CN102848658A - Production technology of composite material for yacht - Google Patents
Production technology of composite material for yacht Download PDFInfo
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- CN102848658A CN102848658A CN2012101239218A CN201210123921A CN102848658A CN 102848658 A CN102848658 A CN 102848658A CN 2012101239218 A CN2012101239218 A CN 2012101239218A CN 201210123921 A CN201210123921 A CN 201210123921A CN 102848658 A CN102848658 A CN 102848658A
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Abstract
The invention relates to a production technology of a composite material for a yacht, comprising the following steps: firstly using a padding-bonding all-in-one machine to pad a mesh cloth layer with a PVC resin-pasting adhesive and drying and preheating; then synchronously bonding the mesh cloth layer with an ink-jet printing film layer and a surface film layer at 190-200 DEG C, wherein the ink-jet printing film layer is arranged between the mesh cloth layer and the surface film layer; bonding the other side surface of the mesh cloth layer with a bottom film layer; and finally cooling to mold, and trimming and reeling to obtain the composite material for the yacht. According to the invention, by preferred formula of the surface film layer, a transparent elastic film with excellent performance is obtained; by using the PVC resin-pasting adhesive, the peeling strength, tearing strength, handle resilience and other physical properties are good; by completing the bonding of the multiple film layers and the mesh film layer in one step, the damage to the PVC film layer caused by multi-time heating and cooling is reduced, and the product performance is raised.
Description
Technical field
The invention belongs to the new textile material field, specifically relate to the production technology that a kind of yacht is used composite.
Background technology
Yacht is a kind of amusement on water advanced durable consumer goods.It integrates the functions such as navigation, motion, amusement, leisure, satisfies the needs that individual and family enjoy life.Along with rapid development of economy and people's growth in the living standard, people turn to yacht to interest.
China is an ocean big country, has 90,000 lakes, 6500 island, 18000 kilometers coastlines, possesses the physical geography condition of yacht consumption.China (Shanghai) in 2011 international yacht exhibition lowers the curtain in Shanghai, in four days exhibition only the yacht transaction value just above 1,000,000,000 yuan.The vigorous pace that yacht is sold indicates that again yacht may become " commanding elevation " of domestic consumption very soon.From quiet several years ago development, powerful gesture by now, oneself begins to cause showing great attention to and paying attention to of country the yacht industry.The coming years, this new industry of yacht will be further flourish, become a universalness of China, high-grade recreation waterborne and motion mode.
The fast development of yacht industry sharply enlarges so that make the materials demand that yacht uses, and the PVC composite is exactly wherein a kind of.In yacht manufacturing process, PVC material series yacht is particularly had higher requirement to the ageing resistance of PVC material, weatherability, water proofing property, intensity, appreciative value etc.
At present, the PVC composite that can be applied to yacht has a lot, but for accomplishing aesthetic property, often directly carry out air brushing on PVC film surface, and yacht and unlike standing motionless commercial paper spray painting cloth, it tends to occur the scraping phenomenon in running, cause the pattern of the width of cloth fineness flaw to occur with regard to being easy to like this; In addition, " wicking " phenomenon often occurs with the PVC composite in traditional yacht easily, affects its aesthetic property and service life; There are the defectives such as peel strength not, easily wears out in traditional yacht with the PVC composite, has had a strong impact on its use.
Summary of the invention
Technical problem to be solved by this invention has been to provide a kind of scientific and reasonable yacht production technology of composite.
A kind of yacht production technology of composite, described production technology comprise the steps: at first to utilize pad that the applying all-in-one sticks with paste with PVC that resin adhesive pads with scrim layer and drying and forewarm after, under 190～200 ℃ scrim layer one side and air brushing rete, face mask layer being carried out three laminatings synchronously again closes, the air brushing rete is between scrim layer and the face mask layer, fitting with bottom membrane in the scrim layer another side, makes the yacht composite finally by cooling and shaping, ballingup again.
Preferably, described face mask layer, air brushing rete and bottom membrane make by following operation: filtration → four-roll calendaring ℃ is extruded in sieve material → → 180 ~ 210 ℃ of high-speed kneading → 190 ~ 210 ℃ banburyings of batching → → 195 ~ 210 ℃ of refining → 170 ~ 190 of 185 ~ 205 ℃ of thick refinings, and 1#170 ~ 190 ℃, 2#170 ~ 190 ℃, 3#160 ~ 180 ℃, 4#150 ~ 170 ℃ → 150 ~ 170 ℃ are drawn and got → 170 ~ 190 ℃ of heating → biaxial tension → 140 ~ 160 ℃ heating → cooling and shapings → cut edge → batch.
