CN107721165A - A kind of anticorrosion glass and preparation method thereof - Google Patents
A kind of anticorrosion glass and preparation method thereof Download PDFInfo
- Publication number
- CN107721165A CN107721165A CN201711032992.6A CN201711032992A CN107721165A CN 107721165 A CN107721165 A CN 107721165A CN 201711032992 A CN201711032992 A CN 201711032992A CN 107721165 A CN107721165 A CN 107721165A
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- parts
- glass
- anticorrosion
- cullet
- glass according
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
- C03B5/16—Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
- C03B5/225—Refining
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
This application discloses a kind of anticorrosion glass and preparation method thereof, include in parts by weight, 5 28 parts of 238 482 parts of cullet, 48 97 parts of quartz sand, 29 74 parts of potassium pyrophosphate, 10 20 parts of sodium cellulose glycolate, 157 199 parts of silane coupler, 210 287 parts of prodan, 27 80 parts of kaolin, 72 104 parts of fluorite, 19 152 parts of perfluoro alkane, 23 46 parts of sodium nitrate, 9 46 parts of calcite, 20 50 parts of polyester resin and reinforcing fiber.Thus, glass structure of the invention is simple, reasonable in design, can effectively prevent from being corroded, and service life length, has a wide range of application.
Description
Technical field
The present invention relates to glass, more particularly to a kind of anticorrosion glass and preparation method thereof.
Background technology
Glass：A kind of transparent semisolid, semiliquid material, contiguous network structure is formed in melting, in cooling procedure
Viscosity gradually increases and hardened and non crystallized silicates nonmetallic materials.The composition of simple glass chemical oxide
(Na2OCaO6SiO2), main component is silica.It is widely used in building, for every wind printing opacity, belonging to mixing
Thing.Separately there are the oxide for being mixed into some metals or salt and show the coloured glass of color, and pass through specific process system
Safety glass obtained etc..Sometimes some transparent plastics (such as polymethyl methacrylate) are also referred to as lucite.
Glass is a kind of non-crystalline solids of random structure (from microcosmic, glass is also a kind of liquid), its molecule
There is the arrangement of long-range order unlike crystal in space, and be similar to liquid has shortrange order like that.Glass is as solid
Specific profile is equally kept, is flowed unlike liquid with Action of Gravity Field.
Glass state material is usually quickly to be cooled down by molten mass and obtained, cooled during from molten state to glassy transition
Viscosity increased dramatically in journey, and particle has little time to do regular arrangement and form crystal, does not disengage latent heat, therefore, glass
State material contains higher interior energy than crystalline state material, and its energy belongs to metastable state between molten state and crystalline state.From
Mechanics viewpoint sees that glass is a kind of unstable upper state, for example the trend of low-energy state conversion be present, that is, has crystallization to incline
To, so, glass is a kind of metastable solids material.
The primary raw material of glass production has glass former, glass adjustment thing and glass intermediate, and remaining is auxiliary material.
Primary raw material guides oxide, intermediate oxide and the network external oxidation thing that network is formed into glass；Auxiliary material includes clear
Clear agent, fluxing agent, opacifiers, colouring agent, decolorising agent, Oxidizing and Reducing Agents etc..
Traditional glass technology formula is simple, and without etch-proof function, service life is short, and application field is smaller.
The content of the invention
It is an object of the invention to provide a kind of anticorrosion glass and preparation method thereof, solves one in above-mentioned prior art problem
It is individual or multiple.
According to an aspect of the present invention, there is provided a kind of anticorrosion glass, include in parts by weight, cullet 238-482
Part, quartz sand 48-97 parts, potassium pyrophosphate 29-74 parts, sodium cellulose glycolate 10-20 parts, silane coupler 157-199 parts, fluorine
Sodium metasilicate 210-287 parts, kaolin 27-80 parts, fluorite 72-104 parts, perfluoro alkane 19-152 parts, sodium nitrate 23-46 parts, side
Solve stone 9-46 parts, polyester resin 20-50 parts and reinforcing fiber 5-28 parts.
