CN107880703A - A kind of preparation method of fire-retardant paint - Google Patents

A kind of preparation method of fire-retardant paint Download PDF

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Publication number
CN107880703A
CN107880703A CN201711249820.4A CN201711249820A CN107880703A CN 107880703 A CN107880703 A CN 107880703A CN 201711249820 A CN201711249820 A CN 201711249820A CN 107880703 A CN107880703 A CN 107880703A
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China
Prior art keywords
parts
fire
preparation
boratex
pentaerythrite
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Application number
CN201711249820.4A
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Chinese (zh)
Inventor
李会玲
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Chengdu Kaisien Technology Co Ltd
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Chengdu Kaisien Technology Co Ltd
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Priority to CN201711249820.4A priority Critical patent/CN107880703A/en
Publication of CN107880703A publication Critical patent/CN107880703A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D135/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D135/02Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0812Aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Fireproofing Substances (AREA)

Abstract

The invention discloses a kind of preparation method of fire-retardant paint, including titanium dioxide, Boratex, methyl methacrylate, trimethylolpropane trimethacrylate, dipropylene glycol dibenzoate, titanium carbide, borax, aluminium powder, butyl stearate, pentaerythrite, sorbitan monostearate, Ludox, 4 morpholine phenyl boric acids, flame retardant and acrylic resin are configured by weight and is modified casein filming agent;Stirring is uniformly mixed and heated after solid matter is crushed with liquid.The beneficial effects of the invention are as follows:The present invention has the advantages of fire resistance property is strong, run into nonflammable after naked light, in the absence of any potential safety hazard so as to improving the security performance of the security performance that uses of paint and storage, and suitable for the adverse circumstances such as high temperature, humidity, pH-value be higher, it has formula simple, low manufacture cost, applied widely, the advantages of being readily produced, and is easy to promote the use of.

