CN108219609A - It is a kind of for environment protection oil paint of building doors and windows and preparation method thereof - Google Patents
It is a kind of for environment protection oil paint of building doors and windows and preparation method thereof Download PDFInfo
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- CN108219609A CN108219609A CN201810067682.6A CN201810067682A CN108219609A CN 108219609 A CN108219609 A CN 108219609A CN 201810067682 A CN201810067682 A CN 201810067682A CN 108219609 A CN108219609 A CN 108219609A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
- C09D101/08—Cellulose derivatives
- C09D101/26—Cellulose ethers
- C09D101/28—Alkyl ethers
- C09D101/286—Alkyl ethers substituted with acid radicals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
Present invention offer is a kind of for environment protection oil paint of building doors and windows and preparation method thereof, which is formulated by following component：Alcohol-soluble resin, triethanolamine, modified epoxy, plant oil pastes, calcium carbonate, titanium dioxide, aluminium oxide, hydracrylic acid, sodium carboxymethylcellulose, curing agent, dispersant, thickener, environmentally friendly auxiliary agent and water.For environment protection oil paint prepared by the present invention using rear non-toxic and tasteless, no environmental pollution can effectively eliminate organic compound volatile quantity, and paint with good stability, and preparation method is simple, easy to operate, is suitble to industrialization large-scale promotion production.
Description
Technical field
The invention belongs to paint manufacture technology field, and in particular to a kind of environment protection oil paint and its preparation for building doors and windows
Method.
Background technology
Paint be it is a kind of can securely be covered in body surface, play protection, decoration, mark and the chemistry of other specific uses and mix
Close object.Paint is generally made of four parts such as film forming matter, filler (color stuffing), solvent, auxiliary agents.According to performance requirement sometimes into
Part can be slightly changed.According to the classification for the chemical products that the modern times pass through, paint belongs to fine chemical product.Modern paint is
Gradually become a kind of multi-functional engineering material, be an important industry in chemical industry.Paint is fitting-up process
In indispensable material.Since improvement of living standard and environmentally friendly cry grow to even greater heights, requirement of the people to paint for decoration
It is higher and higher.Paint as viscous oily pigment, it is inflammable in the case of not dry, it is not soluble in water, be slightly soluble in fat, dissolve in alcohol, aldehyde,
Ether, benzene, alkane are soluble in gasoline, kerosene, diesel oil.There are many paint type currently on the market, but mainly also have a small amount of containing toluene
Benzene influences human body after very big paint at present is all chemicals especially application, can constantly volatile organic compound (VOC)
With episome (TDI).Not only to the Nature generate ozone pollution, but also can make human body cause headache, general paralysis, anaemia,
The various diseases such as cancer bring serious threat to health, but are a kind of unavoidable essential materials.But in the market
Paint contain harmful chemical mostly, it is very big using rear taste, and constantly distribute some organic compounds and be free in air
In, the health of consumer is affected to a certain extent.
In conclusion therefore it is badly in need of a kind of environment protection oil paint to improve the deficiencies in the prior art.
Invention content
The object of the present invention is to provide a kind of for environment protection oil paint of building doors and windows and preparation method thereof, prepared by the present invention
Environment protection oil paint uses rear non-toxic and tasteless, no environmental pollution, can effectively eliminate organic compound volatile quantity, and paint with good
Stability, preparation method is simple, easy to operate, be suitble to industrialization large-scale promotion production.
The present invention provides following technical solutions：
A kind of environment protection oil paint for building doors and windows includes the raw material of following parts by weight：28-35 parts of alcohol-soluble resin, three ethyl alcohol
22-28 parts of amine, 24-30 parts of modified epoxy, 34-38 parts of plant oil pastes, 22-26 parts of calcium carbonate, titanium dioxide 21-25
Part, 12-15 parts of aluminium oxide, 18-22 parts of hydracrylic acid, 17-20 parts of sodium carboxymethylcellulose, 12-16 parts of curing agent, dispersant
40-50 parts of 13-17 parts, 10-14 parts of thickener, 12-15 parts of environmentally friendly auxiliary agent and water.
