CN107418459A - A kind of new-type heat-melting glued membrane, preparation method and application - Google Patents

A kind of new-type heat-melting glued membrane, preparation method and application Download PDF

Info

Publication number
CN107418459A
CN107418459A CN201710605064.8A CN201710605064A CN107418459A CN 107418459 A CN107418459 A CN 107418459A CN 201710605064 A CN201710605064 A CN 201710605064A CN 107418459 A CN107418459 A CN 107418459A
Authority
CN
China
Prior art keywords
new
glued membrane
type heat
hot melt
melt adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710605064.8A
Other languages
Chinese (zh)
Inventor
叶书怀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu And New Materials Ltd By Share Ltd
Original Assignee
Jiangsu And New Materials Ltd By Share Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu And New Materials Ltd By Share Ltd filed Critical Jiangsu And New Materials Ltd By Share Ltd
Priority to CN201710605064.8A priority Critical patent/CN107418459A/en
Publication of CN107418459A publication Critical patent/CN107418459A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B32B37/065—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method resulting in the laminate being partially bonded
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207—Heat-activated adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/26—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer which influences the bonding during the lamination process, e.g. release layers or pressure equalising layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C09J123/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C09J123/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/10—Homopolymers or copolymers of propene
    • C09J123/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207—Heat-activated adhesive
    • B32B2037/1215—Hot-melt adhesive
    • B32B2037/1223—Hot-melt adhesive film-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
    • B32B2266/0221—Vinyl resin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/304—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being heat-activatable, i.e. not tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00—Presence of polyolefin
    • C09J2423/04—Presence of homo or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00—Presence of polyolefin
    • C09J2423/10—Presence of homo or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00—Presence of polyolefin
    • C09J2423/16—Presence of ethen-propene or ethene-propene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2453/00—Presence of block copolymer

Abstract

The invention discloses a kind of hot melt adhesive film, the hot melt adhesive film is made up of antioxidant, Petropols and engineering plastics, also discloses the preparation method of above-mentioned hot melt adhesive film, and hot melt adhesive film cost made from this method is low, technique is simple, economizes on resources, be environmentally friendly.The application of sheet rubber sole formed is overlayed in EVA the invention also discloses above-mentioned hot melt adhesive film.

