CN105948480A - Impact-resistant sheet glass and preparation method thereof - Google Patents
Impact-resistant sheet glass and preparation method thereof Download PDFInfo
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- CN105948480A CN105948480A CN201610255016.6A CN201610255016A CN105948480A CN 105948480 A CN105948480 A CN 105948480A CN 201610255016 A CN201610255016 A CN 201610255016A CN 105948480 A CN105948480 A CN 105948480A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
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Abstract
The invention discloses an impact-resistant sheet glass and a preparation method thereof. The preparation method comprises the following steps: 1) subjecting metavanadate, borax, soluble carbonate and water to a hydro-thermal reaction under an alkaline condition, carrying out filtering and preparing an active composition from the obtained filter cake; 2) mixing quartz sand, soda ash, calcite, fluorite, potassium nitrate, alumina and the active composition, carrying out primary melting and then carrying out primary cooling so as to obtain a cooled product; and 3) mixing kaolin, manganese dioxide, rare earth oxide and the cooled product, carrying out secondary melting and then carrying out secondary cooling so as to obtain the impact-resistant sheet glass. The impact-resistant sheet glass prepared by using the method has excellent mechanical strength; and the method uses easily-available raw materials and is simple in operation.
Description
Technical field
The present invention relates to plate glass, in particular it relates to a kind of impact resistance plate glass and preparation method thereof.
Background technology
Glass is a kind of transparent solid, forms contiguous network structure, viscosity in cooling procedure when melted
It is gradually increased and hardens and non crystallized silicates nonmetallic materials.Simple glass main component is dioxy
SiClx, is widely used in building, is used for every wind printing opacity, belongs to mixture.Separately it is mixed into some gold
Belong to oxide or salt and show the coloured glass of color, and by specific process prepare tempering
Glass etc..
Although glass has been widely used for producing and in life, but due to the mechanical strength of glass self
Relatively low so that glass is difficult to be applicable to the field strict for requirement of mechanical strength.
Summary of the invention
It is an object of the invention to provide a kind of impact resistance plate glass and preparation method thereof, by the party's legal system
Plate glass obtained by Bei has the mechanical strength of excellence, and the method raw material is easy to get simultaneously, and operation is simple.
To achieve these goals, the invention provides the preparation method of a kind of impact resistance plate glass, should
Preparation method includes:
1) metavanadate, Borax, soluble carbonate salt and water are carried out in the basic conditions hydro-thermal reaction,
Then leaching filter cake is crossed with prepared active compound；
2) quartz sand, soda, calcite, fluorite, potassium nitrate, aluminium oxide and active compound are mixed
Carry out first after conjunction to melt, then carry out the first cooling with prepared cooled product；
3) carry out second after Kaolin, manganese dioxide, rare earth oxide and cooled product being mixed to melt,
Then the second cooling is carried out with prepared impact resistance plate glass.
Present invention also offers a kind of impact resistance plate glass, this impact resistance plate glass is by above-mentioned side
Method is prepared.
By technique scheme, the present invention first pass through metavanadate, Borax, soluble carbonate salt and
Synergism between water carries out hydro-thermal reaction in the basic conditions and prepares active compound, then passes through stone
Synergism between sand, soda, calcite, fluorite, potassium nitrate, aluminium oxide and active compound
Prepare cooled product, the finally association between Kaolin, manganese dioxide, rare earth oxide and cooled product
Same-action prepares plate glass.In the method, by utilizing the collaborative work between each raw material and each operation
With so that the plate glass prepared has the mechanical strength of excellence.Meanwhile, the preparation side that the present invention provides
Method raw material is easy to get, and operation is simple so that the method can be widely popularized.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that this place is retouched
The detailed description of the invention stated is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides the preparation method of a kind of impact resistance plate glass, this preparation method includes:
1) metavanadate, Borax, soluble carbonate salt and water are carried out in the basic conditions hydro-thermal reaction,
Then leaching filter cake is crossed with prepared active compound；
2) quartz sand, soda, calcite, fluorite, potassium nitrate, aluminium oxide and active compound are mixed
Carry out first after conjunction to melt, then carry out the first cooling with prepared cooled product；
3) carry out second after Kaolin, manganese dioxide, rare earth oxide and cooled product being mixed to melt,
Then the second cooling is carried out with prepared impact resistance plate glass.
Step 1 in the present invention) in, the concrete consumption of each material can select in wide scope, for
The plate glass prepared is made to have more excellent mechanical strength, it is preferable that in step 1) in, phase
For the metavanadate of 100 weight portions, the consumption of Borax is 14-20 weight portion, soluble carbonate salt
Consumption is 120-140 weight portion, and the consumption of water is 200-300 weight portion.
