CN107868733A - A kind of sea cucumber perfumed soap and preparation method thereof - Google Patents
A kind of sea cucumber perfumed soap and preparation method thereof Download PDFInfo
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- CN107868733A CN107868733A CN201711423395.6A CN201711423395A CN107868733A CN 107868733 A CN107868733 A CN 107868733A CN 201711423395 A CN201711423395 A CN 201711423395A CN 107868733 A CN107868733 A CN 107868733A
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- sea cucumber
- soap
- perfumed soap
- sea
- perfumed
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/02—Compositions of detergents based essentially on soap on alkali or ammonium soaps
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/225—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
- C11D9/262—Organic compounds, e.g. vitamins containing oxygen containing carbohydrates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
- C11D9/265—Organic compounds, e.g. vitamins containing oxygen containing glycerol
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/38—Products in which the composition is not well defined
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to a kind of bath article, relates in particular to a kind of perfumed soap.A kind of sea cucumber perfumed soap, each component percentage by weight are:Soap base 80 90%, sea cucumber activity extract 5 10%, white sugar 2 4%, dye liquor 1 2%, natural plant essential oils 2 4%.Caused cooking waste liquor in fresh and alive sea cucumbers process is carried out recycling by the present invention, therefrom extract with bioactivity, such as soluble active material of sea cucumber of holothurian collagen, sea cucumber polysaccharide, selenka, and be combined these active materials with traditional perfumed soap, the sea cucumber perfumed soap with certain beauty treatment health care efficacy is made.This processing waste of cooking waste liquor has been obtained good recycling, reduce and waste, reduce pollution, have more the beauty and health care functions such as maintenance, skin care, anti-aging, anti-oxidant with seasonal perfumed soap, sea cucumber is no longer simply eaten and supplement the nutrients.
Description
Technical field:
The present invention relates to a kind of bath article, relates in particular to a kind of perfumed soap.
Background technology:
Perfumed soap is one of indispensable daily necessities in people's daily life, in the market common perfumed soap, such as feature
Perfumed soap has germicidal toilet soap, whitening soap and Massage perfumed soap;Ingredient is divided into industrial perfumed soap(Without glycerine)It is fragrant with non-industry
Soap(Handmade soap containing glycerine);There are opaque perfumed soap and transparent soap by outward appearance division." the trichlorine of germicidal toilet soap addition common at present
There are the material such as life ", " triclocarban " 30 s quickly to kill 99.9% bacterium for causing skin infection, but according to U.S.'s food and medicine
Surveillance Authority (FDA), which issues a statement, queries antimicrobial soap, claims long-term use to may interfere with human body hormone, it is hidden to there is safety
Suffer from, and some compositions of these perfumed soaps potentially contribute to drug resistance of bacterial antibiotic etc.;Zhang Xiaorong etc.(" new chrysanthemum
Wormwood artemisia health care fancy soap technique development and quality evaluation " research and development of natural products 25.11 (2013): 1550-1554.)With day
Right plant Artemisia annua aliphatic acid is soap base additive, and volatile oil is that antibiotic effective ingredient have developed Novel artemisia annua health care toilet soap system
Standby technique, but natural macromolecular albumen causes allergic reaction possibly as antigen.Commercially available industrial perfumed soap product is without natural sweet
Oil, lack the nutritional ingredient beneficial to skin, the natural grease of skin surface can not only be washed away by cleaning skin with such product, can also
The natural equilibrium ability of skin is destroyed, it is long-term use of, the resistivity of skin is easily reduced, triggers various disease of skin;Liu Xi
Sun(" technology of preparing of transparent toilet soap " daily chemical industry 31.4 (2001): 50-51.)Delivered with the method for addition NMF
The application characteristic of transparent toilet soap, manufacture method, technological process and quality standard, but the NMF of chemical synthesis is to human body skin
Metabolism has a certain impact.
On the granted patent of perfumed soap, that announces at present is existing, as the B of Chinese patent CN 101240226 are disclosed
A kind of germicidal toilet soap and preparation method thereof;The B of Chinese patent CN 101705164 disclose a kind of health-care massaging perfumed soap and its preparation
Method;The B of Chinese patent CN 102784077 disclose a kind of natural plant soap;Etc. equally exist above mentioned problem.