Description

A kind of preparation method of fire-retardant paint
Technical field
It is a kind of preparation method of fire-retardant paint specifically the present invention relates to paint field.
Background technology
Paint is that one kind can firmly be covered in body surface, and the chemistry for playing protection, decoration, mark and other specific uses mixes Compound coating.Paint as viscous oily pigment, it is inflammable in the case of not dry, it is not soluble in water, be slightly soluble in fat, dissolve in alcohol, aldehyde, Ether, benzene, alkane, it is soluble in gasoline, kerosene, diesel oil.
All it is by three kinds of film forming matter, subsidiary film forming matter and auxiliary film forming matter no matter painting kind or form Base substance forms:
Film forming matter:Also referred to as binding agent, it is organic high molecular compound such as natural resin that film forming matter is most of(It is rosin, big Paint), coating(Tung oil, flame retardant, soya-bean oil, fish oil etc.), the mix such as synthetic resin, form by pyroreaction, also have The paint of inorganic matter combination(Such as:Inorganic zinc rich paint).Various film forming matters press the common xxx classes of national standard.It is to form paint Main body, decide the performance of paint film.If without film forming matter, simple pigment and auxiliary material can not form paint film.
Subsidiary film forming matter:Including various pigment, extender pigment, rust resisting pigment.Pigment provides color and covering for paint film Power, improves the protective value and decorative effect of paint, and the pigment of good weatherability can improve the service life of paint.Extender pigment can It is folded multiple by the accumulation of pigment using the performance of itself " sheet, needle-like " structure to increase the thickness of paint film, form fish scale The paint film of shape, the service life of paint film is improved, improve water proofing property and rust-proof effect.Rust resisting pigment passes through itself physics and chemistry Anti-rust action, prevent that metal surface is by corrosion by air, chemicals attack for body surface.
Auxiliary film forming matter:Including various auxiliary agents, solvent, various auxiliary agents are in the production process of paint, storage process, use Process and the forming process of paint film play very important effect.Although the amount used is all seldom, to the performance shadow of paint film Ring very big.Even it can not form paint film such as:Do not do, sink to the bottom caking, skinning.
The content of the invention
It is an object of the invention to provide a kind of preparation side of long, the strong aging of fire resistance property the fire-retardant paint of service life Method.
The present invention is achieved through the following technical solutions:A kind of preparation method of fire-retardant paint, including following steps:
Step S1:19 ~ 27 parts of titanium dioxide, 9 ~ 16 parts of Boratex, 3 ~ 6 parts of methyl methacrylate, three hydroxyls are configured by weight 5 ~ 7 parts of propane tri, 2 ~ 4 parts of dipropylene glycol dibenzoate, 5 ~ 7 parts of titanium carbide, 8 ~ 12 parts of borax, aluminium powder 5 ~ 11 parts, 3 ~ 7 parts of butyl stearate, 5 ~ 8 parts of pentaerythrite, 5 ~ 7 parts of sorbitan monostearate, 10 ~ 12 parts of Ludox, 4- 6 ~ 8 parts of quinoline phenyl boric acid, 11 ~ 19 parts of flame retardant and acrylic resin are modified 3 ~ 5 parts of casein filming agent;
Step S2:Titanium dioxide, Boratex, titanium carbide, borax, aluminium powder, butyl stearate, Ludox are well mixed, will be uniform Mixed mixture is crushed to more than 1000 mesh;
Step S3:By the mixture after being crushed in step S2 and methyl methacrylate, trimethylolpropane trimethacrylate, two Propylene glycol dibenzoate, pentaerythrite, hydroxy ethyl fiber, 4- morpholines phenyl boric acid, flame retardant and acrylic resin are modified junket Albumen film forming agent is uniformly mixed and heated to 140 DEG C ~ 180 DEG C;
Step S4:The mixture in step S3 is set to be incubated 9 ~ 16 minutes in the environment of 140 DEG C ~ 180 DEG C, soaking time terminates Afterwards, stirred 20 minutes ~ 35 minutes in the environment of 140 DEG C ~ 180 DEG C, mixing speed is 1000 ~ 1200 revs/min;
Step S5:After stirring, Temperature fall is painted.
