CN106245343A - A kind of ultrahigh molecular weight polyethylene weftless fabrics of graphene-containing and preparation method thereof - Google Patents
A kind of ultrahigh molecular weight polyethylene weftless fabrics of graphene-containing and preparation method thereof Download PDFInfo
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0038—Polyolefin fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Polymers & Plastics (AREA)
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- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
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Abstract
The invention discloses the ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing, including the raw material of following weight portion: superhigh molecular weight polyethylene fibers 10～20 parts, LNBR 15～25 parts, Graphene 0.5～1 part, dimethylformamide 6～25 parts, adhesive 8～15 parts, Fanglun slurry cake 1～6 parts, nano cupric oxide 0.5～3 parts, fire retardant 1～3 parts, watery water-proofing agent 0.8～2.5 parts.The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing that the present invention proposes, there is quality good, lightweight, soft, comfortable feature, and there is good waterproof, fire-retardant, antibiotic property, grapheme material improve laminated cloth impact resistance and flexible while, significantly reduce its weight, the invention allows for the preparation method of the ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing, raw materials used simple and easy to get, preparation process is simple to operate, and preparation efficiency is high, and raw material utilizes fully, low cost, is worthy to be popularized.
Description
Technical field
The present invention relates to laminated cloth and preparing technical field thereof, particularly relate to the superhigh molecular weight polyethylene of a kind of graphene-containing
Alkene laminated cloth and preparation method thereof.
Background technology
High-performance fiber laminated cloth, is to use that superelevation is strong, high-modulus polyethylene fiber is base material, equal through advanced high technology equipment
Even piddler, with high-strength elastic body resin dipping gluing and thin film bonding, then forms through biorthogonal is laminated.This product extensively should
For soft bullet-resistant garment, lightweight bulletproof helmet, lightweight bulletproof tank board, anti-stab, preventing cutting clothing liner and special public anti-
Sudden and violent facility, along with socioeconomic development, the raising of people's security protection consciousness, security protection equipment Requirement is increasing, adds
The attack of terrorism in recent years happen occasionally with incident of violence, there is a growing awareness that the importance that inherently safe protects, country
Also increasing the supporting dynamics to safety protection field, laminated cloth kind is few the most on the market, and poor flexibility, hard heaviness,
Ease of use is poor, and combination property is in urgent need to be improved.Based on the problems referred to above, the present invention proposes the supra polymer of a kind of graphene-containing
Weight northylen laminated cloth and preparation method thereof.
Summary of the invention
The invention aims to solve shortcoming present in prior art, and the superelevation of a kind of graphene-containing proposed
Molecular weight polyethylene laminated cloth and preparation method thereof.
The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing, including the raw material of following weight portion: super high molecular weight
Polyethylene fibre 10～20 parts, LNBR 15～25 parts, Graphene 0.5～1 part, dimethylformamide 6～25 parts, glue
Stick 8～15 parts, Fanglun slurry cake 1～6 parts, nano cupric oxide 0.5～3 parts, fire retardant 1～3 parts, watery water-proofing agent 0.8～2.5
Part.
Preferably, the ultrahigh molecular weight polyethylene weftless fabrics of described a kind of graphene-containing, former including following weight portion
Material: superhigh molecular weight polyethylene fibers 12～18 parts, LNBR 18～22 parts, Graphene 0.6～0.8 part, dimethyl
Methanamide 7.2～20 parts, adhesive 10～13 parts, Fanglun slurry cake 2～4 parts, nano cupric oxide 1～2 parts, fire retardant 1.5～2.5
Part, watery water-proofing agent 1～2 parts.
Preferably, the ultrahigh molecular weight polyethylene weftless fabrics of described a kind of graphene-containing, former including following weight portion
Material: superhigh molecular weight polyethylene fibers 18 parts, LNBR 22 parts, Graphene 0.8 part, dimethylformamide 15 parts, glue
Stick 12 parts, Fanglun slurry cake 4 parts, nano cupric oxide 2 parts, fire retardant 2 parts, watery water-proofing agent 1.5 parts.
Preferably, the one during described Graphene is 1～5 layer graphenes.
Preferably, described Graphene, the weight ratio of dimethylformamide are 1:12～25.
Preferably, described adhesive is polyurethane adhesive.
