CN106223051A - A kind of multi-angle bulletproof anti-puncturing laminated cloth and preparation method thereof - Google Patents
A kind of multi-angle bulletproof anti-puncturing laminated cloth and preparation method thereof Download PDFInfo
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- CN106223051A CN106223051A CN201610798791.6A CN201610798791A CN106223051A CN 106223051 A CN106223051 A CN 106223051A CN 201610798791 A CN201610798791 A CN 201610798791A CN 106223051 A CN106223051 A CN 106223051A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/009—Condensation or reaction polymers
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/02—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
- D04H3/04—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments in rectilinear paths, e.g. crossing at right angles
- D04H3/045—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments in rectilinear paths, e.g. crossing at right angles for net manufacturing
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0034—Polyamide fibres
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
- D06N3/103—Thermosetting synthetic rubbers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2201/00—Chemical constitution of the fibres, threads or yarns
- D06N2201/02—Synthetic macromolecular fibres
- D06N2201/0263—Polyamide fibres
- D06N2201/0272—Aromatic polyamide fibres
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- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
- D06N2209/067—Flame resistant, fire resistant
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- D06N2209/00—Properties of the materials
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- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
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- D06N2209/00—Properties of the materials
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- D06N2209/00—Properties of the materials
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Abstract
The invention discloses a kind of multi-angle bulletproof anti-puncturing laminated cloth, including the raw material of following weight portion: nitrile rubber 15～30 parts, polyethylene fibre 10～15 parts, sulfur 3～6 parts, phthalic anhydride 0.5～1 part, Fanglun slurry cake 0.8～1.5 parts, adhesive for polyurethane 8～15 parts, brominated epoxy resin 2～8 parts, watery water-proofing agent 2～6 parts, antibacterial matrices 1～3 parts, aramid fiber 10～20 parts.A kind of multi-angle bulletproof anti-puncturing laminated cloth that the present invention proposes, has the most fire-retardant, waterproof, antibacterial effect, and intensity is high, hardness is high, lightweight, wearability is good, bulletproof anti-puncturing is effective, the invention allows for the preparation method of a kind of multi-angle bulletproof anti-puncturing laminated cloth, by aramid fiber is carried out multi-angle three-dimensional orthogonal woven, the safety system substantially increasing laminated cloth can, raw materials used simple and easy to get, production operation is simple, and production process is pollution-free, low cost, is worthy to be popularized.
Description
Technical field
The present invention relates to laminated cloth and preparing technical field thereof, particularly relate to a kind of multi-angle bulletproof anti-puncturing laminated cloth and
Preparation method.
Background technology
Along with socioeconomic development, the raising of people's security protection consciousness, security protection equipment Requirement is increasing, adds
The attack of terrorism in recent years happen occasionally with incident of violence, there is a growing awareness that the importance that inherently safe protects, country
Also increasing the supporting dynamics to safety protection field, country also clearly indicates in the middle of " 12 " planning and leads public safety
Support dynamics is strengthened in territory, particularly in " fabrics for industrial use 12 planning " the 4th give priority to field and it should be particularly mentioned out
Send out flexible puncture-proof Anti-cutting fabric, so the development of security protection material meets the direction of National Textile industry development.City at present
On face, laminated cloth kind is few, mainly has high-performance fiber laminated cloth, and it uses, and superelevation is strong, high-modulus polyethylene fiber is base material,
Through the advanced uniform piddler of high technology equipment, bond with high-strength elastic body resin dipping gluing and thin film, then through biorthogonal composite bed
Pressure forms.This product flexibility is good, but wears no resistance, and waterproof effect is general, does not possess antibiotic property, and its hardness, intensity also have
Wait to improve.Based on the problems referred to above, the present invention puts forward a kind of multi-angle bulletproof anti-puncturing laminated cloth and preparation method thereof.
