CN106833214A - A kind of environment protection oil paint and preparation method thereof - Google Patents

A kind of environment protection oil paint and preparation method thereof Download PDF

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Publication number
CN106833214A
CN106833214A CN201710151402.5A CN201710151402A CN106833214A CN 106833214 A CN106833214 A CN 106833214A CN 201710151402 A CN201710151402 A CN 201710151402A CN 106833214 A CN106833214 A CN 106833214A
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China
Prior art keywords
parts
acid
resin
environment protection
protection oil
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Pending
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CN201710151402.5A
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Chinese (zh)
Inventor
陈鹏芳
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Nanjing University of Information Science and Technology
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Nanjing University of Information Science and Technology
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Priority to CN201710151402.5A priority Critical patent/CN106833214A/en
Publication of CN106833214A publication Critical patent/CN106833214A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of environment protection oil paint and preparation method thereof.The environment protection oil paint includes the component of following parts by weight:30 40 parts of plastic propene's acid resin, 5 10 parts of cellulose acetate, 35 parts of limonene, 35 parts of polyalcohol, 24 parts of barium chromate, 10 15 parts of polyacrylate, 20 30 parts of alcohol-soluble resin, 5 10 parts of toluene di-isocyanate(TDI), 46 parts of isopropyl titanate, 24 parts of triethanolamine, 13 parts of sodium carboxymethylcellulose, 13 parts of zinc naphthenate, 46 parts of mill base, 13 parts of the smooth hard acid of sorb, 24 parts of cellulose derivative, 13 parts of hydracrylic acid, 13 parts of titanium dioxide, 13 parts of phenylalanine, 24 parts of 5 10 parts of defoamer and dimethyl sulfoxide (DMSO).Harmful substance is free of in raw material prepared by present invention paint, the air pollution in conventional paint drying process can be avoided, use safety.

Description

A kind of environment protection oil paint and preparation method thereof
Technical field
Present invention relates particularly to a kind of environment protection oil paint and preparation method thereof.
Background technology
Paint English name:paint or coating.Paint is that one kind can firmly be covered in body surface, plays protection, dress The chemical mixture coating of decorations, mark and other specific uses.Chinese coating circle is more authoritative《Coating process》One book is this Sample definition:" coating is a kind of material, and this material can be coated in object surface, form adhesion with different construction technologies Firmly, with some strength, continuous solid film.The film common name film for so being formed, also known as paint film or coating." coating one As by film forming matter, filler(Color stuffing), solvent, four parts such as auxiliary agent composition.According to performance requirement, composition can slightly become sometimes Change, such as varnish can be without solvent in not having color stuffing, powdery paints.
Paint is that one kind can firmly be covered in body surface, and the chemistry for playing protection, decoration, mark and other specific uses is mixed Compound coating.It is thickness oil colour to paint, it is not dry in the case of it is inflammable, it is water insoluble, be slightly soluble in fat, dissolve in alcohol, aldehyde, Ether, benzene, alkane, are soluble in gasoline, kerosene, diesel oil.Paint species is many currently on the market, but mainly contains toluene, also there is a small amount of Benzene, after being all chemicals especially application to the very big paint at present of human body influence, can constantly volatile organic compound And episome (TDI) (VOC).Not only to the Nature produce ozone pollution, but also can make human body cause headache, general paralysis, The various diseases such as anaemia, cancer, carry out serious threat, but be a kind of essential material being not fee to human body health care belt.
Therefore, industry is badly in need of providing a kind of environmentally-friendly sanitary, uses the paint of safety.
The content of the invention
The invention aims to solve defect present in prior art, there is provided a kind of environmentally-friendly sanitary, use safety Paint.