The preparation method of a kind of environment protection oil paint for building doors and windows, including following preparation process：
A, it is imported after mixing alcohol-soluble resin, triethanolamine, modified epoxy, hydracrylic acid and sodium carboxymethylcellulose high
It in mixed machine, heats and stirs, temperature is mixed for 80-90 DEG C, mixing speed 200-300r/min, time 30-40min
Close object one；
B, calcium carbonate and titanium dioxide are directed respectively into ball mill and grind 2-3h, recycle ultrasonic grind into nano particle,
Nano-calcium carbonate and nano-titanium dioxide are respectively obtained, then nano-calcium carbonate and nano-titanium dioxide are prepared into Viability receive respectively
Rice calcium carbonate and nano titanium oxide dispersion；
C, plant oil pastes, curing agent and water are added in into mixture one, heats and stirs, is warming up to 100-110 DEG C, stirring
After 15-20min, after natural cooling, add in aluminium oxide and grind, obtain slurry；
D, active nano-calcium carbonate, nano titanium oxide dispersion, dispersant and thickener are added in into slurry, at 60-75 DEG C
Lower heating is simultaneously stirred, mixing speed 100-120r/min, stir to mixture into it is thick when stop heating, add in environmental protection help
Agent stirs evenly and can obtain finished product.
Preferably, the alcohol-soluble resin of the step a is acrylic resin, acrylic resin, isopropyl titanate and poly- third
Any one of olefin(e) acid ester or several mixing.
Preferably, the preparation method of the modified epoxy of the step a is：Epoxy resin is added in reaction kettle,
100-120 DEG C is heated to, then adds aluminum sulfate, suberic acid, after stirring evenly, after keeping the temperature 20-30min, is cooled to 80-90
DEG C, then chitosan, beta-cyclodextrin are added, and 15-25min is stirred under 300-400r/min rotating speeds, after heat preservation stands 15-20min,
Cooled to room temperature, you can.
Preferably, the active nano-calcium carbonate preparation method of the step b is：Nano-calcium carbonate is added to sodium soap
In solution, carbon dioxide is passed through, the pH for adjusting solution is 4-6, and control activation temperature is 90-100 DEG C, after filtering, by what is obtained
Solid matter is dried.
Preferably, the preparation method of the nano titanium oxide dispersion of the step b is：By nano-titanium dioxide, dispersion
Agent and water are added in blender together, and 30-45min is stirred under the rotating speed of 200-300r/min.
Preferably, the preparation method of the curing agent of the step c is：By polyester-diol, glycidol ether and metering system
Isoamyl valerate is added in reaction kettle, after stirring evenly, is heated to 50-55 DEG C, after keeping the temperature 20-30min, adds cashew nut oil and stirs
It mixes uniformly, keeps the temperature 10-15min, you can.
Preferably, the preparation method of the environmentally friendly auxiliary agent of the step d is：By hymecromone, flavonoid glycoside, Kaempferol, dragon
Certain herbaceous plants with big flowers alkali, nordihydrocapsaicin are added in reaction kettle successively, adjust pH to 9-10, add ethanol solution, raise the temperature to
To 45-50 DEG C, after stirring 40-60min under 80-90r/min rotating speeds, stop stirring, heat preservation stands 1-2h, you can.
The beneficial effects of the invention are as follows：
For environment protection oil paint prepared by the present invention using rear non-toxic and tasteless, no environmental pollution can effectively eliminate organic compound volatile quantity,
And paint with good stability, preparation method is simple, easy to operate, is suitble to industrialization large-scale promotion production.
Plant oil pastes materials in the present invention are pure natural, pollution-free, volatility is small, finished product from natural plants
Do not have peculiar smell；Thickener and modified epoxy in the present invention can cause the viscosity of paint to improve, not volatile, be not easy
Blistering is rotten；Active nano-calcium carbonate and nano titanium oxide dispersion in the present invention can play the role of restraining and sterilizing bacteria, also
It can effectively avoid painting the generation of the penetrating odor during storage, it is more environmentally-friendly, environmental pollution and human body will not be caused to hinder
Evil.
Specific embodiment
Embodiment 1
A kind of environment protection oil paint for building doors and windows includes the raw material of following parts by weight：35 parts of alcohol-soluble resin, triethanolamine 28
Part, 24 parts of modified epoxy, 38 parts of plant oil pastes, 22 parts of calcium carbonate, 21 parts of titanium dioxide, 15 parts of aluminium oxide, hydroxyl
18 parts of propionic acid, 20 parts of sodium carboxymethylcellulose, 12 parts of curing agent, 17 parts of dispersant, 10 parts of thickener, 15 parts of environmentally friendly auxiliary agent and water
40 parts.