In some embodiments：Include in parts by weight, 238 parts of cullet, 48 parts of quartz sand, 29 parts of potassium pyrophosphate,
10 parts of sodium cellulose glycolate, 157 parts of silane coupler, 210 parts of prodan, 27 parts of kaolin, 72 parts of fluorite, perfluoro alkane
5 parts of 19 parts, 23 parts of sodium nitrate, 9 parts of calcite, 20 parts of polyester resin and reinforcing fiber.
In some embodiments：Include in parts by weight, 380 parts of cullet, 70 parts of quartz sand, 55 parts of potassium pyrophosphate,
15 parts of sodium cellulose glycolate, 177 parts of silane coupler, 235 parts of prodan, 66 parts of kaolin, 85 parts of fluorite, perfluoro alkane
15 parts of 98 parts, 35 parts of sodium nitrate, 27 parts of calcite, 35 parts of polyester resin and reinforcing fiber.
In some embodiments：Include in parts by weight, 482 parts of cullet, 97 parts of quartz sand, 74 parts of potassium pyrophosphate,
20 parts of sodium cellulose glycolate, 199 parts of silane coupler, 287 parts of prodan, 80 parts of kaolin, 104 parts of fluorite, perfluor alkane
28 parts of 152 parts of hydrocarbon, 46 parts of sodium nitrate, 46 parts of calcite, 50 parts of polyester resin and reinforcing fiber.
In some embodiments：Cullet are flint glass.
Present invention also offers a kind of preparation method of above-mentioned anticorrosion glass, comprise the following steps:
Step 1：Among above-mentioned raw materials are positioned over into respective material container, the aniseed for loading dispensing is entered after being stirred
In pipe or feed bin；
Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed
The glass metal of predetermined viscosity, then be homogenized, clarify, discharge bubble, form flowable molten mass, viscosity is 102 Pa Secs
Clarification, exhaust bubble technological temperature are 950 DEG C -1427 DEG C；
Step 3：Use trombone slide moulding process：Glass is drawn into through tube-pulling apparatus to the melten glass body formed in step 2
Manage and be molded, annealed, cooling, you can glass is made.
In some embodiments：Exhaust bubble technological temperature is 950 DEG C.
In some embodiments：Exhaust bubble technological temperature is 1270 DEG C.
In some embodiments：Exhaust bubble technological temperature is 1427 DEG C.
In some embodiments：Chemical tempering or physical toughened processing are carried out to prepared glass.
The glass structure of the present invention is simple, reasonable in design, can effectively prevent from being corroded, and service life length, has a wide range of application.
Embodiment
The present invention is described in further detail below by embodiment.
Embodiment 1：
Anticorrosion glass, includes in parts by weight, 238 parts of cullet, 48 parts of quartz sand, 29 parts of potassium pyrophosphate, methylol
10 parts of sodium cellulosate, 157 parts of silane coupler, 210 parts of prodan, 27 parts of kaolin, 72 parts of fluorite, 19 parts of perfluoro alkane,
5 parts of 23 parts of sodium nitrate, 9 parts of calcite, 20 parts of polyester resin and reinforcing fiber.
The preparation method of anticorrosion glass of the present invention：Comprise the following steps:
Step 1：Among above-mentioned raw materials are positioned over into respective material container, the aniseed for loading dispensing is entered after being stirred
In pipe or feed bin；
Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed
The glass metal of predetermined viscosity, then be homogenized, clarify, discharge bubble, form flowable molten mass, viscosity is 102 Pa Secs
Clarification, exhaust bubble technological temperature are 950 DEG C；
Step 3：Use trombone slide moulding process：Glass is drawn into through tube-pulling apparatus to the melten glass body formed in step 2
Manage and be molded, annealed, cooling, you can glass is made.
In some embodiments：Chemical tempering or physical toughened processing are carried out to prepared glass.
Embodiment 2：
Anticorrosion glass, includes in parts by weight, 380 parts of cullet, 70 parts of quartz sand, 55 parts of potassium pyrophosphate, methylol
15 parts of sodium cellulosate, 177 parts of silane coupler, 235 parts of prodan, 66 parts of kaolin, 85 parts of fluorite, 98 parts of perfluoro alkane,
15 parts of 35 parts of sodium nitrate, 27 parts of calcite, 35 parts of polyester resin and reinforcing fiber.
