CN107312408A - A kind of novel environment friendly paint and preparation method thereof - Google Patents
A kind of novel environment friendly paint and preparation method thereof Download PDFInfo
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- CN107312408A CN107312408A CN201710536984.9A CN201710536984A CN107312408A CN 107312408 A CN107312408 A CN 107312408A CN 201710536984 A CN201710536984 A CN 201710536984A CN 107312408 A CN107312408 A CN 107312408A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2286—Oxides; Hydroxides of metals of silver
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
The invention discloses a kind of novel environment friendly paint, include the raw material of following parts by weight：10~20 parts of aqueous alkide resin, 20~30 parts of thermoplastic acrylic resin, 15~25 parts of amino resins, 8~13 parts of cobalt iso-octoate, 5~10 parts of pentaerythrite, 3~7 parts of dipropylene, 5~10 parts of kaolin, 4~6 parts of nano phase ag_2 o, 3~12 parts of plant oil pastes, 6~9 parts of mica powder, 2~4 parts of zinc stearate, 5~10 parts of modified Nano diatomite, 0.8~4 part of dispersant, 1~2 part of defoamer, 2~5 parts of thickener, 2~3 parts of coalescents, 15~25 parts of deionized water.Novel environment friendly paint of the present invention is nonpoisonous and tasteless, non-environmental-pollution, can effectively eliminate organic compound volatile quantity.
Description
Technical field
The invention belongs to environment-friendly materials technical field, and in particular to a kind of novel environment friendly paint and preparation method thereof.
Background technology
Paint is that one kind can firmly be covered in body surface, and the chemistry for playing protection, decoration, mark and other specific uses is mixed
Compound coating.Coating is typically made up of four parts such as film forming matter, filler (color stuffing), solvent, auxiliary agents.Had according to performance requirement
When composition can be slightly changed.The classification for the chemical products passed through according to the modern times, coating belongs to fine chemical product.Modern coating
Progressively turn into the multi-functional engineering material of a class, be an important industry in chemical industry.Paint is fitting-up
During indispensable material.Because growth in the living standard, and environmentally friendly cry grow to even greater heights, people are to paint for decoration
It is required that more and more higher.It is very big using rear taste but the paint of in the market contains harmful chemical mostly, and constantly distribute
Organic compound is free in atmosphere, and the health of consumer is have impact on to a certain extent.Therefore, defended in the urgent need to one kind is used
The raw, paint of Environmental Safety.
The content of the invention
The invention provides a kind of novel environment friendly paint and preparation method thereof, the problem of solving in above-mentioned background technology, this
Invent nonpoisonous and tasteless described novel environment friendly paint, non-environmental-pollution, can effectively eliminate organic compound volatile quantity.
In order to solve the problem of prior art is present, adopt the following technical scheme that：
A kind of novel environment friendly paint, includes the raw material of following parts by weight：10~20 parts of aqueous alkide resin, thermoplastic acrylic resin
20~30 parts, 15~25 parts of amino resins, 8~13 parts of cobalt iso-octoate, 5~10 parts of pentaerythrite, 3~7 parts of dipropylene,
5~10 parts of kaolin, 4~6 parts of nano phase ag_2 o, 3~12 parts of plant oil pastes, 6~9 parts of mica powder, zinc stearate 2~4
Part, 5~10 parts of modified Nano diatomite, 0.8~4 part of dispersant, 1~2 part of defoamer, 2~5 parts of thickener, coalescents 2~
3 parts, 15~25 parts of deionized water.
It is preferred that, the novel environment friendly paint includes the raw material of following parts by weight：14~18 parts of aqueous alkide resin, thermoplastic
23~27 parts of acrylic resin of property, 19~24 parts of amino resins, 10~12 parts of cobalt iso-octoate, 6~8 parts of pentaerythrite, dipropyl two
4~5 parts of alcohol butyl ether, 7~9 parts of kaolin, 4.5~5.2 parts of nano phase ag_2 o, 7~11 parts of plant oil pastes, mica powder 7~8
Part, 2.3~2.6 parts of zinc stearate, 7~9 parts of modified Nano diatomite, 1.5~2.5 parts of dispersant, 1.2~1.8 parts of defoamer,
3~4 parts of thickener, 2~3 parts of coalescents, 18~22 parts of deionized water.
