CN107892473A - A kind of anti-explosion glass and preparation method thereof - Google Patents
A kind of anti-explosion glass and preparation method thereof Download PDFInfo
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- CN107892473A CN107892473A CN201711033031.7A CN201711033031A CN107892473A CN 107892473 A CN107892473 A CN 107892473A CN 201711033031 A CN201711033031 A CN 201711033031A CN 107892473 A CN107892473 A CN 107892473A
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- parts
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- cullet
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B15/00—Drawing glass upwardly from the melt
- C03B15/14—Drawing tubes, cylinders, or rods from the melt
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Glass Compositions (AREA)
Abstract
This application discloses a kind of anti-explosion glass and preparation method thereof, include in parts by weight, 5 25 parts of 255 433 parts of cullet, 48 86 parts of quartz sand, 29 74 parts of toluenesulfonic acid sodium salt, 10 20 parts of ethylene glycol monobutyl ether, 165 199 parts of silane coupler, 210 287 parts of prodan, 27 80 parts of kaolin, 72 104 parts of fluorite, 19 152 parts of polystyrene, 23 41 parts of sodium nitrate, 9 41 parts of calcite, 20 50 parts of polyester resin and ethoxylated dodecyl alcohol.Thus, glass structure of the invention is simple, reasonable in design, can effectively prevent, by explosion, service life length, having a wide range of application.
Description
Technical field
The present invention relates to glass, more particularly to a kind of anti-explosion glass and preparation method thereof.
Background technology
Glass：A kind of transparent semisolid, semiliquid material, contiguous network structure is formed in melting, in cooling procedure
Viscosity gradually increases and hardened and non crystallized silicates nonmetallic materials.The composition of simple glass chemical oxide
(Na2OCaO6SiO2), main component is silica.It is widely used in building, for every wind printing opacity, belonging to mixing
Thing.Separately there are the oxide for being mixed into some metals or salt and show the coloured glass of color, and pass through specific process system
Safety glass obtained etc..Sometimes some transparent plastics (such as polymethyl methacrylate) are also referred to as lucite.
Glass is a kind of non-crystalline solids of random structure (from microcosmic, glass is also a kind of liquid), its molecule
There is the arrangement of long-range order unlike crystal in space, and be similar to liquid has shortrange order like that.Glass is as solid
Specific profile is equally kept, is flowed unlike liquid with Action of Gravity Field.
Glass state material is usually quickly to be cooled down by molten mass and obtained, cooled during from molten state to glassy transition
Viscosity increased dramatically in journey, and particle has little time to do regular arrangement and form crystal, does not disengage latent heat, therefore, glass
State material contains higher interior energy than crystalline state material, and its energy belongs to metastable state between molten state and crystalline state.From
Mechanics viewpoint sees that glass is a kind of unstable upper state, for example the trend of low-energy state conversion be present, that is, has crystallization to incline
To, so, glass is a kind of metastable solids material.
The primary raw material of glass production has glass former, glass adjustment thing and glass intermediate, and remaining is auxiliary material.
Primary raw material guides oxide, intermediate oxide and the network external oxidation thing that network is formed into glass；Auxiliary material includes clear
Clear agent, fluxing agent, opacifiers, colouring agent, decolorising agent, Oxidizing and Reducing Agents etc..
Traditional glass technology formula is simple, and without blowout resistant function, service life is short, and application field is smaller.
The content of the invention
It is an object of the invention to provide a kind of anti-explosion glass and preparation method thereof, solves one in above-mentioned prior art problem
It is individual or multiple.
According to an aspect of the present invention, there is provided a kind of anti-explosion glass, include in parts by weight, cullet 255-433
Part, quartz sand 48-86 parts, toluenesulfonic acid sodium salt 29-74 parts, ethylene glycol monobutyl ether 10-20 parts, silane coupler 165-199 parts, fluorine
Sodium metasilicate 210-287 parts, kaolin 27-80 parts, fluorite 72-104 parts, polystyrene 19-152 parts, sodium nitrate 23-41 parts, side
Solve stone 9-41 parts, polyester resin 20-50 parts and ethoxylated dodecyl alcohol 5-25 parts.