Sea cucumber is under the jurisdiction of Echinodermata Holothuroidea, and there are some researches show sea cucumber is rich in natural collagen protein, polypeptide, god
The amino acid and iron that are needed through sphingol, saponin, mucopolysaccharide, multivitamin, 18 kinds of human bodies, phosphorus, manganese, selenium, iodine, calcium, magnesium,
The mineral matters such as zinc, 50 multiple nutritional components, are acknowledged as the natural nutrition invigorant beneficial to body altogether.
Due to containing autolytic enzyme in sea cucumber body, after salvaging disembarkation several hours self-dissolving will occur, be unfavorable for transporting for long-distance,
Therefore need to carry out new fresh sea cucumber boiling enzyme deactivation, substantial amounts of Holothurian machining cooking liquor produces with regard to this.Temperature is all during due to boiling
Close to 100 DEG C, in whole digestion process, such as meeting such as collagen, polysaccharide, saponin(e, various amino acid of some water-soluble substanceses
Enter in sea cucumber cooking liquor, if it directly is regarded into discharging of waste liquid, not only caused environmental pollution but also be a kind of waste of resource.
The content of the invention:
Present invention aim to address above-mentioned insufficient problem, there is provided a kind of sea cucumber perfumed soap, containing active material of sea cucumber, makes full use of
The waste liquid of Holothurian machining, reduce and waste, reduce pollution, the beauty such as maintenance, skin care, anti-aging, anti-oxidant is had more with seasonal perfumed soap
Health-care effect.
The present invention is that technical scheme is used by solving the above problems:A kind of sea cucumber perfumed soap, each component percentage by weight
For:Soap base 80-90%, sea cucumber activity extract 5-10%, white sugar 2-4%, dye liquor 1-2%, natural plant essential oils 2-4%.
The soap base main component is coconut oil 25-30%, palm oil 25-30%, SIMMONDSIA CHINENSIS SEED OIL 10-15%, castor oil 5-
10% and natural glycerin 10% etc..
The sea cucumber activity extract matter extracts from fresh and alive sea cucumbers machining cooking liquid, cooking liquor through precipitating, filtering, digesting,
Post, UF membrane and the technique such as lyophilized are crossed, obtains the soluble sea such as solid powder sea cucumber protein peptides, sea cucumber polysaccharide, selenka
Join active material.
The white sugar is refined particulate white granulated sugar, dry it is loose, pure white, glossy, without obvious stain.
The dye liquor is the high-quality dye liquor of food-grade, including red, yellow, blueness, green are therein one or more of appoints
Meaning combination.
The natural plant essential oils are Rosa Damascana, refined jasmine oil, Lavender, Peppermint essential oil, tea tree ethereal oil, lotus lotus
One or more of any combination in bar essential oil.
Meanwhile present invention also offers a kind of preparation method of sea cucumber perfumed soap, comprise the following steps that:
The first step, active material of sea cucumber extraction:Cooking water after fresh and alive sea cucumbers are processed is concentrated through high temperature, and supernatant is taken after centrifugation
Liquid, saponin(e is adsorbed by large pore resin absorption column, after permeate compound protease digests 4 hours at PH=48 DEG C of 8.5 temperature
By 2-3 nanometer UF membrane molecular sieves, permeate is below 1000KDa sea cucumber protein small peptide, and trapped fluid is more than 1000KDa
Macromolecular sea cucumber polysaccharide, resin column elution after be selenka, it is spray-dried or be freeze-dried after solid powder is made;
Second step, additive dissolving:By active material powder, a small amount of dissolved in purified water of white sugar;
3rd step, melt soap base:The active material of dissolving, white sugar and dye liquor, natural essential oil are added in the soap base melted, gently
To being well mixed, vavuum pump takes out bubble for micro- stirring;
4th step, enter mould cooling:Well mixed soap lye is poured into mould, is positioned at shady and cool ventilation and hangs 24h;
5th step, encapsulation:Finished product soap is encapsulated into bag.
