CN107841267B - 一种免钉胶的制造方法 - Google Patents

一种免钉胶的制造方法 Download PDF

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CN107841267B
CN107841267B CN201711099935.XA CN201711099935A CN107841267B CN 107841267 B CN107841267 B CN 107841267B CN 201711099935 A CN201711099935 A CN 201711099935A CN 107841267 B CN107841267 B CN 107841267B
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陈金才
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    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
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    • C09J11/04—Non-macromolecular additives inorganic
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    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
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    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
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    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract

本发明涉及一种免钉胶的制造方法，按重量份：聚乙烯醇100份，醋酸甲酯5‑15份，石英砂3‑10份，填料6‑12份，聚‑4‑甲基‑1‑戊烯0.1‑0.5份，油酸酰胺分散剂0.01‑0.1份，四(三甲基硅氧基)钛0.1‑0.5份，缓凝剂0.1‑0.5份，甲氧基(环辛二烯)合铱二聚体0.01‑0.1份，水10‑20份，混合均匀制得免钉胶产品。

Description

一种免钉胶的制造方法
技术领域
本发明涉及一种免钉胶的制造方法。
背景技术
随着国内外对装饰装修的个性化需求，以及人们生活水平的快速提升，建材、装饰和广告产业的快速发展，越来越多的放弃了传统材料如铁钉、螺栓等使用，而选择了胶粘剂产品来进行替代。而由于免钉胶材料施工便捷、无钉孔粘接美观的优势逐渐的被人们使用。
CN105885766A公开了一种不含有机锡的环保高强度免钉胶及其制备方法，所述免钉胶包括以下按质量份计算的组分：硅烷封端聚合物10-50份、增强树脂10-50份、增塑剂5-25份、增强填料20-55份、流变剂1-5份、吸水剂0.5-3份、偶联剂1-6份、稳定剂0.2-1.5份、非有机锡催化剂0.1-1份，其中，所述硅烷封端聚合物中含有聚氨酯基团。本发明所得产品具有初粘力大、固化快、强度高、可粘结多种基材、可在潮湿表面施工、表面可刷涂、耐热耐水等性能，特别是不含有毒挥发性溶剂和有机锡催化剂，健康环保。
CN104449523B公开一种环保型免钉胶及其制备方法，所述环保型免钉胶，包括如下重量份的原料：硅烷改性聚醚聚合物10-50份、增塑剂5-30份、甲基MQ硅树脂5-10份、白炭黑3-10份、触变剂0-8份、增强填料24-60份、除水剂0.5-4份、催化剂0.2-3份。该环保型免钉胶综合性能佳、施工效率高，且无需添加溶剂，环境友好，可代替传统的铁钉，起到良好的粘接固定作用。
CN107189718A公开了一种建筑用环保免钉胶，包括以下重量份的原料：聚乙烯醇20-30份、聚醋酸乙烯酯15-25份、醋酸甲酯8-12份、填料10-12份、消泡剂2-3份、偶联剂1-3份、植物胶粉10-18份、纳米二氧化硅4-6份、纳米氧化锌1-3份、纳米二氧化钛0.5-1.5份、防腐剂0.2-0.6份、无机增粘剂7-9份、十二烷基苯磺酸钠2-4份。本发明建筑用环保免钉胶，其粘接强度高，耐老化性能好，具有耐水性、不易发霉、无毒环保、无甲醛、无色无味、稠度好、贮存时间长、保水性佳、低温不凝胶的特点。
然而，传统水泥基免钉胶，其粘结性和水溶性才会大大提高，但是其耐水性较差，如果长期暴露在空气中易受潮、腐蚀，并且容易脱落，出现裂缝，严重影响了建筑质量。因此，研发一种综合性能优良的免钉胶具有重要意义。
发明内容
本发明的目的是：提供一种免钉胶的制造方法，其特征在于以下步骤：
按重量份：聚乙烯醇100份，醋酸甲酯5-15份，石英砂3-10份，填料6-12份，聚-4-甲基-1-戊烯0.1-0.5份，油酸酰胺分散剂0.01-0.1份，四(三甲基硅氧基)钛0.1-0.5份，缓凝剂0.1-0.5份，甲氧基(环辛二烯)合铱二聚体0.01-0.1份，白油10-20份，混合均匀制得免钉胶产品。
所述的述填料包括重钙粉和石英粉。
所述的缓凝剂包括柠檬酸、酒石酸和葡萄糖酸钠。
本发明的有益效果是：本发明针对现有产品的缺点，提供了一种新型的免钉胶，所述免钉胶具有环境友好、施工性能好、粘结强度高、防空鼓、碱度低、防泛碱泛霜等优点。
具体实施方式
以下实例仅仅是进一步说明本发明，并不是限制本发明保护的范围。
实施例1
按重量份：聚乙烯醇100份，醋酸甲酯8份，石英砂7份，重钙粉7份，聚-4-甲基-1-戊烯0.4份，油酸酰胺分散剂0.03份，四(三甲基硅氧基)钛0.3份，柠檬酸0.3份，甲氧基(环辛二烯)合铱二聚体0.05份，白油17份，混合均匀制得免钉胶产品。
实施例2
按重量份：聚乙烯醇100份，醋酸甲酯5份，石英砂3份，重钙粉6份，聚-4-甲基-1-戊烯0.1份，油酸酰胺分散剂0.01份，四(三甲基硅氧基)钛0.1份，酒石酸0.1份，甲氧基(环辛二烯)合铱二聚体0.01份，白油10份，混合均匀制得免钉胶产品。
实施例3
按重量份：聚乙烯醇100份，醋酸甲酯15份，石英砂10份，石英粉12份，聚-4-甲基-1-戊烯0.5份，油酸酰胺分散剂0.1份，四(三甲基硅氧基)钛0.5份，葡萄糖酸钠0.5份，甲氧基(环辛二烯)合铱二聚体0.1份，白油20份，混合均匀制得免钉胶产品。
对比例1
不加入聚-4-甲基-1-戊烯，其他条件同实施例1。
对比例2
不加入四(三甲基硅氧基)钛，其他条件同实施例1。
对比例3
不加入甲氧基(环辛二烯)合铱二聚体，其他条件同实施例1。
对比例4
不加入油酸酰胺分散剂，其他条件同实施例1。
实施例4
分别检验实施例1-3与对比例1-4所生产出的免钉胶产品的主要性能指标。
表1：不同工艺生产出的免钉胶产品的抗剪切强度。
产品编号 剪切强度(MPa)
实施例1 4.3
实施例2 4.2
实施例3 5.1
对比例1 3.0
对比例2 3.8
对比例3 3.9
对比例4 3.2