Summary of the invention
The invention aims to solve shortcoming present in prior art, and a kind of multi-angle bulletproof anti-puncturing proposed
Laminated cloth and preparation method thereof.
A kind of multi-angle bulletproof anti-puncturing laminated cloth, including the raw material of following weight portion: nitrile rubber 15～30 parts, polyethylene
Fiber 10～15 parts, sulfur 3～6 parts, phthalic anhydride 0.5～1 part, Fanglun slurry cake 0.8～1.5 parts, adhesive for polyurethane 8
～15 parts, brominated epoxy resin 2～8 parts, watery water-proofing agent 2～6 parts, antibacterial matrices 1～3 parts, aramid fiber 10～20 parts.
Preferably, described a kind of multi-angle bulletproof anti-puncturing laminated cloth, including the raw material of following weight portion: nitrile rubber 18
～28 parts, polyethylene fibre 12～14 parts, sulfur 4～5 parts, phthalic anhydride 0.6～0.8 part, Fanglun slurry cake 1～1.2 parts,
Adhesive for polyurethane 10～12 parts, brominated epoxy resin 3～6 parts, watery water-proofing agent 3～5 parts, antibacterial matrices 1.5～2.5 parts,
Aramid fiber 12～18 parts.
Preferably, described a kind of multi-angle bulletproof anti-puncturing laminated cloth, including the raw material of following weight portion: nitrile rubber 20
Part, polyethylene fibre 13 parts, 5 parts of sulfur, phthalic anhydride 0.7 part, Fanglun slurry cake 1 part, adhesive for polyurethane 10 parts, bromination
Epoxy resin 5 parts, watery water-proofing agent 4 parts, antibacterial matrices 2 parts, aramid fiber 15 parts.
Preferably, described nitrile rubber, the weight ratio of polyethylene fibre are 1.5～2: 1.
Preferably, the one during described antibacterial matrices is nano zine oxide, nano cupric oxide and nano titanium oxide.
Preferably, described aramid fiber be line footpath be the meta aramid fiber long filament of 10～50 μm.
The invention allows for the preparation method of a kind of multi-angle bulletproof anti-puncturing laminated cloth, comprise the following steps:
S1, the aramid fiber of described proportion is drawn from 1～3 fiber axis, control tension force by tensioner and send into nothing
In latitude cloth production equipment, regulate technical parameter, it is ensured that every aramid fiber is uniformly distributed through parallel, with aramid fiber warp
Line, parallel angle are the mode of 45 °/135 °, are consolidated into the three-dimensional orthogonal woven fabric of entirety, obtain kevlar fabric A；
S2, nitrile rubber, sulfur, phthalic anhydride by described proportion, join in rubber vulcanizing tank, with 150～
High temperature vulcanized the 3 of 180 DEG C～5h, be then cooled to 100～120 DEG C, add the polyethylene fibre of described proportion, Fanglun slurry cake,
Adhesive for polyurethane, brominated epoxy resin, watery water-proofing agent and antibacterial matrices, with the rotating speed of 250～400r/min, stirring 20～
40min, uniform blend glue stuff B to be mixed；
S3, by the blend glue stuff B of gained in step S2 with 5～10kg/min speed extrude, be 70～90 DEG C in temperature
Under conditions of, the two sides of the kevlar fabric A of gained in step sl is rolled with calender, obtaining thickness is 0.5～7mm laminated cloth；
S4, after in step S3, the laminated cloth of gained naturally cools to room temperature, its essence is cut into the laminated cloth of required size
Obtain.
Preferably, the aramid fiber warp in described step S1, the angle of parallel could alternatively be 30 °/160 °, 60 °/
130 °, 90 °/90 °.