The preparation method of a kind of environment protection oil paint for building doors and windows, including following preparation process：
A, it is imported after mixing alcohol-soluble resin, triethanolamine, modified epoxy, hydracrylic acid and sodium carboxymethylcellulose high
It in mixed machine, heats and stirs, temperature obtains mixture one for 90 DEG C, mixing speed 200r/min, time 40min；
B, calcium carbonate and titanium dioxide are directed respectively into ball mill and grind 3h, ultrasonic grind is recycled to divide into nano particle
Nano-calcium carbonate and nano-titanium dioxide are not obtained, then nano-calcium carbonate and nano-titanium dioxide are configured to active nano respectively
Calcium carbonate and nano titanium oxide dispersion；
C, plant oil pastes, curing agent and water are added in into mixture one, heats and stirs, is warming up to 110 DEG C, stirring
After 15min, after natural cooling, add in aluminium oxide and grind, obtain slurry；
D, active nano-calcium carbonate, nano titanium oxide dispersion, dispersant and thickener are added in into slurry, is added at 65 DEG C
Heat simultaneously stirs, mixing speed 120r/min, stir to mixture into it is thick when stop heating, add in environmentally friendly auxiliary agent, stirring
Uniformly it can obtain finished product.
The alcohol-soluble resin of step a is the mixing of acrylic resin, isopropyl titanate and polyacrylate.
The preparation method of the modified epoxy of step a is：Epoxy resin is added in reaction kettle, is heated to 100 DEG C,
Then aluminum sulfate, suberic acid are added, after stirring evenly, after keeping the temperature 20min, is cooled to 90 DEG C, then adds chitosan, β-ring paste
Essence stirs 25min under 300r/min rotating speeds, after heat preservation stands 15min, cooled to room temperature, you can.
The active nano-calcium carbonate preparation method of step b is：Nano-calcium carbonate is added in sodium soap solution, is passed through
Carbon dioxide, the pH for adjusting solution are 5, and control activation temperature is 90 DEG C, and after filtering, obtained solid matter is dried.
The preparation method of the nano titanium oxide dispersion of step b is：Nano-titanium dioxide, dispersant and water are added together
Enter into blender, 35min is stirred under the rotating speed of 200r/min.
The preparation method of the curing agent of step c is：Polyester-diol, glycidol ether and isopentyl methacrylate are added
Into reaction kettle, after stirring evenly, 55 DEG C are heated to, after keeping the temperature 20min, cashew nut oil is added and stirs evenly, keep the temperature 15min,
.
The preparation method of the environmentally friendly auxiliary agent of step d is：By hymecromone, flavonoid glycoside, Kaempferol, solanine, drop dihydro
Capsaicine is added in reaction kettle successively, adjusts pH to 9, adds ethanol solution, raise the temperature to 50 DEG C, in 80r/
After stirring 60min under min rotating speeds, stop stirring, heat preservation stands 1h, you can.
Embodiment 2
A kind of environment protection oil paint for building doors and windows includes the raw material of following parts by weight：28 parts of alcohol-soluble resin, triethanolamine 22
Part, 24 parts of modified epoxy, 34 parts of plant oil pastes, 22 parts of calcium carbonate, 21 parts of titanium dioxide, 12 parts of aluminium oxide, hydroxyl
18 parts of propionic acid, 17 parts of sodium carboxymethylcellulose, 12 parts of curing agent, 13 parts of dispersant, 10 parts of thickener, 12 parts of environmentally friendly auxiliary agent and water
40 parts.
The preparation method of a kind of environment protection oil paint for building doors and windows, including following preparation process：
A, it is imported after mixing alcohol-soluble resin, triethanolamine, modified epoxy, hydracrylic acid and sodium carboxymethylcellulose high
It in mixed machine, heats and stirs, temperature obtains mixture one for 80 DEG C, mixing speed 200r/min, time 30min；
B, calcium carbonate and titanium dioxide are directed respectively into ball mill and grind 2h, ultrasonic grind is recycled to divide into nano particle
Nano-calcium carbonate and nano-titanium dioxide are not obtained, then nano-calcium carbonate and nano-titanium dioxide are configured to active nano respectively
Calcium carbonate and nano titanium oxide dispersion；
C, plant oil pastes, curing agent and water are added in into mixture one, heats and stirs, is warming up to 100 DEG C, stirring
After 15min, after natural cooling, add in aluminium oxide and grind, obtain slurry；
D, active nano-calcium carbonate, nano titanium oxide dispersion, dispersant and thickener are added in into slurry, is added at 65 DEG C
Heat simultaneously stirs, mixing speed 100r/min, stir to mixture into it is thick when stop heating, add in environmentally friendly auxiliary agent, stirring
Uniformly it can obtain finished product.