The invention allows for the preparation method of the ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing, including following
Step:
S1, the superhigh molecular weight polyethylene fibers of described proportion is sent in laminated cloth production equipment, regulate apparatus and process
Parameter, it is ensured that every superhigh molecular weight polyethylene fibers is uniformly distributed through parallel, with superhigh molecular weight polyethylene fibers warp, latitude
Line is orthogonal consolidates to obtain internal layer fabric；
S2, the Graphene of described proportion and dimethylformamide are joined in hypervelocity blender, with 800～1000r/
The rotating speed of min, high-speed stirred 3～5min, make graphene uniform be dispersed in dimethylformamide；
S3, the LNBR by described proportion, adhesive, Fanglun slurry cake, nano cupric oxide, fire retardant, aqueous are prevented
Water preparation joins in the hypervelocity blender in step S2, at a temperature of 70～90 DEG C, with the rotating speed of 350～550r/min, stirs
Mix 20～40min, after mix homogeneously, obtain outer layer sizing material；
S4, the outer layer sizing material insulation of gained in step S3 is at the uniform velocity extruded, roll in step sl in gained with calender
The two sides of layer fabric, obtaining thickness is 0.5～5mm laminated cloth, and after being cooled to solidification with the cold air of 2～15 DEG C, essence is cut into institute
Need the laminated cloth of size and get final product.
The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing that the present invention proposes, has quality good, lightweight, soft
Soft, comfortable feature, and there is good waterproof, fire-retardant, antibiotic property, gather with the super high molecular weight that specific strength and specific modulus are the highest
Basic unit in laminated cloth is done in vinyl fiber spinning, spread, adds other auxiliary agents with LNBR and makes outer layer sizing material, outer layer sizing material
The grapheme material that middle addition is the thinnest, intensity is the highest, improve laminated cloth impact resistance and flexible while, significantly reduce
Its weight, the invention allows for the preparation method of the ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing, raw materials used
Simple and easy to get, preparation process is simple to operate, and preparation efficiency is high, and raw material utilizes fully, and low cost is worthy to be popularized.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is explained orally further.
Embodiment one
The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing that the present invention proposes, former including following weight portion
Material: superhigh molecular weight polyethylene fibers 15 parts, LNBR 20 parts, Graphene 0.8 part, dimethylformamide 15 parts, poly-
Urethane adhesive 9 parts, Fanglun slurry cake 3 parts, nano cupric oxide 1.2 parts, fire retardant 2 parts, watery water-proofing agent 1.5 parts.
Its preparation method, comprises the following steps:
S1, the superhigh molecular weight polyethylene fibers of described proportion is sent in laminated cloth production equipment, regulate apparatus and process
Parameter, it is ensured that every superhigh molecular weight polyethylene fibers is uniformly distributed through parallel, with superhigh molecular weight polyethylene fibers warp, latitude
Line is orthogonal consolidates to obtain internal layer fabric；
S2,3 layer graphenes of described proportion and dimethylformamide are joined in hypervelocity blender, with 900r/min's
Rotating speed, high-speed stirred 4min, make graphene uniform be dispersed in dimethylformamide；
S3, LNBR by described proportion, polyurethane adhesive, Fanglun slurry cake, nano cupric oxide, fire retardant,
Watery water-proofing agent joins in the hypervelocity blender in step S2, at a temperature of 80 DEG C, with the rotating speed of 400r/min, stirring
30min, obtains outer layer sizing material after mix homogeneously；
S4, the outer layer sizing material insulation of gained in step S3 is at the uniform velocity extruded, roll in step sl in gained with calender
The two sides of layer fabric, obtaining thickness is 4mm laminated cloth, and after being cooled to solidification with the cold air of 8 DEG C, essence is cut into the nothing of required size
Latitude cloth and get final product.
Embodiment two
The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing that the present invention proposes, former including following weight portion
Material: superhigh molecular weight polyethylene fibers 12 parts, LNBR 22 parts, Graphene 0.6 part, dimethylformamide 12 parts, poly-
Urethane adhesive 12 parts, Fanglun slurry cake 1 part, nano cupric oxide 0.8 part, fire retardant 1.5 parts, watery water-proofing agent 1 part.
