CN107857949A - A kind of preparation technology of water proof ventilating type gloves - Google Patents
A kind of preparation technology of water proof ventilating type gloves Download PDFInfo
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- CN107857949A CN107857949A CN201710941104.6A CN201710941104A CN107857949A CN 107857949 A CN107857949 A CN 107857949A CN 201710941104 A CN201710941104 A CN 201710941104A CN 107857949 A CN107857949 A CN 107857949A
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- glue
- water proof
- plasticizer
- nitrile rubber
- polyvinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D99/00—Subject matter not provided for in other groups of this subclass
- B29D99/0064—Producing wearing apparel
- B29D99/0067—Gloves
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
- D06N3/065—PVC together with other resins except polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Gloves (AREA)
Abstract
The invention discloses a kind of preparation technology of water proof ventilating type gloves, the preparation technology that water proof ventilating type gloves are completed by the weaving of glove bulk, three proofings processing, the processing of leaching glue and anti-skidding processing step；The special slurries of the present invention to the macromolecular structure of nitrile rubber by being modified, it is set to be changed into the low molecular flexible plasticizer of reactivity, traditional plasticizer for polyvinyl chloride DOP and DINP can partly be substituted, can be compatible well with polyvinyl chloride, form new composite, new composite changes the flexibility and resilience of polyvinyl chloride, improve anti-chemical and oil resistance, the property easy to aging of nitrile rubber is also changed simultaneously, the resistance to low temperature of nitrile rubber can be changed in order to avoid vulcanization shortens process time.The present invention can effectively reduce the surface tension of the fiber in glove bulk by using the use of polynary fluorine surface conditioning agent, realize the impermeable of aqueous water, permeable, the effect of effectively realizing waterproof and breathable of vapor.
Description
Technical field
The present invention relates to a kind of preparation technology of gloves, and in particular to a kind of preparation technology of water proof ventilating type gloves.
Background technology
Polyvinyl chloride (PVC) raw material sources are extensive, and goods cost is low, light weight, construction and maintaining are convenient,
Be occupy second general-purpose plastics.But PVC materials have the shortcomings that poor toughness, poor heat resistance, it is constrained in performance requirement
The development in higher field.
Nitrile rubber is as made from butadiene and acrylonitrile through emulsion polymerization, and nitrile rubber mainly uses low temperature emulsion
Polymerization produces, and oil resistivity is fabulous, and wearability is higher, and heat resistance is preferable, and bonding force is strong, and its shortcoming is that lower temperature resistance is poor, resistance to smelly
Oxygen is poor, and insulating properties are inferior, and elasticity is slightly lower.
Because molecular structure differs greatly, the medium that polyvinyl chloride melts is plasticizer for polyvinyl chloride and nitrile rubber, category
In oil dispersion, and nitrile rubber synthesis butyronitrile latex is aqueous medium, and the two is difficult compatible compound, meanwhile, polyvinyl chloride
Plasticization temperature and nitrile rubber curing temperature it is different, be extremely difficult to identical plasticizing effect.
How polyvinyl chloride and nitrile rubber are carried out to compatible, the shortcomings that can improving polyvinyl chloride, and can improves butyronitrile
The shortcomings that rubber, coexisting for advantage is realized, the problem of seeking to break through into each enterprise.
The existing protection to labourer's both hands, leather glove made of general useful skin, made of cloth fabric gloves, use yarn
Thread yarn gloves protect, and in order to carry out anti-skidding processing, typically can all select coating, but after applying coating, gloves
Soft unrest and gas permeability just substantially reduce, and anti-skidding treatment effect is also poor.
The content of the invention
In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to air permeable waterproof, simultaneously can effectively be realized by now providing one kind
And it can effectively realize the preparation technology of anti-skidding water proof ventilating type gloves.