The alcohol-soluble resin of step a is the mixing of acrylic resin, isopropyl titanate and polyacrylate.
The preparation method of the modified epoxy of step a is：Epoxy resin is added in reaction kettle, is heated to 100 DEG C,
Then aluminum sulfate, suberic acid are added, after stirring evenly, after keeping the temperature 20min, is cooled to 80 DEG C, then adds chitosan, β-ring paste
Essence stirs 15min under 300r/min rotating speeds, after heat preservation stands 15min, cooled to room temperature, you can.
The active nano-calcium carbonate preparation method of step b is：Nano-calcium carbonate is added in sodium soap solution, is passed through
Carbon dioxide, the pH for adjusting solution are 4, and control activation temperature is 90 DEG C, and after filtering, obtained solid matter is dried.
The preparation method of the nano titanium oxide dispersion of step b is：Nano-titanium dioxide, dispersant and water are added together
Enter into blender, 30min is stirred under the rotating speed of 200r/min.
The preparation method of the curing agent of step c is：Polyester-diol, glycidol ether and isopentyl methacrylate are added
Into reaction kettle, after stirring evenly, 50 DEG C are heated to, after keeping the temperature 20min, cashew nut oil is added and stirs evenly, keep the temperature 10min,
.
The preparation method of the environmentally friendly auxiliary agent of step d is：By hymecromone, flavonoid glycoside, Kaempferol, solanine, drop dihydro
Capsaicine is added in reaction kettle successively, adjusts pH to 9, adds ethanol solution, raise the temperature to 45 DEG C, in 80r/
After stirring 40min under min rotating speeds, stop stirring, heat preservation stands 1h, you can.
Embodiment 3
A kind of environment protection oil paint for building doors and windows includes the raw material of following parts by weight：35 parts of alcohol-soluble resin, triethanolamine 28
Part, 30 parts of modified epoxy, 38 parts of plant oil pastes, 26 parts of calcium carbonate, 25 parts of titanium dioxide, 15 parts of aluminium oxide, hydroxyl
22 parts of propionic acid, 17 parts of sodium carboxymethylcellulose, 16 parts of curing agent, 17 parts of dispersant, 10 parts of thickener, 15 parts of environmentally friendly auxiliary agent and water
50 parts.
The preparation method of a kind of environment protection oil paint for building doors and windows, including following preparation process：
A, it is imported after mixing alcohol-soluble resin, triethanolamine, modified epoxy, hydracrylic acid and sodium carboxymethylcellulose high
It in mixed machine, heats and stirs, temperature obtains mixture one for 90 DEG C, mixing speed 300r/min, time 40min；
B, calcium carbonate and titanium dioxide are directed respectively into ball mill and grind 3h, ultrasonic grind is recycled to divide into nano particle
Nano-calcium carbonate and nano-titanium dioxide are not obtained, then nano-calcium carbonate and nano-titanium dioxide are configured to active nano respectively
Calcium carbonate and nano titanium oxide dispersion；
C, plant oil pastes, curing agent and water are added in into mixture one, heats and stirs, is warming up to 110 DEG C, stirring
After 20min, after natural cooling, add in aluminium oxide and grind, obtain slurry；
D, active nano-calcium carbonate, nano titanium oxide dispersion, dispersant and thickener are added in into slurry, is added at 75 DEG C
Heat simultaneously stirs, mixing speed 120r/min, stir to mixture into it is thick when stop heating, add in environmentally friendly auxiliary agent, stirring
Uniformly it can obtain finished product.
The alcohol-soluble resin of step a is the mixed of acrylic resin, acrylic resin, isopropyl titanate and polyacrylate
It closes.
The preparation method of the modified epoxy of step a is：Epoxy resin is added in reaction kettle, is heated to 120 DEG C,
Then aluminum sulfate, suberic acid are added, after stirring evenly, after keeping the temperature 30min, is cooled to 90 DEG C, then adds chitosan, β-ring paste
Essence stirs 25min under 400r/min rotating speeds, after heat preservation stands 20min, cooled to room temperature, you can.