Preferably, described production technology comprises the steps:
(1) the upper paste of scrim layer, pad preliminary treatment:
Wherein, the raw material that PVC sticks with paste resin adhesive consists of: PVC sticks with paste resin 100 weight portions, 40 ~ 60 parts of citric acid ester plasticizers, 5 ~ 10 parts of extender plasticizer epoxidized soybean oils, 4 ~ 6 parts of calcium zinc stabilizers, 3 ~ 5 parts of environment-friendly type bridging agents, 0.5 ~ 1 part of mould inhibitor, 0.5 ~ 1 part of anti-UV auxiliary agent, 3 ~ 5 parts of thinners; Pad paste amount 100 ~ 200g/m
2
(2) preliminary treatment and the applying of scrim layer, face mask layer and air brushing rete:
(2.1.1) scrim layer sends: the scrim layer after will padding adopts the transmission frame of automatic tension control to carry out screen cloth and sends, and wrinkle resistantly when the control of tension force sends take scrim layer is principle, and tension force is controlled at 150 ~ 200N;
(2.1.2) scrim layer preheating: the scrim layer that sends is carried out preheating by the preheating running roller, and preheat temperature is 50 ~ 70 ℃;
(2.2.1) transmission of face mask layer and air brushing rete: adopt film to send frame and carry out the face mask layer transmission, adopt the control of magnetic force automatic tension to adjust the transmission tension force that the speed ratio that sends between frame and the preheat roll is controlled film, the speed that face mask layer sends and the speed ratio of preheating are 1:1.05 ~ 1.12, and the speed that the air brushing rete sends and the speed ratio of preheating are 1:1.02 ~ 1.05;
(2.2.2) preheating of face mask layer and air brushing rete: face mask layer preheat roll temperature is 60 ~ 80 ℃, and air brushing rete preheat roll temperature is 50 ~ 70 ℃;
(2.3) face mask layer, air brushing rete and scrim layer are fitted: the face mask layer after the preheating, air brushing rete and scrim layer are carried out the melting applying synchronously on warm-up mill, heating roller temperature is 195 ~ 205 ℃;
(3) preheating of bottom membrane and applying: bottom membrane heats through 195 ~ 205 ℃ of warm-up mills after temperature is 50 ~ 70 ℃ of preheat roll preheatings again, and last scrim layer with posting face mask layer and air brushing rete is fitted;
(4) embossing and surface treatment: four layer materials that tentatively post carry out embossing through nip rolls, and its laminate pressure is 2 ~ 3Mpa, and cloth speed is 8 ~ 10m/min; Effects on surface carries out weather-proof processing after the embossing;
(5) cooling and shaping, ballingup: will be through behind the process of four layer materials after applying, embossing, the surface treatment chill roll cooling and shaping, ballingup becomes the yacht composite again.
Preferably, it is that 1000D * 1000D, Density are that the woven mesh that forms is made in 28 * 26 pieces/inch terylene twisting silk weavings that described screen cloth is selected line density, described face mask layer is transparent elastic PVC face mask layer, and the air brushing rete is air brushing PVC rete, and bottom membrane is the black bottom membrane.
Preferably, described PVC sticks with paste resin polymerization degree K=70.
Preferably, the raw material of described face mask layer consists of: polyvinyl chloride resin powder 100 weight portions of degree of polymerization K=80, the thermoplastic polyurethane is that 5 ~ 8 parts, citric acid ester plasticizer are that 40 ~ 60 parts, extender plasticizer epoxidized soybean oil are that 4 ~ 8 parts, organic tin stabilizer are that 2 ~ 4 parts, anti-UV auxiliary agent are 0.5 ~ 1 part.
Preferably, adopt up and down two nip rolls in the described embossing process, the top is rubber rollers, and the below is steel rider.
Preferably, described weather-proof processing adopts a steel rider effects on surface that scribbles the weather resistant surface conditioning agent to process.
Preferably, described production technology concrete steps are:
(1) transparent elastic PVC face mask layer, air brushing PVC rete and black bottom membrane make by following operation respectively:
Filtration → four-roll calendaring ℃ is extruded in sieve material → → 195 ℃ of high-speed kneading → 200 ℃ banburyings of batching → → 205 ℃ of refining → 180 of 195 ℃ of thick refinings, and 1#180 ℃, 2#185 ℃, 3#170 ℃, 4#163 ℃ → 160 ℃ draw to be got → 180 ℃ of heating → biaxial tension → 150 ℃ heating → cooling and shapings → cut edge → batch;
Wherein: the raw material of transparent elastic PVC face mask layer consists of: polyvinyl chloride resin powder 100 weight portions of degree of polymerization K=80, and the thermoplastic polyurethane is that 5 parts, citric acid ester plasticizer are that 40 parts, extender plasticizer epoxidized soybean oil are that 8 parts, organic tin stabilizer are that 2 parts, anti-UV auxiliary agent are 0.5 part; The process velocity of rete is 40m/min;
(2) the upper paste of woven net layer of cloth, pad preliminary treatment:
Wherein, the raw material that PVC sticks with paste resin adhesive consists of: the PVC of degree of polymerization K=70 sticks with paste resin 100 weight portions, and citric acid ester plasticizer is 60 parts, 5 parts of extender plasticizer epoxidized soybean oils, 4 parts of calcium zinc stabilizers, 5 parts of environment-friendly type bridging agents, 0.5 part of mould inhibitor, 0.5 part of anti-UV auxiliary agent, 3 parts of thinners; Pad paste amount 150g/m
2
(3) preliminary treatment and the applying of woven net layer of cloth, transparent elastic PVC face mask layer and air brushing PVC rete:
(3.1.1) the woven net layer of cloth sends: send tension force and be controlled at 150N;
(3.1.2) woven net layer of cloth preheating: preheat temperature is 55 ℃;
(3.2.1) transmission of transparent elastic PVC face mask layer and air brushing PVC rete: the speed that transparent elastic PVC face mask layer sends and the speed ratio of preheating are 1:1.06, and the speed that air brushing PVC rete sends and the speed ratio of preheating are 1:1.03;
(3.2.2) preheating of transparent elastic PVC face mask layer and air brushing PVC rete: transparent elastic PVC face mask layer preheat roll temperature is 65 ℃, and air brushing PVC rete preheat roll temperature is 55 ℃;
(3.3) transparent elastic PVC face mask layer, air brushing PVC rete and woven mesh laminating close: transparent elastic PVC face mask layer, air brushing PVC rete and the woven net layer of cloth after the preheating carries out melting synchronously on warm-up mill fits, and heating roller temperature is 195 ℃;
(4) preheating of black bottom membrane and applying: the black bottom membrane heats through 195 ℃ of warm-up mills after temperature is 55 ℃ of preheat roll preheatings again, and last woven mesh laminating with posting transparent elastic PVC face mask layer and air brushing PVC rete closes;
(5) embossing and surface treatment: laminate pressure is 2Mpa during embossing, and cloth speed is 10m/min, carries out weather-proof processing by a steel rider effects on surface that scribbles the weather resistant surface conditioning agent after the embossing;
(6) cooling and shaping, ballingup: will through four layer materials after applying, embossing, the surface treatment through 3 chill roll cooling and shapings after, ballingup becomes the yacht composite again; Wherein, the inner logical recirculated water of chill roll cools off.