A kind of multi-angle bulletproof anti-puncturing laminated cloth that the present invention proposes, has the most fire-retardant, waterproof a, antibacterial effect, and by force
Degree is high, hardness is high, lightweight, and wearability is good, and bulletproof anti-puncturing is effective, the invention allows for a kind of multi-angle bulletproof anti-puncturing without
The preparation method of latitude cloth, uses multi-angle three-dimensional orthogonal woven method that aramid fiber consolidates molding and does the interior basic unit of laminated cloth, with
Vulcanie adds flame retardant resin and other auxiliary agents are mixed and made into the outer layered material of laminated cloth, is pressed into by ectonexine by calender
Type and obtain, substantially increase laminated cloth safety system can, raw materials used simple and easy to get, production operation is simple, and production process is without dirt
Dye, low cost, it is worthy to be popularized.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is explained orally further.
Embodiment one
A kind of multi-angle bulletproof anti-puncturing laminated cloth that the present invention proposes, including the raw material of following weight portion: nitrile rubber 20
Part, polyethylene fibre 12 parts, 4 parts of sulfur, phthalic anhydride 0.6 part, Fanglun slurry cake 0.8 part, adhesive for polyurethane 10 parts, bromine
Change epoxy resin 4 parts, watery water-proofing agent 4 parts, nano zine oxide 2.5 parts, meta aramid fiber long filament 12 parts.
Its preparation method, comprises the following steps:
S1, the meta aramid fiber long filament that line footpath is 40 μm of described proportion is drawn from 1 fiber axis, pass through tension force
Device controls tension force and sends in laminated cloth production equipment, regulates technical parameter, it is ensured that every meta aramid fiber long filament
It is uniformly distributed through parallel, in the way of aramid fiber warp, parallel angle are 45 °/135 °, is consolidated into the three-dimensional orthogonal machine of entirety
Fabric, obtains kevlar fabric A；
S2, nitrile rubber, sulfur, phthalic anhydride by described proportion, join in rubber vulcanizing tank, with 160 DEG C
High temperature vulcanized 4h, be then cooled to 105 DEG C, add the polyethylene fibre of described proportion, Fanglun slurry cake, adhesive for polyurethane,
Brominated epoxy resin, watery water-proofing agent and nano zine oxide, with the rotating speed of 300r/min, stir 30min, to be mixed uniform must mix
Rubber alloy material B；
S3, the blend glue stuff B of gained in step S2 is extruded with the speed of 6kg/min, under conditions of temperature is 80 DEG C,
Roll the two sides of the kevlar fabric A of gained in step sl with calender, obtaining thickness is 1.2mm laminated cloth；
S4, after in step S3, the laminated cloth of gained naturally cools to room temperature, its essence is cut into the laminated cloth of required size
Obtain.
Embodiment two
A kind of multi-angle bulletproof anti-puncturing laminated cloth that the present invention proposes, including the raw material of following weight portion: nitrile rubber 25
Part, polyethylene fibre 15 parts, 3 parts of sulfur, phthalic anhydride 0.8 part, Fanglun slurry cake 1.2 parts, adhesive for polyurethane 8 parts, bromine
Change epoxy resin 5 parts, watery water-proofing agent 2 parts, nano cupric oxide 1 part, meta aramid fiber long filament 18 parts.
Its preparation method, comprises the following steps:
S1, the meta aramid fiber long filament that line footpath is 30 μm of described proportion is drawn from 3 fiber axis, pass through tension force
Device controls tension force and sends in laminated cloth production equipment, regulates technical parameter, it is ensured that every meta aramid fiber long filament
It is uniformly distributed through parallel, in the way of aramid fiber warp, parallel angle are 30 °/160 °, is consolidated into the three-dimensional orthogonal machine of entirety
Fabric, obtains kevlar fabric A；
S2, nitrile rubber, sulfur, phthalic anhydride by described proportion, join in rubber vulcanizing tank, with 155 DEG C
High temperature vulcanized 3.5h, be then cooled to 120 DEG C, add the polyethylene fibre of described proportion, Fanglun slurry cake, polyurethane gluing
Agent, brominated epoxy resin, watery water-proofing agent and nano cupric oxide, with the rotating speed of 250r/min, stir 40min, to be mixed uniformly
Obtain blend glue stuff B；
S3, the blend glue stuff B of gained in step S2 is extruded with the speed of 8kg/min, under conditions of temperature is 75 DEG C,
Roll the two sides of the kevlar fabric A of gained in step sl with calender, obtaining thickness is 3.8mm laminated cloth；
S4, after in step S3, the laminated cloth of gained naturally cools to room temperature, its essence is cut into the laminated cloth of required size
Obtain.