Step 1 in the present invention) in, the actual conditions of hydro-thermal reaction can select in wide scope,
So that the plate glass prepared has more excellent mechanical strength, it is preferable that in step 1) in,
Hydro-thermal reaction at least meets following condition: reaction temperature is 550-570 DEG C, and the response time is 36-48h,
PH is 9-12.
Step 1 in the present invention) in, the concrete kind of metavanadate and soluble carbonate salt can be at width
In the range of select so that prepare plate glass there is more excellent mechanical strength, it is preferable that
In step 1) in, metavanadate one or many in potassium metavanadate, sodium metavanadate and ammonium metavanadate
Kind；One or more in potassium carbonate, sodium carbonate and ammonium carbonate of soluble carbonate salt.
Step 2 in the present invention) in, the concrete consumption of each material can select in wide scope, for
The plate glass prepared is made to have more excellent mechanical strength, it is preferable that in step 2) in, phase
For the quartz sand of 100 weight portions, the consumption of soda is 22-28 weight portion, and the consumption of calcite is 46-52
Weight portion, the consumption of fluorite is 22-28 weight portion, and the consumption of potassium nitrate is 15-30 weight portion, oxidation
The consumption of aluminum is 2-6 weight portion, and the consumption of active compound is 30-46 weight portion.
Step 2 in the present invention) in, the first melted and the first cooling actual conditions can be at wide model
Enclose interior selection, so that the plate glass prepared has more excellent mechanical strength, it is preferable that in step
Rapid 2), in, first melted at least meets following condition: melt temperature is 1820-1870 DEG C, time melted
Between be 6-10h；The chilling temperature of the first cooling is 15-20 DEG C, and until the temperature of thing to be cooled is less than
30 DEG C terminate refrigerating work procedure.
Step 3 in the present invention) in, the consumption of each material can select, in order to make in wide scope
The plate glass that must prepare has more excellent mechanical strength, it is preferable that in step 3) in, relative to
The Kaolin of 100 weight portions, the consumption of manganese dioxide is 45-51 weight portion, the consumption of rare earth oxide
For 12-16 weight portion, the consumption of cooled product is 600-690 weight portion.
Step 3 in the present invention) in, the second melted and the second cooling actual conditions can be at wide model
Enclose interior selection, so that the plate glass prepared has more excellent mechanical strength, it is preferable that in step
Rapid 3), in, second melted at least meets following condition: melt temperature is 1890-1950 DEG C, time melted
Between be 3-5h；The chilling temperature of the second cooling is 15-20 DEG C, and until the temperature of thing to be cooled is less than
30 DEG C terminate refrigerating work procedure.
Step 3 in the present invention) in, the concrete kind of rare earth oxide can select in wide scope,
So that the plate glass prepared has more excellent mechanical strength, it is preferable that in step 3) in,
One or more in lanthana, praseodymium oxide, Disamarium trioxide and dysprosia of rare earth oxide.
Present invention also offers a kind of impact resistance plate glass, this impact resistance plate glass is by above-mentioned side
Method is prepared.
Hereinafter will be described the present invention by embodiment.
Embodiment 1
1) by metavanadate (sodium metavanadate), Borax, soluble carbonate salt (sodium carbonate) and water according to
The weight ratio of 100:17:130:260 carries out hydro-thermal under conditions of pH is 11 and temperature is 560 DEG C
Reaction 40h, then crosses leaching filter cake with prepared active compound；
2) quartz sand, soda, calcite, fluorite, potassium nitrate, aluminium oxide and active compound are pressed
Melt according to carrying out first at 1850 DEG C after the weight ratio mixing of 100:25:49:26:19:5:36
8h, then carries out the first cooling to prepare the cooled product less than 30 DEG C at 18 DEG C；
3) by Kaolin, manganese dioxide, rare earth oxide (Disamarium trioxide) and cooled product according to 100:
At 1920 DEG C, carry out second after the weight ratio mixing of 49:14:650 and melt 4h, then at 18 DEG C
Carry out the second cooling to prepare the impact resistance plate glass A1 less than 30 DEG C.