Preferably, described production technology concrete steps are:
(1) transparent elastic PVC face mask layer, air brushing PVC rete and black bottom membrane make by following operation respectively:
Filtration → four-roll calendaring ℃ is extruded in sieve material → → 200 ℃ of high-speed kneading → 205 ℃ banburyings of batching → → 205 ℃ of refining → 185 of 195 ℃ of thick refinings, and 1#185 ℃, 2#190 ℃, 3#175 ℃, 4#165 ℃ → 162 ℃ draw to be got → 185 ℃ of heating → biaxial tension → 155 ℃ heating → cooling and shapings → cut edge → batch;
Wherein: the raw material of transparent elastic PVC face mask layer consists of: polyvinyl chloride resin powder 100 weight portions of degree of polymerization K=80, and the thermoplastic polyurethane is that 8 parts, citric acid ester plasticizer are that 55 parts, extender plasticizer epoxidized soybean oil are that 8 parts, organic tin stabilizer are that 3 parts, anti-UV auxiliary agent are 1 part; The process velocity of rete is 38m/min;
(2) the upper paste of woven net layer of cloth, pad preliminary treatment:
Wherein, the raw material that PVC sticks with paste resin adhesive consists of: the PVC of degree of polymerization K=70 sticks with paste resin 100 weight portions, and citric acid ester plasticizer is 60 parts, 5 parts of extender plasticizer epoxidized soybean oils, 5 parts of calcium zinc stabilizers, 4 parts of environment-friendly type bridging agents, 1 part of mould inhibitor, 1 part of anti-UV auxiliary agent, 4 parts of thinners; Pad paste amount 200g/m
2
(3) preliminary treatment and the applying of woven net layer of cloth, transparent elastic PVC face mask layer and air brushing PVC rete:
(3.1.1) the woven net layer of cloth sends: send tension force and be controlled at 200N;
(3.1.2) woven net layer of cloth preheating: preheat temperature is 65 ℃;
(3.2.1) transmission of transparent elastic PVC face mask layer and air brushing PVC rete: the speed that transparent elastic PVC face mask layer sends and the speed ratio of preheating are 1:1.07, and the speed that air brushing PVC rete sends and the speed ratio of preheating are 1:1.04;
(3.2.2) preheating of transparent elastic PVC face mask layer and air brushing PVC rete: transparent elastic PVC face mask layer preheat roll temperature is 70 ℃, and air brushing PVC rete preheat roll temperature is 65 ℃;
(3.3) transparent elastic PVC face mask layer, air brushing PVC rete and woven mesh laminating close: transparent elastic PVC face mask layer, air brushing PVC rete and the woven net layer of cloth after the preheating carries out melting synchronously on warm-up mill fits, and heating roller temperature is 200 ℃;
(4) preheating of black bottom membrane and applying: the black counterdie heats through 200 ℃ of warm-up mills after temperature is 65 ℃ of preheat roll preheatings again, and last woven mesh laminating with posting transparent elastic PVC face mask layer and air brushing PVC rete closes;
(5) embossing and surface treatment: the embossing laminate pressure is 3Mpa, and cloth speed is 8m/min, carries out weather-proof processing by a steel rider effects on surface that scribbles the weather resistant surface conditioning agent after the embossing;
(6) cooling and shaping, ballingup: will through four layer materials after applying, embossing, the surface treatment through 3 chill roll cooling and shapings after, ballingup becomes the yacht composite again; Wherein, the inner logical recirculated water of chill roll cools off.
The present invention is scientific and reasonable, has significant economic benefit.The advantages such as the product that obtains by this technique has the intensity height, peel load is high, elasticity is good, resistance to hydrostatic pressure, water resistance are good, long service life have the very high market competitiveness.The compound layer of transparent elastic surface rete again on the surface of air brushing rete make pattern originally attractive in appearance still as seen, and when scraping occured, because the protection of the rete of high resiliency, the high grade of transparency, pattern can be not impaired.