Claims (2)

1.一种防 泛碱泛霜 免钉胶的制造方法，其特征在于包括以下步骤：
按重量份：聚乙烯醇100份，醋酸甲酯5-15份，石英砂3-10份，填料6-12份，聚-4-甲基-1-戊烯0.1-0.5份，油酸酰胺分散剂0.01-0.1份，四(三甲基硅氧基)钛0.1-0.5份，缓凝剂0.1-0.5份，甲氧基(环辛二烯)合铱二聚体0.01-0.1份，水10-20份，混合均匀制得防泛碱泛霜 免钉胶；
所述的缓凝剂包括柠檬酸、酒石酸。
2.根据权利要求1所述的一种防泛碱泛霜 免钉胶的制造方法，其特征在于所述的填料包括重钙粉或石英粉。
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Citations (3)

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Publication number Priority date Publication date Assignee Title
CN104610900A (zh) * 2015-02-03 2015-05-13 广东新展化工新材料有限公司 一种免钉胶及其制备方法
CN105885766A (zh) * 2016-06-02 2016-08-24 广州集泰化工股份有限公司 一种不含有机锡的环保高强度免钉胶及其制备方法
CN107189718A (zh) * 2017-07-07 2017-09-22 滁州隆扬农业科技有限公司 一种建筑用环保免钉胶及其制备方法

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GB1572481A (en) * 1976-12-13 1980-07-30 Du Pont Adhesive compositions

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104610900A (zh) * 2015-02-03 2015-05-13 广东新展化工新材料有限公司 一种免钉胶及其制备方法
CN105885766A (zh) * 2016-06-02 2016-08-24 广州集泰化工股份有限公司 一种不含有机锡的环保高强度免钉胶及其制备方法
CN107189718A (zh) * 2017-07-07 2017-09-22 滁州隆扬农业科技有限公司 一种建筑用环保免钉胶及其制备方法

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