CN108610876A - A kind of environment protection oil paint - Google Patents

A kind of environment protection oil paint Download PDF

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Publication number
CN108610876A
CN108610876A CN201611167494.8A CN201611167494A CN108610876A CN 108610876 A CN108610876 A CN 108610876A CN 201611167494 A CN201611167494 A CN 201611167494A CN 108610876 A CN108610876 A CN 108610876A
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Prior art keywords
parts
nano
environment protection
calcium carbonate
oil
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CN201611167494.8A
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Chinese (zh)
Inventor
肖启宝
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Huizhou Green Peacock Polytron Technologies Inc
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Huizhou Green Peacock Polytron Technologies Inc
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Priority to CN201611167494.8A priority Critical patent/CN108610876A/en
Publication of CN108610876A publication Critical patent/CN108610876A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses a kind of environment protection oil paints, include the raw material of following parts by weight：10 18 parts of epoxy resin, 23 27 parts of amino resins, 15 19 parts of acrylic resin, 13 17 parts of alkyd resin, 17 21 parts of acrylic emulsion, 6 10 parts of nano-calcium carbonate calcium powder, 5 10 parts of nano-zinc oxide powder, 36 48 parts of limonene, 0.8 2.4 parts of the mica of coated by titanium dioxide, 5 11 parts of lactic acid, 15 20 parts of turpentine oil, 23 27 parts of tea-seed oil, 8 10 parts of acetic acid virtue camphor tree ester, 0.32 0.45 parts of dispersing aid, 0.32 0.45 parts of antifoaming agent, 8 15 parts of phthalic anhydride, 37 parts of coupling agent, 69 parts of pentaerythrite, the environment protection oil paint is nontoxic, water resistance is stronger, free from extraneous odour after having brushed, it will not cause damages to environment.