The invention has the beneficial effects as follows:
1. the preferred resin-oatmeal of high polymerization degree, thermoplastic polyurethane, citric acid ester type and epoxidized soybean oil environment-friendly plasticizer, organic tin stabilizer etc. have obtained the very good transparent elastic film of performance as the prescription of face mask layer;
2. adopt PVC to stick with paste resin adhesive, avoided conventional P U adhesive that the deteriorated defective of hydrolysis occurs, make the physical properties such as peel strength, tearing strength, feel resilience of product better;
3. the step that is fitted in of multilayer film and scrim layer is finished, and has reduced the PVC rete because of heating for multiple times and has cooled off the damage that causes, and has promoted the performance of product;
4. selecting density is that 1000D * 1000D, Density are that 28 * 26 pieces/inch high elongations, low contraction terylene twisting silk weaving are made the woven mesh that forms as framework material, can guarantee on the one hand the physical strength of product, prevent that on the other hand the screen cloth fiber from causing the generation of infiltration phenomenon owing to wicking.
Description of drawings
Each Film preparation process frame chart of Fig. 1.
Fig. 2 is the process flow diagram that each rete and scrim layer are fitted.
The 1-face mask layer, 2-air brushing rete, 3-scrim layer, 4-bottom membrane.
The specific embodiment
The invention will be further described below in conjunction with the drawings and specific embodiments, but protection scope of the present invention is not limited to this.
Face mask layer 1 is transparent elastic PVC face mask layer, air brushing rete 2 is air brushing PVC rete, scrim layer 3 is the woven net layer of cloth, it is that 1000D * 1000D, Density are that the woven mesh that forms is made in 28 * 26 pieces/inch high elongations, low contraction terylene twisting silk weaving that its screen cloth is selected line density, and bottom membrane 4 is the black bottom membrane.
Embodiment 1
A kind of yacht the steps include: with the production technology of composite
(1) transparent elastic PVC face mask layer 1, air brushing PVC rete 2, black bottom membrane 4 make by following operation respectively:
Filtration → four-roll calendaring ℃ is extruded in sieve material → → 195 ℃ of high-speed kneading → 200 ℃ banburyings of batching → → 205 ℃ of refining → 180 of 195 ℃ of thick refinings, and 1#180 ℃, 2#185 ℃, 3#170 ℃, 4#163 ℃ → 160 ℃ draw to be got → 180 ℃ of heating → biaxial tension → 150 ℃ heating → cooling and shapings → cut edge → batch; Wherein, the air brushing PVC rete 2 various exquisite patterns of air brushing of can drawing a portrait as required.
The raw material of transparent elastic PVC face mask layer 1 consists of: polyvinyl chloride resin powder 100 weight portions of degree of polymerization K=80, and the thermoplastic polyurethane is that 5 parts, citric acid ester plasticizer are that 40 parts, extender plasticizer epoxidized soybean oil are that 8 parts, organic tin stabilizer are that 2 parts, anti-UV auxiliary agent are 0.5 part; The process velocity of rete is 40m/min;
(2) the upper paste of woven net layer of cloth 3, pad preliminary treatment:
Wherein, the raw material that PVC sticks with paste resin adhesive consists of: the PVC of degree of polymerization K=70 sticks with paste resin 100 weight portions, and citric acid ester plasticizer is 60 parts, 5 parts of extender plasticizer epoxidized soybean oils, 4 parts of calcium zinc stabilizers, 5 parts of environment-friendly type bridging agents, 0.5 part of mould inhibitor, 0.5 part of anti-UV auxiliary agent, 3 parts of thinners; Pad paste amount 150g/m
2
(3) preliminary treatment and the applying of woven net layer of cloth 3, transparent elastic PVC face mask layer 1 and air brushing PVC rete 2:
(3.1.1) woven net layer of cloth 3 sends: the woven mesh after will padding adopts the transmission frame of automatic tension control to carry out woven mesh and sends, and wrinkle resistantly when the control of tension force sends take woven mesh is principle, and tension force is controlled at 150N;
(3.1.2) woven net layer of cloth 3 preheatings: the woven mesh that sends is carried out preheating by the preheating running roller, and preheat temperature is 55 ℃;
(3.2.1) transmission of transparent elastic PVC face mask layer 1 and air brushing PVC rete 2: adopt film transmission frame to carry out rete and initiatively send, adopt the control of magnetic force automatic tension to adjust the transmission tension force that the speed ratio that sends between frame and the preheat roll is controlled film, the speed that transparent elastic PVC face mask layer 1 sends and the speed ratio of preheating are 1:1.06, and the speed that air brushing PVC rete 2 sends and the speed ratio of preheating are 1:1.03;
(3.2.2) preheating of transparent elastic PVC face mask layer 1 and air brushing PVC rete 2: transparent elastic PVC face mask layer 1 preheat roll temperature is 65 ℃, and air brushing PVC rete 2 preheat roll temperature are 55 ℃;
(3.3) transparent elastic PVC face mask layer 1, air brushing PVC rete 2 are fitted with woven net layer of cloth 3: the transparent elastic PVC face mask layer 1 after the preheating, air brushing PVC rete 2 carry out melting synchronously with woven net layer of cloth 3 on warm-up mill fits, and heating roller temperature is 195 ℃; The film that sends the frame transmission is normal temperature, and film must be heated near molten condition when entering applying, and temperature progressively raises in the heating process;
(4) preheating of black bottom membrane 4 and applying: black bottom membrane 4 heats through 195 ℃ of warm-up mills after temperature is 55 ℃ of preheat roll preheatings again, and last woven mesh laminating with posting transparent elastic PVC face mask layer 1 and air brushing PVC rete 2 closes;
(5) embossing and surface treatment: four layer materials after tentatively posting must be through embossing and surface treatment, with bonding strength and the surface property of further raising four layer materials; Adopt up and down two nip rolls in the embossing process, the top is rubber rollers, and the below is steel rider; Will add larger pressure between two rollers during embossing, with further lifting bonding strength, its laminate pressure is 2Mpa, and cloth speed is 10m/min, carries out weather-proof processing by a steel rider effects on surface that scribbles the weather resistant surface conditioning agent after the embossing;
(6) cooling and shaping, ballingup: will through four layer materials after applying, embossing, the surface treatment through 3 chill roll cooling and shapings after, ballingup becomes the yacht composite again; Wherein, the inner logical recirculated water of chill roll cools off.