Embodiment three
A kind of multi-angle bulletproof anti-puncturing laminated cloth that the present invention proposes, including the raw material of following weight portion: nitrile rubber 20
Part, polyethylene fibre 11 parts, 5 parts of sulfur, phthalic anhydride 0.5 part, Fanglun slurry cake 1 part, adhesive for polyurethane 12 parts, bromination
Epoxy resin 2 parts, watery water-proofing agent 5 parts, nano titanium oxide 3 parts, meta aramid fiber long filament 10 parts.
Its preparation method, comprises the following steps:
S1, the meta aramid fiber long filament that line footpath is 50 μm of described proportion is drawn from 2 fiber axis, pass through tension force
Device controls tension force and sends in laminated cloth production equipment, regulates technical parameter, it is ensured that every meta aramid fiber long filament
It is uniformly distributed through parallel, in the way of aramid fiber warp, parallel angle are 60 °/130 °, is consolidated into the three-dimensional orthogonal machine of entirety
Fabric, obtains kevlar fabric A；
S2, nitrile rubber, sulfur, phthalic anhydride by described proportion, join in rubber vulcanizing tank, with 175 DEG C
High temperature vulcanized 3h, be then cooled to 110 DEG C, add the polyethylene fibre of described proportion, Fanglun slurry cake, adhesive for polyurethane,
Brominated epoxy resin, watery water-proofing agent and nano titanium oxide, with the rotating speed of 400r/min, stir 25min, to be mixed uniform
Blend glue stuff B；
S3, the blend glue stuff B of gained in step S2 is extruded with the speed of 5kg/min, under conditions of temperature is 90 DEG C,
Roll the two sides of the kevlar fabric A of gained in step sl with calender, obtaining thickness is 5mm laminated cloth；
S4, after in step S3, the laminated cloth of gained naturally cools to room temperature, its essence is cut into the laminated cloth of required size
Obtain.
Embodiment four
A kind of multi-angle bulletproof anti-puncturing laminated cloth that the present invention proposes, including the raw material of following weight portion: nitrile rubber 28
Part, polyethylene fibre 14 parts, 6 parts of sulfur, phthalic anhydride 1 part, Fanglun slurry cake 1.5 parts, adhesive for polyurethane 11 parts, bromination
Epoxy resin 8 parts, watery water-proofing agent 3 parts, nano zine oxide 1.5 parts, meta aramid fiber long filament 20 parts.
Its preparation method, comprises the following steps:
S1, the meta aramid fiber long filament that line footpath is 10 μm of described proportion is drawn from 3 fiber axis, pass through tension force
Device controls tension force and sends in laminated cloth production equipment, regulates technical parameter, it is ensured that every meta aramid fiber long filament
It is uniformly distributed through parallel, in the way of aramid fiber warp, parallel angle are 90 °/90 °, is consolidated into the three-dimensional orthogonal machine of entirety
Fabric, obtains kevlar fabric A；
S2, nitrile rubber, sulfur, phthalic anhydride by described proportion, join in rubber vulcanizing tank, with 180 DEG C
High temperature vulcanized 4.5h, be then cooled to 115 DEG C, add the polyethylene fibre of described proportion, Fanglun slurry cake, polyurethane gluing
Agent, brominated epoxy resin, watery water-proofing agent and nano zine oxide, with the rotating speed of 350r/min, stir 20min, to be mixed uniformly
Obtain blend glue stuff B；
S3, the blend glue stuff B of gained in step S2 is extruded with the speed of 10kg/min, in the condition that temperature is 85 DEG C
Under, the two sides of the kevlar fabric A of gained in step sl is rolled with calender, obtaining thickness is 2.5mm laminated cloth；
S4, after in step S3, the laminated cloth of gained naturally cools to room temperature, its essence is cut into the laminated cloth of required size
Obtain.