3 parts of 10 parts of 20 parts of titanium dioxide, Boratex, methyl methacrylate, trimethylolpropane in described step S1 5 parts of triacrylate, 2 parts of dipropylene glycol dibenzoate, 5 parts of titanium carbide, 8 parts of borax, 6 parts of aluminium powder, 3 parts of butyl stearate, 5 parts of pentaerythrite, 5 parts of sorbitan monostearate, 10 parts of Ludox, 6 parts of 4- morpholines phenyl boric acid, 12 parts of flame retardant and third 3 parts of olefin(e) acid resin modified casein filming agent.
3 parts of 12 parts of 22 parts of titanium dioxide, Boratex, methyl methacrylate, trimethylolpropane in described step S1 6 parts of triacrylate, 2 parts of dipropylene glycol dibenzoate, 5 parts of titanium carbide, 9 parts of borax, 7 parts of aluminium powder, 4 parts of butyl stearate, 8 parts of pentaerythrite, 6 parts of sorbitan monostearate, 11 parts of Ludox, 6 parts of 4- morpholines phenyl boric acid, 14 parts of flame retardant and third 3 parts of olefin(e) acid resin modified casein filming agent.
5 parts of 14 parts of 24 parts of titanium dioxide, Boratex, methyl methacrylate, trimethylolpropane in described step S1 6 parts of triacrylate, 2 parts of dipropylene glycol dibenzoate, 5 parts of titanium carbide, 10 parts of borax, 8 parts of aluminium powder, 4 parts of butyl stearate, 7 parts of pentaerythrite, 6 parts of sorbitan monostearate, 10 parts of Ludox, 7 parts of 4- morpholines phenyl boric acid, 16 parts of flame retardant and third 3 parts of olefin(e) acid resin modified casein filming agent.
6 parts of 15 parts of 26 parts of titanium dioxide, Boratex, methyl methacrylate, trimethylolpropane in described step S1 7 parts of triacrylate, 4 parts of dipropylene glycol dibenzoate, 7 parts of titanium carbide, 12 parts of borax, 10 parts of aluminium powder, butyl stearate 7 Part, 8 parts of pentaerythrite, 7 parts of sorbitan monostearate, 12 parts of Ludox, 8 parts of 4- morpholines phenyl boric acid, 18 parts of flame retardant 5 parts of casein filming agent is modified with acrylic resin.
In described step S4, mixture is incubated 15 minutes in the environment of 140 DEG C, after soaking time terminates, 140 DEG C DEG C in the environment of stir 35 minutes, mixing speed be 1200 revs/min.
In described step S4, mixture is incubated 10 minutes in the environment of 180 DEG C, after soaking time terminates, 180 Stirred 20 minutes in the environment of DEG C, mixing speed is 1000 revs/min.
The present invention compared with prior art, has advantages below and beneficial effect:
The present invention has the advantages of fire resistance property is strong, run into it is nonflammable after naked light, in the absence of any potential safety hazard so as to improving The security performance and the security performance of storage that paint uses, and suitable for the severe ring such as high temperature, humidity, pH-value be higher Border, it has formula simple, low manufacture cost, applied widely, the advantages of being readily produced, is easy to promote the use of.
Embodiment
The present invention is described in further detail with reference to embodiment, but the implementation of the present invention is not limited to this.
Embodiment 1:
In the present embodiment, a kind of preparation method of fire-retardant paint, including following steps:
Step S1:19 ~ 27 parts of titanium dioxide, 9 ~ 16 parts of Boratex, 3 ~ 6 parts of methyl methacrylate, three hydroxyls are configured by weight 5 ~ 7 parts of propane tri, 2 ~ 4 parts of dipropylene glycol dibenzoate, 5 ~ 7 parts of titanium carbide, 8 ~ 12 parts of borax, aluminium powder 5 ~ 11 parts, 3 ~ 7 parts of butyl stearate, 5 ~ 8 parts of pentaerythrite, 5 ~ 7 parts of sorbitan monostearate, 10 ~ 12 parts of Ludox, 4- 6 ~ 8 parts of quinoline phenyl boric acid, 11 ~ 19 parts of flame retardant and acrylic resin are modified 3 ~ 5 parts of casein filming agent;
Step S2:Titanium dioxide, Boratex, titanium carbide, borax, aluminium powder, butyl stearate, Ludox are well mixed, will be uniform Mixed mixture is crushed to more than 1000 mesh;
Step S3:By the mixture after being crushed in step S2 and methyl methacrylate, trimethylolpropane trimethacrylate, two Propylene glycol dibenzoate, pentaerythrite, hydroxy ethyl fiber, 4- morpholines phenyl boric acid, flame retardant and acrylic resin are modified junket Albumen film forming agent is uniformly mixed and heated to 140 DEG C ~ 180 DEG C;
Step S4:The mixture in step S3 is set to be incubated 9 ~ 16 minutes in the environment of 140 DEG C ~ 180 DEG C, soaking time terminates Afterwards, stirred 20 minutes ~ 35 minutes in the environment of 140 DEG C ~ 180 DEG C, mixing speed is 1000 ~ 1200 revs/min;