As shown in table 1 below with the properties of composite according to the prepared yacht of above step:
The properties of table 1 composite
A kind of yacht the steps include: with the production technology of composite
(1) transparent elastic PVC face mask layer 1, air brushing PVC rete 2, black bottom membrane 4 make by following operation respectively:
Filtration → four-roll calendaring ℃ is extruded in sieve material → → 200 ℃ of high-speed kneading → 205 ℃ banburyings of batching → → 205 ℃ of refining → 185 of 195 ℃ of thick refinings, and 1#185 ℃, 2#190 ℃, 3#175 ℃, 4#165 ℃ → 162 ℃ draw to be got → 185 ℃ of heating → biaxial tension → 155 ℃ heating → cooling and shapings → cut edge → batch; Wherein, the air brushing PVC rete 2 various exquisite patterns of air brushing of can drawing a portrait as required.
The raw material of transparent elastic PVC face mask layer 1 consists of: polyvinyl chloride resin powder 100 weight portions of degree of polymerization K=80, and the thermoplastic polyurethane is that 8 parts, citric acid ester plasticizer are that 55 parts, extender plasticizer epoxidized soybean oil are that 8 parts, organic tin stabilizer are that 3 parts, anti-UV auxiliary agent are 1 part; The process velocity of rete is 38m/min;
(2) the upper paste of woven net layer of cloth 3, pad preliminary treatment:
Wherein, the raw material that PVC sticks with paste resin adhesive consists of: the PVC of degree of polymerization K=70 sticks with paste resin 100 weight portions, and citric acid ester plasticizer is 60 parts, 5 parts of extender plasticizer epoxidized soybean oils, 5 parts of calcium zinc stabilizers, 4 parts of environment-friendly type bridging agents, 1 part of mould inhibitor, 1 part of anti-UV auxiliary agent, 4 parts of thinners; Pad paste amount 200g/m
2
(3) preliminary treatment and the applying of woven net layer of cloth 3, transparent elastic PVC face mask layer 1 and air brushing PVC rete 2:
(3.1.1) woven net layer of cloth 3 sends: the woven mesh after will padding adopts the transmission frame of automatic tension control to carry out woven mesh and sends, and wrinkle resistantly when the control of tension force sends take woven mesh is principle, and tension force is controlled at 200N;
(3.1.2) woven net layer of cloth 3 preheatings: the woven mesh that sends is carried out preheating by the preheating running roller, and preheat temperature is 65 ℃;
(3.2.1) transmission of transparent elastic PVC face mask layer 1 and air brushing PVC rete 2: adopt film transmission frame to carry out rete and initiatively send, adopt the control of magnetic force automatic tension to adjust the transmission tension force that the speed ratio that sends between frame and the preheat roll is controlled film, the speed that transparent elastic PVC face mask layer 1 sends and the speed ratio of preheating are 1:1.07, and the speed that air brushing PVC rete 2 sends and the speed ratio of preheating are 1:1.04;
(3.2.2) preheating of transparent elastic PVC face mask layer 1 and air brushing PVC rete 2: transparent elastic PVC face mask layer 1 preheat roll temperature is 70 ℃, and air brushing PVC rete 2 preheat roll temperature are 65 ℃;
(3.3) transparent elastic PVC face mask layer 1, air brushing PVC rete 2 are fitted with woven net layer of cloth 3: the transparent elastic PVC face mask layer 1 after the preheating, air brushing PVC rete 2 carry out melting synchronously with woven net layer of cloth 3 on warm-up mill fits, and heating roller temperature is 200 ℃;
(4) preheating of black bottom membrane 4 and applying: black bottom membrane 4 heats through 200 ℃ of warm-up mills after temperature is 65 ℃ of preheat roll preheatings again, and last woven mesh laminating with posting transparent elastic PVC face mask layer 1 and air brushing PVC rete 2 closes;
(5) embossing and surface treatment: four layer materials that tentatively post carry out embossing through nip rolls, and its laminate pressure is 3Mpa, and cloth speed is 8m/min, carries out weather-proof processing by a steel rider effects on surface that scribbles the weather resistant surface conditioning agent after the embossing;
(6) cooling and shaping, ballingup: will through four layer materials after applying, embossing, the surface treatment through 3 chill roll cooling and shapings after, ballingup becomes the yacht composite again; Wherein, the inner logical recirculated water of chill roll cools off.
As shown in table 2 below with the properties of composite according to the prepared yacht of above step:
The properties of table 2 composite
Claims (10)
1. a yacht is with the production technology of composite, it is characterized in that: described production technology comprise the steps: at first to utilize pad that the applying all-in-one sticks with paste with PVC that resin adhesive pads with scrim layer and drying and forewarm after, under 190～200 ℃ scrim layer one side and air brushing rete, face mask layer being carried out three laminatings synchronously again closes, the air brushing rete is between scrim layer and the face mask layer, fitting with bottom membrane in the scrim layer another side, makes the yacht composite finally by cooling and shaping, ballingup again.