Its preparation method, comprises the following steps:
S1, the superhigh molecular weight polyethylene fibers of described proportion is sent in laminated cloth production equipment, regulate apparatus and process
Parameter, it is ensured that every superhigh molecular weight polyethylene fibers is uniformly distributed through parallel, with superhigh molecular weight polyethylene fibers warp, latitude
Line is orthogonal consolidates to obtain internal layer fabric；
S2,1 layer graphene of described proportion and dimethylformamide are joined in hypervelocity blender, with 850r/min's
Rotating speed, high-speed stirred 4.5min, make graphene uniform be dispersed in dimethylformamide；
S3, LNBR by described proportion, polyurethane adhesive, Fanglun slurry cake, nano cupric oxide, fire retardant,
Watery water-proofing agent joins in the hypervelocity blender in step S2, at a temperature of 75 DEG C, with the rotating speed of 380r/min, stirring
35min, obtains outer layer sizing material after mix homogeneously；
S4, the outer layer sizing material insulation of gained in step S3 is at the uniform velocity extruded, roll in step sl in gained with calender
The two sides of layer fabric, obtaining thickness is 2mm laminated cloth, and after being cooled to solidification with the cold air of 6 DEG C, essence is cut into the nothing of required size
Latitude cloth and get final product.
Embodiment three
The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing that the present invention proposes, former including following weight portion
Material: superhigh molecular weight polyethylene fibers 10 parts, LNBR 20 parts, Graphene 1 part, dimethylformamide 20 parts, poly-ammonia
Ester gum stick 10 parts, Fanglun slurry cake 4 parts, nano cupric oxide 2.5 parts, fire retardant 3 parts, watery water-proofing agent 0.8 part.
Its preparation method, comprises the following steps:
S1, the superhigh molecular weight polyethylene fibers of described proportion is sent in laminated cloth production equipment, regulate apparatus and process
Parameter, it is ensured that every superhigh molecular weight polyethylene fibers is uniformly distributed through parallel, with superhigh molecular weight polyethylene fibers warp, latitude
Line is orthogonal consolidates to obtain internal layer fabric；
S2,4 layer graphenes of described proportion and dimethylformamide are joined in hypervelocity blender, with 1000r/min
Rotating speed, high-speed stirred 3min, make graphene uniform be dispersed in dimethylformamide；
S3, LNBR by described proportion, polyurethane adhesive, Fanglun slurry cake, nano cupric oxide, fire retardant,
Watery water-proofing agent joins in the hypervelocity blender in step S2, at a temperature of 90 DEG C, with the rotating speed of 350r/min, stirring
40min, obtains outer layer sizing material after mix homogeneously；
S4, the outer layer sizing material insulation of gained in step S3 is at the uniform velocity extruded, roll in step sl in gained with calender
The two sides of layer fabric, obtaining thickness is 1mm laminated cloth, and after being cooled to solidification with the cold air of 10 DEG C, essence is cut into required size
Laminated cloth and get final product.
Embodiment four
The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing that the present invention proposes, former including following weight portion
Material: superhigh molecular weight polyethylene fibers 20 parts, LNBR 15 parts, Graphene 0.5 part, dimethylformamide 12 parts, poly-
Urethane adhesive 15 parts, Fanglun slurry cake 6 parts, nano cupric oxide 2 parts, fire retardant 1 part, watery water-proofing agent 2 parts.
Its preparation method, comprises the following steps:
S1, the superhigh molecular weight polyethylene fibers of described proportion is sent in laminated cloth production equipment, regulate apparatus and process
Parameter, it is ensured that every superhigh molecular weight polyethylene fibers is uniformly distributed through parallel, with superhigh molecular weight polyethylene fibers warp, latitude
Line is orthogonal consolidates to obtain internal layer fabric；
S2,2 layer graphenes of described proportion and dimethylformamide are joined in hypervelocity blender, with 800r/min's
Rotating speed, high-speed stirred 5min, make graphene uniform be dispersed in dimethylformamide；
S3, LNBR by described proportion, polyurethane adhesive, Fanglun slurry cake, nano cupric oxide, fire retardant,
Watery water-proofing agent joins in the hypervelocity blender in step S2, at a temperature of 70 DEG C, with the rotating speed of 550r/min, stirring
20min, obtains outer layer sizing material after mix homogeneously；
S4, the outer layer sizing material insulation of gained in step S3 is at the uniform velocity extruded, roll in step sl in gained with calender
The two sides of layer fabric, obtaining thickness is 3mm laminated cloth, and after being cooled to solidification with the cold air of 12 DEG C, essence is cut into required size
Laminated cloth and get final product.