Embodiment five
A kind of multi-angle bulletproof anti-puncturing laminated cloth that the present invention proposes, including the raw material of following weight portion: nitrile rubber 15
Part, polyethylene fibre 10 parts, 3.5 parts of sulfur, phthalic anhydride 0.9 part, Fanglun slurry cake 1.1 parts, adhesive for polyurethane 15 parts,
Brominated epoxy resin 6 parts, watery water-proofing agent 6 parts, nano titanium oxide 2 parts, meta aramid fiber long filament 15 parts.
Its preparation method, comprises the following steps:
S1, the meta aramid fiber long filament that line footpath is 20 μm of described proportion is drawn from 1 fiber axis, pass through tension force
Device controls tension force and sends in laminated cloth production equipment, regulates technical parameter, it is ensured that every meta aramid fiber long filament
It is uniformly distributed through parallel, in the way of aramid fiber warp, parallel angle are 45 °/135 °, is consolidated into the three-dimensional orthogonal machine of entirety
Fabric, obtains kevlar fabric A；
S2, nitrile rubber, sulfur, phthalic anhydride by described proportion, join in rubber vulcanizing tank, with 170 DEG C
High temperature vulcanized 5h, be then cooled to 100 DEG C, add the polyethylene fibre of described proportion, Fanglun slurry cake, adhesive for polyurethane,
Brominated epoxy resin, watery water-proofing agent and nano titanium oxide, with the rotating speed of 320r/min, stir 35min, to be mixed uniform
Blend glue stuff B；
S3, the blend glue stuff B of gained in step S2 is extruded with the speed of 7kg/min, under conditions of temperature is 70 DEG C,
Roll the two sides of the kevlar fabric A of gained in step sl with calender, obtaining thickness is 4.2mm laminated cloth；
S4, after in step S3, the laminated cloth of gained naturally cools to room temperature, its essence is cut into the laminated cloth of required size
Obtain.
The multi-angle bulletproof anti-puncturing laminated cloth prepared in the five groups of embodiments present invention proposed carries out wearability and compares,
With harden steel knife apply identical external force effect under, scrape sliding laminated cloth 10s, calculate its wear rate, result is as follows: (wear rate
The lowest, wearability is the best)
| Embodiment | One | Two | Three | Four | Five |
| Wear rate | 0.018% | 0.012% | 0.04% | 0.035% | 0.02% |
A kind of multi-angle bulletproof anti-puncturing laminated cloth that the present invention proposes, has the most fire-retardant, waterproof a, antibacterial effect, and by force
Degree is high, hardness is high, lightweight, and wearability is good, and bulletproof anti-puncturing is effective, the invention allows for a kind of multi-angle bulletproof anti-puncturing without
The preparation method of latitude cloth, uses multi-angle three-dimensional orthogonal woven method that aramid fiber consolidates molding and does the interior basic unit of laminated cloth, with
Vulcanie adds flame retardant resin and other auxiliary agents are mixed and made into the outer layered material of laminated cloth, is pressed into by ectonexine by calender
Type and obtain, substantially increase laminated cloth safety system can, raw materials used simple and easy to get, production operation is simple, and production process is without dirt
Dye, low cost, it is worthy to be popularized.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (8)
1. a multi-angle bulletproof anti-puncturing laminated cloth, it is characterised in that include the raw material of following weight portion: nitrile rubber 15～30
Part, polyethylene fibre 10～15 parts, sulfur 3～6 parts, phthalic anhydride 0.5～1 part, Fanglun slurry cake 0.8～1.5 parts, poly-ammonia
Ester adhesive 8～15 parts, brominated epoxy resin 2～8 parts, watery water-proofing agent 2～6 parts, antibacterial matrices 1～3 parts, aramid fiber 10
～20 parts.