In order to solve the above technical problems, the technical solution adopted by the present invention is：A kind of preparation work of water proof ventilating type gloves
Skill, its innovative point are：Water proof ventilating type gloves are completed by the weaving of glove bulk, three proofings processing and leaching glue processing step
Preparation technology；Comprise the following steps that：
（1）The weaving of glove bulk：It is raw material from nylon, carries out seamless knitted using 15 pins or 18 pins, complete gloves sheet
The weaving of body；
（2）Three proofings processing：Above-mentioned glove bulk is put in polynary fluorine surface conditioning agent and impregnated, at the polynary fluorine surface
The addition of reason machine is 20g/L, and the dip time is 1-3s, then carries out high temperature baking, the stoving temperature is 150-170
DEG C, the baking time is 10-20min；
（3）Drench glue processing：Gloves after processing are subjected to once leaching glue and secondary leaching glue using special glue, complete waterproof and breathable
The preparation technology of type gloves；
（4）Anti-skidding processing：Gloves after leaching glue are put in antiskid liquid and carry out soaking paste, then plastify 15- at 170-180 DEG C
20min, complete the preparation technology of water proof ventilating type gloves.
Further, the step（3）In special glue pass through nitrile rubber modified technique, polyvinyl chloride and butyronitrile
The combination process of rubber, the preparation of special glue is completed, is comprised the following steps that：
A. the modified technique of nitrile rubber：Nitrile rubber is mixed with flexible plasticizer, it is Celsius that water proof is heated to 45-55
Degree, then carries out high-speed stirred, stands 22-26 hours after stirring, obtains modified butadiene acrylonitrile rubber；
B. the combination process of polyvinyl chloride and nitrile rubber：By modified butadiene acrylonitrile rubber, flexible plasticizer, stabilizer, rheological agent and
Antistatic agent is mixed, and water proof is heated to 42-44 degrees Celsius, is then carried out high-speed stirred, is stirred, and completes polyvinyl chloride
With the preparation of the composite material of nitrile rubber.
Further, the step（a）In flexible plasticizer be citric acid plasticizer and polyester plasticizer, the butyronitrile
The mixing quality ratio of rubber, citric acid plasticizer and polyester plasticizer is 2:1:1.
Further, the step（a）In high-speed stirred speed be 800-1000r/min, the mixing time is 1-
1.5 hour.
Further, the step（b）In flexible plasticizer be citric acid plasticizer and polyester plasticizer, the flexibility
The mixing quality of plasticizer and modified butadiene acrylonitrile rubber ratio is 1:1, the addition of the stabilizer accounts for polyvinyl chloride and nitrile rubber
Composite material gross mass 2-3%, the addition of the antistatic agent accounts for the composite material of polyvinyl chloride and nitrile rubber
The 1% of gross mass.
Further, the step（b）In high-speed stirred speed be 800-1000r/min, the mixing time is 1-
1.5 hour.
Further, the step（3）In first time leaching glue processing concretely comprise the following steps：Gloves after three proofings is handled enter
Row once drenches glue, carries out drop glue after drenching cementing beam, the drop glue time is 5-10min, and 150-160 DEG C of temperature is put in after dripping cementing beam
Pre- plastotype 5-8min under degree, complete leaching glue processing for the first time.
Further, the step（3）In second leaching glue processing concretely comprise the following steps：Gloves after once leaching glue are entered
The secondary leaching glue of row, drop glue is carried out after the secondary cementing beam of leaching, the drop glue time is 5-10min, and 150-160 is put in after dripping cementing beam
Pre- plastotype 5-8min at a temperature of DEG C, complete second of leaching glue processing.
Further, the step（4）In antiskid liquid be polyvinyl chloride resin, sagging inhibitor and plasticizer mixed solution, institute
State sagging inhibitor accounts for gross mass 10%, the polyvinyl chloride resin accounts for the 50% of gross mass, and remaining is all plasticizer, the polyvinyl chloride resin by
The resin and paste resin of variable grain mix, and the resin of the variable grain and the mixing ratio of paste resin are 1:1.