Description

A kind of new-type heat-melting glued membrane, preparation method and application
Technical field
The present invention relates to polymeric material field, and in particular to a kind of hot melt adhesive film, preparation method and applications.
Background technology
EVA composite soles combine the advantages of wearability of rubber, the portability of foamed shoe sole, comfortableness, turn into motion The most frequently used sole of footwear, playshoes.The bonding of rubber sole and EVA midsoles is compound typically using Solution Chloroprene Rubber Adhesives or poly- Urethane adhesive is bonded, and using solvent-based adhesive complex process, need to be carried out roughening treatment to rubber sole, EVA midsoles, be rinsed bottom Paint, gluing, solvent, bonding are dried, flow is cumbersome, wastes time and energy, and production cost is high, and the middle benzene series solvent of adhesive is to environment Huge pollution is caused, has seriously endangered the physical and mental health of shoemaking worker.
Although also having now using hot melt adhesive film bonding EVA shoe bottom, its complex process, consumptive material is taken.
The content of the invention
An object of the present invention is to provide a kind of new-type heat-melting glued membrane, and cost is low, technique is simple, economizes on resources, to ring Border is friendly.
To reach above-mentioned purpose, the technical solution adopted by the present invention is：
A kind of new-type heat-melting glued membrane, it is characterised in that including following mass percent component：
Antioxidant 0.2%-0.8%
Petropols 0.1%-40.0%, surplus are engineering plastics.
Further, age resistor is also included in described hot melt adhesive film, antiaging agent content is 0.01-2.5%, preferably Age resistor selects antioxidant 4020, also referred to as antioxidant D MBPPD, belongs to p-phenylenediamine rubber aging inhibitor.
Preferably, described antioxidant is antioxidant 2246, antioxidant 1010, and antioxidant 2246 is that one kind is used for plastics rubber Antioxidant in glue product, be one of kind more excellent in phenolic antioxidant, to hot oxygen, Weather, flexion aging and It is excellent to the protective action of variable valency metal, suitable for light color and colored rubber article.
Further, antiscorching is also included in described hot melt adhesive film, the content of antiscorching is 0.01-1.5%, preferably Ground, antiscorching are selected from the thio phthalamide of N- cyclohexyls.
Further, heat stabilizer is also included in described hot melt adhesive film, the content of heat stabilizer is 0.3-1.2%, excellent Selection of land, Petropols are selected from hydrogenated rosin Petropols.
Further, described heat stabilizer is selected from calcium stearate.
Further, thiuram is also included in described hot melt adhesive film, the content of thiuram is 0.8-1.2%.
As a kind of preferred scheme of new-type heat-melting glued membrane of the present invention, including following weight percent composition：
Further, described engineering plastics are acrylate rubber like body and acrylonitrile, the graft copolymer of styrene ASA, SBS SBS, styrene-isoprene-phenylethene block copolymer SIS, One or more in ternary ethylene-propylene copolymer EPDM, ethylene propylene copolymer, POE.
The present invention discloses a kind of preparation method of hot melt adhesive film, comprise the following steps：
(1) major ingredient and auxiliary material are put into blending apparatus, is warming up to 30-100 DEG C, mix 30min；
(2) double screw extruder is warming up to 120 and arrives 180 degree, by gained mixture extruding pelletization；
(3) casting machine is warming up to 120 and arrives 180 degree, the film forming after curtain coating is extruded.
The present invention discloses a kind of application that above-mentioned hot melt adhesive film is overlayed to sheet rubber sole formed for EVA.
Specifically, mould is heated to 180 DEG C, then put three layers of one step foaming EVA, hot melt adhesive film, raw stock mould material Enter in mould, heating 300-400s, the vulcanizing agent in raw stock permeates to glued membrane so that membrane material crosslinks, bis- hairs of EVA Bubble, can be used directly as sole material.
Beneficial effect
1st, cost is low, several times or even tens times of prices compared with conventional hot melt glued membrane；
2nd, firmness is strong, is had a clear superiority compared with traditional glue and other hot melt adhesive films；
3rd, mould proof, ventilative, environmentally friendly, nontoxic, odorlessness；
4th, time material is saved.
Embodiment
Embodiment
First, hot melt adhesive film：
Such as table 1, nine kinds of different hot melt adhesive films of embodiment 1-9 are listed, concrete composition composition refers to table 1,
Wherein supplementary material ratio (unit：Wt%).
Table 1
2nd, the preparation of hot melt adhesive film：
(1) major ingredient and auxiliary material are put into blending apparatus, is warming up to 30-100 DEG C, mix 30min；
(2) double screw extruder is warming up to 120 and arrives 180 degree, by gained mixture extruding pelletization；
(3) casting machine is warming up to 120 and arrives 180 degree, the film forming after curtain coating is extruded.
3rd, the application of hot melt adhesive film
Above-mentioned manufactured hot melt adhesive film is placed between one step foaming EVA layer and rubber lamella, forms three layers of covering knot Structure, mould is then heated to 180 DEG C, then above-mentioned three-decker is put into mould, heating 300-400s, the sulphur in raw stock Agent is permeated to glued membrane so that membrane material crosslinks, EVA second time of foaming, can be used directly as sole material.
4th, performance test
Sample preparation：Above-described embodiment 1-9 product and a glued membrane in the prior art are placed on one step foaming EVA layer and life Between film layers, three layers of covered structure are formed, mould is then heated to 180 DEG C, then above-mentioned three-decker is put into mould, Heat 300-400s.Then the sample that clip posts, wide 2.5 centimeters, long 10 centimeters of progress peel test.
Speed：300mm/min
Instrument：Single-column tensile testing machine
Table 2
By above-mentioned performance test, the Average peel force for the hot melt adhesive film that the application obtains is 5.2kgf, and prior art In be 3.2kgf, it is strong to substantially increase firmness.
Although embodiments of the present invention are illustrated in specification, these embodiments are intended only as prompting, It should not limit protection scope of the present invention.It is equal that various omission, substitution, and alteration are carried out without departing from the spirit and scope of the present invention It should include within the scope of the present invention.