Description

A kind of environment protection oil paint
Technical field
The present invention relates to a kind of environment protection oil paints, more specifically, being related to paint field.
Background technology
Paint English name：paint or coating.Paint be it is a kind of can securely be covered in body surface, rise protection, dress The chemical mixture coating of decorations, mark and other specific uses.Chinese coating circle is more authoritative《Coating process》One book is this What sample defined：" coating is a kind of material, and this material can be coated in object surface with different construction technologies, form adherency Securely, there is some strength, continuous solid film.The film common name film formed in this way, also known as paint film or coating." belong to and have Machine chemical industry high molecular material is formed by film and belongs to high-molecular compound type.According to point of modern times current chemical products Class, coating belong to fine chemical product.Modern coating gradually becomes a kind of multi-functional engineering material, is chemical work An important industry in industry.
With the continuous improvement of people's lives, and environmentally friendly cry grows to even greater heights, and requirement of the people to decorative paint is more next Higher, paint product is not only related to the beauty and comfort of living environment, at present the taste after use of paint on the market Road is very big, poor water resistance, generally will can just be moved in or so point ventilative two weeks, many paint use in process of production Benzene class, ketone equal solvent, these solvent highly volatiles can cause environmental pollution, not only have in the production and use process Irritation taste, and the body of people can be injured, crisis health.So being currently badly in need of a kind of paint of low toxic and environment-friendly, to environment It is harmless with human body.
Invention content
In view of this, it is an object of the present invention to provide one kind, nontoxic, water resistance is relatively strong, has brushed rear free from extraneous odour, to environment The environment protection oil paint that will not be caused damages.
In order to solve the above-mentioned technical problem, the technical scheme is that：
A kind of environment protection oil paint includes the raw material of following parts by weight：10-18 parts of epoxy resin, 23-27 parts of amino resins, acrylic acid 15-19 parts of resin, 13-17 parts of alkyd resin, 17-21 parts of acrylic emulsion, 6-10 parts of nano-calcium carbonate calcium powder, nano zine oxide 5-11 parts of 0.8-2.4 parts of mica, lactic acid, the turpentine oil 15-20 of 5-10 parts of powder, 36-48 parts of limonene, coated by titanium dioxide Part, 23-27 parts of tea-seed oil, 8-10 parts of acetic acid virtue camphor tree ester, 0.32-0.45 parts of dispersing aid, 0.32-0.45 parts of antifoaming agent, adjacent benzene 8-15 parts of dicarboxylic acid anhydride, 3-7 parts of coupling agent, 6-9 parts of pentaerythrite.
Further, include the raw material of following parts by weight：10 parts of epoxy resin, 23 parts of amino resins, acrylic resin 15 Part, 13 parts of alkyd resin, 17 parts of acrylic emulsion, 6 parts of nano-calcium carbonate calcium powder, 5 parts of nano-zinc oxide powder, limonene 36 Part, 23 parts of 15 parts of 5 parts of 0.8 part of mica, lactic acid, turpentine oil, the tea-seed oil of coated by titanium dioxide, 8 parts of acetic acid virtue camphor tree ester, dispersion help 0.32 part of agent, 0.32 part of antifoaming agent, 8 parts of phthalic anhydride, 3 parts of coupling agent, 6 parts of pentaerythrite.
Further, include the raw material of following parts by weight：18 parts of epoxy resin, 27 parts of amino resins, acrylic resin 19 Part, 17 parts of alkyd resin, 21 parts of acrylic emulsion, 10 parts of nano-calcium carbonate calcium powder, 10 parts of nano-zinc oxide powder, limonene 48 Part, 27 parts of 20 parts of 11 parts of 2.4 parts of mica, lactic acid, turpentine oil, the tea-seed oil of coated by titanium dioxide, 10 parts of acetic acid virtue camphor tree ester, dispersion 0.45 part of auxiliary agent, 0.45 part of antifoaming agent, 15 parts of phthalic anhydride, 7 parts of coupling agent, 9 parts of pentaerythrite.
Further, include the raw material of following parts by weight：14 parts of epoxy resin, 25 parts of amino resins, acrylic resin 17 Part, 15 parts of alkyd resin, 19 parts of acrylic emulsion, 8 parts of nano-calcium carbonate calcium powder, 7.5 parts of nano-zinc oxide powder, limonene 42 Part, 25 parts of 17.5 parts of 8 parts of 1.6 parts of mica, lactic acid, turpentine oil, the tea-seed oil of coated by titanium dioxide, 9 parts of acetic acid virtue camphor tree ester, dispersion 0.39 part of auxiliary agent, 0.39 part of antifoaming agent, 11.5 parts of phthalic anhydride, 5 parts of coupling agent, 7.5 parts of pentaerythrite.
Further, the dispersing aid is styrene.
Further, the antifoaming agent is aluminum stearate.
Further, the nano-calcium carbonate calcium powder is activation nano-calcium carbonate calcium powder.