In order to achieve the above object, the invention provides a kind of environment protection oil paint, including following parts by weight component:Plasticity Acrylic resin 30-40 parts, cellulose acetate 5-10 parts, limonene 3-5 parts, polyalcohol 3-5 parts, barium chromate 2-4 parts, polypropylene Acid esters 10-15 parts, alcohol-soluble resin 20-30 parts, toluene di-isocyanate(TDI) 5-10 parts, isopropyl titanate 4-6 parts, triethanolamine 2- 4 parts, sodium carboxymethylcellulose 1-3 parts, zinc naphthenate 1-3 parts, mill base 4-6 parts, smooth hard acid 1-3 parts of sorb, cellulose derivative 2-4 parts, hydracrylic acid 1-3 parts, titanium dioxide 1-3 parts, phenylalanine 1-3 parts, defoamer 5-10 parts and dimethyl sulfoxide (DMSO) 2-4 parts.
The preferred ingredient weight proportion of environment protection oil paint of the present invention is:35 parts of plastic propene's acid resin, 7 parts of cellulose acetate, 4 parts of limonene, 4 parts of polyalcohol, 3 parts of barium chromate, 12 parts of polyacrylate, 25 parts of alcohol-soluble resin, toluene di-isocyanate(TDI) 7 Part, 5 parts of isopropyl titanate, 3 parts of triethanolamine, 2 parts of sodium carboxymethylcellulose, 2 parts of zinc naphthenate, 5 parts of mill base, the smooth hard acid of sorb 2 parts, 3 parts of cellulose derivative, 2 parts of hydracrylic acid, 2 parts of titanium dioxide, 2 parts of phenylalanine, 7 parts of defoamer and dimethyl sulfoxide (DMSO) 3 Part.
Wherein, polyalcohol uses propane diols;Alcohol-soluble resin uses rosin modified alkyd resin;Mill base uses resin color Slurry;Cellulose derivative uses methylcellulose;Defoamer uses polypropylene glycerol aether.
Present invention also offers the preparation method of above-mentioned environment protection oil paint, it is characterised in that comprise the following steps:
(1)By plastic propene's acid resin, cellulose acetate, limonene, polyalcohol, barium chromate, polyacrylate, alcohol-soluble tree After the mixing of fat, toluene di-isocyanate(TDI), isopropyl titanate, triethanolamine and sodium carboxymethylcellulose, 70 DEG C are heated to, stirring is straight To being completely dissolved and be well mixed;
(2)By zinc naphthenate, mill base, the smooth hard acid of sorb, cellulose derivative, hydracrylic acid, titanium dioxide, phenylalanine, froth breaking After agent and dimethyl sulfoxide (DMSO) mixing, it is heated to 100 DEG C and is stirred, to being completely dissolved and be well mixed;
(3)By step(1)And step(2)The two kinds of solution for obtaining are stirred at room temperature uniformly, and being subsequently adding in grinder is carried out Grinding 40 minutes.
The present invention has advantages below compared to existing technology:Nuisance is not contained in raw material prepared by present invention paint Matter, can avoid the air pollution in conventional paint drying process, using safety, to the basic non-hazardous of operating personnel, realize clear Clean production.And obtained environment protection oil paint tinting strength, tinting power is high, strong covering power, have nontoxic fragrance, environmental protection can also be effectively deodorant.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.
Embodiment one:
A kind of environment protection oil paint, including following parts by weight composition:30 parts of plastic propene's acid resin, 5 parts of cellulose acetate, lemon 3 parts of alkene, 3 parts of propane diols, 2 parts of barium chromate, 10 parts of polyacrylate, 20 parts of rosin modified alkyd resin, toluene di-isocyanate(TDI) 5 Part, 4 parts of isopropyl titanate, 2 parts of triethanolamine, 1 part of sodium carboxymethylcellulose, 1 part of zinc naphthenate, 4 parts of resin mill base, sorb are smooth 1 part of hard acid, 2 parts of methyl cellulose derivatives, 1 part of hydracrylic acid, 1 part of titanium dioxide, 1 part of phenylalanine, polypropylene glycerol aether 5 2 parts of part and dimethyl sulfoxide (DMSO).