Beneficial effects of the present invention are as follows：
（1）The special slurries of the present invention are changed into it low molecular by being modified to the macromolecular structure of nitrile rubber
The flexible plasticizer of reactivity, can partly substitute traditional plasticizer for polyvinyl chloride DOP and DINP, can be with polyvinyl chloride very
Good is compatible, forms new composite, new composite changes the flexibility and resilience of polyvinyl chloride, improves anti-
Chemically and oil resistance, while the property easy to aging of nitrile rubber is also changed, can changed in order to avoid vulcanization shortens process time
The resistance to low temperature of nitrile rubber.
（2）The present invention by being used cooperatively for the resin of variable grain, is realized to gloves by the use of antiskid liquid
Anti-skidding effect.
（3）The present invention can effectively reduce the fibre in glove bulk by using the use of polynary fluorine surface conditioning agent
The surface tension of dimension, realizes the impermeable of aqueous water, permeable, the effect of effectively realizing waterproof and breathable of vapor.
Embodiment
Embodiments of the present invention are illustrated by particular specific embodiment below, those skilled in the art can be by this explanation
Content disclosed by book understands other advantages and effect of the present invention easily.
Embodiment 1
A kind of preparation technology of water proof ventilating type gloves, it is complete by the weaving of glove bulk, three proofings processing and leaching glue processing step
Into the preparation technology of water proof ventilating type gloves；Comprise the following steps that：
（1）The weaving of glove bulk：It is raw material from nylon, carries out seamless knitted using 15 pins or 18 pins, complete gloves sheet
The weaving of body；
（2）Three proofings processing：Above-mentioned glove bulk is put in polynary fluorine surface conditioning agent and impregnated, polynary fluorine surface treating machine
Addition be 20g/L, dip time 1s, then carry out high temperature baking, stoving temperature is 150 DEG C, bakees the time and is
10min；
（3）Drench glue processing：Gloves after processing are subjected to once leaching glue and secondary leaching glue using special glue, complete waterproof and breathable
The preparation technology of type gloves；
（4）Anti-skidding processing：Gloves after leaching glue are put in antiskid liquid and carry out soaking paste, then plastify 15- at 170-180 DEG C
20min, complete the preparation technology of water proof ventilating type gloves.
Step（3）In special glue by the modified technique of nitrile rubber, polyvinyl chloride and nitrile rubber compound work
Skill, the preparation of special glue is completed, is comprised the following steps that：
A. the modified technique of nitrile rubber：Nitrile rubber is mixed with flexible plasticizer, water proof is heated to 45 degrees Celsius, so
After carry out high-speed stirred, stand 22 hours after stirring, obtain modified butadiene acrylonitrile rubber；
B. the combination process of polyvinyl chloride and nitrile rubber：By modified butadiene acrylonitrile rubber, flexible plasticizer, stabilizer, rheological agent and
Antistatic agent is mixed, and water proof is heated to 42 degrees Celsius, is then carried out high-speed stirred, is stirred, complete polyvinyl chloride and
The preparation of the composite material of nitrile rubber.
Step（a）In flexible plasticizer be citric acid plasticizer and polyester plasticizer, nitrile rubber, citric acid plasticizer
Mixing quality ratio with polyester plasticizer is 2:1:1, high-speed stirred speed is 800r/min, and mixing time is 1-1.5 hours.
Step（b）In flexible plasticizer be citric acid plasticizer and polyester plasticizer, flexible plasticizer and modified butyronitrile
The mixing quality ratio of rubber is 1:1, the addition of stabilizer accounts for the composite material gross mass of polyvinyl chloride and nitrile rubber
2%, the addition of antistatic agent accounts for the 1% of the composite material gross mass of polyvinyl chloride and nitrile rubber, and high-speed stirred speed is
800r/min, mixing time are 1 hour.
Step（3）In first time leaching glue processing concretely comprise the following steps：Gloves after three proofings is handled once are drenched glue, leaching
Carry out drop glue after cementing beam, the drop glue time be 5min, drips pre- plastotype 5min at a temperature of being put in 150 DEG C after cementing beam, completion
Leaching glue processing for the first time.
