity glass metal, then be homogenized, clarify, discharge bubble, form flowable molten mass, clarification that viscosity is 102 Pa Secs, Exhaust bubble technological temperature is 1250 DEG C -1430 DEG C；Step 3：Use trombone slide moulding process：Through tube-pulling apparatus glass tube is drawn into the melten glass body that is formed in step 2 and Shaping, annealed, cooling, you can glass is made.
- A kind of 7. preparation method of frost shield according to claim 6, it is characterised in that：The exhaust bubble technological temperature For 1250 DEG C.
- A kind of 8. preparation method of frost shield according to claim 6, it is characterised in that：The exhaust bubble technological temperature For 1300 DEG C.
- A kind of 9. preparation method of frost shield according to claim 6, it is characterised in that：The exhaust bubble technological temperature For 1430 DEG C.
- A kind of 10. preparation method of frost shield according to claim 6, it is characterised in that：Prepared glass is entered Row chemical tempering or physical toughened processing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711051875.4A CN107892477A (en) | 2017-10-30 | 2017-10-30 | A kind of frost shield and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711051875.4A CN107892477A (en) | 2017-10-30 | 2017-10-30 | A kind of frost shield and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107892477A true CN107892477A (en) | 2018-04-10 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711051875.4A Pending CN107892477A (en) | 2017-10-30 | 2017-10-30 | A kind of frost shield and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102177102A (en) * | 2008-10-10 | 2011-09-07 | 株式会社小原 | Glass ceramics and process for production thereof, process for producing sintered glass ceramics, process for producing complex, molded article having photocatalytic function, and hydrophilic molded article |
| CN104829132A (en) * | 2015-05-28 | 2015-08-12 | 南京亚欣照明有限公司 | Milky white glass lamp tube for LEDs, milky white bulb for LEDs, and their manufacturing method |
| CN105948480A (en) * | 2016-04-22 | 2016-09-21 | 芜湖新利德玻璃制品有限公司 | Impact-resistant sheet glass and preparation method thereof |
-
2017
- 2017-10-30 CN CN201711051875.4A patent/CN107892477A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102177102A (en) * | 2008-10-10 | 2011-09-07 | 株式会社小原 | Glass ceramics and process for production thereof, process for producing sintered glass ceramics, process for producing complex, molded article having photocatalytic function, and hydrophilic molded article |
| CN104829132A (en) * | 2015-05-28 | 2015-08-12 | 南京亚欣照明有限公司 | Milky white glass lamp tube for LEDs, milky white bulb for LEDs, and their manufacturing method |
| CN105948480A (en) * | 2016-04-22 | 2016-09-21 | 芜湖新利德玻璃制品有限公司 | Impact-resistant sheet glass and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 吴柏诚 等编著: "《玻璃制造技术》", 31 October 1993, 北京：中国轻工业出版社 * |
| 孙静 等主编: "《建筑材料》", 31 August 2015, 成都：西南交通大学出版社 * |
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Application publication date: 20180410 |
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| RJ01 | Rejection of invention patent application after publication |