Embodiment five
The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing that the present invention proposes, former including following weight portion
Material: superhigh molecular weight polyethylene fibers 18 parts, LNBR 18 parts, Graphene 0.9 part, dimethylformamide 22.5 parts,
Polyurethane adhesive 8 parts, Fanglun slurry cake 2 parts, nano cupric oxide 3 parts, fire retardant 2.5 parts, watery water-proofing agent 2.5 parts.
Its preparation method, comprises the following steps:
S1, the superhigh molecular weight polyethylene fibers of described proportion is sent in laminated cloth production equipment, regulate apparatus and process
Parameter, it is ensured that every superhigh molecular weight polyethylene fibers is uniformly distributed through parallel, with superhigh molecular weight polyethylene fibers warp, latitude
Line is orthogonal consolidates to obtain internal layer fabric；
S2,5 layer graphenes of described proportion and dimethylformamide are joined in hypervelocity blender, with 950r/min's
Rotating speed, high-speed stirred 3.5min, make graphene uniform be dispersed in dimethylformamide；
S3, LNBR by described proportion, polyurethane adhesive, Fanglun slurry cake, nano cupric oxide, fire retardant,
Watery water-proofing agent joins in the hypervelocity blender in step S2, at a temperature of 85 DEG C, with the rotating speed of 500r/min, stirring
25min, obtains outer layer sizing material after mix homogeneously；
S4, the outer layer sizing material insulation of gained in step S3 is at the uniform velocity extruded, roll in step sl in gained with calender
The two sides of layer fabric, obtaining thickness is 5mm laminated cloth, and after being cooled to solidification with the cold air of 2 DEG C, essence is cut into the nothing of required size
Latitude cloth and get final product.
With reference to water resistance testing standard: AATCC 22-2001, five groups of embodiments that the present invention is proposed are prepared
The water resistance of the ultrahigh molecular weight polyethylene weftless fabrics of graphene-containing is tested, and the superelevation at every piece of graphene-containing is divided respectively
The different parts of sub-weight northylen laminated cloth takes 3 pieces of samples (being respectively labeled as sample 1,2,3), tests with fountain water repellency
Instrument, in the case of water temperature is 20 DEG C, sprays sample, then evaluates the rank of sample wetness degree, draws following knot
Really: (moistening rank comprises 1～5 grade, and 5 grades represent that water proofing property is best, and 1 grade then represents that water proofing property is worst)
| Embodiment | One | Two | Three | Four | Five |
| Sample 1 | 5 grades | 5 grades | 5 grades | 5 grades | 5 grades |
| Sample 2 | 5 grades | 5 grades | 5 grades | 5 grades | 5 grades |
| Sample 3 | 5 grades | 5 grades | 5 grades | 5 grades | 5 grades |
The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing that the present invention proposes, has quality good, lightweight, soft
Soft, comfortable feature, and there is good waterproof, fire-retardant, antibiotic property, gather with the super high molecular weight that specific strength and specific modulus are the highest
Basic unit in laminated cloth is done in vinyl fiber spinning, spread, adds other auxiliary agents with LNBR and makes outer layer sizing material, outer layer sizing material
The grapheme material that middle addition is the thinnest, intensity is the highest, improve laminated cloth impact resistance and flexible while, significantly reduce
Its weight, the invention allows for the preparation method of the ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing, raw materials used
Simple and easy to get, preparation process is simple to operate, and preparation efficiency is high, and raw material utilizes fully, and low cost is worthy to be popularized.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (7)
1. the ultrahigh molecular weight polyethylene weftless fabrics of a graphene-containing, it is characterised in that include the raw material of following weight portion: super
High molecular weight polyethylene fiber 10～20 parts, LNBR 15～25 parts, Graphene 0.5～1 part, dimethylformamide 6
～25 parts, adhesive 8～15 parts, Fanglun slurry cake 1～6 parts, nano cupric oxide 0.5～3 parts, fire retardant 1～3 parts, Waterproof
Agent 0.8～2.5 parts.