A kind of multi-angle bulletproof anti-puncturing laminated cloth the most according to claim 1, it is characterised in that include following weight portion
Raw material: nitrile rubber 18～28 parts, polyethylene fibre 12～14 parts, sulfur 4～5 parts, phthalic anhydride 0.6～0.8 part, virtue
Synthetic fibre pulp 1～1.2 parts, adhesive for polyurethane 10～12 parts, brominated epoxy resin 3～6 parts, watery water-proofing agent 3～5 parts, antibacterial
Master batch 1.5～2.5 parts, aramid fiber 12～18 parts.
A kind of multi-angle bulletproof anti-puncturing laminated cloth the most according to claim 1, it is characterised in that include following weight portion
Raw material: nitrile rubber 20 parts, polyethylene fibre 13 parts, 5 parts of sulfur, phthalic anhydride 0.7 part, Fanglun slurry cake 1 part, polyurethane
Adhesive 10 parts, brominated epoxy resin 5 parts, watery water-proofing agent 4 parts, antibacterial matrices 2 parts, aramid fiber 15 parts.
A kind of multi-angle bulletproof anti-puncturing laminated cloth the most according to claim 1, it is characterised in that described nitrile rubber, poly-
The weight ratio of vinyl fiber is 1.5～2: 1.
A kind of multi-angle bulletproof anti-puncturing laminated cloth the most according to claim 1, it is characterised in that described antibacterial matrices is for receiving
One in rice zinc oxide, nano cupric oxide and nano titanium oxide.
A kind of multi-angle bulletproof anti-puncturing laminated cloth the most according to claim 1, it is characterised in that described aramid fiber is line
Footpath is the meta aramid fiber long filament of 10～50 μm.
7. the preparation method of a multi-angle bulletproof anti-puncturing laminated cloth, it is characterised in that comprise the following steps:
S1, the aramid fiber of described proportion is drawn from 1～3 fiber axis, control tension force by tensioner and send into laminated cloth
In production equipment, regulate technical parameter, it is ensured that every aramid fiber is uniformly distributed through parallel, with aramid fiber warp, latitude
Line angle degree is the mode of 45 °/135 °, is consolidated into the three-dimensional orthogonal woven fabric of entirety, obtains kevlar fabric A；
S2, nitrile rubber, sulfur, phthalic anhydride by described proportion, join in rubber vulcanizing tank, with 150～180 DEG C
High temperature vulcanized 3～5h, be then cooled to 100～120 DEG C, add the polyethylene fibre of described proportion, Fanglun slurry cake, polyurethane
Adhesive, brominated epoxy resin, watery water-proofing agent and antibacterial matrices, with the rotating speed of 250～400r/min, stir 20～40min,
Uniform blend glue stuff B to be mixed；
S3, by the blend glue stuff B of gained in step S2 with 5～10kg/min speed extrude, at the bar that temperature is 70～90 DEG C
Under part, rolling the two sides of the kevlar fabric A of gained in step sl with calender, obtaining thickness is 0.5～7mm laminated cloth；
S4, after in step S3, the laminated cloth of gained naturally cools to room temperature, its essence is cut into the laminated cloth of required size and get final product.
The preparation method of a kind of multi-angle bulletproof anti-puncturing laminated cloth the most according to claim 7, it is characterised in that described step
Aramid fiber warp, the angle of parallel in rapid S1 could alternatively be 30 °/160 °, 60 °/130 °, 90 °/90 °.
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| CN201610798791.6A CN106223051A (en) | 2016-08-31 | 2016-08-31 | A kind of multi-angle bulletproof anti-puncturing laminated cloth and preparation method thereof |
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