It is preferred that, the novel environment friendly paint includes the raw material of following parts by weight：16 parts of aqueous alkide resin, thermoplasticity third
25 parts of olefin(e) acid resin, 22 parts of amino resins, 11 parts of cobalt iso-octoate, 7 parts of pentaerythrite, 4.3 parts of dipropylene, kaolin 8
Part, 5 parts of nano phase ag_2 o, 10 parts of plant oil pastes, 7.8 parts of mica powder, 2.5 parts of zinc stearate, modified Nano diatomite 8.3
Part, 2 parts of dispersant, 1.6 parts of defoamer, 3.5 parts of thickener, 2.8 parts of coalescents, 20 parts of deionized water.
It is preferred that, the thickener is hydroxyethyl cellulose or montmorillonitic clay thickener.
It is preferred that, the modified Nano diatomite is made using following methods：Nano diatomite is added to sodium soap
In solution, be passed through carbon dioxide regulation solution pH be 5~6, controlling reaction temperature be 100~110 DEG C, the reaction time be 25~
Obtained solid matter is dried, obtains the modified Nano diatomite by 35min, filtering.
It is preferred that, the defoamer is organic silicon defoamer.
It is preferred that, the coalescents are 2,2,4- trimethyl -1,3- pentanediol diisobutyrates.
A kind of method for preparing the novel environment friendly paint, comprises the following steps：
（1）Aqueous alkide resin, thermoplastic acrylic resin, amino resins, cobalt iso-octoate, Ji Wusi are weighed by above-mentioned formula
Alcohol, dipropylene, kaolin, nano phase ag_2 o, plant oil pastes, mica powder, zinc stearate, modified Nano diatom
Soil, dispersant, defoamer, thickener, coalescents, deionized water, it is standby；
（2）The mica powder, modified Nano diatomite, kaolin are respectively placed in grind into powder in grinder, and described point
Powder, nano phase ag_2 o and deionized water are placed in mixer together, under 200~300r/min mixing speed stir 20~
30 minutes；
（3）Plant oil pastes are respectively placed in the powder for being ground to that fineness is 30~50 μm in grinder, it is standby；
（4）By aqueous alkide resin, thermoplastic acrylic resin and zinc stearate at 50~60 DEG C 10~15 points of heating stirring
Clock, after composition mixing, normal temperature cooling；
（5）By amino resins, pentaerythrite and step（4）Obtained mixture is put into reactor together, in 600~800r/
Under min stirring condition, uniform stirring 30~40 minutes；
（6）By step（5）Obtained mixture and step（2）Gained mixed slurry is well mixed, and sequentially adds plant oiliness color
Slurry, cobalt iso-octoate, dipropylene and defoamer and coalescents, with 300~400r/min mixing speed stirring 30~
50 minutes, thickener is added, mixing speed is adjusted to 800~900r/min and stirred 15~25 minutes, produces the novel environment friendly
Paint.
Compared with prior art, it has the advantages that the present invention：
The present invention is aided with kaolin, nano oxidized using aqueous alkide resin, thermoplastic acrylic resin, amino resins as raw material
Silver, plant oil pastes, mica powder, zinc stearate, modified Nano diatomite are as additive, the novel environment friendly paint prepared,
It is nontoxic with good environmental-protecting performance, the gas of environmental pollution will not be given out in use, while to people's
Body does not have any influence, has a safety feature, specific as follows：
（1）Novel environment-friendlymaterial material of the present invention with the addition of plant oil pastes, and plant oil pastes are drawn materials from natural plants,
Pure natural, pollution-free, volatility is small, and finished product does not have peculiar smell；Thickener and epoxy resin anti-yellowing agent cause paint viscous
Degree is high, not volatile, not easy to foaming rotten；
（2）Nano material is with the addition of in novel environment friendly paint paint of the present invention, energy restraining and sterilizing bacteria is prevented effectively from paint in storage
During penetrating odor generation, it is more environmentally-friendly, do not result in environmental pollution and human injury.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.