Feature is possessed by the present invention, caused cooking waste liquor in fresh and alive sea cucumbers process is reclaimed again sharp
With by the enzymolysis to sea cucumber cooking liquor, crossing post and the methods of UF membrane by active ingredient separation and Extraction therein, wherein albumen
The rate of recovery of polypeptide, polysaccharide and saponin(e is up to 72%, 82% and 75%.Therefrom extract with bioactivity, such as sea cucumber collagen egg
In vain, the soluble active material of sea cucumber such as sea cucumber polysaccharide, selenka, and these active materials are combined with traditional perfumed soap, make
Into the sea cucumber perfumed soap with certain beauty treatment health care efficacy.Not only obtain this processing waste of cooking waste liquor sharp again well
With reduction wastes, reduces pollution, has more the beauty and health care functions such as maintenance, skin care, anti-aging, anti-oxidant with seasonal perfumed soap, makes sea
Ginseng is no longer simply eaten and supplemented the nutrients.
Active material of sea cucumber primary efficacy:
(1)Holothurian collagen peptide can improve the activity of SOD and GSH-PX in skin, so as to increase the anti-oxidant energy of skin
Power;Holothurian collagen peptide can also increase the content of hydroxyproline in skin simultaneously, so as to promote collagen egg in skin histology
White synthesis, skin photoage caused by ultraviolet radiation resisting short of money, prevents skin injury.
(2)Sea cucumber mucopolysaccharide can suppress the oxidation reaction of 5,6- dihydroxy indoles -2- carboxylic oxidases in skin,
Suppress the synthesis of intracellular tyrosine enzymatic activity and melanin, there is white-skinned face function;Sea cucumber mucopolysaccharide can be with inhibitory activity oxygen
Produce, and strengthen cutaneous immunisation power by activating panimmunity cell, so as to have the function that anti-oxidant, anti-aging.In addition,
Sea cucumber mucopolysaccharide also has moisturizing, more wound and other effects.
(3)Selenka is very strong surfactant, can be spumed, and has significant suppression to various Gram-negative bacterias
Effect, there is very strong antifungic action to Candida albicans, salmonella, saccharomycete etc..
The present invention is added in perfumed soap using the extract in Holothurian machining cooking liquor as function adding ingredient, is made one
Kind sea cucumber perfumed soap, pure natural bactericide is used as by the use of the bactericidal action of selenka;The natural anti-aging of sea cucumber polysaccharide, antioxygen
Change, moisturizing and raising skin immunity and other effects;And the sea cucumber small-molecular peptides no antigen after enzymolysis processing, it is impossible to caused
Quick reaction, the advantages that being more easy to be absorbed by the body etc..By Holothurian machining cooking waste liquor carried out recycle, turn waste into wealth it is same
When, feature perfumed soap is manufactured, the shortcomings that overcoming the existing perfumed soap function of China and security deficiency, sea cucumber perfumed soap is a kind of new
Security functionality perfumed soap, be a brand-new trial in perfumed soap manufacturing industry.
Embodiment
Embodiment 1:
The sea cucumber perfumed soap each component percentage by weight that this example provides is as follows:Soap base 85%, holothurian collagen 8%, white granulated sugar 2%,
Dye liquor 1%, Rosa Damascana 4%.
The present embodiment sea cucumber perfumed soap making step:
Holothurian collagen peptide extracts:Machining cooking waste liquid is filtered, removes wherein silt, crosses saponin(e adsorption resin column afterwards,
Permeate is digested by compound protease in a kettle, is finally carried out the technologies such as the UF membrane of 2-3 nanometers and is obtained
Below 1000KDa small molecule sea cucumber protein peptides.Sea cucumber protein peptides solid powder is obtained after lyophilized crushing.
Additive dissolves:By holothurian collagen dry powder with a small amount of dissolved in purified water, while white granulated sugar is added, dissolve and stir
Mix uniformly.
Melt soap base:Soap base is positioned in container, boiling water bath melts to prevent from being sticking, and after soap base melts completely, adds
Enter additives mixed liquid and dye liquor, natural essential oil, gentle agitation is uniform, and vavuum pump takes out bubble.
Enter mould:The soap lye mixed is poured into mould, is positioned at shady and cool ventilation and hangs 24h.
Encapsulation:Finished product soap is encapsulated into bag.
Embodiment 2:
The sea cucumber perfumed soap each component percentage by weight that this example provides is as follows:Soap base 88%, sea cucumber polysaccharide 5%, white granulated sugar 3%, dye liquor
1%, tea tree ethereal oil 3%.