The preparation method of anticorrosion glass of the present invention：Comprise the following steps:
Step 1：Among above-mentioned raw materials are positioned over into respective material container, the aniseed for loading dispensing is entered after being stirred
In pipe or feed bin；
Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed
The glass metal of predetermined viscosity, then be homogenized, clarify, discharge bubble, form flowable molten mass, viscosity is 102 Pa Secs
Clarification, exhaust bubble technological temperature are 1270 DEG C；
Step 3：Use trombone slide moulding process：Glass is drawn into through tube-pulling apparatus to the melten glass body formed in step 2
Manage and be molded, annealed, cooling, you can glass is made.
In some embodiments：Chemical tempering or physical toughened processing are carried out to prepared glass.
Embodiment 3：
Anticorrosion glass, includes in parts by weight, 482 parts of cullet, 97 parts of quartz sand, 74 parts of potassium pyrophosphate, methylol
20 parts of sodium cellulosate, 199 parts of silane coupler, 287 parts of prodan, 80 parts of kaolin, 104 parts of fluorite, perfluoro alkane 152
Part, 46 parts of sodium nitrate, 46 parts of calcite, 50 parts of polyester resin and 28 parts of reinforcing fiber.
The preparation method of anticorrosion glass of the present invention：Comprise the following steps:
Step 1：Among above-mentioned raw materials are positioned over into respective material container, the aniseed for loading dispensing is entered after being stirred
In pipe or feed bin；
Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed
The glass metal of predetermined viscosity, then be homogenized, clarify, discharge bubble, form flowable molten mass, viscosity is 102 Pa Secs
Clarification, exhaust bubble technological temperature are 1427 DEG C；
Step 3：Use trombone slide moulding process：Glass is drawn into through tube-pulling apparatus to the melten glass body formed in step 2
Manage and be molded, annealed, cooling, you can glass is made.
In some embodiments：Chemical tempering or physical toughened processing are carried out to prepared glass.
In summary, glass structure of the invention is simple, reasonable in design, can effectively prevent from being corroded, service life length, should
It is wide with scope.
Described above is only one embodiment of the present invention, it is noted that to those skilled in the art,
Without departing from the concept of the premise of the invention, some similar modification and improvement can also be made, these also should be regarded as this
Within the protection domain of invention.
Claims (10)
- A kind of 1. anticorrosion glass, it is characterised in that：Include in parts by weight, cullet 238-482 parts, quartz sand 48-97 parts, Potassium pyrophosphate 29-74 parts, sodium cellulose glycolate 10-20 parts, silane coupler 157-199 parts, prodan 210-287 parts, Kaolin 27-80 parts, fluorite 72-104 parts, perfluoro alkane 19-152 parts, sodium nitrate 23-46 parts, calcite 9-46 parts, polyester tree Fat 20-50 parts and reinforcing fiber 5-28 parts.
- A kind of 2. anticorrosion glass according to claim 1, it is characterised in that：Include in parts by weight, cullet 238 Part, 48 parts of quartz sand, 29 parts of potassium pyrophosphate, 10 parts of sodium cellulose glycolate, 157 parts of silane coupler, 210 parts of prodan, 27 parts of kaolin, 72 parts of fluorite, 19 parts of perfluoro alkane, 23 parts of sodium nitrate, 9 parts of calcite, 20 parts of polyester resin and reinforcing fiber 5 Part.
- A kind of 3. anticorrosion glass according to claim 2, it is characterised in that：Include in parts by weight, cullet 380 Part, 70 parts of quartz sand, 55 parts of potassium pyrophosphate, 15 parts of sodium cellulose glycolate, 177 parts of silane coupler, 235 parts of prodan, 66 parts of kaolin, 85 parts of fluorite, 98 parts of perfluoro alkane, 35 parts of sodium nitrate, 27 parts of calcite, 35 parts of polyester resin and reinforcing fiber 15 parts.
- A kind of 4. anticorrosion glass according to claim 1, it is characterised in that：Include in parts by weight, cullet 482 Part, 97 parts of quartz sand, 74 parts of potassium pyrophosphate, 20 parts of sodium cellulose glycolate, 199 parts of silane coupler, 287 parts of prodan, 80 parts of kaolin, 104 parts of fluorite, 152 parts of perfluoro alkane, 46 parts of sodium nitrate, 46 parts of calcite, 50 parts of polyester resin and enhancing are fine 28 parts of dimension.
