CN107022046A - A kind of yarn fabric coating special emulsion formula - Google Patents
A kind of yarn fabric coating special emulsion formula Download PDFInfo
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- CN107022046A CN107022046A CN201710316097.0A CN201710316097A CN107022046A CN 107022046 A CN107022046 A CN 107022046A CN 201710316097 A CN201710316097 A CN 201710316097A CN 107022046 A CN107022046 A CN 107022046A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/42—Nitriles
- C08F220/44—Acrylonitrile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/273—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having epoxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses yarn fabric coating special emulsion, it is formulated and is：10~15 parts of hard monomer, 20~40 parts of soft monomer, 5~15 parts of function monomer, 5~15 parts of emulsifying agent, 0.5~1 part of initiator, 30~50 parts of water；Described soft monomer, hard monomer, function monomer are acrylic acid derivative or polymer.Yarn fabric after being handled using emulsion of the present invention, has the advantages that fast light, weatherability and fastness to washing are good.Due to the continuity of film forming, pore-free and larger film tension, also with certain water proofing property.
Description
Technical field
The invention belongs to technical field of fine, and in particular to a kind of yarn fabric coating special emulsion formula.
Background technology
Fabric coating is a kind of with fastest developing speed in recent years, widest Final finishing technology, and the fabric through top finish has
Leather sense, high resilience and plentiful soft feel and other effects, have the spy such as waterproof and breathable, moisture-inhibiting, antifouling, fire-retardant, antistatic again
Different performance, all occupies critical role in terms of the three big pillar products-clothing material, industrial cloth, interior decoration of textile.
Textile industry was the pillar industry that China's export is earned foreign exchange, by the development of more than 20 years, and China introduces and made by oneself near
Thousand set top finish production lines, the annual production of domestic coating adhesive has also reached 150,000 tons of scale, the manufacturer of coating adhesive
The provinces and cities such as China Jiangsu, Zhejiang, Shandong, Fujian and Shanghai are mainly distributed on user.It is domestic in recent years also to develop much
Coating adhesive kind, mainly has solvent-borne type to include acrylate, polyurethane and polyvinyl chloride, and water aqua type includes acrylate, gathered
Urethane and a small amount of organic-silicon-modified product, but still it is maximum with the yield of solvent-based coating glue.With the environmentally friendly new legislation of developed country
Issuing and implementation, solvent-based coating textile exports are obstructed, and the application total amount of aqueous coating glue in production has more than solvent-borne type
The trend of coating adhesive.Domestic coated fabric uses esters of acrylic acid mostly, and it is low to be primarily due to its price, production and technique for applying
More ripe, its fabric coating processed has the advantages that fast light, weatherability and fastness to washing are good, has the disadvantage feel " not well ", low
Temperature modeling sense is strong, vapor transfer rate is low, and aqueous polyurethane coating fabric has that feel is smooth, plentiful fine and smooth, low temperature resistant, vapor transfer rate
High, comfortable and easy to wear the advantages of, uniquely unfortunately cost is higher, and weatherability and fastness to washing are not so good as esters of acrylic acid.
At present, new polyurethane emulsion just develops towards functionalization, Composite direction, by introducing various work(in system
The composition of energy property, complex emulsions of the synthesis with property, has a extensive future.Relevant waterborne polyurethane-polyacrylate (PUA)
The research of complex emulsions is existing both at home and abroad much to be reported, but the application on fabric coating is still in conceptual phase.
The content of the invention
Goal of the invention：For weak point of the prior art, the invention provides a kind of yarn fabric coating special emulsion
Formula.
Technical scheme：Yarn fabric coating special emulsion of the present invention, is formulated and is：10~15 parts of hard monomer, soft monomer
20~40 parts, 5~15 parts of function monomer, 5~15 parts of emulsifying agent, 0.5~1 part of initiator, 30~50 parts of water；Described soft list
Body, hard monomer, function monomer are acrylic acid derivative or polymer.
Described hard monomer is that one or both of acrylic acid, methyl acrylate, acrylonitrile, methyl methacrylate are mixed
Close monomer.It is preferred that the mixture of methyl acrylate and acrylonitrile.
The soft monomer is ethyl acrylate, butyl acrylate, 2-ethyl hexyl acrylate, Isooctyl acrylate monomer, acrylic acid 2- second
One or both of the own ester of base, EMA, butyl methacrylate mix monomer.It is preferred that Isooctyl acrylate monomer with
The mixture of EMA.