A kind of preparation method of environment protection oil paint, comprises the following steps:
1)By 30 parts of plastic propene's acid resin, 5 parts of cellulose acetate, 3 parts of limonene, 3 parts of propane diols, 2 parts of barium chromate, polypropylene 10 parts of acid esters, 20 parts of rosin modified alkyd resin, 5 parts of toluene di-isocyanate(TDI), 4 parts of isopropyl titanate, 2 parts of triethanolamine and carboxylic 1 part of sodium carboxymethylcellulose pyce is placed on a container for stirring, is heated to 70 DEG C, until being completely dissolved;
2)By 1 part of zinc naphthenate, 4 parts of resin mill base, 1 part of the smooth hard acid of sorb, 2 parts of methyl cellulose derivatives, hydracrylic acid 1 Part, 1 part of titanium dioxide, 1 part of phenylalanine, 5 parts of polypropylene glycerol aether and 2 parts of dimethyl sulfoxide (DMSO) are placed on another vessel in heating It is stirred to 100 DEG C;
3)By step 1)With step 2)The two kinds of solution for obtaining are stirred at room temperature uniformly, are subsequently adding in grinder and are ground 40 minutes.
Embodiment two:
A kind of environment protection oil paint, including following parts by weight composition:40 parts of plastic propene's acid resin, 10 parts of cellulose acetate, lemon 5 parts of lemon alkene, 5 parts of propane diols, 4 parts of barium chromate, 15 parts of polyacrylate, 30 parts of rosin modified alkyd resin, toluene diisocynate 10 parts of ester, 6 parts of isopropyl titanate, 4 parts of triethanolamine, 3 parts of sodium carboxymethylcellulose, 3 parts of zinc naphthenate, 6 parts of resin mill base, mountain 3 parts of the smooth hard acid of pears, 4 parts of methyl cellulose derivatives, 3 parts of hydracrylic acid, 3 parts of titanium dioxide, phenylalanine-3,4-quinone part, polyoxypropylene are sweet 4 parts of 10 parts of oily ether and dimethyl sulfoxide (DMSO).
A kind of preparation method of environment protection oil paint, comprises the following steps:
1)By 40 parts of plastic propene's acid resin, 10 parts of cellulose acetate, 5 parts of limonene, 5 parts of propane diols, 4 parts of barium chromate, poly- third 15 parts of olefin(e) acid ester, 30 parts of rosin modified alkyd resin, 10 parts of toluene di-isocyanate(TDI), 6 parts of isopropyl titanate, 4 parts of triethanolamine 3 parts are placed on a container for stirring with sodium carboxymethylcellulose, 70 DEG C are heated to, until being completely dissolved;
2)By 3 parts of zinc naphthenate, 6 parts of resin mill base, 3 parts of the smooth hard acid of sorb, 4 parts of methyl cellulose derivatives, hydracrylic acid 3 4 parts of part, 3 parts of titanium dioxide, phenylalanine-3,4-quinone part, 10 parts of polypropylene glycerol aether and dimethyl sulfoxide (DMSO) add in being placed on another container Heat is stirred to 100 DEG C;
3)By step 1)With step 2)The two kinds of solution for obtaining are stirred at room temperature uniformly, are subsequently adding in grinder and are ground 40 minutes.
Embodiment three:
A kind of environment protection oil paint, including following parts by weight composition:35 parts of plastic propene's acid resin, 7 parts of cellulose acetate, lemon 4 parts of alkene, 4 parts of propane diols, 3 parts of barium chromate, 12 parts of polyacrylate, 25 parts of rosin modified alkyd resin, toluene di-isocyanate(TDI) 7 Part, 5 parts of isopropyl titanate, 3 parts of triethanolamine, 2 parts of sodium carboxymethylcellulose, 2 parts of zinc naphthenate, 5 parts of resin mill base, sorb are smooth 2 parts of hard acid, 3 parts of methylcellulose, 2 parts of hydracrylic acid, 2 parts of titanium dioxide, 2 parts of phenylalanine, 7 parts of polypropylene glycerol aether and two 3 parts of methyl sulfoxide.