- A kind of 5. anticorrosion glass according to claim 1, it is characterised in that：The cullet are flint glass.
- A kind of 6. method for preparing any one of the claim 1-5 anticorrosion glass, it is characterised in that, comprise the following steps:Step 1：Among above-mentioned raw materials are positioned over into respective material container, after being stirred enter load dispensing big expects pipe or In feed bin；Step 2：The raw material for making to work good enters in molten bath, in the fusion temperature fusing corresponding to each glass formula, is formed predetermined Viscosity glass metal, then be homogenized, clarify, discharge bubble, form flowable molten mass, clarification that viscosity is 102 Pa Secs, Exhaust bubble technological temperature is 950 DEG C -1427 DEG C；Step 3：Use trombone slide moulding process：Through tube-pulling apparatus glass tube is drawn into the melten glass body that is formed in step 2 and Shaping, annealed, cooling, you can glass is made.
- A kind of 7. preparation method of anticorrosion glass according to claim 6, it is characterised in that：The exhaust bubble process warm Spend for 950 DEG C.
- A kind of 8. preparation method of anticorrosion glass according to claim 6, it is characterised in that：The exhaust bubble process warm Spend for 1270 DEG C.
- A kind of 9. preparation method of anticorrosion glass according to claim 6, it is characterised in that：The exhaust bubble process warm Spend for 1427 DEG C.
- A kind of 10. preparation method of anticorrosion glass according to claim 6, it is characterised in that：To prepared glass Carry out chemical tempering or physical toughened processing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711032992.6A CN107721165A (en) | 2017-10-30 | 2017-10-30 | A kind of anticorrosion glass and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711032992.6A CN107721165A (en) | 2017-10-30 | 2017-10-30 | A kind of anticorrosion glass and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107721165A true CN107721165A (en) | 2018-02-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711032992.6A Pending CN107721165A (en) | 2017-10-30 | 2017-10-30 | A kind of anticorrosion glass and preparation method thereof |
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| CN (1) | CN107721165A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109279777A (en) * | 2018-09-18 | 2019-01-29 | 江苏锐阳照明电器设备有限公司 | A kind of implosion guard |
| CN111844960A (en) * | 2020-06-22 | 2020-10-30 | 扬州恒泰玻璃有限公司 | Preparation process of light composite structure toughened glass |
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| CN102050583A (en) * | 2010-10-27 | 2011-05-11 | 泰山玻璃纤维有限公司 | Chemical corrosion resistant fiberglass |
| CN102807324A (en) * | 2012-09-05 | 2012-12-05 | 北京大有盛和科技有限公司 | Natural-hetian-jade-imitated glass ceramics and preparation method for same |
| CN104829132A (en) * | 2015-05-28 | 2015-08-12 | 南京亚欣照明有限公司 | Milky white glass lamp tube for LEDs, milky white bulb for LEDs, and their manufacturing method |
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2017
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102050583A (en) * | 2010-10-27 | 2011-05-11 | 泰山玻璃纤维有限公司 | Chemical corrosion resistant fiberglass |
| CN102807324A (en) * | 2012-09-05 | 2012-12-05 | 北京大有盛和科技有限公司 | Natural-hetian-jade-imitated glass ceramics and preparation method for same |
| CN104829132A (en) * | 2015-05-28 | 2015-08-12 | 南京亚欣照明有限公司 | Milky white glass lamp tube for LEDs, milky white bulb for LEDs, and their manufacturing method |
Non-Patent Citations (2)
| Title |
|---|
| 孙静 等主编: "《建筑材料》", 31 August 2015, 成都：西南交通大学出版社 * |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109279777A (en) * | 2018-09-18 | 2019-01-29 | 江苏锐阳照明电器设备有限公司 | A kind of implosion guard |
| CN111844960A (en) * | 2020-06-22 | 2020-10-30 | 扬州恒泰玻璃有限公司 | Preparation process of light composite structure toughened glass |
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Application publication date: 20180223 |
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