Further, the coupling agent is tetrapropoxysilane KH-301, KH-570, A-151, Si-602, monoalkoxy It is one or more in type titanate coupling agent.
The technology of the present invention effect major embodiment is in the following areas：By the way that epoxy resin, amino resins, acrylic acid tree is added Fat, alkyd resin, acrylic emulsion come ensure the environmentally protective paint being prepared have good environmental-protecting performance, nontoxic nothing Evil, will not give out the gas of environmental pollution in use；It is added to nano-calcium carbonate calcium powder, nano zinc oxide powder End, limonene, coated by titanium dioxide mica, improve paint meet water meet high temperature it is not easily to fall off, cracking performance.
Specific implementation mode
With reference to embodiments, the specific implementation mode of the present invention is described in further detail, so that technical solution of the present invention It is more readily understood and grasps.
Embodiment 1：
A kind of environment protection oil paint includes the raw material of following parts by weight：10 parts of epoxy resin, 23 parts of amino resins, acrylic resin 15 Part, 13 parts of alkyd resin, 17 parts of acrylic emulsion, 6 parts of nano-calcium carbonate calcium powder, 5 parts of nano-zinc oxide powder, limonene 36 Part, 23 parts of 15 parts of 5 parts of 0.8 part of mica, lactic acid, turpentine oil, the tea-seed oil of coated by titanium dioxide, 8 parts of acetic acid virtue camphor tree ester, dispersion help 0.32 part of agent, 0.32 part of antifoaming agent, 8 parts of phthalic anhydride, 3 parts of coupling agent, 6 parts of pentaerythrite, the dispersing aid are benzene Ethylene, the antifoaming agent are aluminum stearate, and the nano-calcium carbonate calcium powder is activation nano-calcium carbonate calcium powder, and the coupling agent is Tetrapropoxysilane KH-301.
A kind of preparation method of environment protection oil paint, includes the following steps：
1）By in 23 parts of 10 parts of epoxy resin, amino resins addition reaction kettle A, warming while stirring, speed of agitator is 280 turns/ Minute, 20 minutes time；
2）When temperature rises to 120 degrees Celsius, 17 parts of acrylic emulsion, 6 parts of nano-calcium carbonate calcium powder, nano zine oxide are added 5 parts of powder continues warming while stirring, when temperature rises to 180 degree, is kept for 15 minutes；
3) it is added by 0.32 part of 23 parts of tea-seed oil, 8 parts of acetic acid virtue camphor tree ester, dispersing aid additive formed, is put into stirring together It is smashed and is stirred evenly in machine, obtain mixture A.
4）By in 13 parts of 15 parts of acrylic resin, alkyd resin addition reaction kettle B, warming while stirring, speed of agitator is 200 revs/min, 25 minutes time；
5）When temperature rises to 120 degrees Celsius, add 36 parts of limonene, coated by titanium dioxide 5 parts of 0.8 part of mica, lactic acid, 15 parts of turpentine oil continues warming while stirring, when temperature rises to 150 degree, is kept for 20 minutes；
6) it is added by 6 parts of 0.32 part of antifoaming agent, 8 parts of phthalic anhydride, 3 parts of coupling agent, pentaerythrite additives formed, It is put into together in blender and is smashed and stirred evenly, obtain mixture B.
7) mixture A is put into mixing 2h in mixer together with mixture B, the mixture after mixing is fed by forcing Expect to carry out quickly rotation chain rupture in device indentation double screw extruder, the paint is made in 100 revs/min of rotary speed.
Embodiment 2：
A kind of environment protection oil paint includes the raw material of following parts by weight：18 parts of epoxy resin, 27 parts of amino resins, acrylic resin 19 Part, 17 parts of alkyd resin, 21 parts of acrylic emulsion, 10 parts of nano-calcium carbonate calcium powder, 10 parts of nano-zinc oxide powder, limonene 48 Part, 27 parts of 20 parts of 11 parts of 2.4 parts of mica, lactic acid, turpentine oil, the tea-seed oil of coated by titanium dioxide, 10 parts of acetic acid virtue camphor tree ester, dispersion 0.45 part of auxiliary agent, 0.45 part of antifoaming agent, 15 parts of phthalic anhydride, 7 parts of coupling agent, 9 parts of pentaerythrite, the dispersing aid are Styrene, the antifoaming agent are aluminum stearate, and the nano-calcium carbonate calcium powder is activation nano-calcium carbonate calcium powder, the coupling agent For tetrapropoxysilane KH-570.
A kind of preparation method of environment protection oil paint, includes the following steps：
1）By in 27 parts of 18 parts of epoxy resin, amino resins addition reaction kettle A, warming while stirring, speed of agitator is 280 turns/ Minute, 20 minutes time；
2）When temperature rises to 120 degrees Celsius, 21 parts of acrylic emulsion, 10 parts of nano-calcium carbonate calcium powder, nano oxidized is added 10 parts of zinc powder continues warming while stirring, when temperature rises to 180 degree, is kept for 15 minutes；
3) it is added by 0.45 part of 27 parts of tea-seed oil, 10 parts of acetic acid virtue camphor tree ester, dispersing aid additive formed, is put into stirs together It mixes and is smashed and stirred evenly in machine, obtain mixture A.