Embodiment 2
1) by metavanadate (potassium metavanadate), Borax, soluble carbonate salt (potassium carbonate) and water according to
It is anti-that the weight ratio of 100:14:120:200 carries out hydro-thermal under conditions of pH is 9 and temperature is 550 DEG C
Answer 36h, then cross leaching filter cake with prepared active compound；
2) quartz sand, soda, calcite, fluorite, potassium nitrate, aluminium oxide and active compound are pressed
Melt according to carrying out first at 1820 DEG C after the weight ratio mixing of 100:22:46:22:15:2:30
6h, then carries out the first cooling to prepare the cooled product less than 30 DEG C at 15 DEG C；
3) by Kaolin, manganese dioxide, rare earth oxide (lanthana) and cooled product according to 100:
At 189 DEG C, carry out second after the weight ratio mixing of 45:12:600 and melt 3h, then enter at 15 DEG C
Row second cools down to prepare the impact resistance plate glass A2 less than 30 DEG C.
Embodiment 3
1) by metavanadate (ammonium metavanadate), Borax, soluble carbonate salt (ammonium carbonate) and water according to
The weight ratio of 100:20:140:300 carries out hydro-thermal under conditions of pH is 12 and temperature is 570 DEG C
Reaction 48h, then crosses leaching filter cake with prepared active compound；
2) quartz sand, soda, calcite, fluorite, potassium nitrate, aluminium oxide and active compound are pressed
Melt according to carrying out first at 1870 DEG C after the weight ratio mixing of 100:28:52:28:30:6:46
10h, then carries out the first cooling to prepare the cooled product less than 30 DEG C at 20 DEG C；
3) by Kaolin, manganese dioxide, rare earth oxide (dysprosia) and cooled product according to 100:
At 1950 DEG C, carry out second after the weight ratio mixing of 51:16:690 and melt 5h, then at 20 DEG C
Carry out the second cooling to prepare the impact resistance plate glass A3 less than 30 DEG C.
Comparative example 1
Carry out preparing plate glass B1, except for the difference that, step 1 according to the method for embodiment 1) in do not make
Use metavanadate.
Comparative example 2
Carry out preparing plate glass B2, except for the difference that, step 1 according to the method for embodiment 1) in do not make
Use Borax.
Comparative example 3
Carry out preparing plate glass B3, except for the difference that, step 2 according to the method for embodiment 1) in do not make
Use active compound.
Comparative example 4
Carry out preparing plate glass B4, except for the difference that, step 2 according to the method for embodiment 1) in do not make
Use Kaolin.
Comparative example 5
Carry out preparing plate glass B4, except for the difference that, step 2 according to the method for embodiment 1) in do not make
Use rare earth oxide.
Detection example 1
Above-mentioned prepared plate glass is carried out mechanical strength detection, main by resistance in this test example
Compressive Strength and impact energy values reaction mechanical strength, the numerical value of burst strength and impact energy values is the biggest,
Representing that the mechanical strength of plate glass is the most excellent, concrete outcome is shown in Table 1.
Table 1
| Burst strength/MPa | Impact energy values/N m | |
| A1 | 3.4 | 3.5 |
| A2 | 3.2 | 3.4 |
| A3 | 3.3 | 3.3 |
| B1 | 2.3 | 2.0 |
| B2 | 2.2 | 2.1 |
| B3 | 2.1 | 1.8 |
| B4 | 2.2 | 2.2 |
| B5 | 2.0 | 1.9 |
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited to above-mentioned reality
Execute the detail in mode, in the technology concept of the present invention, can be to the technical side of the present invention
Case carries out multiple simple variant, and these simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technology described in above-mentioned detailed description of the invention is special
Levy, in the case of reconcilable, can be combined by any suitable means, in order to avoid need not
The repetition wanted, various possible compound modes are illustrated by the present invention the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as its
Without prejudice to the thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (10)
1. the preparation method of an impact resistance plate glass, it is characterised in that described preparation method includes:
1) metavanadate, Borax, soluble carbonate salt and water are carried out in the basic conditions hydro-thermal reaction, then cross leaching filter cake with prepared active compound；
2) carry out first after quartz sand, soda, calcite, fluorite, potassium nitrate, aluminium oxide and described active compound being mixed to melt, then carry out the first cooling with prepared cooled product；
3) carry out second after Kaolin, manganese dioxide, rare earth oxide and described cooled product being mixed to melt, then carry out the second cooling with prepared impact resistance plate glass.
Preparation method the most according to claim 1, wherein, in step 1) in, described metavanadate relative to 100 weight portions, the consumption of described Borax is 14-20 weight portion, and the consumption of described soluble carbonate salt is 120-140 weight portion, and the consumption of described water is 200-300 weight portion.
Preparation method the most according to claim 2, wherein, in step 1) in, described hydro-thermal reaction at least meets following condition: reaction temperature is 550-570 DEG C, the response time be 36-48h, pH be 9-12.
4. according to the preparation method described in any one in claim 1-3, wherein, in step 1) in, one or more in potassium metavanadate, sodium metavanadate and ammonium metavanadate of described metavanadate；One or more in potassium carbonate, sodium carbonate and ammonium carbonate of described soluble carbonate salt.