2. yacht according to claim 1 is with the production technology of composite, it is characterized in that: described face mask layer, air brushing rete and bottom membrane make by following operation: filtration → four-roll calendaring ℃ is extruded in sieve material → → 180 ~ 210 ℃ of high-speed kneading → 190 ~ 210 ℃ banburyings of batching → → 195 ~ 210 ℃ of refining → 170 ~ 190 of 185 ~ 205 ℃ of thick refinings, and 1#170 ~ 190 ℃, 2#170 ~ 190 ℃, 3#160 ~ 180 ℃, 4#150 ~ 170 ℃ → 150 ~ 170 ℃ are drawn and got → 170 ~ 190 ℃ of heating → biaxial tension → 140 ~ 160 ℃ heating → cooling and shapings → cut edge → batch.
3. yacht according to claim 1 and 2 is with the production technology of composite, and it is characterized in that: described production technology comprises the steps:
(1) the upper paste of scrim layer, pad preliminary treatment:
Wherein, the raw material that PVC sticks with paste resin adhesive consists of: PVC sticks with paste resin 100 weight portions, 40 ~ 60 parts of citric acid ester plasticizers, 5 ~ 10 parts of extender plasticizer epoxidized soybean oils, 4 ~ 6 parts of calcium zinc stabilizers, 3 ~ 5 parts of environment-friendly type bridging agents, 0.5 ~ 1 part of mould inhibitor, 0.5 ~ 1 part of anti-UV auxiliary agent, 3 ~ 5 parts of thinners; Pad paste amount 100 ~ 200g/m
2
(2) preliminary treatment and the applying of scrim layer, face mask layer and air brushing rete:
(2.1.1) scrim layer sends: the scrim layer after will padding adopts the transmission frame of automatic tension control to carry out screen cloth and sends, and wrinkle resistantly when the control of tension force sends take scrim layer is principle, and tension force is controlled at 150 ~ 200N;
(2.1.2) scrim layer preheating: the scrim layer that sends is carried out preheating by the preheating running roller, and preheat temperature is 50 ~ 70 ℃;
(2.2.1) transmission of face mask layer and air brushing rete: adopt film to send frame and carry out the face mask layer transmission, adopt the control of magnetic force automatic tension to adjust the transmission tension force that the speed ratio that sends between frame and the preheat roll is controlled film, the speed that face mask layer sends and the speed ratio of preheating are 1:1.05 ~ 1.12, and the speed that the air brushing rete sends and the speed ratio of preheating are 1:1.02 ~ 1.05;
(2.2.2) preheating of face mask layer and air brushing rete: face mask layer preheat roll temperature is 60 ~ 80 ℃, and air brushing rete preheat roll temperature is 50 ~ 70 ℃;
(2.3) face mask layer, air brushing rete and scrim layer are fitted: the face mask layer after the preheating, air brushing rete and scrim layer are carried out the melting applying synchronously on warm-up mill, heating roller temperature is 195 ~ 205 ℃;
(3) preheating of bottom membrane and applying: bottom membrane heats through 195 ~ 205 ℃ of warm-up mills after temperature is 50 ~ 70 ℃ of preheat roll preheatings again, and last scrim layer with posting face mask layer and air brushing rete is fitted;
(4) embossing and surface treatment: four layer materials that tentatively post carry out embossing through nip rolls, and its laminate pressure is 2 ~ 3Mpa, and cloth speed is 8 ~ 10m/min; Effects on surface carries out weather-proof processing after the embossing;
(5) cooling and shaping, ballingup: will be through behind the process of four layer materials after applying, embossing, the surface treatment chill roll cooling and shaping, ballingup becomes the yacht composite again.
According to claim 1 or 3 described yachts with the production technology of composites, it is characterized in that: it is that 1000D * 1000D, Density are that the woven mesh that forms is made in 28 * 26 pieces/inch terylene twisting silk weavings that described screen cloth is selected line density, described face mask layer is transparent elastic PVC face mask layer, the air brushing rete is air brushing PVC rete, and bottom membrane is the black bottom membrane.
According to claim 1 or 3 described yachts with the production technology of composites, it is characterized in that: described PVC sticks with paste resin polymerization degree K=70.
According to claim 1 or 3 described yachts with the production technology of composites, it is characterized in that: the raw material of described face mask layer consists of: polyvinyl chloride resin powder 100 weight portions of degree of polymerization K=80, the thermoplastic polyurethane is that 5 ~ 8 parts, citric acid ester plasticizer are that 40 ~ 60 parts, extender plasticizer epoxidized soybean oil are that 4 ~ 8 parts, organic tin stabilizer are that 2 ~ 4 parts, anti-UV auxiliary agent are 0.5 ~ 1 part.
7. yacht according to claim 3 is with the production technology of composite, and it is characterized in that: adopt up and down two nip rolls in the described embossing process, the top is rubber rollers, and the below is steel rider.
8. yacht according to claim 3 is with the production technology of composite, and it is characterized in that: described weather-proof processing adopts a steel rider effects on surface that scribbles the weather resistant surface conditioning agent to process.