Embodiment 1
The present embodiment is related to a kind of novel environment friendly paint, includes the raw material of following parts by weight：10 parts of aqueous alkide resin, thermoplasticity third
20 parts of olefin(e) acid resin, 15 parts of amino resins, 8 parts of cobalt iso-octoate, 5 parts of pentaerythrite, 3 parts of dipropylene, 5 parts of kaolin,
4 parts of nano phase ag_2 o, 3 parts of plant oil pastes, 6 parts of mica powder, 2 parts of zinc stearate, 5 parts of modified Nano diatomite, dispersant
0.8 part, 1 part of defoamer, 2 parts of thickener, 2 parts of coalescents, 15 parts of deionized water.
Wherein, the thickener is hydroxyethyl cellulose.
Wherein, the modified Nano diatomite is made using following methods：Nano diatomite is added to sodium soap molten
In liquid, the pH for being passed through carbon dioxide regulation solution is 5, and controlling reaction temperature is 100 DEG C, and the reaction time is 25min, is filtered, will
Obtained solid matter drying, obtains the modified Nano diatomite.
Wherein, the defoamer is organic silicon defoamer.
Wherein, the coalescents are 2,2,4- trimethyl -1,3- pentanediol diisobutyrates.
A kind of method for preparing the novel environment friendly paint, comprises the following steps：
（1）Aqueous alkide resin, thermoplastic acrylic resin, amino resins, cobalt iso-octoate, Ji Wusi are weighed by above-mentioned formula
Alcohol, dipropylene, kaolin, nano phase ag_2 o, plant oil pastes, mica powder, zinc stearate, modified Nano diatom
Soil, dispersant, defoamer, thickener, coalescents, deionized water, it is standby；
（2）The mica powder, modified Nano diatomite, kaolin are respectively placed in grind into powder in grinder, and described point
Powder, nano phase ag_2 o and deionized water are placed in mixer together, are stirred 20 minutes under 200r/min mixing speed；
（3）Plant oil pastes are respectively placed in the powder for being ground to that fineness is 30~50 μm in grinder, it is standby；
（4）By aqueous alkide resin, thermoplastic acrylic resin and zinc stearate at 50 DEG C heating stirring 10 minutes, composition mix
After conjunction, normal temperature cooling；
（5）By amino resins, pentaerythrite and step（4）Obtained mixture is put into reactor together, 600r/min's
Under stirring condition, uniform stirring 30 minutes；
（6）By step（5）Obtained mixture and step（2）Gained mixed slurry is well mixed, and sequentially adds plant oiliness color
Slurry, cobalt iso-octoate, dipropylene and defoamer and coalescents, are stirred 30 minutes with 300r/min mixing speed, plus
Enter thickener, mixing speed is adjusted to 800r/min and stirred 15 minutes, produces the novel environment friendly paint.
Embodiment 2
The present embodiment is related to a kind of novel environment friendly paint, includes the raw material of following parts by weight：20 parts of aqueous alkide resin, thermoplasticity third
30 parts of olefin(e) acid resin, 25 parts of amino resins, 13 parts of cobalt iso-octoate, 10 parts of pentaerythrite, 7 parts of dipropylene, kaolin 10
Part, 6 parts of nano phase ag_2 o, 12 parts of plant oil pastes, 9 parts of mica powder, 4 parts of zinc stearate, modified Nano diatomite 10 part, point
4 parts of powder, 2 parts of defoamer, 5 parts of thickener, 3 parts of coalescents, 25 parts of deionized water.
Wherein, the thickener is montmorillonitic clay thickener.
Wherein, the modified Nano diatomite is made using following methods：Nano diatomite is added to sodium soap molten
In liquid, the pH for being passed through carbon dioxide regulation solution is 6, and controlling reaction temperature is 110 DEG C, and the reaction time is 35min, is filtered, will
Obtained solid matter drying, obtains the modified Nano diatomite.
Wherein, the defoamer is organic silicon defoamer.
Wherein, the coalescents are 2,2,4- trimethyl -1,3- pentanediol diisobutyrates.