The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing the most according to claim 1, it is characterised in that include
The raw material of following weight portion: superhigh molecular weight polyethylene fibers 12～18 parts, LNBR 18～22 parts, Graphene 0.6
～0.8 part, dimethylformamide 7.2～20 parts, adhesive 10～13 parts, Fanglun slurry cake 2～4 parts, nano cupric oxide 1～2 parts,
Fire retardant 1.5～2.5 parts, watery water-proofing agent 1～2 parts.
The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing the most according to claim 1, it is characterised in that include
The raw material of following weight portion: superhigh molecular weight polyethylene fibers 18 parts, LNBR 22 parts, Graphene 0.8 part, dimethyl
Methanamide 15 parts, adhesive 12 parts, Fanglun slurry cake 4 parts, nano cupric oxide 2 parts, fire retardant 2 parts, watery water-proofing agent 1.5 parts.
The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing the most according to claim 1, it is characterised in that described
Graphene is the one in 1～5 layer graphenes.
The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing the most according to claim 1, it is characterised in that described
Graphene, the weight ratio of dimethylformamide are 1:12～25.
The ultrahigh molecular weight polyethylene weftless fabrics of a kind of graphene-containing the most according to claim 1, it is characterised in that described
Adhesive is polyurethane adhesive.
7. the preparation method of the ultrahigh molecular weight polyethylene weftless fabrics of a graphene-containing, it is characterised in that comprise the following steps:
S1, the superhigh molecular weight polyethylene fibers of described proportion is sent in laminated cloth production equipment, regulates technical parameter,
Ensure that every superhigh molecular weight polyethylene fibers is uniformly distributed through parallel, with superhigh molecular weight polyethylene fibers warp, parallel just
Friendship consolidates to obtain internal layer fabric；
S2, the Graphene of described proportion and dimethylformamide are joined in hypervelocity blender, with 800～1000r/min
Rotating speed, high-speed stirred 3～5min, make graphene uniform be dispersed in dimethylformamide；
S3, the LNBR by described proportion, adhesive, Fanglun slurry cake, nano cupric oxide, fire retardant, watery water-proofing agent
Join in the hypervelocity blender in step S2, at a temperature of 70～90 DEG C, with the rotating speed of 350～550r/min, stir 20
～40min, obtain outer layer sizing material after mix homogeneously；
S4, by step S3 gained outer layer sizing material insulation at the uniform velocity extrude, roll gained internal layer in step sl with calender and knit
The two sides of thing, obtaining thickness is 0.5～5mm laminated cloth, and after being cooled to solidification with the cold air of 2～15 DEG C, essence is cut into required chi
Very little laminated cloth and get final product.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107675321A (en) * | 2017-09-21 | 2018-02-09 | 成都新柯力化工科技有限公司 | A kind of charging pile cable special intelligent deformation textile cloth and preparation method thereof |
| CN108611870A (en) * | 2018-04-18 | 2018-10-02 | 江苏工程职业技术学院 | A kind of production method of graphene adhesive lining |
| CN108797142A (en) * | 2018-07-29 | 2018-11-13 | 段小宁 | Moisture absorption, antibacterial and water vapor permeability graphene modified polyurethane synthetic leather preparation method |
| CN109944081A (en) * | 2019-03-31 | 2019-06-28 | 任国峰 | A kind of anti-cutting fabric of graphene and preparation method thereof |
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| CN107675321A (en) * | 2017-09-21 | 2018-02-09 | 成都新柯力化工科技有限公司 | A kind of charging pile cable special intelligent deformation textile cloth and preparation method thereof |
| CN107675321B (en) * | 2017-09-21 | 2019-08-23 | 上海盈兹无纺布有限公司 | A kind of charging pile cable special intelligent deformation textile cloth and preparation method thereof |
| CN108611870A (en) * | 2018-04-18 | 2018-10-02 | 江苏工程职业技术学院 | A kind of production method of graphene adhesive lining |
| CN108797142A (en) * | 2018-07-29 | 2018-11-13 | 段小宁 | Moisture absorption, antibacterial and water vapor permeability graphene modified polyurethane synthetic leather preparation method |
| CN108797142B (en) * | 2018-07-29 | 2021-09-21 | 浙江英飞实业有限公司 | Preparation method of moisture-absorbing, antibacterial and water vapor permeable graphene modified polyurethane synthetic leather |
| CN109944081A (en) * | 2019-03-31 | 2019-06-28 | 任国峰 | A kind of anti-cutting fabric of graphene and preparation method thereof |
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Application publication date: 20161221 |