In some embodiments：Include in parts by weight, 255 parts of cullet, 48 parts of quartz sand, toluenesulfonic acid sodium salt 29
Part, 10 parts of ethylene glycol monobutyl ether, 165 parts of silane coupler, 210 parts of prodan, 27 parts of kaolin, 72 parts of fluorite, polyphenyl second
5 parts of 19 parts of alkene, 23 parts of sodium nitrate, 9 parts of calcite, 20 parts of polyester resin and ethoxylated dodecyl alcohol.
In some embodiments：Include in parts by weight, 380 parts of cullet, 70 parts of quartz sand, toluenesulfonic acid sodium salt 55
Part, 15 parts of ethylene glycol monobutyl ether, 177 parts of silane coupler, 235 parts of prodan, 66 parts of kaolin, 85 parts of fluorite, polyphenyl second
15 parts of 98 parts of alkene, 35 parts of sodium nitrate, 27 parts of calcite, 35 parts of polyester resin and ethoxylated dodecyl alcohol.
In some embodiments：Include in parts by weight, 433 parts of cullet, 86 parts of quartz sand, toluenesulfonic acid sodium salt 74
Part, 20 parts of ethylene glycol monobutyl ether, 199 parts of silane coupler, 287 parts of prodan, 80 parts of kaolin, 104 parts of fluorite, polyphenyl second
25 parts of 152 parts of alkene, 41 parts of sodium nitrate, 41 parts of calcite, 50 parts of polyester resin and ethoxylated dodecyl alcohol.
In some embodiments：Cullet are flint glass.
Present invention also offers a kind of preparation method of above-mentioned anti-explosion glass, comprise the following steps:
Step 1：Among above-mentioned raw materials are positioned over into respective material container, the aniseed for loading dispensing is entered after being stirred
In pipe or feed bin；
Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed
The glass metal of predetermined viscosity, then be homogenized, clarify, discharge bubble, form flowable molten mass, viscosity is 102 Pa Secs
Clarification, exhaust bubble technological temperature are 950 DEG C -1427 DEG C；
Step 3：Use trombone slide moulding process：Glass is drawn into through tube-pulling apparatus to the melten glass body formed in step 2
Manage and be molded, annealed, cooling, you can glass is made.
In some embodiments：Exhaust bubble technological temperature is 950 DEG C.
In some embodiments：Exhaust bubble technological temperature is 1270 DEG C.
In some embodiments：Exhaust bubble technological temperature is 1427 DEG C.
In some embodiments：Chemical tempering or physical toughened processing are carried out to prepared glass.
The glass structure of the present invention is simple, reasonable in design, can effectively prevent, by explosion, service life length, having a wide range of application.
Embodiment
The present invention is described in further detail below by embodiment.
Embodiment 1：
Anti- explosion glass, includes in parts by weight, 255 parts of cullet, 48 parts of quartz sand, 29 parts of toluenesulfonic acid sodium salt, second two
10 parts of alcohol monobutyl ether, 165 parts of silane coupler, 210 parts of prodan, 27 parts of kaolin, 72 parts of fluorite, 19 parts of polystyrene,
5 parts of 23 parts of sodium nitrate, 9 parts of calcite, 20 parts of polyester resin and ethoxylated dodecyl alcohol.
The preparation method of the anti-explosion glass of the present invention：Comprise the following steps:
Step 1：Among above-mentioned raw materials are positioned over into respective material container, the aniseed for loading dispensing is entered after being stirred
In pipe or feed bin；
Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed
The glass metal of predetermined viscosity, then be homogenized, clarify, discharge bubble, form flowable molten mass, viscosity is 102 Pa Secs
Clarification, exhaust bubble technological temperature are 950 DEG C；
Step 3：Use trombone slide moulding process：Glass is drawn into through tube-pulling apparatus to the melten glass body formed in step 2
Manage and be molded, annealed, cooling, you can glass is made.