A kind of method for preparing the novel environment friendly paint, comprises the following steps：
（1）Aqueous alkide resin, thermoplastic acrylic resin, amino resins, cobalt iso-octoate, Ji Wusi are weighed by above-mentioned formula
Alcohol, dipropylene, kaolin, nano phase ag_2 o, plant oil pastes, mica powder, zinc stearate, modified Nano diatom
Soil, dispersant, defoamer, thickener, coalescents, deionized water, it is standby；
（2）The mica powder, modified Nano diatomite, kaolin are respectively placed in grind into powder in grinder, and described point
Powder, nano phase ag_2 o and deionized water are placed in mixer together, are stirred 30 minutes under 300r/min mixing speed；
（3）Plant oil pastes are respectively placed in the powder for being ground to that fineness is 30~50 μm in grinder, it is standby；
（4）By aqueous alkide resin, thermoplastic acrylic resin and zinc stearate at 60 DEG C heating stirring 15 minutes, composition mix
After conjunction, normal temperature cooling；
（5）By amino resins, pentaerythrite and step（4）Obtained mixture is put into reactor together, 800r/min's
Under stirring condition, uniform stirring 40 minutes；
（6）By step（5）Obtained mixture and step（2）Gained mixed slurry is well mixed, and sequentially adds plant oiliness color
Slurry, cobalt iso-octoate, dipropylene and defoamer and coalescents, are stirred 50 minutes with 400r/min mixing speed, plus
Enter thickener, mixing speed is adjusted to 900r/min and stirred 25 minutes, produces the novel environment friendly paint.
Embodiment 3
The present embodiment is related to a kind of novel environment friendly paint, includes the raw material of following parts by weight：14 parts of aqueous alkide resin, thermoplasticity third
23 parts of olefin(e) acid resin, 19 parts of amino resins, 10 parts of cobalt iso-octoate, 6 parts of pentaerythrite, 4 parts of dipropylene, 7 parts of kaolin,
4.5 parts of nano phase ag_2 o, 7 parts of plant oil pastes, 7 parts of mica powder, 2.3 parts of zinc stearate, modified Nano diatomite 7 part, point
1.5 parts of powder, 1.2 parts of defoamer, 3 parts of thickener, 2 parts of coalescents, 18 parts of deionized water.
Wherein, the thickener is hydroxyethyl cellulose.
Wherein, the modified Nano diatomite is made using following methods：Nano diatomite is added to sodium soap molten
In liquid, the pH for being passed through carbon dioxide regulation solution is 5.2, and controlling reaction temperature is 102 DEG C, and the reaction time is 28min, filtering,
By the drying of obtained solid matter, the modified Nano diatomite is obtained.
Wherein, the defoamer is organic silicon defoamer.
Wherein, the coalescents are 2,2,4- trimethyl -1,3- pentanediol diisobutyrates.
A kind of method for preparing the novel environment friendly paint, comprises the following steps：
（1）Aqueous alkide resin, thermoplastic acrylic resin, amino resins, cobalt iso-octoate, Ji Wusi are weighed by above-mentioned formula
Alcohol, dipropylene, kaolin, nano phase ag_2 o, plant oil pastes, mica powder, zinc stearate, modified Nano diatom
Soil, dispersant, defoamer, thickener, coalescents, deionized water, it is standby；
（2）The mica powder, modified Nano diatomite, kaolin are respectively placed in grind into powder in grinder, and described point
Powder, nano phase ag_2 o and deionized water are placed in mixer together, are stirred 23 minutes under 220r/min mixing speed；
（3）Plant oil pastes are respectively placed in the powder for being ground to that fineness is 30~50 μm in grinder, it is standby；
（4）By aqueous alkide resin, thermoplastic acrylic resin and zinc stearate at 52 DEG C heating stirring 10~15 minutes, into
Divide after mixing, normal temperature cooling；
（5）By amino resins, pentaerythrite and step（4）Obtained mixture is put into reactor together, 635r/min's
Under stirring condition, uniform stirring 34 minutes；
（6）By step（5）Obtained mixture and step（2）Gained mixed slurry is well mixed, and sequentially adds plant oiliness color
Slurry, cobalt iso-octoate, dipropylene and defoamer and coalescents, are stirred 35 minutes with 310r/min mixing speed, plus
Enter thickener, mixing speed is adjusted to 820r/min and stirred 18 minutes, produces the novel environment friendly paint.
