CN107829295A - 一种羊毛帽子专用抗菌防霉整理剂 - Google Patents
一种羊毛帽子专用抗菌防霉整理剂 Download PDFInfo
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Abstract
本发明公开了一种羊毛帽子专用抗菌防霉整理剂，其原料按重量份包括：氰酸钠2‑10份、过氧化氢2‑10份、改性壳聚糖10‑35份、杜仲提取液2‑10份、竹叶提取液3‑9份、白鲜皮提取液1‑5份、石榴皮提取液2‑10份、紫草提取液3‑16份、β‑环糊精3‑18份、转谷氨酰胺酶0.1‑1.2份、氨基硅氧烷1‑5份、柠檬酸2‑10份、亲水性表面活性剂2‑4份。本发明提出的羊毛帽子专用抗菌防霉整理剂，其能赋予羊毛帽子优异的抗菌性和防霉性，同时降低了羊毛帽子的缩绒性，使所得羊毛帽子手感柔软，光泽柔和。
Description
技术领域
本发明涉及羊毛帽子技术领域，尤其涉及一种羊毛帽子专用抗菌防霉整理剂。
背景技术
羊毛是一种应用广泛的天然蛋白质纤维，具有手感柔和、弹性好、保暖性好等特点。羊毛帽子是以羊毛为原料制作而成的，是人们日常备用的生活用品，可装饰、可遮阳、可保暖，深受消费者喜爱。随着人们对时尚的追求，功能性羊毛制品越来越受到人们的喜爱和亲睐。作为天然蛋白质纤维的羊毛本身并不具有抗菌防霉功能，用其制成的羊毛帽子往往为细菌提供了生存的“温床”，在使用和存放的过程中，细菌能迅速的生长、繁殖，对人体健康和环境都造成危害，同时会使羊毛帽子发生霉变，影响其性能。
发明内容
基于背景技术存在的技术问题，本发明提出了一种羊毛帽子专用抗菌防霉整理剂，其能赋予羊毛帽子优异的抗菌性和防霉性，同时降低了羊毛帽子的缩绒性，使所得羊毛帽子手感柔软，光泽柔和。
本发明提出的一种羊毛帽子专用抗菌防霉整理剂，其原料按重量份包括：氰酸钠2-10份、过氧化氢2-10份、改性壳聚糖10-35份、杜仲提取液2-10份、竹叶提取液3-9份、白鲜皮提取液1-5份、石榴皮提取液2-10份、紫草提取液3-16份、β-环糊精3-18份、转谷氨酰胺酶0.1-1.2份、氨基硅氧烷1-5份、柠檬酸2-10份、亲水性表面活性剂2-4份。
优选地，所述改性壳聚糖按照以下工艺进行制备：将硫脲、尿素、钛酸丁酯加入无水乙醇中混合均匀，调节pH值至2-3，加入去离子水搅拌至出现丁达尔效应，静置陈化2-4h，干燥、研磨后在500-550℃下煅烧2-3h得到改性纳米二氧化钛；将壳聚糖加入醋酸水溶液中，调节pH值为1-2，加入改性纳米二氧化钛，搅拌均匀后调节体系pH值为11-12，升温至65-75℃，加入戊二醛，静置反应3-5h后经离心、洗涤、干燥得到改性壳聚糖。
优选地，硫脲、尿素、钛酸丁酯的重量比为15-23：15-21：110-150。
优选地，壳聚糖、改性纳米二氧化钛、戊二醛的重量比为15-35：3-10：0.5-2.5。
优选地，所述杜仲提取液为杜仲乙醇提取液；所述竹叶提取液为竹叶乙醇提取液；所述白鲜皮提取液为白鲜皮乙醇提取液；所述石榴皮提取液为石榴皮乙醇提取液；所述紫草提取液为紫草乙醇提取液。
优选地，所述亲水性表面活性剂为烷基苯磺酸钠、十六烷基三甲基溴化铵、聚乙二醇、羧甲基纤维素、聚乙烯吡咯烷酮中的一种或者多种的混合物。