According to claim 2 or 3 described yachts with the production technology of composites, it is characterized in that: described production technology concrete steps are:
(1) transparent elastic PVC face mask layer, air brushing PVC rete and black bottom membrane make by following operation respectively:
Filtration → four-roll calendaring ℃ is extruded in sieve material → → 195 ℃ of high-speed kneading → 200 ℃ banburyings of batching → → 205 ℃ of refining → 180 of 195 ℃ of thick refinings, and 1#180 ℃, 2#185 ℃, 3#170 ℃, 4#163 ℃ → 160 ℃ draw to be got → 180 ℃ of heating → biaxial tension → 150 ℃ heating → cooling and shapings → cut edge → batch;
Wherein: the raw material of transparent elastic PVC face mask layer consists of: polyvinyl chloride resin powder 100 weight portions of degree of polymerization K=80, and the thermoplastic polyurethane is that 5 parts, citric acid ester plasticizer are that 40 parts, extender plasticizer epoxidized soybean oil are that 8 parts, organic tin stabilizer are that 2 parts, anti-UV auxiliary agent are 0.5 part; The process velocity of rete is 40m/min;
(2) the upper paste of woven net layer of cloth, pad preliminary treatment:
Wherein, the raw material that PVC sticks with paste resin adhesive consists of: the PVC of degree of polymerization K=70 sticks with paste resin 100 weight portions, and citric acid ester plasticizer is 60 parts, 5 parts of extender plasticizer epoxidized soybean oils, 4 parts of calcium zinc stabilizers, 5 parts of environment-friendly type bridging agents, 0.5 part of mould inhibitor, 0.5 part of anti-UV auxiliary agent, 3 parts of thinners; Pad paste amount 150g/m
2
(3) preliminary treatment and the applying of woven net layer of cloth, transparent elastic PVC face mask layer and air brushing PVC rete:
(3.1.1) the woven net layer of cloth sends: send tension force and be controlled at 150N;
(3.1.2) woven net layer of cloth preheating: preheat temperature is 55 ℃;
(3.2.1) transmission of transparent elastic PVC face mask layer and air brushing PVC rete: the speed that transparent elastic PVC face mask layer sends and the speed ratio of preheating are 1:1.06, and the speed that air brushing PVC rete sends and the speed ratio of preheating are 1:1.03;
(3.2.2) preheating of transparent elastic PVC face mask layer and air brushing PVC rete: transparent elastic PVC face mask layer preheat roll temperature is 65 ℃, and air brushing PVC rete preheat roll temperature is 55 ℃;
(3.3) transparent elastic PVC face mask layer, air brushing PVC rete and woven mesh laminating close: the rete after the preheating carries out melting synchronously on warm-up mill fits, and heating roller temperature is 195 ℃;
(4) preheating of black bottom membrane and applying: the black bottom membrane heats through 195 ℃ of warm-up mills after temperature is 55 ℃ of preheat roll preheatings again, and last woven mesh laminating with posting transparent elastic PVC face mask layer and air brushing PVC rete closes;
(5) embossing and surface treatment: laminate pressure is 2Mpa during embossing, and cloth speed is 10m/min, carries out weather-proof processing by a steel rider effects on surface that scribbles the weather resistant surface conditioning agent after the embossing;
(6) cooling and shaping, ballingup: will through four layer materials after applying, embossing, the surface treatment through 3 chill roll cooling and shapings after, ballingup becomes the yacht composite again; Wherein, the inner logical recirculated water of chill roll cools off.
10. described yacht is with the production technology of composite according to claim 1 ~ 3, and it is characterized in that: described production technology concrete steps are:
(1) transparent elastic PVC face mask layer, air brushing PVC rete and black bottom membrane make by following operation respectively:
Filtration → four-roll calendaring ℃ is extruded in sieve material → → 200 ℃ of high-speed kneading → 205 ℃ banburyings of batching → → 205 ℃ of refining → 185 of 195 ℃ of thick refinings, and 1#185 ℃, 2#190 ℃, 3#175 ℃, 4#165 ℃ → 162 ℃ draw to be got → 185 ℃ of heating → biaxial tension → 155 ℃ heating → cooling and shapings → cut edge → batch;
Wherein: the raw material of transparent elastic PVC face mask layer consists of: polyvinyl chloride resin powder 100 weight portions of degree of polymerization K=80, and the thermoplastic polyurethane is that 8 parts, citric acid ester plasticizer are that 55 parts, extender plasticizer epoxidized soybean oil are that 8 parts, organic tin stabilizer are that 3 parts, anti-UV auxiliary agent are 1 part; The process velocity of rete is 38m/min;
(2) the upper paste of woven net layer of cloth, pad preliminary treatment:
Wherein, the raw material that PVC sticks with paste resin adhesive consists of: the PVC of degree of polymerization K=70 sticks with paste resin 100 weight portions, and citric acid ester plasticizer is 60 parts, 5 parts of extender plasticizer epoxidized soybean oils, 5 parts of calcium zinc stabilizers, 4 parts of environment-friendly type bridging agents, 1 part of mould inhibitor, 1 part of anti-UV auxiliary agent, 4 parts of thinners; Pad paste amount 200g/m
2
(3) preliminary treatment and the applying of woven net layer of cloth, transparent elastic PVC face mask layer and air brushing PVC rete:
(3.1.1) the woven net layer of cloth sends: send tension force and be controlled at 200N;