Embodiment 4
The present embodiment is related to a kind of novel environment friendly paint, includes the raw material of following parts by weight：18 parts of aqueous alkide resin, thermoplasticity third
27 parts of olefin(e) acid resin, 24 parts of amino resins, 12 parts of cobalt iso-octoate, 8 parts of pentaerythrite, 5 parts of dipropylene, 9 parts of kaolin,
5.2 parts of nano phase ag_2 o, 11 parts of plant oil pastes, 8 parts of mica powder, 2.6 parts of zinc stearate, modified Nano diatomite 9 part, point
2.5 parts of powder, 1.8 parts of defoamer, 4 parts of thickener, 3 parts of coalescents, 22 parts of deionized water.
Wherein, the thickener is montmorillonitic clay thickener.
Wherein, the modified Nano diatomite is made using following methods：Nano diatomite is added to sodium soap molten
In liquid, the pH for being passed through carbon dioxide regulation solution is 5.5, and controlling reaction temperature is 105 DEG C, and the reaction time is 30min, filtering,
By the drying of obtained solid matter, the modified Nano diatomite is obtained.
Wherein, the defoamer is organic silicon defoamer.
Wherein, the coalescents are 2,2,4- trimethyl -1,3- pentanediol diisobutyrates.
A kind of method for preparing the novel environment friendly paint, comprises the following steps：
（1）Aqueous alkide resin, thermoplastic acrylic resin, amino resins, cobalt iso-octoate, Ji Wusi are weighed by above-mentioned formula
Alcohol, dipropylene, kaolin, nano phase ag_2 o, plant oil pastes, mica powder, zinc stearate, modified Nano diatom
Soil, dispersant, defoamer, thickener, coalescents, deionized water, it is standby；
（2）The mica powder, modified Nano diatomite, kaolin are respectively placed in grind into powder in grinder, and described point
Powder, nano phase ag_2 o and deionized water are placed in mixer together, are stirred 25 minutes under 250r/min mixing speed；
（3）Plant oil pastes are respectively placed in the powder for being ground to that fineness is 30~50 μm in grinder, it is standby；
（4）By aqueous alkide resin, thermoplastic acrylic resin and zinc stearate at 55 DEG C heating stirring 13 minutes, composition mix
After conjunction, normal temperature cooling；
（5）By amino resins, pentaerythrite and step（4）Obtained mixture is put into reactor together, 700r/min's
Under stirring condition, uniform stirring 35 minutes；
（6）By step（5）Obtained mixture and step（2）Gained mixed slurry is well mixed, and sequentially adds plant oiliness color
Slurry, cobalt iso-octoate, dipropylene and defoamer and coalescents, are stirred 40 minutes with 350r/min mixing speed, plus
Enter thickener, mixing speed is adjusted to 850r/min and stirred 20 minutes, produces the novel environment friendly paint.
Embodiment 5
The present embodiment is related to a kind of novel environment friendly paint, includes the raw material of following parts by weight：16 parts of aqueous alkide resin, thermoplasticity third
25 parts of olefin(e) acid resin, 22 parts of amino resins, 11 parts of cobalt iso-octoate, 7 parts of pentaerythrite, 4.3 parts of dipropylene, kaolin 8
Part, 5 parts of nano phase ag_2 o, 10 parts of plant oil pastes, 7.8 parts of mica powder, 2.5 parts of zinc stearate, modified Nano diatomite 8.3
Part, 2 parts of dispersant, 1.6 parts of defoamer, 3.5 parts of thickener, 2.8 parts of coalescents, 20 parts of deionized water.
Wherein, the thickener is montmorillonitic clay thickener.
Wherein, the modified Nano diatomite is made using following methods：Nano diatomite is added to sodium soap molten
In liquid, the pH for being passed through carbon dioxide regulation solution is 5.8, and controlling reaction temperature is 110 DEG C, and the reaction time is 32min, filtering,
By the drying of obtained solid matter, the modified Nano diatomite is obtained.