Preparation method the most according to claim 4, wherein, in step 2) in, relative to the described quartz sand of 100 weight portions, the consumption of described soda is 22-28 weight portion, and the consumption of described calcite is 46-52 weight portion, the consumption of described fluorite is 22-28 weight portion, the consumption of described potassium nitrate is 15-30 weight portion, and the consumption of described aluminium oxide is 2-6 weight portion, and the consumption of described active compound is 30-46 weight portion.
Preparation method the most according to claim 5, wherein, in step 2) in, described first melted at least meets following condition: melt temperature is 1820-1870 DEG C, and the melting time is 6-10h；
The chilling temperature of described first cooling is 15-20 DEG C, and until the temperature of thing to be cooled terminates refrigerating work procedure less than 30 DEG C.
7. according to the preparation method described in claim 5 or 6, wherein, in step 3) in, described Kaolin relative to 100 weight portions, the consumption of described manganese dioxide is 45-51 weight portion, the consumption of described rare earth oxide is 12-16 weight portion, and the consumption of described cooled product is 600-690 weight portion.
Preparation method the most according to claim 7, wherein, in step 3) in, described second melted at least meets following condition: melt temperature is 1890-1950 DEG C, and the melting time is 3-5h；
The chilling temperature of described second cooling is 15-20 DEG C, and until the temperature of thing to be cooled terminates refrigerating work procedure less than 30 DEG C.
9. according to the preparation method described in claim 7 or 8, wherein, in step 3) in, one or more in lanthana, praseodymium oxide, Disamarium trioxide and dysprosia of described rare earth oxide.
10. an impact resistance plate glass, it is characterised in that described impact resistance plate glass is prepared by the method described in any one in claim 1-9.
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| CN201610255016.6A CN105948480B (en) | 2016-04-22 | 2016-04-22 | Impact resistance plate glass and preparation method thereof |
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|---|---|---|---|
| CN201610255016.6A CN105948480B (en) | 2016-04-22 | 2016-04-22 | Impact resistance plate glass and preparation method thereof |
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| CN105948480B CN105948480B (en) | 2018-01-30 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107892476A (en) * | 2017-10-30 | 2018-04-10 | 江苏铁锚玻璃股份有限公司 | A kind of splashproof glass and preparation method thereof |
| CN107892477A (en) * | 2017-10-30 | 2018-04-10 | 江苏铁锚玻璃股份有限公司 | A kind of frost shield and preparation method thereof |
| CN107892473A (en) * | 2017-10-30 | 2018-04-10 | 江苏铁锚玻璃股份有限公司 | A kind of anti-explosion glass and preparation method thereof |
| CN108483905A (en) * | 2018-05-14 | 2018-09-04 | 江苏铁锚玻璃股份有限公司 | A kind of vehicle glass and its manufacturing method |
| CN108585526A (en) * | 2018-05-15 | 2018-09-28 | 江苏铁锚玻璃股份有限公司 | A kind of aircraft glass and its manufacturing method |
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| CN102515563A (en) * | 2011-11-03 | 2012-06-27 | 中国科学院上海硅酸盐研究所 | Organic vanadium source for preparation of vanadium dioxide intelligent temperature control film and preparation method of film |
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| JPH09202650A (en) * | 1996-01-24 | 1997-08-05 | Central Glass Co Ltd | Water-repellent, oil-repellent and antistaining membrane and its formation |
| US20100077837A1 (en) * | 2008-10-01 | 2010-04-01 | Fryxell Glen E | Porous Thin Film and Process for Analyte Preconcentration and Determination |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107892476A (en) * | 2017-10-30 | 2018-04-10 | 江苏铁锚玻璃股份有限公司 | A kind of splashproof glass and preparation method thereof |
| CN107892477A (en) * | 2017-10-30 | 2018-04-10 | 江苏铁锚玻璃股份有限公司 | A kind of frost shield and preparation method thereof |
| CN107892473A (en) * | 2017-10-30 | 2018-04-10 | 江苏铁锚玻璃股份有限公司 | A kind of anti-explosion glass and preparation method thereof |
| CN108483905A (en) * | 2018-05-14 | 2018-09-04 | 江苏铁锚玻璃股份有限公司 | A kind of vehicle glass and its manufacturing method |
| CN108585526A (en) * | 2018-05-15 | 2018-09-28 | 江苏铁锚玻璃股份有限公司 | A kind of aircraft glass and its manufacturing method |
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| CN105948480B (en) | 2018-01-30 |
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