In some embodiments：Chemical tempering or physical toughened processing are carried out to prepared glass.
Embodiment 2：
Anti- explosion glass, includes in parts by weight, 380 parts of cullet, 70 parts of quartz sand, 55 parts of toluenesulfonic acid sodium salt, second two
15 parts of alcohol monobutyl ether, 177 parts of silane coupler, 235 parts of prodan, 66 parts of kaolin, 85 parts of fluorite, 98 parts of polystyrene,
15 parts of 35 parts of sodium nitrate, 27 parts of calcite, 35 parts of polyester resin and ethoxylated dodecyl alcohol.
The preparation method of the anti-explosion glass of the present invention：Comprise the following steps:
Step 1：Among above-mentioned raw materials are positioned over into respective material container, the aniseed for loading dispensing is entered after being stirred
In pipe or feed bin；
Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed
The glass metal of predetermined viscosity, then be homogenized, clarify, discharge bubble, form flowable molten mass, viscosity is 102 Pa Secs
Clarification, exhaust bubble technological temperature are 1270 DEG C；
Step 3：Use trombone slide moulding process：Glass is drawn into through tube-pulling apparatus to the melten glass body formed in step 2
Manage and be molded, annealed, cooling, you can glass is made.
In some embodiments：Chemical tempering or physical toughened processing are carried out to prepared glass.
Embodiment 3：
Anti- explosion glass, includes in parts by weight, 433 parts of cullet, 86 parts of quartz sand, 74 parts of toluenesulfonic acid sodium salt, second two
20 parts of alcohol monobutyl ether, 199 parts of silane coupler, 287 parts of prodan, 80 parts of kaolin, 104 parts of fluorite, polystyrene 152
Part, 41 parts of sodium nitrate, 41 parts of calcite, 50 parts of polyester resin and 25 parts of ethoxylated dodecyl alcohol.
The preparation method of the anti-explosion glass of the present invention：Comprise the following steps:
Step 1：Among above-mentioned raw materials are positioned over into respective material container, the aniseed for loading dispensing is entered after being stirred
In pipe or feed bin；
Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed
The glass metal of predetermined viscosity, then be homogenized, clarify, discharge bubble, form flowable molten mass, viscosity is 102 Pa Secs
Clarification, exhaust bubble technological temperature are 1427 DEG C；
Step 3：Use trombone slide moulding process：Glass is drawn into through tube-pulling apparatus to the melten glass body formed in step 2
Manage and be molded, annealed, cooling, you can glass is made.
In some embodiments：Chemical tempering or physical toughened processing are carried out to prepared glass.
In summary, glass structure of the invention is simple, reasonable in design, can effectively prevent by explosion, service life length, should
It is wide with scope.
Described above is only one embodiment of the present invention, it is noted that to those skilled in the art,
Without departing from the concept of the premise of the invention, some similar modification and improvement can also be made, these also should be regarded as this
Within the protection domain of invention.
Claims (10)
- A kind of 1. anti-explosion glass, it is characterised in that：Include in parts by weight, cullet 255-433 parts, quartz sand 48-86 parts, Toluenesulfonic acid sodium salt 29-74 parts, ethylene glycol monobutyl ether 10-20 parts, silane coupler 165-199 parts, prodan 210-287 parts, Kaolin 27-80 parts, fluorite 72-104 parts, polystyrene 19-152 parts, sodium nitrate 23-41 parts, calcite 9-41 parts, polyester tree Fat 20-50 parts and ethoxylated dodecyl alcohol 5-25 parts.
- A kind of 2. anti-explosion glass according to claim 1, it is characterised in that：Include in parts by weight, cullet 255 Part, 48 parts of quartz sand, 29 parts of toluenesulfonic acid sodium salt, 10 parts of ethylene glycol monobutyl ether, 165 parts of silane coupler, 210 parts of prodan, 27 parts of kaolin, 72 parts of fluorite, 19 parts of polystyrene, 23 parts of sodium nitrate, 9 parts of calcite, 20 parts of polyester resin and laruyl alcohol gather 5 parts of oxygen vinethene.