Wherein, the defoamer is organic silicon defoamer.
Wherein, the coalescents are 2,2,4- trimethyl -1,3- pentanediol diisobutyrates.
A kind of method for preparing the novel environment friendly paint, comprises the following steps：
（1）Aqueous alkide resin, thermoplastic acrylic resin, amino resins, cobalt iso-octoate, Ji Wusi are weighed by above-mentioned formula
Alcohol, dipropylene, kaolin, nano phase ag_2 o, plant oil pastes, mica powder, zinc stearate, modified Nano diatom
Soil, dispersant, defoamer, thickener, coalescents, deionized water, it is standby；
（2）The mica powder, modified Nano diatomite, kaolin are respectively placed in grind into powder in grinder, and described point
Powder, nano phase ag_2 o and deionized water are placed in mixer together, are stirred 28 minutes under 280r/min mixing speed；
（3）Plant oil pastes are respectively placed in the powder for being ground to that fineness is 30~50 μm in grinder, it is standby；
（4）By aqueous alkide resin, thermoplastic acrylic resin and zinc stearate at 58 DEG C heating stirring 14 minutes, composition mix
After conjunction, normal temperature cooling；
（5）By amino resins, pentaerythrite and step（4）Obtained mixture is put into reactor together, 750r/min's
Under stirring condition, uniform stirring 37 minutes；
（6）By step（5）Obtained mixture and step（2）Gained mixed slurry is well mixed, and sequentially adds plant oiliness color
Slurry, cobalt iso-octoate, dipropylene and defoamer and coalescents, are stirred 45 minutes with 380r/min mixing speed, plus
Enter thickener, mixing speed is adjusted to 870r/min and stirred 23 minutes, produces the novel environment friendly paint.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of novel environment friendly paint, it is characterised in that include the raw material of following parts by weight：10~20 parts of aqueous alkide resin, heat
20~30 parts of plastic propene's acid resin, 15~25 parts of amino resins, 8~13 parts of cobalt iso-octoate, 5~10 parts of pentaerythrite, dipropyl
3~7 parts of glycol butyl ether, 5~10 parts of kaolin, 4~6 parts of nano phase ag_2 o, 3~12 parts of plant oil pastes, mica powder 6~9
Part, 2~4 parts of zinc stearate, 5~10 parts of modified Nano diatomite, 0.8~4 part of dispersant, 1~2 part of defoamer, thickener 2~
5 parts, 2~3 parts of coalescents, 15~25 parts of deionized water.
2. novel environment friendly paint according to claim 1, it is characterised in that include the raw material of following parts by weight：Water alcohol acid
14~18 parts of resin, 23~27 parts of thermoplastic acrylic resin, 19~24 parts of amino resins, 10~12 parts of cobalt iso-octoate, season penta
6~8 parts of tetrol, 4~5 parts of dipropylene, 7~9 parts of kaolin, 4.5~5.2 parts of nano phase ag_2 o, plant oil pastes 7
~11 parts, 7~8 parts of mica powder, 2.3~2.6 parts of zinc stearate, 7~9 parts of modified Nano diatomite, 1.5~2.5 parts of dispersant,
1.2~1.8 parts of defoamer, 3~4 parts of thickener, 2~3 parts of coalescents, 18~22 parts of deionized water.
3. novel environment friendly paint according to claim 1, it is characterised in that include the raw material of following parts by weight：Water alcohol acid
16 parts of resin, 25 parts of thermoplastic acrylic resin, 22 parts of amino resins, 11 parts of cobalt iso-octoate, 7 parts of pentaerythrite, DPG
4.3 parts of butyl ether, 8 parts of kaolin, 5 parts of nano phase ag_2 o, 10 parts of plant oil pastes, 7.8 parts of mica powder, 2.5 parts of zinc stearate,
8.3 parts of modified Nano diatomite, 2 parts of dispersant, 1.6 parts of defoamer, 3.5 parts of thickener, 2.8 parts of coalescents, deionized water
20 parts.
4. novel environment friendly paint according to claim 1, it is characterised in that the thickener is hydroxyethyl cellulose or covers de-
Stone clay thickener.