The active nano-calcium carbonate preparation method of step b is：Nano-calcium carbonate is added in sodium soap solution, is passed through
Carbon dioxide, the pH for adjusting solution are 6, and control activation temperature is 100 DEG C, and after filtering, obtained solid matter is dried.
The preparation method of the nano titanium oxide dispersion of step b is：Nano-titanium dioxide, dispersant and water are added together
Enter into blender, 45min is stirred under the rotating speed of 300r/min.
The preparation method of the curing agent of step c is：Polyester-diol, glycidol ether and isopentyl methacrylate are added
Into reaction kettle, after stirring evenly, 55 DEG C are heated to, after keeping the temperature 30min, cashew nut oil is added and stirs evenly, keep the temperature 15min,
.
The preparation method of the environmentally friendly auxiliary agent of step d is：By hymecromone, flavonoid glycoside, Kaempferol, solanine, drop dihydro
Capsaicine is added in reaction kettle successively, adjusts pH to 10, adds ethanol solution, raise the temperature to 50 DEG C, in 90r/
After stirring 60min under min rotating speeds, stop stirring, heat preservation stands 2h, you can.
Finished product prepared by above example is detected, obtains data below：
Table one：
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Detection method |
| Condition in container | Homogeneous (uniform) fluid, no lump | Homogeneous (uniform) fluid, no lump | Homogeneous (uniform) fluid, no lump | Range estimation |
| Volatile organic compound content（g/L） | 168 | 165 | 170 | HBC12-2002 |
| Covering power（g/m3） | 35 | 45 | 43 | GB/T1726 |
| Dry thickness（um） | 52 | 60 | 61 | GB11764 |
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to the foregoing embodiments
The present invention is described in detail, it for those skilled in the art, still can be to foregoing embodiments institute
The technical solution of record modifies or carries out equivalent replacement to which part technical characteristic.It is all the present invention spirit and
Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of environment protection oil paint for building doors and windows, which is characterized in that include the raw material of following parts by weight：Alcohol-soluble resin
28-35 parts, 22-28 parts of triethanolamine, 24-30 parts of modified epoxy, 34-38 parts of plant oil pastes, calcium carbonate 22-26
Part, 21-25 parts of titanium dioxide, 12-15 parts of aluminium oxide, 18-22 parts of hydracrylic acid, 17-20 parts of sodium carboxymethylcellulose, curing agent
40-50 parts of 12-16 parts, 13-17 parts of dispersant, 10-14 parts of thickener, 12-15 parts of environmentally friendly auxiliary agent and water.
2. the preparation method of a kind of environment protection oil paint for building doors and windows described in claim 1, which is characterized in that including following
Preparation process：
A, it is imported after mixing alcohol-soluble resin, triethanolamine, modified epoxy, hydracrylic acid and sodium carboxymethylcellulose high
It in mixed machine, heats and stirs, temperature is mixed for 80-90 DEG C, mixing speed 200-300r/min, time 30-40min
Close object one；
B, calcium carbonate and titanium dioxide are directed respectively into ball mill and grind 2-3h, recycle ultrasonic grind into nano particle,
Nano-calcium carbonate and nano-titanium dioxide are respectively obtained, then nano-calcium carbonate and nano-titanium dioxide are prepared into Viability receive respectively
Rice calcium carbonate and nano titanium oxide dispersion；
C, plant oil pastes, curing agent and water are added in into mixture one, heats and stirs, is warming up to 100-110 DEG C, stirring
After 15-20min, after natural cooling, add in aluminium oxide and grind, obtain slurry；
D, active nano-calcium carbonate, nano titanium oxide dispersion, dispersant and thickener are added in into slurry, at 60-75 DEG C
Lower heating is simultaneously stirred, mixing speed 100-120r/min, stir to mixture into it is thick when stop heating, add in environmental protection help
Agent stirs evenly and can obtain finished product.
3. the preparation method of a kind of environment protection oil paint for building doors and windows according to claim 2, which is characterized in that described
The alcohol-soluble resin of step a is any one of acrylic resin, acrylic resin, isopropyl titanate and polyacrylate or several
The mixing of kind.
