Fluorescent powder coating device and coating method
Technical field
The present invention relates to a kind of apparatus for coating and coating method, more particularly to one kind can be in even spread phosphor on substrate
The device and coating method of material.
Background technology
In recent years, because light emitting diode (LED) has, luminous efficiency is high, power consumption is few, service life is long and component size
The advantages that small, it is widely used in various light-emitting devices, and substitutes several lighting apparatus.
White light LEDs currently used for illumination have coordinates feux rouges, green glow and blue light using ultraviolet light-emitting diodes chip
Three-color phosphor, by red bluish-green trichromatic light mixing mechanism, white light can be mixed into.
But fluorescent material can be dispersed in resin by conventionally manufactured white light LEDs method.Then, fluorescent material will be dispersed with
Resin is mixed with curing agent, and the colloid for being dispersed with fluorescent material is covered in LED chip with point gum machine, drying and encapsulation work
Skill, a LED element can be made.According to the LED element obtained by the above method, because the external form and size of fluorescent material are irregular,
Therefore phosphor powder layer is easily because of fluorescent material material property disunity, and the problems such as cause colour temperature inaccurate with mixed light inequality.
And material and operating condition are limited to, is only capable of at present artificial in the method for substrate with water surface epistasis coating fluorescent material
Operation, and can not rapid, high volume production, it is necessary to skilled has training operator's operation.
Therefore, need badly at present and develop a kind of fluorescent-powder coating method, it can produce coating uniform rapid, high volume
Substrate, with applied in LED luminous lighting equipment.
The content of the invention
The main object of the present invention is providing a kind of fluorescent material apparatus for coating, and it can be quickly and easily by fluorescent material shape
Into on substrate, and can be applied to largely produce.
Another object of the present invention is providing a kind of fluorescent material coating method, and it can be quickly and easily by fluorescent material shape
Into on substrate, and can be applied to largely produce.
The fluorescent powder coating device of the present invention, comprising:One has a cell wall, a fluid injection entrance, and the groove of discharge opeing outlet
Body;One dividing plate, one first groove and the second groove are separated into the cell body, and by the cell body;Wherein the divider height, which is less than, is somebody's turn to do
Cell wall height;An and fluorescent material injecting device.
The fluorescent-powder coating method of the present invention, is comprised the steps of:One substrate and a fluorescent powder coating device are provided, its
In the fluorescent powder coating device include:One has a cell wall, a fluid injection entrance, and the cell body of discharge opeing outlet;One dividing plate, is located at
In the cell body, and the cell body is separated into one first groove and the second groove;Wherein the divider height is less than cell wall height;And one
Limitation kickboard with hollow space;And the substrate is placed in second groove;Then sequentially by water from fluid injection entrance inject this
One groove and second groove;In the hollow space for the limitation kickboard that fluorescent material injection is floated on into the first tank liquor face;It is higher than in liquid level
During the divider height, mobile limitation kickboard to second groove;And liquid level is reduced from discharge opeing outfall drain, so that the limitation is floated
Fluorescent powder coating in plate is in the substrate surface.
The fluorescent powder coating device of the present invention, selectively also comprising a limitation kickboard with hollow space.This has
The limitation kickboard of hollow space, the water surface can be floated on by the buoyancy of itself when water injects cell body.The limitation kickboard of the present invention
Shape need to be with accommodating and limit and inject the fluorescent material scope for floating on the water surface of cell body with a hollow space.The present invention's
The shape of kickboard is limited preferably with the framework shape with hollow space.
The fluorescent powder coating device of the present invention, selectively also comprising a limitation kickboard shifter, to be moved in technique
Float on the limitation kickboard of the water surface.The limitation kickboard shifter of the present invention can be the mechanism of any movement or promotion limitation kickboard,
A preferably mechanical arm, a gripper, a bracket, a bar, or its combination.
The fluorescent powder coating device of the present invention, selectively also includes a baseplate carrier, to fix the substrate.The present invention's
Baseplate carrier is preferably placed in second groove.The baseplate carrier of the present invention can be portable or fixed, to coordinate process requirements.