Described functional monomer is Glycidyl Acrylate, the one or two kinds of mix monomers of glycidyl acrylate.
Described emulsifying agent is for one or more of mixtures in potassium oleate, sodium abietate.
Described initiator is isopropyl benzene hydroperoxide, cumyl peroxide or dibenzoyl peroxide.
Present invention also offers the preparation method of described yarn fabric coating special emulsion, carry out according to the following steps：Will be soft
Monomer, hard monomer, function monomer and water are mixed and made into pre-emulsion, add emulsifying agent in a part of pre-emulsion thereto and remaining
Water, stirring is warming up to 35 DEG C~45 DEG C, continues to be heated to 50 DEG C~60 DEG C, stops heating, adds a part of initiator, be warming up to
65 DEG C~75 DEG C, remaining pre-emulsion and initiator are added, is added in 3~5 hours, insulation reaction 1~3 hour is cooled down, and is adjusted
PH value is saved to 6.5~7.0.Described a part of pre-emulsion is the 40% of total amount；Described a part of initiator is total amount
40%.
Beneficial effect：Formula of the present invention with the addition of a certain amount of cross-linking monomer so that polymer macromolecule is poly-
Just there is a certain degree of crosslinking during conjunction, by low-temperature curing with regard to energy film forming, meet the current requirement for saving energy consumption.The present invention
Described preparation method technological process is brief, reaction can be carried out at a lower temperature, is not in gelatin phenomenon and adds automatically
Fast phenomenon.
Yarn fabric after being handled using emulsion of the present invention is good etc. with fast light, weatherability and fastness to washing
Advantage.Due to the continuity of film forming, pore-free and larger film tension, also with certain water proofing property.
Embodiment：
Embodiment 1
It is formulated and is：10 parts of acrylic acid, 20 parts of Isooctyl acrylate monomer, 5 parts of glycidyl acrylate, 5 parts of potassium oleate, isopropyl
.5 parts of benzene hydrogen peroxidase 10,30 parts of water.
Preparation method is：Soft monomer, hard monomer, function monomer and water are mixed and made into pre-emulsion, 40% pre-emulsion is taken
Emulsifying agent and remaining water are added thereto, stirring is warming up to 35 DEG C, continue to be heated to 50 DEG C, stop heating, add total amount
40% initiator, is warming up to 65 DEG C DEG C, adds remaining 60% pre-emulsion and 60% initiator, is added in 3 hours, protects
Temperature reaction 1 hour, cooling, regulation pH value to 6.5.Obtain special emulsion of the present invention.
Embodiment 2
Preparation method is same as Example 1, and difference is that changing formula is：10 parts of methyl methacrylate, propylene
20 parts of acid butyl ester, 5 parts of Glycidyl Acrylate, 5 parts of potassium oleate, 0.5 part of dibenzoyl peroxide, 30 parts of water.
Embodiment 3
Preparation method is same as Example 1, and difference is that changing formula is：10 parts of acrylonitrile, methacrylic acid fourth
20 parts of ester, 5 parts of Glycidyl Acrylate, 5 parts of potassium oleate, 0.5 part of cumyl peroxide, 30 parts of water.
Embodiment 4
Preparation method is same as Example 1, and difference is that changing formula is：The mixing of methyl acrylate and acrylonitrile
20 parts of 10 parts of thing, Isooctyl acrylate monomer and EMA, 5 parts of glycidyl acrylate, 5 parts of potassium oleate, isopropylbenzene
.5 parts of hydrogen peroxidase 10,30 parts of water.
Embodiment 5
Preparation method is same as Example 1, and difference is that changing formula is：15 parts of acrylic acid, Isooctyl acrylate monomer
40 parts, 15 parts of glycidyl acrylate, 15 parts of potassium oleate, 1 part of isopropyl benzene hydroperoxide, 50 parts of water.
Embodiment 6
Preparation method is same as Example 1, and difference is that changing formula is：15 parts of methyl methacrylate, propylene
40 parts of acid butyl ester, 15 parts of Glycidyl Acrylate, 15 parts of potassium oleate, 1 part of dibenzoyl peroxide, 50 parts of water.
Embodiment 7
Preparation method is same as Example 1, and difference is that changing formula is：115 parts of acrylonitrile, methacrylic acid fourth
40 parts of ester, 15 parts of Glycidyl Acrylate, 15 parts of potassium oleate, 1 part of cumyl peroxide, 50 parts of water.