The present embodiment sea cucumber perfumed soap making step:
Sea cucumber polysaccharide extracts:Machining cooking waste liquid is filtered, wherein silt is removed, is existed afterwards by adsorption resin column, permeate
Digested in reactor by compound protease, finally carry out the technologies such as the UF membrane of 2-3 nanometers and obtain more than 1000KDa's
Macromolecular sea cucumber polysaccharide.Sea cucumber polysaccharide solid powder is obtained after lyophilized crushing.
Additive dissolves:By sea cucumber polysaccharide dry powder with a small amount of dissolved in purified water, while white granulated sugar is added, dissolve and stir
It is even.
Melt soap base:Soap base is positioned in container, boiling water bath melts to prevent from being sticking, and after soap base melts completely, adds
Enter additives mixed liquid and dye liquor, natural essential oil, gentle agitation is uniform, and vavuum pump takes out air.
Enter mould:The soap lye mixed is poured into mould, is positioned at shady and cool ventilation and hangs 24h.
Encapsulation:Finished product soap is encapsulated into bag.
Embodiment 3:
The sea cucumber perfumed soap each component percentage by weight that this example provides is as follows:Soap base 90%, selenka 5%, white granulated sugar 2%, dye liquor
1%, Lavender 2%.
The present embodiment sea cucumber perfumed soap making step:
Selenka extracts:Machining cooking waste liquid is filtered, mid-term silt is removed, passes through compound protease in a kettle afterwards
Digested, saponin(e adsorption resin column is crossed after enzymolysis is complete, adsorb selenka and lipid, elution medicinal extract is extracted with ethyl acetate
Extracting degreasing, extract is extracted with saturation n-butanol after degreasing, and sea cucumber is made through vacuum rotary steam, freeze-dried powder in butanol extraction liquid
Saponin(e solid powder.
Additive dissolves:By sea cucumber polysaccharide dry powder with a small amount of dissolved in purified water, while white granulated sugar is added, dissolve and stir
It is even.
Melt soap base:Soap base is positioned in container, boiling water bath melts to prevent from being sticking, and after soap base melts completely, adds
Enter additives mixed liquid and dye liquor, natural essential oil, gentle agitation are uniform.
Enter mould:The soap lye mixed is poured into mould, is positioned at shady and cool ventilation and hangs 24h.
Encapsulation:Finished product soap is encapsulated into bag.
Embodiment 4:
The sea cucumber perfumed soap each component percentage by weight that this example provides is as follows:Soap base 80%, holothurian collagen 5%, sea cucumber polysaccharide
3%, selenka 2%, white granulated sugar 4%, dye liquor 2%, refined jasmine oil 4%.
The present embodiment sea cucumber perfumed soap making step:
It is prepared by active material of sea cucumber concentrate:Machining cooking waste liquid is filtered, entered in a kettle by compound protease
Row digests, and direct freeze-dried powder after enzymolysis, active component hybrid solid powder is made.
Additive dissolves:By sea cucumber polysaccharide dry powder with a small amount of dissolved in purified water, while white granulated sugar is added, dissolve and stir
It is even.
Melt soap base:Soap base is positioned in container, boiling water bath melts to prevent from being sticking, and after soap base melts completely, adds
Enter additives mixed liquid and dye liquor, natural essential oil, gentle agitation are uniform.
Enter mould:The soap lye mixed is poured into mould, is positioned at shady and cool ventilation and hangs 24h.
Encapsulation:Finished product soap is encapsulated into bag.
Clinical trial results:
Clinical trial volunteer 80 is collected, is including male 26, women 54, age composition composition:18-30 year 29
People, 31-45 year 32 people, 46-60 year 19 people.It is required that volunteer is at least per daily sea cucumber perfumed soap 2-3 time, application method and normal perfume
Soap is identical.It is recommended that with perfumed soap cleans hand, melanin deposition is more on face, and skin, aging is dry and cracked significantly
Position, such as neck, ancon.Adhere to using 30 days by this requirement, during which cannot use the similar productions such as other perfumed soaps, mildy wash
Product, in order to avoid experimental result is interfered.
After 30 days, experimental result is obtained by volunteer's readme.In all 80 volunteers, it is believed that product of the present invention are beautiful
In vain, moisturizing, antiageing effect significantly have 49 people, it is believed that there is product of the present invention certain whitening, moisturizing, antiageing effect to have 26
People, it is believed that ineffective 5 people of product of the present invention, it is 93.75% to illustrate product total effective rate of the present invention.Meanwhile in above-mentioned all aspirations
In person, the ill symptomses such as red swelling of the skin, itch, allergy are found no.