Step（3）In second leaching glue processing concretely comprise the following steps：The gloves after glue will once be drenched and carry out secondary leaching glue, two
Drop glue is carried out after the cementing beam of secondary leaching, the drop glue time is 5min, drips pre- plastotype 5min at a temperature of being put in 150 DEG C after cementing beam, completion
Second of leaching glue processing.
Step（4）In antiskid liquid be polyvinyl chloride resin, sagging inhibitor and plasticizer mixed solution, sagging inhibitor accounts for total matter
The 10% of amount, polyvinyl chloride resin accounts for the 50% of gross mass, and remaining is all plasticizer, polyvinyl chloride resin by variable grain resin and paste resin
Mix, the resin of variable grain and the mixing ratio of paste resin are 1:1.
Embodiment 2
A kind of preparation technology of water proof ventilating type gloves, it is complete by the weaving of glove bulk, three proofings processing and leaching glue processing step
Into the preparation technology of water proof ventilating type gloves；Comprise the following steps that：
（1）The weaving of glove bulk：It is raw material from nylon, carries out seamless knitted using 15 pins or 18 pins, complete gloves sheet
The weaving of body；
（2）Three proofings processing：Above-mentioned glove bulk is put in polynary fluorine surface conditioning agent and impregnated, polynary fluorine surface treating machine
Addition be 20g/L, dip time 3s, then carry out high temperature baking, stoving temperature is 170 DEG C, bakees the time and is
20min；
（3）Drench glue processing：Gloves after processing are subjected to once leaching glue and secondary leaching glue using special glue, complete waterproof and breathable
The preparation technology of type gloves；
（4）Anti-skidding processing：Gloves after leaching glue are put in antiskid liquid and carry out soaking paste, 20min is then plastified at 180 DEG C, it is complete
Into the preparation technology of water proof ventilating type gloves.
Step（3）In special glue by the modified technique of nitrile rubber, polyvinyl chloride and nitrile rubber compound work
Skill, the preparation of special glue is completed, is comprised the following steps that：
A. the modified technique of nitrile rubber：Nitrile rubber is mixed with flexible plasticizer, water proof is heated to 55 degrees Celsius, so
After carry out high-speed stirred, stand 26 hours after stirring, obtain modified butadiene acrylonitrile rubber；
B. the combination process of polyvinyl chloride and nitrile rubber：By modified butadiene acrylonitrile rubber, flexible plasticizer, stabilizer, rheological agent and
Antistatic agent is mixed, and water proof is heated to 44 degrees Celsius, is then carried out high-speed stirred, is stirred, complete polyvinyl chloride and
The preparation of the composite material of nitrile rubber.
Step（a）In flexible plasticizer be citric acid plasticizer and polyester plasticizer, nitrile rubber, citric acid plasticizer
Mixing quality ratio with polyester plasticizer is 2:1:1, high-speed stirred speed is 1000r/min, and mixing time is 1.5 hours.
Step（b）In flexible plasticizer be citric acid plasticizer and polyester plasticizer, flexible plasticizer and modified butyronitrile
The mixing quality ratio of rubber is 1:1, the addition of stabilizer accounts for the composite material gross mass of polyvinyl chloride and nitrile rubber
3%, the addition of antistatic agent accounts for the 1% of the composite material gross mass of polyvinyl chloride and nitrile rubber, and high-speed stirred speed is
1000r/min, mixing time are 1.5 hours.
Step（3）In first time leaching glue processing concretely comprise the following steps：Gloves after three proofings is handled once are drenched glue, leaching
Carry out drop glue after cementing beam, the drop glue time be 10min, drips pre- plastotype 8min at a temperature of being put in 160 DEG C after cementing beam, completion
Leaching glue processing for the first time.
Step（3）In second leaching glue processing concretely comprise the following steps：The gloves after glue will once be drenched and carry out secondary leaching glue, two
Drop glue is carried out after the cementing beam of secondary leaching, the drop glue time is 10min, drips pre- plastotype 8min at a temperature of being put in 160 DEG C after cementing beam, completion
Second of leaching glue processing.
