CN107881039A - A kind of low foam laundry piece and preparation method thereof - Google Patents

A kind of low foam laundry piece and preparation method thereof Download PDF

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Publication number
CN107881039A
CN107881039A CN201710962232.9A CN201710962232A CN107881039A CN 107881039 A CN107881039 A CN 107881039A CN 201710962232 A CN201710962232 A CN 201710962232A CN 107881039 A CN107881039 A CN 107881039A
Authority
CN
China
Prior art keywords
parts
low foam
detergent
laundry piece
forming agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710962232.9A
Other languages
Chinese (zh)
Inventor
钱钢
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Connaught Environmental Protection Technology (suzhou) Co Ltd
Original Assignee
Connaught Environmental Protection Technology (suzhou) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Connaught Environmental Protection Technology (suzhou) Co Ltd filed Critical Connaught Environmental Protection Technology (suzhou) Co Ltd
Priority to CN201710962232.9A priority Critical patent/CN107881039A/en
Publication of CN107881039A publication Critical patent/CN107881039A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/042Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/0065Solid detergents containing builders
    • C11D17/0073Tablets
    • C11D17/0086Laundry tablets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/02Compositions of detergents based essentially on soap on alkali or ammonium soaps

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of low foam laundry piece, including following components and the parts by weight of each component to be:35~50 parts of detergent;8~10 parts of polyvinyl alcohol;2~5 parts of glycerine;1~2 part of the fatty acid potassium salts of C12 18 or amine salt;3~8 parts of film forming agent.The invention also discloses a kind of preparation method of low foam laundry piece, comprise the following steps:(1)Detergent, polyvinyl alcohol, film forming agent, EDETATE SODIUM, glycerine is first added in deionized water to stir;(2)Then the fatty acid potassium salts of C12 18 or amine salt stirring are added, is finally putting into even up on film-forming machine and is dried into film.The present invention can effectively control the foam of liquid detergent by adding the fatty acid potassium salts of C12 18 or amine salt, favorably wash rinse.