Step S5:After stirring, Temperature fall is painted.The present invention has the advantages of high temperature resistant, fire-resistant ability is strong, can reduce Trigger the risk of fire, consequently facilitating storage and managenent, and be painted on after furniture, wall coverings, wall, can be when fire occurs Play fire retardation, loss caused by reduce fire, its have formula simple, low manufacture cost, it is applied widely, be easy to raw The advantages of production, it is easy to promote the use of.
Embodiment 2:
On the basis of above-described embodiment, in the present embodiment, 10 parts of 20 parts of titanium dioxide, Boratex in described step S1, first 2 parts of base methyl acrylate, 5 parts of trimethylolpropane trimethacrylate, 2 parts of dipropylene glycol dibenzoate, 5 parts of titanium carbide, boron 8 parts of sand, 6 parts of aluminium powder, 3 parts of butyl stearate, 5 parts of pentaerythrite, 5 parts of sorbitan monostearate, 10 parts of Ludox, 4- 6 parts of quinoline phenyl boric acid, 12 parts of flame retardant and acrylic resin are modified 3 parts of casein filming agent.In the present embodiment, other are not described Part it is identical with the content of above-described embodiment, therefore do not repeat.
Embodiment 3:
On the basis of above-described embodiment, in the present embodiment, 10 parts of 20 parts of titanium dioxide, Boratex in described step S1, first 3 parts of base methyl acrylate, 5 parts of trimethylolpropane trimethacrylate, 2 parts of dipropylene glycol dibenzoate, 5 parts of titanium carbide, boron 8 parts of sand, 6 parts of aluminium powder, 3 parts of butyl stearate, 6 parts of pentaerythrite, 5 parts of sorbitan monostearate, 10 parts of Ludox, 4- 6 parts of quinoline phenyl boric acid, 12 parts of flame retardant and acrylic resin are modified 3 parts of casein filming agent.In the present embodiment, other are not described Part it is identical with the content of above-described embodiment, therefore do not repeat.
Embodiment 4:
On the basis of above-described embodiment, in the present embodiment, 12 parts of 22 parts of titanium dioxide, Boratex in described step S1, first 3 parts of base methyl acrylate, 6 parts of trimethylolpropane trimethacrylate, 2 parts of dipropylene glycol dibenzoate, 5 parts of titanium carbide, boron 9 parts of sand, 7 parts of aluminium powder, 4 parts of butyl stearate, 7 parts of pentaerythrite, 6 parts of sorbitan monostearate, 11 parts of Ludox, 4- 6 parts of quinoline phenyl boric acid, 14 parts of flame retardant and acrylic resin are modified 3 parts of casein filming agent.In the present embodiment, other are not described Part it is identical with the content of above-described embodiment, therefore do not repeat.
Embodiment 5:
On the basis of above-described embodiment, in the present embodiment, 14 parts of 24 parts of titanium dioxide, Boratex in described step S1, first 5 parts of base methyl acrylate, 6 parts of trimethylolpropane trimethacrylate, 2 parts of dipropylene glycol dibenzoate, 5 parts of titanium carbide, boron 10 parts of sand, 8 parts of aluminium powder, 4 parts of butyl stearate, 8 parts of pentaerythrite, 6 parts of sorbitan monostearate, 10 parts of Ludox, 4- 7 parts of morpholine phenyl boric acid, 16 parts of flame retardant and acrylic resin are modified 3 parts of casein filming agent.In the present embodiment, other are not retouched The part stated is identical with the content of above-described embodiment, therefore does not repeat.
Embodiment 6:
On the basis of above-described embodiment, in the present embodiment, 15 parts of 26 parts of titanium dioxide, Boratex in described step S1, first 6 parts of base methyl acrylate, 7 parts of trimethylolpropane trimethacrylate, 4 parts of dipropylene glycol dibenzoate, 7 parts of titanium carbide, boron 12 parts of sand, 10 parts of aluminium powder, 7 parts of butyl stearate, 2 parts of pentaerythrite, 7 parts of sorbitan monostearate, 12 parts of Ludox, 4- 8 parts of morpholine phenyl boric acid, 18 parts of flame retardant and acrylic resin are modified 5 parts of casein filming agent.In the present embodiment, other are not retouched The part stated is identical with the content of above-described embodiment, therefore does not repeat.
It is described above, be only presently preferred embodiments of the present invention, any formal limitation not done to the present invention, it is every according to Any simply modification, the equivalent variations made according to the technical spirit of the present invention to above example, each fall within the protection of the present invention Within the scope of.