A kind of preparation method of environment protection oil paint, comprises the following steps:
1)By 35 parts of plastic propene's acid resin, 7 parts of cellulose acetate, 4 parts of limonene, 4 parts of propane diols, 3 parts of barium chromate, polypropylene 12 parts of acid esters, 25 parts of rosin modified alkyd resin, 7 parts of toluene di-isocyanate(TDI), 5 parts of isopropyl titanate, 3 parts of triethanolamine and carboxylic 2 parts of sodium carboxymethylcellulose pyce is placed on a container for stirring, is heated to 70 DEG C, until being completely dissolved;
2)By 2 parts of zinc naphthenate, 5 parts of resin mill base, 2 parts of the smooth hard acid of sorb, 3 parts of methylcellulose, 2 parts of hydracrylic acid, titanium white 3 parts of 2 parts of powder, 2 parts of phenylalanine, 7 parts of polypropylene glycerol aether and dimethyl sulfoxide (DMSO) are placed on another vessel in heating to 100 DEG C It is stirred;
3)By step 1)With step 2)The two kinds of solution for obtaining are stirred at room temperature uniformly, are subsequently adding in grinder and are ground 40 minutes.
Under standard environment, environment protection oil paint obtained in various embodiments of the present invention is entered with existing paint as a control group Row performance comparison detects that the former paint viscosity of the paint that the present invention is prepared is 100-200, and working viscosity is 50-65, surface drying time ≤ 1h, does solid work the time≤24h, content of volatile organic compound≤200g/L, covering power≤40 g/m2, thickness of dry film >= 50um, concrete outcome is as follows:
As can be seen from the above table, its tinting strength, tinting power of the environment protection oil paint of the application, covering power are all better than existing paint on the market, and its Content of volatile organic compound is also significant lower, while also with nontoxic fragrance.
The present invention can avoid the air in conventional paint drying process dirty using harmful substance is not contained in raw material Dye, using safety, to the basic non-hazardous of operating personnel, realizes clean manufacturing;Tinting strength, tinting power is high, strong covering power, have nontoxic fragrance Smell, environmental protection can also be effectively deodorant.
The above, specific embodiment only of the invention, but protection scope of the present invention is not limited thereto, and it is any The change or replacement expected without creative work, should all cover and be defined in the new protection domain of this practicality.

Claims (4)

1. a kind of environment protection oil paint, it is characterised in that the component including following parts by weight:30-40 parts of plastic propene's acid resin, vinegar Acid cellulose 5-10 parts, limonene 3-5 parts, polyalcohol 3-5 parts, barium chromate 2-4 parts, polyacrylate 10-15 parts, alcohol-soluble tree Fat 20-30 parts, toluene di-isocyanate(TDI) 5-10 parts, isopropyl titanate 4-6 parts, triethanolamine 2-4 parts, sodium carboxymethylcellulose 1- 3 parts, zinc naphthenate 1-3 parts, mill base 4-6 parts, smooth hard acid 1-3 parts of sorb, cellulose derivative 2-4 parts, hydracrylic acid 1-3 parts, Titanium dioxide 1-3 parts, phenylalanine 1-3 parts, defoamer 5-10 parts and dimethyl sulfoxide (DMSO) 2-4 parts.
2. environment protection oil paint according to claim 1, it is characterised in that the component including following parts by weight:Plastic propene 35 parts of acid resin, 7 parts of cellulose acetate, 4 parts of limonene, 4 parts of polyalcohol, 3 parts of barium chromate, 12 parts of polyacrylate, alcohol-soluble 25 parts of resin, 7 parts of toluene di-isocyanate(TDI), 5 parts of isopropyl titanate, 3 parts of triethanolamine, 2 parts of sodium carboxymethylcellulose, aphthenic acids 2 parts of zinc, 5 parts of mill base, 2 parts of the smooth hard acid of sorb, 3 parts of cellulose derivative, 2 parts of hydracrylic acid, 2 parts of titanium dioxide, phenylalanine 2 3 parts of part, 7 parts of defoamer and dimethyl sulfoxide (DMSO).