Embodiment 8
Preparation method is same as Example 1, and difference is that changing formula is：The mixing of methyl acrylate and acrylonitrile
40 parts of 15 parts of thing, Isooctyl acrylate monomer and EMA, 15 parts of glycidyl acrylate, 5 parts of potassium oleate, isopropylbenzene
1 part of hydrogen peroxide, 50 parts of water.
Embodiment 9
It is formulated and is：10 parts of acrylic acid, 20 parts of Isooctyl acrylate monomer, 5 parts of glycidyl acrylate, 5 parts of potassium oleate, isopropyl
.5 parts of benzene hydrogen peroxidase 10,30 parts of water.
Preparation method is：Soft monomer, hard monomer, function monomer and water are mixed and made into pre-emulsion, 40% pre-emulsion is taken
Emulsifying agent and remaining water are added thereto, stirring is warming up to 45 DEG C, continue to be heated to 60 DEG C, stop heating, add total amount
40% initiator, is warming up to 75 DEG C, adds remaining 60% pre-emulsion and 60% initiator, is added in 5 hours, insulation
Reaction 3 hours, cooling, regulation pH value to 7.0.Obtain special emulsion of the present invention.
Embodiment 10
Preparation method is same as Example 9, and difference is that changing formula is：10 parts of methyl methacrylate, propylene
20 parts of acid butyl ester, 5 parts of Glycidyl Acrylate, 5 parts of potassium oleate, 0.5 part of dibenzoyl peroxide, 30 parts of water.
Embodiment 11
Preparation method is same as Example 9, and difference is that changing formula is：10 parts of acrylonitrile, methacrylic acid fourth
20 parts of ester, 5 parts of Glycidyl Acrylate, 5 parts of potassium oleate, 0.5 part of cumyl peroxide, 30 parts of water.
Embodiment 12
Preparation method is same as Example 9, and difference is that changing formula is：The mixing of methyl acrylate and acrylonitrile
20 parts of 10 parts of thing, Isooctyl acrylate monomer and EMA, 5 parts of glycidyl acrylate, 5 parts of potassium oleate, isopropylbenzene
.5 parts of hydrogen peroxidase 10,30 parts of water.
Embodiment 13
Preparation method is same as Example 9, and difference is that changing formula is：15 parts of acrylic acid, Isooctyl acrylate monomer
40 parts, 15 parts of glycidyl acrylate, 15 parts of potassium oleate, 1 part of isopropyl benzene hydroperoxide, 50 parts of water.
Embodiment 14
Preparation method is same as Example 9, and difference is that changing formula is：15 parts of methyl methacrylate, propylene
40 parts of acid butyl ester, 15 parts of Glycidyl Acrylate, 15 parts of potassium oleate, 1 part of dibenzoyl peroxide, 50 parts of water.
Embodiment 15
Preparation method is same as Example 9, and difference is that changing formula is：115 parts of acrylonitrile, methacrylic acid fourth
40 parts of ester, 15 parts of Glycidyl Acrylate, 15 parts of potassium oleate, 1 part of cumyl peroxide, 50 parts of water.
Embodiment 16
Preparation method is same as Example 9, and difference is that changing formula is：The mixing of methyl acrylate and acrylonitrile
40 parts of 15 parts of thing, Isooctyl acrylate monomer and EMA, 15 parts of glycidyl acrylate, 15 parts of potassium oleate, isopropyl
1 part of benzene hydrogen peroxide, 50 parts of water.
Claims (10)
1. a kind of yarn fabric coating special emulsion formula, it is characterised in that be formulated and be：10~15 parts of hard monomer, soft monomer 20~40
Part, 5~15 parts of function monomer, 5~15 parts of emulsifying agent, 0.5~1 part of initiator, 30~50 parts of water；It is described soft monomer, hard single
Body, function monomer are acrylic acid derivative or polymer.
2. yarn fabric coating special emulsion formula according to claim 1, it is characterised in that described hard monomer is propylene
One or both of acid, methyl acrylate, acrylonitrile, methyl methacrylate mix monomer.
3. yarn fabric coating special emulsion formula according to claim 2, it is characterised in that described hard monomer is propylene
The mixture of sour methyl esters and acrylonitrile.
4. yarn fabric coating special emulsion formula according to claim 1, it is characterised in that the soft monomer is acrylic acid
Ethyl ester, butyl acrylate, 2-ethyl hexyl acrylate, Isooctyl acrylate monomer, 2-EHA, EMA, methyl
One or both of butyl acrylate mix monomer.