- A kind of 3. anti-explosion glass according to claim 2, it is characterised in that：Include in parts by weight, cullet 380 Part, 70 parts of quartz sand, 55 parts of toluenesulfonic acid sodium salt, 15 parts of ethylene glycol monobutyl ether, 177 parts of silane coupler, 235 parts of prodan, 66 parts of kaolin, 85 parts of fluorite, 98 parts of polystyrene, 35 parts of sodium nitrate, 27 parts of calcite, 35 parts of polyester resin and laruyl alcohol gather 15 parts of oxygen vinethene.
- A kind of 4. anti-explosion glass according to claim 1, it is characterised in that：Include in parts by weight, cullet 433 Part, 86 parts of quartz sand, 74 parts of toluenesulfonic acid sodium salt, 20 parts of ethylene glycol monobutyl ether, 199 parts of silane coupler, 287 parts of prodan, 80 parts of kaolin, 104 parts of fluorite, 152 parts of polystyrene, 41 parts of sodium nitrate, 41 parts of calcite, 50 parts of polyester resin and laruyl alcohol 25 parts of APEO.
- A kind of 5. anti-explosion glass according to claim 1, it is characterised in that：The cullet are flint glass.
- A kind of 6. method for preparing any one of the claim 1-5 anti-explosion glass, it is characterised in that, comprise the following steps:Step 1：Among above-mentioned raw materials are positioned over into respective material container, after being stirred enter load dispensing big expects pipe or In feed bin；Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed predetermined Viscosity glass metal, then be homogenized, clarify, discharge bubble, form flowable molten mass, clarification that viscosity is 102 Pa Secs, Exhaust bubble technological temperature is 950 DEG C -1427 DEG C；Step 3：Use trombone slide moulding process：Through tube-pulling apparatus glass tube is drawn into the melten glass body that is formed in step 2 and Shaping, annealed, cooling, you can glass is made.
- A kind of 7. preparation method of anti-explosion glass according to claim 6, it is characterised in that：The exhaust bubble process warm Spend for 950 DEG C.
- A kind of 8. preparation method of anti-explosion glass according to claim 6, it is characterised in that：The exhaust bubble process warm Spend for 1270 DEG C.
- A kind of 9. preparation method of anti-explosion glass according to claim 6, it is characterised in that：The exhaust bubble process warm Spend for 1427 DEG C.
- A kind of 10. preparation method of anti-explosion glass according to claim 6, it is characterised in that：To prepared glass Carry out chemical tempering or physical toughened processing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711033031.7A CN107892473A (en) | 2017-10-30 | 2017-10-30 | A kind of anti-explosion glass and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711033031.7A CN107892473A (en) | 2017-10-30 | 2017-10-30 | A kind of anti-explosion glass and preparation method thereof |
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| Publication Number | Publication Date |
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| CN107892473A true CN107892473A (en) | 2018-04-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201711033031.7A Pending CN107892473A (en) | 2017-10-30 | 2017-10-30 | A kind of anti-explosion glass and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109279777A (en) * | 2018-09-18 | 2019-01-29 | 江苏锐阳照明电器设备有限公司 | A kind of implosion guard |
| CN111018349A (en) * | 2019-12-17 | 2020-04-17 | 安徽凤阳玻璃有限公司 | Ultraviolet-proof plate glass and preparation method thereof |
| CN111844960A (en) * | 2020-06-22 | 2020-10-30 | 扬州恒泰玻璃有限公司 | Preparation process of light composite structure toughened glass |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109279777A (en) * | 2018-09-18 | 2019-01-29 | 江苏锐阳照明电器设备有限公司 | A kind of implosion guard |
| CN111018349A (en) * | 2019-12-17 | 2020-04-17 | 安徽凤阳玻璃有限公司 | Ultraviolet-proof plate glass and preparation method thereof |
| CN111844960A (en) * | 2020-06-22 | 2020-10-30 | 扬州恒泰玻璃有限公司 | Preparation process of light composite structure toughened glass |
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Application publication date: 20180410 |