Step（4）In antiskid liquid be polyvinyl chloride resin, sagging inhibitor and plasticizer mixed solution, sagging inhibitor accounts for total matter
The 10% of amount, polyvinyl chloride resin accounts for the 50% of gross mass, and remaining is all plasticizer, polyvinyl chloride resin by variable grain resin and paste resin
Mix, the resin of variable grain and the mixing ratio of paste resin are 1:1.
Embodiment 3
A kind of preparation technology of water proof ventilating type gloves, it is complete by the weaving of glove bulk, three proofings processing and leaching glue processing step
Into the preparation technology of water proof ventilating type gloves；Comprise the following steps that：
（1）The weaving of glove bulk：It is raw material from nylon, carries out seamless knitted using 15 pins or 18 pins, complete gloves sheet
The weaving of body；
（2）Three proofings processing：Above-mentioned glove bulk is put in polynary fluorine surface conditioning agent and impregnated, polynary fluorine surface treating machine
Addition be 20g/L, dip time 2s, then carry out high temperature baking, stoving temperature is 160 DEG C, bakees the time and is
15min；
（3）Drench glue processing：Gloves after processing are subjected to once leaching glue and secondary leaching glue using special glue, complete waterproof and breathable
The preparation technology of type gloves；
（4）Anti-skidding processing：Gloves after leaching glue are put in antiskid liquid and carry out soaking paste, 17min is then plastified at 175 DEG C, it is complete
Into the preparation technology of water proof ventilating type gloves.
Step（3）In special glue by the modified technique of nitrile rubber, polyvinyl chloride and nitrile rubber compound work
Skill, the preparation of special glue is completed, is comprised the following steps that：
A. the modified technique of nitrile rubber：Nitrile rubber is mixed with flexible plasticizer, water proof is heated to 50 degrees Celsius, so
After carry out high-speed stirred, stand 24 hours after stirring, obtain modified butadiene acrylonitrile rubber；
B. the combination process of polyvinyl chloride and nitrile rubber：By modified butadiene acrylonitrile rubber, flexible plasticizer, stabilizer, rheological agent and
Antistatic agent is mixed, and water proof is heated to 43 degrees Celsius, is then carried out high-speed stirred, is stirred, complete polyvinyl chloride and
The preparation of the composite material of nitrile rubber.
Step（a）In flexible plasticizer be citric acid plasticizer and polyester plasticizer, nitrile rubber, citric acid plasticizer
Mixing quality ratio with polyester plasticizer is 2:1:1, high-speed stirred speed is 900r/min, and mixing time is 1.2 hours.
Step（b）In flexible plasticizer be citric acid plasticizer and polyester plasticizer, flexible plasticizer and modified butyronitrile
The mixing quality ratio of rubber is 1:1, the addition of stabilizer accounts for the composite material gross mass of polyvinyl chloride and nitrile rubber
2.5%, the addition of antistatic agent accounts for the 1% of the composite material gross mass of polyvinyl chloride and nitrile rubber, high-speed stirred speed
For 900r/min, mixing time is 1.3 hours.
Step（3）In first time leaching glue processing concretely comprise the following steps：Gloves after three proofings is handled once are drenched glue, leaching
Carry out drop glue after cementing beam, the drop glue time be 7min, drips pre- plastotype 7min at a temperature of being put in 155 DEG C after cementing beam, completion
Leaching glue processing for the first time.
Step（3）In second leaching glue processing concretely comprise the following steps：The gloves after glue will once be drenched and carry out secondary leaching glue, two
Drop glue is carried out after the cementing beam of secondary leaching, the drop glue time is 7min, drips pre- plastotype 6min at a temperature of being put in 155 DEG C after cementing beam, completion
Second of leaching glue processing.