Claims (10)

1. a kind of new-type heat-melting glued membrane, it is characterised in that including following mass percent component：
Antioxidant 0.2%-0.8%
Petropols 0.1%-40.0%, surplus are engineering plastics.
2. new-type heat-melting glued membrane according to claim 1, it is characterised in that：Also include age resistor, antiaging agent content is 0.01-2.5%.
3. new-type heat-melting glued membrane according to claim 1, it is characterised in that：Also include antiscorching, the content of antiscorching is 0.01-1.5%.
4. new-type heat-melting glued membrane according to claim 1, it is characterised in that：Also include heat stabilizer, heat stabilizer contains Measure as 0.3-1.2%.
5. new-type heat-melting glued membrane according to claim 1, it is characterised in that：Also include thiuram, the content of thiuram is 0.8-1.2%.
6. new-type heat-melting glued membrane according to claim 1, it is characterised in that：Including following weight percent composition：
7. new-type heat-melting glued membrane according to claim 1, it is characterised in that：Described engineering plastics are esters of acrylic acid rubber Colloid and acrylonitrile, the graft copolymer ASA of styrene, SBS SBS, styrene- The block copolymer SIS of isoprene styrene, ternary ethylene-propylene copolymer EPDM, ethylene propylene copolymer, ethylene octene copolymerization One or more in thing.
A kind of 8. method for being used to prepare the hot melt adhesive film described in claim 1-7 any one, it is characterised in that including following Step：
(1) major ingredient and auxiliary material are put into blending apparatus, is warming up to 30-100 DEG C, mix 30min；
(2) double screw extruder is warming up to 120 and arrives 180 degree, by gained mixture extruding pelletization；
(3) casting machine is warming up to 120 and arrives 180 degree, the film forming after curtain coating is extruded.
9. a kind of hot melt adhesive film by described in claim 1-7 any one is used for the application that EVA overlays sheet rubber sole formed.
10. application according to claim 9, it is characterised in that：Mould is heated to 180 DEG C, then by one step foaming Three layers of EVA, hot melt adhesive film, raw stock molding are put into mould, heat 300-400s.
CN201710605064.8A 2017-07-24 2017-07-24 A kind of new-type heat-melting glued membrane, preparation method and application Pending CN107418459A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710605064.8A CN107418459A (en) 2017-07-24 2017-07-24 A kind of new-type heat-melting glued membrane, preparation method and application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710605064.8A CN107418459A (en) 2017-07-24 2017-07-24 A kind of new-type heat-melting glued membrane, preparation method and application

Publications (1)

Publication Number Publication Date
CN107418459A true CN107418459A (en) 2017-12-01

Family

ID=60431012

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710605064.8A Pending CN107418459A (en) 2017-07-24 2017-07-24 A kind of new-type heat-melting glued membrane, preparation method and application

Country Status (1)

Country Link
CN (1) CN107418459A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108467685A (en) * 2018-03-29 2018-08-31 重庆渝茁科技有限公司 Vehicle polyester resin cellular board material
CN110733194A (en) * 2019-10-24 2020-01-31 东莞市五世昌新材料有限公司 kinds of net films used for adhering rubber outsole and EVA midsole in compression molding mode
CN110856563A (en) * 2018-02-13 2020-03-03 陈志勇 Hot melt adhesive film composition and method for manufacturing shoe sole
CN115011282A (en) * 2022-05-20 2022-09-06 杭州福斯特应用材料股份有限公司 Preparation method of packaging adhesive film

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1441833A (en) * 2000-06-24 2003-09-10 诚一化学株式会社 Polyolefin-based hot melt adhesive for deflection yoke
CN101245228A (en) * 2008-02-29 2008-08-20 广州市合诚化学有限公司 Hot melt adhesive special for random copolymerization polypropylene multiunit tube and manufacture method thereof
CN103540281A (en) * 2013-10-21 2014-01-29 广东东方树脂有限公司 Quickly-cured rubber-type hot melt adhesive
CN105647461A (en) * 2016-03-30 2016-06-08 广东工业大学 Hot melt adhesive and application thereof to wood-plastic composites

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1441833A (en) * 2000-06-24 2003-09-10 诚一化学株式会社 Polyolefin-based hot melt adhesive for deflection yoke
CN101245228A (en) * 2008-02-29 2008-08-20 广州市合诚化学有限公司 Hot melt adhesive special for random copolymerization polypropylene multiunit tube and manufacture method thereof
CN103540281A (en) * 2013-10-21 2014-01-29 广东东方树脂有限公司 Quickly-cured rubber-type hot melt adhesive
CN105647461A (en) * 2016-03-30 2016-06-08 广东工业大学 Hot melt adhesive and application thereof to wood-plastic composites