本发明所述羊毛帽子专用抗菌防霉整理剂，其原料中加入了氰酸钠和过氧化氢，两者能反应得到氨基过氧甲酸，从而对羊毛起到活化作用，腐蚀破坏了羊毛纤维的鳞片和表面细胞膜，使羊毛纤维的缩绒性下降，改善了羊毛纤维的白度和润湿性，赋予羊毛帽子优异的防缩性；优选方式中，以硫脲、尿素、钛酸丁酯为原料，调节反应的条件，得到了改性纳米二氧化钛，其中的硫和氮掺杂进入了二氧化钛晶格中，生成中间能带，减小了二氧化钛的禁带宽度，提高了二氧化钛的光催化活性和可见光响应能力，之后将其与壳聚糖混合，在戊二醛的作用下，得到了改性壳聚糖，将其加入体系中，与杜仲提取液、竹叶提取液、白鲜皮提取液、石榴皮提取液、紫草提取液、β-环糊精配合用作羊毛纤维的整理剂，与羊毛纤维的结合牢度高，赋予羊毛纤维优异的抗菌防霉性，且耐久性好，与转谷氨酰胺酶、氨基硅氧烷配合，大幅降低了羊毛纤维的缩水率，并防止了羊毛帽子泛黄，同时在保持羊毛强力的同时使所得羊毛帽子手感柔软，爽滑，光泽柔和，明显降低了羊毛帽子起毛起球现象。
具体实施方式
下面，通过具体实施例对本发明的技术方案进行详细说明。
实施例1
本发明提出的一种羊毛帽子专用抗菌防霉整理剂，其原料按重量份包括：氰酸钠10份、过氧化氢2份、改性壳聚糖35份、杜仲提取液2份、竹叶提取液9份、白鲜皮提取液1份、石榴皮提取液10份、紫草提取液3份、β-环糊精18份、转谷氨酰胺酶0.1份、氨基硅氧烷5份、柠檬酸2份、亲水性表面活性剂4份。
实施例2
本发明提出的一种羊毛帽子专用抗菌防霉整理剂，其原料按重量份包括：氰酸钠2份、过氧化氢10份、改性壳聚糖10份、杜仲提取液10份、竹叶提取液3份、白鲜皮提取液5份、石榴皮提取液2份、紫草提取液16份、β-环糊精3份、转谷氨酰胺酶1.2份、氨基硅氧烷1份、柠檬酸10份、亲水性表面活性剂2份。
实施例3
本发明提出的一种羊毛帽子专用抗菌防霉整理剂，其原料按重量份包括：氰酸钠4份、过氧化氢9份、改性壳聚糖14份、杜仲提取液8份、竹叶提取液4.5份、白鲜皮提取液4份、石榴皮提取液4.5份、紫草提取液13份、β-环糊精6份、转谷氨酰胺酶1份、氨基硅氧烷2份、柠檬酸8份、亲水性表面活性剂2.6份；
其中，所述改性壳聚糖按照以下工艺进行制备：将硫脲、尿素、钛酸丁酯加入无水乙醇中混合均匀，其中，硫脲、尿素、钛酸丁酯的重量比为15：21：110，调节pH值至3，加入去离子水搅拌至出现丁达尔效应，静置陈化2h，干燥、研磨后在550℃下煅烧2h得到改性纳米二氧化钛；将壳聚糖加入醋酸水溶液中，调节pH值为2，加入改性纳米二氧化钛，搅拌均匀后调节体系pH值为12，升温至65℃，加入戊二醛，其中，壳聚糖、改性纳米二氧化钛、戊二醛的重量比为35：3：2.5，静置反应3h后经离心、洗涤、干燥得到改性壳聚糖；
所述杜仲提取液为杜仲乙醇提取液；所述竹叶提取液为竹叶乙醇提取液；所述白鲜皮提取液为白鲜皮乙醇提取液；所述石榴皮提取液为石榴皮乙醇提取液；所述紫草提取液为紫草乙醇提取液；
所述亲水性表面活性剂为十六烷基三甲基溴化铵、聚乙二醇、羧甲基纤维素、聚乙烯吡咯烷酮的混合物，且十六烷基三甲基溴化铵、聚乙二醇、羧甲基纤维素、聚乙烯吡咯烷酮的质量比为3：2：4：1。
实施例4
本发明提出的一种羊毛帽子专用抗菌防霉整理剂，其原料按重量份包括：氰酸钠8份、过氧化氢5份、改性壳聚糖31份、杜仲提取液3份、竹叶提取液8份、白鲜皮提取液2份、石榴皮提取液8份、紫草提取液6份、β-环糊精15份、转谷氨酰胺酶0.4份、氨基硅氧烷4.3份、柠檬酸4份、亲水性表面活性剂3.5份；