Step（4）In antiskid liquid be polyvinyl chloride resin, sagging inhibitor and plasticizer mixed solution, sagging inhibitor accounts for total matter
The 10% of amount, polyvinyl chloride resin accounts for the 50% of gross mass, and remaining is all plasticizer, polyvinyl chloride resin by variable grain resin and paste resin
Mix, the resin of variable grain and the mixing ratio of paste resin are 1:1.
The special slurries of the present invention are changed into it low molecular by being modified to the macromolecular structure of nitrile rubber
The flexible plasticizer of reactivity, can partly substitute traditional plasticizer for polyvinyl chloride DOP and DINP, can be with polyvinyl chloride very
Good is compatible, forms new composite, new composite changes the flexibility and resilience of polyvinyl chloride, improves anti-
Chemically and oil resistance, while the property easy to aging of nitrile rubber is also changed, can changed in order to avoid vulcanization shortens process time
The resistance to low temperature of nitrile rubber.The present invention is real by being used cooperatively for the resin of variable grain by the use of antiskid liquid
Anti-skidding effect to gloves is showed.The present invention can effectively reduce gloves by using the use of polynary fluorine surface conditioning agent
The surface tension of intrinsic fiber, realizes the impermeable of aqueous water, vapor it is permeable, effectively realize waterproof and breathable
The effect of.
Above-described embodiment is presently preferred embodiments of the present invention, is not the limitation to technical solution of the present invention, as long as
The technical scheme that can be realized on the basis of above-described embodiment without creative work, it is regarded as falling into patent of the present invention
Rights protection scope in.
Claims (9)
- A kind of 1. preparation technology of water proof ventilating type gloves, it is characterised in that：By the weaving of glove bulk, three proofings processing, leaching Glue processing and anti-skidding processing step complete the preparation technology of water proof ventilating type gloves；Comprise the following steps that：The weaving of glove bulk：It is raw material from nylon, carries out seamless knitted using 15 pins or 18 pins, complete glove bulk Weaving；Three proofings processing：Above-mentioned glove bulk is put in polynary fluorine surface conditioning agent and impregnated, the polynary fluorine surface treatment The addition of machine is 20g/L, and the dip time is 1-3s, then carries out high temperature baking, the stoving temperature is 150-170 DEG C, the baking time is 10-20min；Drench glue processing：Gloves after processing are subjected to once leaching glue and secondary leaching glue using special glue；Anti-skidding processing：Gloves after leaching glue are put in antiskid liquid and carry out soaking paste, then plastify 15- at 170-180 DEG C 20min, complete the preparation technology of water proof ventilating type gloves.
- A kind of 2. preparation technology of water proof ventilating type gloves according to claim 1, it is characterised in that：The step（3） In special glue by the combination process of the modified technique of nitrile rubber, polyvinyl chloride and nitrile rubber, complete special glue Preparation, comprise the following steps that：A. the modified technique of nitrile rubber：Nitrile rubber is mixed with flexible plasticizer, it is Celsius that water proof is heated to 45-55 Degree, then carries out high-speed stirred, stands 22-26 hours after stirring, obtains modified butadiene acrylonitrile rubber；B. the combination process of polyvinyl chloride and nitrile rubber：By modified butadiene acrylonitrile rubber, flexible plasticizer, stabilizer, rheological agent and Antistatic agent is mixed, and water proof is heated to 42-44 degrees Celsius, is then carried out high-speed stirred, is stirred, and completes polyvinyl chloride With the preparation of the composite material of nitrile rubber.
- A kind of 3. preparation technology of water proof ventilating type gloves according to claim 2, it is characterised in that：The step（a） In flexible plasticizer be citric acid plasticizer and polyester plasticizer, the nitrile rubber, citric acid plasticizer and polyester plasticising The mixing quality ratio of agent is 2:1:1.
- A kind of 4. preparation technology of water proof ventilating type gloves according to claim 2, it is characterised in that：The step（a） In high-speed stirred speed be 800-1000r/min, the mixing time is 1-1.5 hours.