5. yarn fabric coating special emulsion formula according to claim 4, it is characterised in that the soft monomer acrylic acid is different
The mixture of monooctyl ester and EMA.
6. yarn fabric coating special emulsion according to claim 1 formula, it is characterised in that described functional monomer is
The one or two kinds of mix monomers of Glycidyl Acrylate, glycidyl acrylate.
7. yarn fabric coating special emulsion formula according to claim 1, it is characterised in that described emulsifying agent is for oil
One or more of mixtures in sour potassium, sodium abietate.
8. yarn fabric coating special emulsion formula according to claim 1, it is characterised in that described initiator is isopropyl
Benzene hydrogen peroxide, cumyl peroxide or dibenzoyl peroxide.
9. the preparation method of the yarn fabric coating special emulsion in claim 1~8 described in any one, it is characterised in that by with
Lower step is carried out：Soft monomer, hard monomer, function monomer and water are mixed and made into pre-emulsion, added thereto in a part of pre-emulsion
Enter emulsifying agent and remaining water, stirring is warming up to 35 DEG C~45 DEG C, continue to be heated to 50 DEG C~60 DEG C, stop heating, add one
Part initiator, is warming up to 65 DEG C~75 DEG C, adds remaining pre-emulsion and initiator, is added in 3~5 hours, and insulation is anti-
Answer 1~3 hour, cool down, regulation pH value to 6.5~7.0.
10. preparation method according to claim 9, it is characterised in that described a part of pre-emulsion is the 40% of total amount；
Described a part of initiator is the 40% of total amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710316097.0A CN107022046A (en) | 2017-05-08 | 2017-05-08 | A kind of yarn fabric coating special emulsion formula |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710316097.0A CN107022046A (en) | 2017-05-08 | 2017-05-08 | A kind of yarn fabric coating special emulsion formula |
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| Publication Number | Publication Date |
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| CN107022046A true CN107022046A (en) | 2017-08-08 |
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ID=59528718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201710316097.0A Pending CN107022046A (en) | 2017-05-08 | 2017-05-08 | A kind of yarn fabric coating special emulsion formula |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109281171A (en) * | 2018-09-28 | 2019-01-29 | 安徽省永欣织带有限公司 | A kind of preparation method of the anti-breaking silk weaving with coating |
| CN114232325A (en) * | 2021-12-31 | 2022-03-25 | 湖州新利商标制带有限公司 | Polyester-based label tape |
| CN115058894A (en) * | 2022-08-17 | 2022-09-16 | 江苏金呢工程织物股份有限公司 | Hydrolysis-resistant textile auxiliary for drying net |
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| CN1544566A (en) * | 2003-11-18 | 2004-11-10 | 上海市印染技术研究所 | Method for preparing formaldehyde-free coating adhesive for printing |
| CN101717468A (en) * | 2009-11-18 | 2010-06-02 | 北京高盟化工有限公司 | Aqueous acrylic emulsion, aqueous adhesive for plastic-plastic composite materials and preparation method thereof |
| CN102757525A (en) * | 2012-07-25 | 2012-10-31 | 上海雅运纺织助剂有限公司 | Environmental-friendly pigment printing binding agent and preparation method thereof |
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2017
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| CN1544566A (en) * | 2003-11-18 | 2004-11-10 | 上海市印染技术研究所 | Method for preparing formaldehyde-free coating adhesive for printing |
| CN101717468A (en) * | 2009-11-18 | 2010-06-02 | 北京高盟化工有限公司 | Aqueous acrylic emulsion, aqueous adhesive for plastic-plastic composite materials and preparation method thereof |
| CN102757525A (en) * | 2012-07-25 | 2012-10-31 | 上海雅运纺织助剂有限公司 | Environmental-friendly pigment printing binding agent and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109281171A (en) * | 2018-09-28 | 2019-01-29 | 安徽省永欣织带有限公司 | A kind of preparation method of the anti-breaking silk weaving with coating |
| CN114232325A (en) * | 2021-12-31 | 2022-03-25 | 湖州新利商标制带有限公司 | Polyester-based label tape |
| CN115058894A (en) * | 2022-08-17 | 2022-09-16 | 江苏金呢工程织物股份有限公司 | Hydrolysis-resistant textile auxiliary for drying net |
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Application publication date: 20170808 |