Description

A kind of low foam laundry piece and preparation method thereof
Technical field
The present invention relates to a kind of low foam laundry piece and preparation method thereof, belong to articles for washing technical field.
Background technology
Laundry sheet is a kind of brand-new cleaning product, changes the form of conventional cleaning product, light is its maximum spy Point, because it does not contain the harmful components such as fluorescent whitening agent, phosphorus, gradual fashionable European & American Market, turn into cleaning product of new generation, be one The neutral synthetic detergent of kind.
But no small, most common washing powder on the market at present is but had in many washing markets domestic at present With in liquid detergent, generally being endangered containing the compositions such as fluorescent whitening agent, proteolytic enzyme, sodium tripolyphosphate, fluorescent whitening agent therein Evil is maximum, to old man or child, must select cleaning product with caution.
The quantitative washing that laundry sheet is realized, overcome and cumbersome, i.e. saving is measured in traditional washing powder, liquid detergent use Articles for washing, the environmental protection characteristic of its low bubble hyperconcetration has been saved again uses water, is expected to be promoted at home, with people's lives water Flat raising, requirement of the people to laundry sheet product quality also more and more higher, the demand of laundry sheet will be increasing, quality It is required that also more and more higher, active matter it is high, multi-functional, easy to use by be laundry sheet development trend.
The content of the invention
The technical problems to be solved by the invention are the defects of overcoming prior art, there is provided a kind of ring easy to use, safe Low foam laundry piece protect, being easy to carry about with one and preparation method thereof.
In order to solve the above technical problems, the present invention provides a kind of low foam laundry piece, it is characterized in that, including following components and each The parts by weight of component are:
35~50 parts of detergent;
8~10 parts of polyvinyl alcohol;
2~5 parts of glycerine;
1~2 part of C12-18 fatty acid potassium salts or amine salt;
3~8 parts of film forming agent.
Further, the detergent is made up of lauryl sodium sulfate and a- alkene sulfonic acid sodiums.
Further, in addition to 1~2 part of 0.1~0.3 part of EDETATE SODIUM and sodium citrate.
Further, the film forming agent is polyvinyl alcohol material.
Further, including following components and the parts by weight of each component are:
35 parts of detergent;
9 parts of polyvinyl alcohol;
4 parts of glycerine;
1 part of C12-18 fatty acid potassium salts or amine salt;
8 parts of film forming agent.
Present invention also offers a kind of preparation method of low foam laundry piece, it is characterized in that, comprise the following steps:
(1)Detergent, polyvinyl alcohol, film forming agent, EDETATE SODIUM, glycerine is first added in deionized water to stir;
(2)Then C12-18 fatty acid potassium salts or amine salt stirring are added, is finally putting into even up on film-forming machine and is dried into film.
Further, the detergent is made up of lauryl sodium sulfate and a- alkene sulfonic acid sodiums.
Further, the film forming agent is polyvinyl alcohol material.
The beneficial effect that the present invention is reached:C12-18 fatty acid potassium salts or amine salt are good to liquid detergent integral formula compatibility It is good.The foam of liquid detergent can be effectively controlled, favorably washs rinse.C12-18 fatty acid potassium salts or amine salt are a kind of excellent in itself Anion surfactant, integrate detergency or taking dirt force and defoaming power.The natural acid of soaps as defoamer, It is lower than surfactant foam medium surface tension, and interface and the drawout for being capable of air inlet/water are next.Hydrophobic soap Class instead of the surfactant between interface, finally make lather collapse.The preparation process of the laundry sheet is simple, production technology letter Just, production cost can be substantially reduced, improves production efficiency.
Embodiment
The invention will be further described below.Following examples are only used for the technical side for clearly illustrating the present invention Case, and can not be limited the scope of the invention with this.
Embodiment one
A kind of low foam laundry piece includes following components and the parts by weight of each component are:
40 parts of detergent;10 parts of polyvinyl alcohol;2 parts of glycerine;1 part of C12-18 fatty acid potassium salts or amine salt;6 parts of film forming agent; 0.1 part of EDETATE SODIUM;1.5 parts of sodium citrate.
The detergent is made up of lauryl sodium sulfate and a- alkene sulfonic acid sodiums.
The film forming agent is polyvinyl alcohol material.
A kind of preparation method of low foam laundry piece, comprises the following steps:
(1)Detergent, polyvinyl alcohol, film forming agent, EDETATE SODIUM, glycerine is first added in deionized water to stir;
(2)Then C12-18 fatty acid potassium salts or amine salt stirring are added, is finally putting into even up on film-forming machine and is dried into film.
Embodiment two
A kind of low foam laundry piece includes following components and the parts by weight of each component are:
35 parts of detergent;9 parts of polyvinyl alcohol;4 parts of glycerine;2 parts of C12-18 fatty acid potassium salts or amine salt;8 parts of film forming agent; 0.1 part of EDETATE SODIUM;1 part of sodium citrate.
The detergent is made up of lauryl sodium sulfate and a- alkene sulfonic acid sodiums.
The film forming agent is polyvinyl alcohol material.
A kind of preparation method of low foam laundry piece, comprises the following steps:
(1)Detergent, polyvinyl alcohol, film forming agent, EDETATE SODIUM, glycerine is first added in deionized water to stir;
(2)Then C12-18 fatty acid potassium salts or amine salt stirring are added, is finally putting into even up on film-forming machine and is dried into film.
Embodiment three
A kind of low foam laundry piece includes following components and the parts by weight of each component are:
50 parts of detergent;8 parts of polyvinyl alcohol;5 parts of glycerine;1 part of C12-18 fatty acid potassium salts or amine salt;3 parts of film forming agent; 0.3 part of EDETATE SODIUM;2 parts of sodium citrate.
The detergent is made up of lauryl sodium sulfate and a- alkene sulfonic acid sodiums.
The film forming agent is polyvinyl alcohol material.
A kind of preparation method of low foam laundry piece, comprises the following steps:
(1)Detergent, polyvinyl alcohol, film forming agent, EDETATE SODIUM, glycerine is first added in deionized water to stir;
(2)Then C12-18 fatty acid potassium salts or amine salt stirring are added, is finally putting into even up on film-forming machine and is dried into film.
Laundry sheet of the present invention is good to laundry sheet integral formula compatibility by adding C12-18 fatty acid potassium salts or amine salt. The foam of laundry sheet can be effectively controlled, favorably washs rinse.C12-18 fatty acid potassium salts or amine salt are a kind of excellent in itself Anion surfactant, integrate detergency or taking dirt force and defoaming power.The natural acid of soaps as defoamer, it Lower than surfactant foam medium surface tension, the interface and drawout for being capable of air inlet/water are come.Hydrophobic soaps The surfactant between interface is instead of, finally makes lather collapse.The preparation process of the laundry sheet is simple, production technology letter Just, production cost can be substantially reduced, improves production efficiency.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, some improvement and deformation can also be made, these are improved and deformation Also it should be regarded as protection scope of the present invention.