Claims (7)

  1. A kind of 1. preparation method of fire-retardant paint, it is characterised in that:Including following steps:
    Step S1:19 ~ 27 parts of titanium dioxide, 9 ~ 16 parts of Boratex, 5 ~ 7 parts of titanium carbide, 8 ~ 12 parts of borax, aluminium are configured by weight 5 ~ 11 parts of powder, 3 ~ 6 parts of methyl methacrylate, 5 ~ 7 parts of trimethylolpropane trimethacrylate, dipropylene glycol dibenzoate 2 ~ 4 parts, 3 ~ 7 parts of butyl stearate, 5 ~ 8 parts of pentaerythrite, 5 ~ 7 parts of sorbitan monostearate, 10 ~ 12 parts of Ludox, 4- 6 ~ 8 parts of quinoline phenyl boric acid, 11 ~ 19 parts of flame retardant and acrylic resin are modified 3 ~ 5 parts of casein filming agent;
    Step S2:Titanium dioxide, Boratex, titanium carbide, borax, aluminium powder, butyl stearate, Ludox are well mixed, will be uniform Mixed mixture is crushed to more than 1000 mesh;
    Step S3:By the mixture after being crushed in step S2 and methyl methacrylate, trimethylolpropane trimethacrylate, two Propylene glycol dibenzoate, pentaerythrite, hydroxy ethyl fiber, 4- morpholines phenyl boric acid, flame retardant and acrylic resin are modified junket Albumen film forming agent is uniformly mixed and heated to 140 DEG C ~ 180 DEG C;
    Step S4:The mixture in step S3 is set to be incubated 9 ~ 16 minutes in the environment of 140 DEG C ~ 180 DEG C, soaking time terminates Afterwards, stirred 20 minutes ~ 35 minutes in the environment of 140 DEG C ~ 180 DEG C, mixing speed is 1000 ~ 1200 revs/min;
    Step S5:After stirring, Temperature fall is painted.
  2. A kind of 2. preparation method of fire-retardant paint according to claim 1, it is characterised in that:Titanium in described step S1 20 parts of white powder, 10 parts of Boratex, 3 parts of methyl methacrylate, 5 parts of trimethylolpropane trimethacrylate, DPG hexichol 2 parts of formic acid esters, 5 parts of titanium carbide, 8 parts of borax, 6 parts of aluminium powder, 3 parts of butyl stearate, 5 parts of pentaerythrite, sorbitol anhydride list are stearic 5 parts of acid esters, 10 parts of Ludox, 6 parts of 4- morpholines phenyl boric acid, 12 parts of flame retardant and acrylic resin are modified casein filming agent 3 Part.
  3. A kind of 3. preparation method of fire-retardant paint according to claim 1, it is characterised in that:Titanium in described step S1 22 parts of white powder, 12 parts of Boratex, 3 parts of methyl methacrylate, 6 parts of trimethylolpropane trimethacrylate, DPG hexichol 2 parts of formic acid esters, 5 parts of titanium carbide, 9 parts of borax, 7 parts of aluminium powder, 4 parts of butyl stearate, 6 parts of pentaerythrite, sorbitol anhydride list are stearic 6 parts of acid esters, 11 parts of Ludox, 6 parts of 4- morpholines phenyl boric acid, 14 parts of flame retardant and acrylic resin are modified casein filming agent 3 Part.
  4. A kind of 4. preparation method of fire-retardant paint according to claim 1, it is characterised in that:Titanium in described step S1 24 parts of white powder, 14 parts of Boratex, 5 parts of methyl methacrylate, 6 parts of trimethylolpropane trimethacrylate, DPG hexichol 2 parts of formic acid esters, 5 parts of titanium carbide, 10 parts of borax, 8 parts of aluminium powder, 4 parts of butyl stearate, 7 parts of pentaerythrite, sorbitol anhydride list are stearic 6 parts of acid esters, 10 parts of Ludox, 7 parts of 4- morpholines phenyl boric acid, 16 parts of flame retardant and acrylic resin are modified casein filming agent 3 Part.
  5. A kind of 5. preparation method of fire-retardant paint according to claim 1, it is characterised in that:Titanium in described step S1 26 parts of white powder, 15 parts of Boratex, 6 parts of methyl methacrylate, 7 parts of trimethylolpropane trimethacrylate, DPG hexichol 4 parts of formic acid esters, 7 parts of titanium carbide, 12 parts of borax, 10 parts of aluminium powder, 7 parts of butyl stearate, 8 parts of pentaerythrite, sorbitol anhydride list are hard 7 parts of resin acid ester, 12 parts of Ludox, 8 parts of 4- morpholines phenyl boric acid, 18 parts of flame retardant and acrylic resin are modified casein filming agent 5 parts.
  6. A kind of 6. preparation method of fire-retardant paint according to claim 1, it is characterised in that:, will in described step S4 Mixture is incubated 15 minutes in the environment of 140 DEG C, after soaking time terminates, stirs 35 minutes, stirs in the environment of 140 DEG C DEG C Speed is mixed as 1200 revs/min.
  7. A kind of 7. preparation method of fire-retardant paint according to claim 1, it is characterised in that:, will in described step S4 Mixture is incubated 10 minutes in the environment of 180 DEG C, after soaking time terminates, is stirred 20 minutes in the environment of 180 DEG C, stirring Speed is 1000 revs/min.
CN201711249820.4A 2017-12-01 2017-12-01 A kind of preparation method of fire-retardant paint Withdrawn CN107880703A (en)

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CN201711249820.4A CN107880703A (en) 2017-12-01 2017-12-01 A kind of preparation method of fire-retardant paint

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109467969A (en) * 2018-11-27 2019-03-15 徐州世澳木业有限公司 A kind of timber processing fire-retardant paint

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109467969A (en) * 2018-11-27 2019-03-15 徐州世澳木业有限公司 A kind of timber processing fire-retardant paint

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