4）By in 17 parts of 19 parts of acrylic resin, alkyd resin addition reaction kettle B, warming while stirring, speed of agitator is 200 revs/min, 25 minutes time；
5）When temperature rises to 120 degrees Celsius, add 48 parts of limonene, coated by titanium dioxide 2.4 parts of mica, lactic acid 11 Part, 20 parts of turpentine oil continue warming while stirring, when temperature rises to 150 degree, are kept for 20 minutes；
6) it is added by 9 parts of 0.45 part of antifoaming agent, 15 parts of phthalic anhydride, 7 parts of coupling agent, pentaerythrite additives formed, It is put into together in blender and is smashed and stirred evenly, obtain mixture B.
7) mixture A is put into mixing 2h in mixer together with mixture B, the mixture after mixing is fed by forcing Expect to carry out quickly rotation chain rupture in device indentation double screw extruder, the paint is made in 160 revs/min of rotary speed.
Embodiment 3：
A kind of environment protection oil paint includes the raw material of following parts by weight：14 parts of epoxy resin, 25 parts of amino resins, acrylic resin 17 Part, 15 parts of alkyd resin, 19 parts of acrylic emulsion, 8 parts of nano-calcium carbonate calcium powder, 7.5 parts of nano-zinc oxide powder, limonene 42 Part, 25 parts of 17.5 parts of 8 parts of 1.6 parts of mica, lactic acid, turpentine oil, the tea-seed oil of coated by titanium dioxide, 9 parts of acetic acid virtue camphor tree ester, dispersion 0.39 part of auxiliary agent, 0.39 part of antifoaming agent, 11.5 parts of phthalic anhydride, 5 parts of coupling agent, 7.5 parts of pentaerythrite, the dispersion help Agent is styrene, and the antifoaming agent is aluminum stearate, and the nano-calcium carbonate calcium powder is activation nano-calcium carbonate calcium powder, the idol Connection agent is tetrapropoxysilane Si-602.
A kind of preparation method of environment protection oil paint, includes the following steps：
1）By in 25 parts of 14 parts of epoxy resin, amino resins addition reaction kettle A, warming while stirring, speed of agitator is 280 turns/ Minute, 20 minutes time；
2）When temperature rises to 120 degrees Celsius, 19 parts of acrylic emulsion, 8 parts of nano-calcium carbonate calcium powder, nano zine oxide are added 7.5 parts of powder continues warming while stirring, when temperature rises to 180 degree, is kept for 15 minutes；
3) it is added by 0.39 part of 25 parts of tea-seed oil, 9 parts of acetic acid virtue camphor tree ester, dispersing aid additive formed, is put into stirring together It is smashed and is stirred evenly in machine, obtain mixture A.
4）By in 15 parts of 17 parts of acrylic resin, alkyd resin addition reaction kettle B, warming while stirring, speed of agitator is 200 revs/min, 25 minutes time；
5）When temperature rises to 120 degrees Celsius, add 42 parts of limonene, coated by titanium dioxide 8 parts of 1.6 parts of mica, lactic acid, 17.5 parts of turpentine oil continues warming while stirring, when temperature rises to 150 degree, is kept for 20 minutes；
6) it is added and is added by what 0.39 part of antifoaming agent, 11.5 parts of phthalic anhydride, 5 parts of coupling agent, 7.5 parts of pentaerythrite were formed Add agent, be put into together in blender and smashed and stirred evenly, obtains mixture B.
7) mixture A is put into mixing 2h in mixer together with mixture B, the mixture after mixing is fed by forcing Expect to carry out quickly rotation chain rupture in device indentation double screw extruder, the paint is made in 130 revs/min of rotary speed.
Experimental example：
Paint and the commercially available contrast test for painting progress performance respectively is made in above-described embodiment, the results show that sample items It can be superior to commercially available floor.Specific experiment result see the table below
As shown in the table：
As seen from the above table, the formaldehyde of environment protection oil paint of the invention and benzene hydrocarbon gase burst size are significantly lower than commercially available paint, and heat-resisting Water cycle, heat-resisting quantity and water resistance are apparently higher than commercially available paint.
The technology of the present invention effect major embodiment is in the following areas：By the way that epoxy resin, amino resins, acrylic acid tree is added Fat, alkyd resin, acrylic emulsion come ensure the environmentally protective paint being prepared have good environmental-protecting performance, nontoxic nothing Evil, will not give out the gas of environmental pollution in use；It is added to nano-calcium carbonate calcium powder, nano zinc oxide powder End, limonene, coated by titanium dioxide mica, improve paint meet water meet high temperature it is not easily to fall off, cracking performance.
Certainly, the representative instance of the above only present invention, in addition to this, the present invention can also have other a variety of specific implementations Mode, all technical solutions formed using equivalent substitution or equivalent transformation, is all fallen within the scope of protection of present invention.