4. the preparation method of a kind of environment protection oil paint for building doors and windows according to claim 2, which is characterized in that described
The preparation method of the modified epoxy of step a is：Epoxy resin is added in reaction kettle, is heated to 100-120 DEG C, then
Aluminum sulfate, suberic acid are added, after stirring evenly, after keeping the temperature 20-30min, is cooled to 80-90 DEG C, then adds chitosan, β-ring paste
Essence stirs 15-25min under 300-400r/min rotating speeds, after heat preservation stands 15-20min, cooled to room temperature, you can.
5. the preparation method of a kind of environment protection oil paint for building doors and windows according to claim 2, which is characterized in that described
The active nano-calcium carbonate preparation method of step b is：Nano-calcium carbonate is added in sodium soap solution, is passed through titanium dioxide
Carbon, the pH for adjusting solution are 4-6, and control activation temperature is 90-100 DEG C, and after filtering, obtained solid matter is dried.
6. the preparation method of a kind of environment protection oil paint for building doors and windows according to claim 2, which is characterized in that described
The preparation method of the nano titanium oxide dispersion of step b is：Nano-titanium dioxide, dispersant and water are added to stirring together
In machine, 30-45min is stirred under the rotating speed of 200-300r/min.
7. the preparation method of a kind of environment protection oil paint for building doors and windows according to claim 2, which is characterized in that described
The preparation method of the curing agent of step c is：Polyester-diol, glycidol ether and isopentyl methacrylate are added to reaction kettle
In, after stirring evenly, 50-55 DEG C is heated to, after keeping the temperature 20-30min, cashew nut oil is added and stirs evenly, keep the temperature 10-15min,
.
8. the preparation method of a kind of environment protection oil paint for building doors and windows according to claim 2, which is characterized in that described
The preparation method of the environmentally friendly auxiliary agent of step d is：By hymecromone, flavonoid glycoside, Kaempferol, solanine, nordihydrocapsaicin according to
It is secondary to be added in reaction kettle, pH to 9-10 is adjusted, ethanol solution is added, raises the temperature to 45-50 DEG C, in 80-90r/
After stirring 40-60min under min rotating speeds, stop stirring, heat preservation stands 1-2h, you can.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810067682.6A CN108219609A (en) | 2018-01-24 | 2018-01-24 | It is a kind of for environment protection oil paint of building doors and windows and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810067682.6A CN108219609A (en) | 2018-01-24 | 2018-01-24 | It is a kind of for environment protection oil paint of building doors and windows and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN108219609A true CN108219609A (en) | 2018-06-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810067682.6A Withdrawn CN108219609A (en) | 2018-01-24 | 2018-01-24 | It is a kind of for environment protection oil paint of building doors and windows and preparation method thereof |
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| CN (1) | CN108219609A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109054610A (en) * | 2018-07-11 | 2018-12-21 | 合肥伊只门窗有限公司 | A kind of aluminum alloy doors and windows anticorrosive paint and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE728735A (en) * | 1967-09-07 | 1969-08-01 | ||
| CN1491893A (en) * | 2002-10-25 | 2004-04-28 | 张生生 | Process for preparing high activity active nano calcium carbonate |
| CN105670510A (en) * | 2016-04-05 | 2016-06-15 | 陈淳 | Environment-friendly paint and preparation method thereof |
| CN106221502A (en) * | 2016-08-17 | 2016-12-14 | 安徽江淮车轮有限公司 | A kind of antifouling environment protection oil paint of steel ring wheel |
| CN106833214A (en) * | 2017-03-14 | 2017-06-13 | 南京信息工程大学 | A kind of environment protection oil paint and preparation method thereof |
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2018
- 2018-01-24 CN CN201810067682.6A patent/CN108219609A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE728735A (en) * | 1967-09-07 | 1969-08-01 | ||
| CN1491893A (en) * | 2002-10-25 | 2004-04-28 | 张生生 | Process for preparing high activity active nano calcium carbonate |
| CN105670510A (en) * | 2016-04-05 | 2016-06-15 | 陈淳 | Environment-friendly paint and preparation method thereof |
| CN106221502A (en) * | 2016-08-17 | 2016-12-14 | 安徽江淮车轮有限公司 | A kind of antifouling environment protection oil paint of steel ring wheel |
| CN106833214A (en) * | 2017-03-14 | 2017-06-13 | 南京信息工程大学 | A kind of environment protection oil paint and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109054610A (en) * | 2018-07-11 | 2018-12-21 | 合肥伊只门窗有限公司 | A kind of aluminum alloy doors and windows anticorrosive paint and preparation method thereof |
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Application publication date: 20180629 |