Claims (7)
1. a kind of sea cucumber perfumed soap, it is characterised in that each component percentage by weight is:Soap base 80-90%, sea cucumber activity extract 5-
10%, white sugar 2-4%, dye liquor 1-2%, natural plant essential oils 2-4%.
2. according to a kind of sea cucumber perfumed soap described in claim 1, it is characterised in that the soap base main component is coconut oil
25-30%, palm oil 25-30%, SIMMONDSIA CHINENSIS SEED OIL 10-15%, castor oil 5-10% and natural glycerin 10%;
The sea cucumber activity extract extracts from fresh and alive sea cucumbers machining cooking liquid, through precipitating, filtering, digesting, cross post, UF membrane,
Concentration, drying process, obtain solid powder sea cucumber protein peptides, sea cucumber polysaccharide, selenka solubility active material of sea cucumber;
The white sugar is refined particulate white granulated sugar;
The dye liquor is food-grade dye liquor;
The essential oil is extracted form natural plant essential oil.
3. according to a kind of sea cucumber perfumed soap described in claim 2, it is characterised in that the sea cucumber protein peptides are steamed by sea cucumber
Boil liquid concentrates, by 2-3 nanometer UF membrane molecular sieves after being digested 4 hours at PH=48 DEG C of 8.5 temperature with compound protease, thoroughly
It is refined to cross the small-molecular peptides concentration containing below 1000KDa in liquid.
4. according to a kind of sea cucumber perfumed soap described in claim 2, it is characterised in that the sea cucumber polysaccharide is by sea cucumber boiling
Liquid concentrates, and passes through 2-3 nanometer UF membrane molecular sieves, retention after being digested 4 hours at PH=48 DEG C of 8.5 temperature with compound protease
The sea cucumber polysaccharide concentration containing more than 1000KDa is refined in liquid.
5. according to a kind of sea cucumber perfumed soap described in claim 2, it is characterised in that the selenka is by sea cucumber boiling
After liquid centrifugation, saponin(e and lipid, extracting and refining after elution are adsorbed by large pore resin absorption column.
6. according to a kind of sea cucumber perfumed soap described in claim 2,3,4,5, it is characterised in that the Holothurian machining cooking liquor,
It is used for sea cucumber boiling to ripe fresh water, every batch of 200 jin of cooking liquor processing fresh and alive sea cucumbers amount in fresh and alive sea cucumbers process
More than, cooking liquor 500L, more than digestion time 20min.
7. according to a kind of preparation method of any described sea cucumber perfumed soaps of claim 1-6, it is characterised in that including following step
Suddenly:
Active material of sea cucumber extracts:Cooking water after fresh and alive sea cucumbers are processed by precipitate, filter, digest, cross post, UF membrane,
Sea cucumber protein peptides, sea cucumber polysaccharide, selenka active material are extracted in concentration, drying process method respectively, are made after freeze-dried
Into solid powder;
Additive dissolves:By active material powder, a small amount of dissolved in purified water of white sugar;
Melt soap base:The active material of dissolving, white sugar and dye liquor, natural essential oil are added in the soap base melted, gentle agitation
To well mixed, vacuum pump depletion gas;
Enter mould cooling:Well mixed soap lye is poured into mould, is positioned at shady and cool ventilation and hangs 24h;
Encapsulation:Finished product soap is encapsulated into bag.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111471540A (en) * | 2020-05-27 | 2020-07-31 | 山东恒鲁生物科技有限公司 | Sea cucumber oil soap base and preparation method and application thereof |
CN113101231A (en) * | 2020-01-13 | 2021-07-13 | 大连鑫玉龙海洋生物种业科技股份有限公司 | Sea cucumber bath salt |
-
2017
- 2017-12-25 CN CN201711423395.6A patent/CN107868733A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113101231A (en) * | 2020-01-13 | 2021-07-13 | 大连鑫玉龙海洋生物种业科技股份有限公司 | Sea cucumber bath salt |
CN111471540A (en) * | 2020-05-27 | 2020-07-31 | 山东恒鲁生物科技有限公司 | Sea cucumber oil soap base and preparation method and application thereof |
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Application publication date: 20180403 |