3. environment protection oil paint according to claim 2, it is characterised in that:The polyalcohol uses propane diols;The alcohol-soluble Resin uses rosin modified alkyd resin;The mill base uses resin mill base;The cellulose derivative uses methylcellulose; The defoamer uses polypropylene glycerol aether.
4. the preparation method of any environment protection oil paint of claims 1 to 3, it is characterised in that comprise the following steps:
(1)By plastic propene's acid resin, cellulose acetate, limonene, polyalcohol, barium chromate, polyacrylate, alcohol-soluble tree After the mixing of fat, toluene di-isocyanate(TDI), isopropyl titanate, triethanolamine and sodium carboxymethylcellulose, 70 DEG C are heated to, stirring is straight To being completely dissolved and be well mixed;
(2)By zinc naphthenate, mill base, the smooth hard acid of sorb, cellulose derivative, hydracrylic acid, titanium dioxide, phenylalanine, froth breaking After agent and dimethyl sulfoxide (DMSO) mixing, it is heated to 100 DEG C and is stirred, to being completely dissolved and be well mixed;
(3)By step(1)And step(2)The two kinds of solution for obtaining are stirred at room temperature uniformly, and being subsequently adding in grinder is carried out Grinding 40 minutes.
CN201710151402.5A 2017-03-14 2017-03-14 A kind of environment protection oil paint and preparation method thereof Pending CN106833214A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108219609A (en) * 2018-01-24 2018-06-29 合肥万之景门窗有限公司 It is a kind of for environment protection oil paint of building doors and windows and preparation method thereof
CN109749551A (en) * 2017-11-08 2019-05-14 丹阳市博元安全生产服务有限公司 A kind of corrosion-resistant acrylic paint
CN111117462A (en) * 2020-01-06 2020-05-08 深圳市美施美克新材料有限公司 Two-component environment-friendly coating rich in d-limonene and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103642283A (en) * 2013-11-27 2014-03-19 潘海楠 Environment-friendly paint
CN104231757A (en) * 2014-09-02 2014-12-24 三凯社(江苏)新材料有限公司 Novel environment-friendly paint
CN104559630A (en) * 2014-12-30 2015-04-29 青岛佳尚创意文化有限公司 Environment-friendly paint formula
CN104559760A (en) * 2014-12-30 2015-04-29 青岛佳尚创意文化有限公司 Anti-corrosive paint formula
CN104893473A (en) * 2015-06-18 2015-09-09 张家港市山牧新材料技术开发有限公司 Environment-friendly compound paint
CN105462492A (en) * 2015-12-31 2016-04-06 文登蓝岛建筑工程有限公司 Environment-friendly paint and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103642283A (en) * 2013-11-27 2014-03-19 潘海楠 Environment-friendly paint
CN104231757A (en) * 2014-09-02 2014-12-24 三凯社(江苏)新材料有限公司 Novel environment-friendly paint
CN104559630A (en) * 2014-12-30 2015-04-29 青岛佳尚创意文化有限公司 Environment-friendly paint formula
CN104559760A (en) * 2014-12-30 2015-04-29 青岛佳尚创意文化有限公司 Anti-corrosive paint formula
CN104893473A (en) * 2015-06-18 2015-09-09 张家港市山牧新材料技术开发有限公司 Environment-friendly compound paint
CN105462492A (en) * 2015-12-31 2016-04-06 文登蓝岛建筑工程有限公司 Environment-friendly paint and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109749551A (en) * 2017-11-08 2019-05-14 丹阳市博元安全生产服务有限公司 A kind of corrosion-resistant acrylic paint
CN108219609A (en) * 2018-01-24 2018-06-29 合肥万之景门窗有限公司 It is a kind of for environment protection oil paint of building doors and windows and preparation method thereof
CN111117462A (en) * 2020-01-06 2020-05-08 深圳市美施美克新材料有限公司 Two-component environment-friendly coating rich in d-limonene and preparation method thereof

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Application publication date: 20170613

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