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
刘建华: "《材料成型工艺基础》", 29 February 2016, 西安电子科技大学出版社 *
廖晖 等: "《环保型胶粘剂配方及生产工艺》", 31 March 2007, 中南大学出版社 *
李子东 等: "《现代胶粘技术手册》", 31 January 2002, 新时代出版社 *
李明智: "《胶接新技术》", 31 March 1978, 上海科学技术出版社 *
杨卫民 等: "《塑料连接手册 原书第2版》", 31 January 2013, 机械工业出版社 *
熊腊森: "《粘接手册》", 31 August 2008, 机械工业出版社 *
黄世强 等: "《胶粘剂及其工程应用》", 31 July 2006, 机械工业出版社 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110856563A (en) * 2018-02-13 2020-03-03 陈志勇 Hot melt adhesive film composition and method for manufacturing shoe sole
US11779079B2 (en) 2018-02-13 2023-10-10 National Cheng Kung University Composition of hot-melt adhesive film and method for producing shoe sole
CN108467685A (en) * 2018-03-29 2018-08-31 重庆渝茁科技有限公司 Vehicle polyester resin cellular board material
CN110733194A (en) * 2019-10-24 2020-01-31 东莞市五世昌新材料有限公司 kinds of net films used for adhering rubber outsole and EVA midsole in compression molding mode
CN115011282A (en) * 2022-05-20 2022-09-06 杭州福斯特应用材料股份有限公司 Preparation method of packaging adhesive film

Similar Documents

Publication Publication Date Title
CN107418459A (en) A kind of new-type heat-melting glued membrane, preparation method and application
CN104559843A (en) Hot melt adhesive film for adhering rubber/foamed EVA (ethylene-vinyl acetate copolymer) composite sole and preparation method thereof
CN103756576B (en) Hot melt adhesive film for adhering sole, and preparation method thereof
NO303581B1 (en) A composition which is coextrudable with polyvinylidene fluoride, a coextrudation product containing the mixture, and a composite material obtained with the mixture
CN102433087A (en) High-temperature-resistant paper-plastic laminating adhesive and preparation method thereof
KR101104252B1 (en) Composition of foam midsole compound can adhere with Non-UV and preparing method of foam midsole using it
CN108949046B (en) EVA hot melt adhesive film for wall cloth and preparation method thereof
CN110283399B (en) Bamboo-wood fiber wallboard and preparation method thereof
CN102922839B (en) High-performance EVA multifunctional composite shed plastic film
CN106752994A (en) Self-adhesive film/diaphragm thickening masterbatch
EP3350261B1 (en) Polyolefin hot melt adhesive with low reactivation temperature and high temperature resistance and its use for vacuum deep draw laminating
CN101942279A (en) Self-bonding layer strip material with environmental protection and wide temperature change
CN103832027B (en) It is a kind of by rubber, plastic foil, chemical fabric composite waterproof sheet product
CN104260379A (en) Method for preparing composite film compounded by non-woven fabric and breathable film
KR101552161B1 (en) Rubber sheet composition for bonding sole of shoes, and method for preparing sole of shoes
KR102458609B1 (en) Composite with direct bond between rubber and foam
CN104789142A (en) Special polyethylene protection membrane for glass
KR101265551B1 (en) Oriented Polypropylene Film and Composition for Adhesive Layer
CN106142787A (en) A kind of light guide plate is fitted protecting film and preparation technology thereof online
KR101315784B1 (en) Starch based hot melt adhesive
CN105419684A (en) Hot melt adhesive film for rubber and metal adhesion and preparation method of hot melt adhesive film
CN110027295B (en) Method for manufacturing shoe upper
CN103622644B (en) A kind of modified sticky mats and manufacture craft thereof
CN112795332A (en) Hot melt adhesive film for bonding PVC (polyvinyl chloride) waterproof coiled material and metal plate and preparation method thereof
CN111718669A (en) Environment-friendly roof heat-insulating waterproof coiled material and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20171201

RJ01 Rejection of invention patent application after publication