(3.1.2) woven net layer of cloth preheating: preheat temperature is 65 ℃;
(3.2.1) transmission of transparent elastic PVC face mask layer and air brushing PVC rete: the speed that transparent elastic PVC face mask layer sends and the speed ratio of preheating are 1:1.07, and the speed that air brushing PVC rete sends and the speed ratio of preheating are 1:1.04;
(3.2.2) preheating of transparent elastic PVC face mask layer and air brushing PVC rete: transparent elastic PVC face mask layer preheat roll temperature is 70 ℃, and air brushing PVC rete preheat roll temperature is 65 ℃;
(3.3) transparent elastic PVC face mask layer, air brushing PVC rete and woven mesh laminating close: the rete after the preheating carries out melting synchronously on warm-up mill fits, and heating roller temperature is 200 ℃;
(4) preheating of black bottom membrane and applying: the black counterdie heats through 200 ℃ of warm-up mills after temperature is 65 ℃ of preheat roll preheatings again, and last woven mesh laminating with posting transparent elastic PVC face mask layer and air brushing PVC rete closes;
(5) embossing and surface treatment: the embossing laminate pressure is 3Mpa, and cloth speed is 8m/min, carries out weather-proof processing by a steel rider effects on surface that scribbles the weather resistant surface conditioning agent after the embossing;
(6) cooling and shaping, ballingup: will through four layer materials after applying, embossing, the surface treatment through 3 chill roll cooling and shapings after, ballingup becomes the yacht composite again; Wherein, the inner logical recirculated water of chill roll cools off.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104057684A (en) * | 2013-03-23 | 2014-09-24 | 上海纳尔数码喷印材料股份有限公司 | Spray-painting advertisement cloth and production process thereof |
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| CN107531937A (en) * | 2015-10-27 | 2018-01-02 | 株式会社Lg化学 | Plasticizer composition, resin combination and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1858341A (en) * | 2006-06-01 | 2006-11-08 | 上海光仁塑胶制品有限公司 | High strength anti-stamen suction water-proof net clamping cloth and its preparing method |
| CN101333772A (en) * | 2008-07-23 | 2008-12-31 | 黄金明 | Novel process for making material for PVC pneumatic boat |
| CN101698977A (en) * | 2008-12-30 | 2010-04-28 | 福建思嘉环保材料科技有限公司 | Process for producing composite material for over-water leisure and recreation apparatus |
| WO2010130986A1 (en) * | 2009-05-14 | 2010-11-18 | Dupont Teijin Films U.S. Limited Partnership | Transparent conductive composite films |
-
2012
- 2012-04-26 CN CN201210123921.8A patent/CN102848658B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1858341A (en) * | 2006-06-01 | 2006-11-08 | 上海光仁塑胶制品有限公司 | High strength anti-stamen suction water-proof net clamping cloth and its preparing method |
| CN101333772A (en) * | 2008-07-23 | 2008-12-31 | 黄金明 | Novel process for making material for PVC pneumatic boat |
| CN101698977A (en) * | 2008-12-30 | 2010-04-28 | 福建思嘉环保材料科技有限公司 | Process for producing composite material for over-water leisure and recreation apparatus |
| WO2010130986A1 (en) * | 2009-05-14 | 2010-11-18 | Dupont Teijin Films U.S. Limited Partnership | Transparent conductive composite films |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104057684A (en) * | 2013-03-23 | 2014-09-24 | 上海纳尔数码喷印材料股份有限公司 | Spray-painting advertisement cloth and production process thereof |
| TWI492846B (en) * | 2013-05-10 | 2015-07-21 | Formosan Rubber Group Inc | Manufacturing method of single-sided adhesive mesh cloth |
| CN107531937A (en) * | 2015-10-27 | 2018-01-02 | 株式会社Lg化学 | Plasticizer composition, resin combination and preparation method thereof |
| US10590260B2 (en) | 2015-10-27 | 2020-03-17 | Lg Chem, Ltd. | Plasticizer composition, resin composition, and methods for preparing same |
| CN107351492A (en) * | 2017-07-28 | 2017-11-17 | 浙江明士达新材料有限公司 | The Inflatable swimming pool of resistance to chlorine water material |
| CN107641949A (en) * | 2017-09-05 | 2018-01-30 | 绍兴思安阻燃科技有限公司 | Flame-proof treatment equipment |
| JP2019162831A (en) * | 2018-03-20 | 2019-09-26 | ダイヤプラスフィルム株式会社 | Transparent noncombustible sheet, smokeproof hanging wall using the transparent noncombustible sheet, smokeproof screen and curtain, and manufacturing method of transparent noncombustible sheet |
| CN110154492A (en) * | 2018-11-26 | 2019-08-23 | 四川金路高新材料有限公司 | A kind of production technology of anti-fold hot-water bottle leather |
| CN110154492B (en) * | 2018-11-26 | 2021-07-09 | 四川金路高新材料有限公司 | Production process of anti-wrinkle hot-water bag leather |
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| CN113442518A (en) * | 2021-06-02 | 2021-09-28 | 福建思嘉环保材料科技有限公司 | Thermochromic composite material and preparation method thereof |
| CN115678458A (en) * | 2021-07-26 | 2023-02-03 | 内蒙古天陆实业有限公司 | Environment-friendly adhesive and preparation method thereof |
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Address after: No. 8 Jiaxing City, Zhejiang province 314419 Haining Maqiao Street Hongqi Avenue Patentee after: Wahson Polytron Technologies Inc, Zhejiang Address before: No. 5 Jiaxing City, Zhejiang province 314419 Haining Maqiao Street Hongqi Avenue Patentee before: Zhejiang Huasheng Warp Knitting New Material Co.,Ltd. |