Claims (8)

1. a kind of low foam laundry piece, it is characterized in that, including following components and the parts by weight of each component are:
35~50 parts of detergent;
8~10 parts of polyvinyl alcohol;
2~5 parts of glycerine;
1~2 part of C12-18 fatty acid potassium salts or amine salt;
3~8 parts of film forming agent.
2. a kind of low foam laundry piece according to claim 1, it is characterized in that, the detergent by lauryl sodium sulfate and A- alkene sulfonic acid sodiums form.
3. a kind of low foam laundry piece according to claim 1, it is characterized in that, in addition to 0.1~0.3 part of EDETATE SODIUM and lemon 1~2 part of lemon acid sodium.
4. a kind of low foam laundry piece according to claim 1, it is characterized in that, the film forming agent is polyvinyl alcohol material.
5. a kind of low foam laundry piece according to any one in Claims 1 to 4, it is characterized in that, including following components and The parts by weight of each component are:
35 parts of detergent;
9 parts of polyvinyl alcohol;
4 parts of glycerine;
1 part of C12-18 fatty acid potassium salts or amine salt;
8 parts of film forming agent.
6. a kind of preparation method of low foam laundry piece, it is characterized in that, comprise the following steps:
(1)Detergent, polyvinyl alcohol, film forming agent, EDETATE SODIUM, glycerine is first added in deionized water to stir;
(2)Then C12-18 fatty acid potassium salts or amine salt stirring are added, is finally putting into even up on film-forming machine and is dried into film.
7. a kind of preparation method of low foam laundry piece according to claim 6, it is characterized in that, the detergent is by dodecane Base sodium sulphate and a- alkene sulfonic acid sodiums composition.
8. a kind of preparation method of low foam laundry piece according to claim 6, it is characterized in that, the film forming agent is polyethylene Alcohols material.
CN201710962232.9A 2017-10-17 2017-10-17 A kind of low foam laundry piece and preparation method thereof Pending CN107881039A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710962232.9A CN107881039A (en) 2017-10-17 2017-10-17 A kind of low foam laundry piece and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710962232.9A CN107881039A (en) 2017-10-17 2017-10-17 A kind of low foam laundry piece and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107881039A true CN107881039A (en) 2018-04-06

Family

ID=61781537

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710962232.9A Pending CN107881039A (en) 2017-10-17 2017-10-17 A kind of low foam laundry piece and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107881039A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106281736A (en) * 2016-08-11 2017-01-04 孔令超 A kind of ultra concentration clear water type laundry sheet and preparation method thereof
CN106434024A (en) * 2016-09-12 2017-02-22 广州洁明洗涤制品有限公司 Nanometer hyperconcentration clear water laundry flake and preparation method thereof
CN106916659A (en) * 2017-01-24 2017-07-04 纳爱斯集团有限公司 A kind of multilayer laundry sheet and preparation method thereof
CN107012014A (en) * 2017-05-23 2017-08-04 诺圆环保科技(苏州)有限公司 A kind of antibacterial laundry sheet and preparation method thereof
CN107189866A (en) * 2017-06-16 2017-09-22 诺圆环保科技(苏州)有限公司 A kind of antibacterial antistatic laundry sheet and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106281736A (en) * 2016-08-11 2017-01-04 孔令超 A kind of ultra concentration clear water type laundry sheet and preparation method thereof
CN106434024A (en) * 2016-09-12 2017-02-22 广州洁明洗涤制品有限公司 Nanometer hyperconcentration clear water laundry flake and preparation method thereof
CN106916659A (en) * 2017-01-24 2017-07-04 纳爱斯集团有限公司 A kind of multilayer laundry sheet and preparation method thereof
CN107012014A (en) * 2017-05-23 2017-08-04 诺圆环保科技(苏州)有限公司 A kind of antibacterial laundry sheet and preparation method thereof
CN107189866A (en) * 2017-06-16 2017-09-22 诺圆环保科技(苏州)有限公司 A kind of antibacterial antistatic laundry sheet and preparation method thereof

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PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
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Application publication date: 20180406