The fluorescent powder coating device of the present invention, selectively also includes a microprocessor control system, to use program certainly
Dynamicization controls moving for the valve of each fluid injection entrance, the valve of discharge opeing outlet, fluorescent material injecting device, and limitation kickboard shifter
Make.
The fluorescent powder coating device of the present invention, auxiliary injection ports selectively are provided with cell body, aid in outlet, or its
Combination, to adjust or accelerate coating speed.
In fluorescent material coating method of the invention and it is coated with the substrate of fluorescent material, substrate is unrestricted, preferably may be used
For any LED chip or LED element semi-finished product, the blue light epi-wafer formed with epitaxial layer of a more preferably sapphire substrate, one or
Flip LED chip.
Using the substrate for being coated with fluorescent material made by the fluorescent material coating method of the present invention, due to fluorescent material
Particle diameter and property are homogeneous, and can form uniform fluorescent material film in substrate surface.Meanwhile by fluorescent material film
Packed layer, except that can protect fluorescence, how material film will not be peeled off from substrate easily, can also lift the refraction of institute's formation substrate
Rate.
The cell body number or dividing plate number of fluorescent powder coating device of the present invention can increase because of needs, and its configuration can also
Array is adjusted or lined up according to the demand of production technology, to increase coating efficiency and yield.
Brief description of the drawings
Fig. 1 is the side view of fluorescent material apparatus for coating of the present invention.
Fig. 2 is the top view of fluorescent material apparatus for coating of the present invention.
Fig. 3 A-3C use schematic diagram for fluorescent material apparatus for coating of the present invention.
【Description of reference numerals】
100 fluorescent material apparatus for coating
110 cell bodies
111 first grooves
112 cell walls
113 second grooves
114 main inlets
115 auxiliary injection ports
116 main outlets
117 auxiliary outlets
120 dividing plates
130 fluorescent material injecting devices
140 microscope carriers
142 substrates
150 limitation kickboards
152 limitation kickboard shifters
160 hollow spaces
Embodiment
Illustrate embodiments of the present invention following with particular specific embodiment, those skilled in the art can be by this explanation
Book disclosure of that understands advantage of the present invention and other effects easily.The present invention also can be by other different specific implementations
Example is implemented or applied, and the various details in this specification can also be directed to different viewpoints and application, without departing substantially from this hair
Bright spirit is lower to carry out various modifications and change.
It refer to Fig. 1 and Fig. 2.Fig. 1 is the side view of fluorescent material apparatus for coating of the present invention.Fig. 2 is phosphor of the present invention
Expect the top view of apparatus for coating.Fluorescent material apparatus for coating 100 of the present invention, which includes one, has a main inlet 114, a main discharge
Mouth 116, and the hollow cell body 110 that cell wall 112 is circular.The center of cell body 110 is provided with a dividing plate 120, and dividing plate separates cell body
Into the first groove 111 and the second groove 113.And the height of cell wall 112 is substantially higher than the height of demarcation strip 120, to facilitate technique to carry out.
Apparatus of the present invention 100 additionally comprise a fluorescent material injecting device 130, in manufacturing process, to inject fluorescence according to scheduled volume in order
Powder.
Fluorescent powder coating device 100 of the present invention, on cell wall 112 and more several auxiliary injection ports 115 and more can be provided with
Several auxiliary outlets 117, during fluorescent powder coating, to accelerate water filling or draining to accelerate the speed of processing in passing.This
Invention fluorescent powder coating, which is installed on fluorescent powder coating, which still needs, will be used cooperatively a limitation kickboard 150 with hollow space, and it is
One has the framework of closed housing, can bubble through the water column.