- A kind of 5. preparation technology of water proof ventilating type gloves according to claim 2, it is characterised in that：The step（b） In flexible plasticizer be citric acid plasticizer and polyester plasticizer, the mixing matter of the flexible plasticizer and modified butadiene acrylonitrile rubber Amount is than being 1:1, the addition of the stabilizer accounts for the 2-3% of the composite material gross mass of polyvinyl chloride and nitrile rubber, described The addition of antistatic agent accounts for the 1% of the composite material gross mass of polyvinyl chloride and nitrile rubber.
- A kind of 6. preparation technology of water proof ventilating type gloves according to claim 2, it is characterised in that：The step（b） In high-speed stirred speed be 800-1000r/min, the mixing time is 1-1.5 hours.
- A kind of 7. preparation technology of water proof ventilating type gloves according to claim 1, it is characterised in that：The step（3） In first time leaching glue processing concretely comprise the following steps：Gloves after three proofings is handled once are drenched glue, are dripped after drenching cementing beam Glue, the drop glue time be 5-10min, drips pre- plastotype 5-8min at a temperature of being put in 150-160 DEG C after cementing beam, completes first time Drench glue processing.
- A kind of 8. preparation technology of water proof ventilating type gloves according to claim 1, it is characterised in that：The step（3） In second leaching glue processing concretely comprise the following steps：Gloves after once leaching glue are subjected to secondary leaching glue, the secondary cementing Shu Houjin of leaching Row drop glue, the drop glue time be 5-10min, drips pre- plastotype 5-8min at a temperature of being put in 150-160 DEG C after cementing beam, completion the Secondary leaching glue processing.
- A kind of 9. preparation technology of water proof ventilating type gloves according to claim 1, it is characterised in that：The step（4） In antiskid liquid be polyvinyl chloride resin, sagging inhibitor and plasticizer mixed solution, the sagging inhibitor accounts for the 10% of gross mass, described Polyvinyl chloride resin accounts for the 50% of gross mass, and remaining is all plasticizer, and the polyvinyl chloride resin is mixed by the resin and paste resin of variable grain Form, the resin of the variable grain and the mixing ratio of paste resin are 1:1.
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| CN201710941104.6A CN107857949A (en) | 2017-10-11 | 2017-10-11 | A kind of preparation technology of water proof ventilating type gloves |
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| CN201710941104.6A CN107857949A (en) | 2017-10-11 | 2017-10-11 | A kind of preparation technology of water proof ventilating type gloves |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109721890A (en) * | 2019-01-24 | 2019-05-07 | 山东星宇手套有限公司 | A kind of preparation method of PVC foam gloves |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102336988A (en) * | 2011-08-15 | 2012-02-01 | 江苏尤佳手套有限公司 | Environmentally-friendly polyvinyl chloride/nitrile butadiene rubber (PVC/NBR) composite gloves |
| CN102535165A (en) * | 2012-01-10 | 2012-07-04 | 昆山华成织染有限公司 | Waterproof and breathable coated fabric and preparation method thereof |
| WO2017117193A1 (en) * | 2015-12-31 | 2017-07-06 | Ringers Techologies Llc | Safety glove including chemical resistance and impact protection and method of manufacturing the same |
-
2017
- 2017-10-11 CN CN201710941104.6A patent/CN107857949A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102336988A (en) * | 2011-08-15 | 2012-02-01 | 江苏尤佳手套有限公司 | Environmentally-friendly polyvinyl chloride/nitrile butadiene rubber (PVC/NBR) composite gloves |
| CN102535165A (en) * | 2012-01-10 | 2012-07-04 | 昆山华成织染有限公司 | Waterproof and breathable coated fabric and preparation method thereof |
| WO2017117193A1 (en) * | 2015-12-31 | 2017-07-06 | Ringers Techologies Llc | Safety glove including chemical resistance and impact protection and method of manufacturing the same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109721890A (en) * | 2019-01-24 | 2019-05-07 | 山东星宇手套有限公司 | A kind of preparation method of PVC foam gloves |
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