5. novel environment friendly paint according to claim 1, it is characterised in that the modified Nano diatomite uses following methods
It is made：Nano diatomite is added in sodium soap solution, the pH for being passed through carbon dioxide regulation solution is 5~6, control reaction
Temperature is 100~110 DEG C, and the reaction time is 25~35min, and obtained solid matter is dried, obtains the modification and receive by filtering
Rice diatomite.
6. novel environment friendly paint according to claim 1, it is characterised in that the defoamer is organic silicon defoamer.
7. novel environment friendly paint according to claim 1, it is characterised in that the coalescents are 2,2,4- trimethyls -1
, 3- pentanediol diisobutyrates.
8. a kind of method for preparing any one of the claim 1~7 novel environment friendly paint, it is characterised in that comprise the following steps：
（1）Aqueous alkide resin, thermoplastic acrylic resin, amino resins, cobalt iso-octoate, Ji Wusi are weighed by above-mentioned formula
Alcohol, dipropylene, kaolin, nano phase ag_2 o, plant oil pastes, mica powder, zinc stearate, modified Nano diatom
Soil, dispersant, defoamer, thickener, coalescents, deionized water, it is standby；
（2）The mica powder, modified Nano diatomite, kaolin are respectively placed in grind into powder in grinder, and described point
Powder, nano phase ag_2 o and deionized water are placed in mixer together, under 200~300r/min mixing speed stir 20~
30 minutes；
（3）Plant oil pastes are respectively placed in the powder for being ground to that fineness is 30~50 μm in grinder, it is standby；
（4）By aqueous alkide resin, thermoplastic acrylic resin and zinc stearate at 50~60 DEG C 10~15 points of heating stirring
Clock, after composition mixing, normal temperature cooling；
（5）By amino resins, pentaerythrite and step（4）Obtained mixture is put into reactor together, in 600~800r/
Under min stirring condition, uniform stirring 30~40 minutes；
（6）By step（5）Obtained mixture and step（2）Gained mixed slurry is well mixed, and sequentially adds plant oiliness color
Slurry, cobalt iso-octoate, dipropylene and defoamer and coalescents, with 300~400r/min mixing speed stirring 30~
50 minutes, thickener is added, mixing speed is adjusted to 800~900r/min and stirred 15~25 minutes, produces the novel environment friendly
Paint.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710536984.9A CN107312408A (en) | 2017-07-04 | 2017-07-04 | A kind of novel environment friendly paint and preparation method thereof |
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| CN201710536984.9A CN107312408A (en) | 2017-07-04 | 2017-07-04 | A kind of novel environment friendly paint and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233386A (en) * | 2018-07-20 | 2019-01-18 | 宁波柯乐芙家居科技股份有限公司 | A kind of spraying method of environmental protection door-plate |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101195727A (en) * | 2006-12-05 | 2008-06-11 | 郭强 | Disinfecting and deodorizing environmental protection paint |
| CN102888156A (en) * | 2012-09-15 | 2013-01-23 | 安徽省怀远县尚冠模具科技有限公司 | Uvioresistant fluorocarbon metal anti-rust paint and preparation method thereof |
| CN106519931A (en) * | 2016-09-26 | 2017-03-22 | 笪亚臣 | Environmental-protection paint for surface of kitchen furniture and preparation method thereof |
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2017
- 2017-07-04 CN CN201710536984.9A patent/CN107312408A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101195727A (en) * | 2006-12-05 | 2008-06-11 | 郭强 | Disinfecting and deodorizing environmental protection paint |
| CN102888156A (en) * | 2012-09-15 | 2013-01-23 | 安徽省怀远县尚冠模具科技有限公司 | Uvioresistant fluorocarbon metal anti-rust paint and preparation method thereof |
| CN106519931A (en) * | 2016-09-26 | 2017-03-22 | 笪亚臣 | Environmental-protection paint for surface of kitchen furniture and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233386A (en) * | 2018-07-20 | 2019-01-18 | 宁波柯乐芙家居科技股份有限公司 | A kind of spraying method of environmental protection door-plate |
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