Fluorescent-powder coating method (refer to Fig. 3 A-3C) of the present invention, first by the base of required coating fluorescent material when implementing
The microscope carrier 140 that plate 142 is placed in the second groove 113, and limitation kickboard 150 is inserted in the first groove 111.Used in the present embodiment
Substrate 142 be a flip LED chip.Water is then injected into the first groove 111 and the second groove 113 through main inlet 114.Now,
Limitation kickboard 150 can float on the water surface of the first groove 111 because of water injection, and raise and raise with the water surface.To accelerate process speed, and can
So that water optionally is injected into two cell body (111,113) through auxiliary injection ports 115.Treat that water enters the first groove 111 not up to separation
During 120 height of plate, it can be mixed so that the fluorescent material to be coated with is slowly added dropwise into fluorescent material in water surface by fluorescent material injecting device 130
Solution is closed to inject the hollow space 160 of limitation kickboard 150 in the first groove 111.Fluorescent material floats on limitation kickboard after injection
The water surface of hollow space 160 in 150, it will not largely be spread in the outer water surface of limitation kickboard.
The fluorescent material in fluorescent material injecting device 130 used in the present embodiment is a fluorescent material solution, takes fluorescent material to do
For a fluorescent material, it for 500nm and material is SiO that the ball-type carrier of wherein fluorescent material, which uses particle diameter,2Nanosphere, and fluorescent powder
Then use particle diameter about 30nm Y2O3:La3+、YAG:La3+And CdSe:ZnS mixture, and fluorescent powder passes through silane point
Sub (APTMS) bond is in ball-type carrier surface.Fluorescent material is mixed in the ethanol with polymolecularity, a fluorescent material is obtained and mixes
Close solution.
Persistently inject water afterwards so that the liquid level of the first groove 111 and the second groove 113 continue to increase to higher than dividing plate 120. this
Shi Yinwei the first grooves 111 and the water surface of the second groove 113 are higher than dividing plate 120 with height, it is possible to utilize a limitation kickboard shifter
152 movements are surrounded by the limitation kickboard 150 of fluorescent material.By limitation kickboard 150 from the water surface movable of the first groove 111 to the second groove 113
The water surface.And the fluorescent material that kickboard 150 encases is limited, also just as the movement of limitation kickboard 150 smoothly moves to the water of the second groove 113
Face.Limitation kickboard shifter 152 used in the present embodiment, can be gripper or mechanical arm.
After the second groove 113 is moved into the limitation kickboard 150 of fluorescent material, then the water of the second groove 113 is independently discharged
Mouth 116 is discharged, to reduce the water surface of the second groove 113.When the water surface is reduced, the rough alignment institute of hollow space of kickboard 150 will be limited
The substrate 142 to be coated with., can be with stably equably by fluorescent powder coating in the upper surface of substrate 142 when the water surface reduces
And side surface.
Then, substrate 142 is placed in equipment for drying (not shown), the ethanol of tool polymolecularity is removed with evaporation
(not shown).It is to be dried completely after, then can obtain the surface of a substrate 142 has the substrate of fluorescent powder film.
The substrate for being coated with fluorescent material can use silicon alkoxide (such as:TEOS the aqueous solution) is molten as collosol and gel precursor
Liquid, and by by YAG and La3+Salt be dissolved in acid solution that a nitric acid is formulated it is well mixed after, with rotary coating
Mixed solution is coated on fluorescent powder film 21 by method, and forms a packed layer 22, and it is then to contain YAG: La that packed layer, which is made,3+'s
SiO2Material layer.After standing, the substrate 20 with fluorescent powder film 21 and packed layer 22 is heat-treated, then carries out at annealing
Reason, then complete the substrate for being coated with fluorescent material of the present embodiment.
This case will not be such that fluorescent material expands in large quantities because smoothly moving the fluorescent material bubbled through the water column using kickboard is limited
Dissipate, save material.And by water surface fluctuation control flow speed, cost is cheap and speed improvement, technique are simple, can be largely fast
Fast ground is by fluorescent powder coating in substrate.Fluorescent material smoothly declines by the limitation and the water surface of limitation kickboard, can be equably
It is coated on substrate surface.