Claims (8)

1. a kind of environment protection oil paint, which is characterized in that include the raw material of following parts by weight：10-18 parts of epoxy resin, amino resins 23-27 parts, 15-19 parts of acrylic resin, 13-17 parts of alkyd resin, 17-21 parts of acrylic emulsion, nano-calcium carbonate calcium powder 6- 10 parts, 0.8-2.4 parts of mica, the lactic acid 5-11 of 5-10 parts of nano-zinc oxide powder, 36-48 parts of limonene, coated by titanium dioxide Part, 15-20 parts of turpentine oil, 23-27 parts of tea-seed oil, 8-10 parts of acetic acid virtue camphor tree ester, 0.32-0.45 parts of dispersing aid, antifoaming agent 0.32-0.45 parts, 8-15 parts of phthalic anhydride, 3-7 parts of coupling agent, 6-9 parts of pentaerythrite.
2. environment protection oil paint according to claim 1, it is characterised in that：Include the raw material of following parts by weight：Epoxy resin 10 Part, 23 parts of amino resins, 15 parts of acrylic resin, 13 parts of alkyd resin, 17 parts of acrylic emulsion, 6 parts of nano-calcium carbonate calcium powder, 5 parts of nano-zinc oxide powder, 36 parts of limonene, 15 parts of 5 parts of 0.8 part of mica, lactic acid, the turpentine oil of coated by titanium dioxide, ribes 23 parts of oil, 8 parts of acetic acid virtue camphor tree ester, 0.32 part of dispersing aid, 0.32 part of antifoaming agent, 8 parts of phthalic anhydride, 3 parts of coupling agent, season Penta 6 parts of tetrol.
3. environment protection oil paint according to claim 1, it is characterised in that：Include the raw material of following parts by weight：Epoxy resin 18 Part, 27 parts of amino resins, 19 parts of acrylic resin, 17 parts of alkyd resin, 21 parts of acrylic emulsion, nano-calcium carbonate calcium powder 10 Part, 10 parts of nano-zinc oxide powder, 48 parts of limonene, coated by titanium dioxide 20 parts of 11 parts of 2.4 parts of mica, lactic acid, turpentine oil, 27 parts of tea-seed oil, 10 parts of acetic acid virtue camphor tree ester, 0.45 part of dispersing aid, 0.45 part of antifoaming agent, 15 parts of phthalic anhydride, coupling agent 7 parts, 9 parts of pentaerythrite.
4. environment protection oil paint according to claim 3, it is characterised in that：Include the raw material of following parts by weight：Epoxy resin 14 Part, 25 parts of amino resins, 17 parts of acrylic resin, 15 parts of alkyd resin, 19 parts of acrylic emulsion, 8 parts of nano-calcium carbonate calcium powder, 7.5 parts of nano-zinc oxide powder, 42 parts of limonene, coated by titanium dioxide 17.5 parts of 8 parts of 1.6 parts of mica, lactic acid, turpentine oil, 25 parts of tea-seed oil, 9 parts of acetic acid virtue camphor tree ester, 0.39 part of dispersing aid, 0.39 part of antifoaming agent, 11.5 parts of phthalic anhydride, coupling 5 parts of agent, 7.5 parts of pentaerythrite.
5. according to the environment protection oil paint described in any one of claim 1-4, it is characterised in that：The dispersing aid is styrene.
6. environment protection oil paint according to claim 5, it is characterised in that：The antifoaming agent is aluminum stearate.
7. environment protection oil paint according to claim 6, it is characterised in that：The nano-calcium carbonate calcium powder is activation nano-calcium carbonate Calcium powder.
8. environment protection oil paint according to claim 7, it is characterised in that：The coupling agent is tetrapropoxysilane KH- 301, one or more in KH-570, A-151, Si-602, monoalkoxy type titanate coupling agent.
CN201611167494.8A 2016-12-16 2016-12-16 A kind of environment protection oil paint Withdrawn CN108610876A (en)

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CN201611167494.8A CN108610876A (en) 2016-12-16 2016-12-16 A kind of environment protection oil paint

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Application Number Priority Date Filing Date Title
CN201611167494.8A CN108610876A (en) 2016-12-16 2016-12-16 A kind of environment protection oil paint

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111117462A (en) * 2020-01-06 2020-05-08 深圳市美施美克新材料有限公司 Two-component environment-friendly coating rich in d-limonene and preparation method thereof
CN112898860A (en) * 2019-11-19 2021-06-04 湖南红崀山木业科技有限公司 Production process of plate-type furniture

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112898860A (en) * 2019-11-19 2021-06-04 湖南红崀山木业科技有限公司 Production process of plate-type furniture
CN111117462A (en) * 2020-01-06 2020-05-08 深圳市美施美克新材料有限公司 Two-component environment-friendly coating rich in d-limonene and preparation method thereof

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