其中，所述改性壳聚糖按照以下工艺进行制备：将硫脲、尿素、钛酸丁酯加入无水乙醇中混合均匀，其中，硫脲、尿素、钛酸丁酯的重量比为23：15：150，调节pH值至2，加入去离子水搅拌至出现丁达尔效应，静置陈化4h，干燥、研磨后在500℃下煅烧3h得到改性纳米二氧化钛；将壳聚糖加入醋酸水溶液中，调节pH值为1，加入改性纳米二氧化钛，搅拌均匀后调节体系pH值为11，升温至75℃，加入戊二醛，其中，壳聚糖、改性纳米二氧化钛、戊二醛的重量比为15：10：0.5，静置反应5h后经离心、洗涤、干燥得到改性壳聚糖；
所述杜仲提取液为杜仲乙醇提取液；所述竹叶提取液为竹叶乙醇提取液；所述白鲜皮提取液为白鲜皮乙醇提取液；所述石榴皮提取液为石榴皮乙醇提取液；所述紫草提取液为紫草乙醇提取液；
所述亲水性表面活性剂为烷基苯磺酸钠。
实施例5
本发明提出的一种羊毛帽子专用抗菌防霉整理剂，其原料按重量份包括：氰酸钠6份、过氧化氢7份、改性壳聚糖20份、杜仲提取液5份、竹叶提取液6份、白鲜皮提取液3份、石榴皮提取液5份、紫草提取液11份、β-环糊精10份、转谷氨酰胺酶0.8份、氨基硅氧烷3份、柠檬酸7份、亲水性表面活性剂3份；
其中，所述改性壳聚糖按照以下工艺进行制备：将硫脲、尿素、钛酸丁酯加入无水乙醇中混合均匀，其中，硫脲、尿素、钛酸丁酯的重量比为20：17：125，调节pH值至2.5，加入去离子水搅拌至出现丁达尔效应，静置陈化3h，干燥、研磨后在525℃下煅烧2.5h得到改性纳米二氧化钛；将壳聚糖加入醋酸水溶液中，调节pH值为1.5，加入改性纳米二氧化钛，搅拌均匀后调节体系pH值为11.5，升温至70℃，加入戊二醛，其中，壳聚糖、改性纳米二氧化钛、戊二醛的重量比为20：7：1.6，静置反应4h后经离心、洗涤、干燥得到改性壳聚糖；
所述杜仲提取液为杜仲乙醇提取液；所述竹叶提取液为竹叶乙醇提取液；所述白鲜皮提取液为白鲜皮乙醇提取液；所述石榴皮提取液为石榴皮乙醇提取液；所述紫草提取液为紫草乙醇提取液；
所述亲水性表面活性剂为烷基苯磺酸钠、十六烷基三甲基溴化铵、聚乙二醇、羧甲基纤维素、聚乙烯吡咯烷酮的混合物，且烷基苯磺酸钠、十六烷基三甲基溴化铵、聚乙二醇、羧甲基纤维素、聚乙烯吡咯烷酮的质量比为3：2：2：1：4。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。
Claims (6)
1.一种羊毛帽子专用抗菌防霉整理剂，其特征在于，其原料按重量份包括：氰酸钠2-10份、过氧化氢2-10份、改性壳聚糖10-35份、杜仲提取液2-10份、竹叶提取液3-9份、白鲜皮提取液1-5份、石榴皮提取液2-10份、紫草提取液3-16份、β-环糊精3-18份、转谷氨酰胺酶0.1-1.2份、氨基硅氧烷1-5份、柠檬酸2-10份、亲水性表面活性剂2-4份。
2.根据权利要求1所述羊毛帽子专用抗菌防霉整理剂，其特征在于，所述改性壳聚糖按照以下工艺进行制备：将硫脲、尿素、钛酸丁酯加入无水乙醇中混合均匀，调节pH值至2-3，加入去离子水搅拌至出现丁达尔效应，静置陈化2-4h，干燥、研磨后在500-550℃下煅烧2-3h得到改性纳米二氧化钛；将壳聚糖加入醋酸水溶液中，调节pH值为1-2，加入改性纳米二氧化钛，搅拌均匀后调节体系pH值为11-12，升温至65-75℃，加入戊二醛，静置反应3-5h后经离心、洗涤、干燥得到改性壳聚糖。
3.根据权利要求2所述羊毛帽子专用抗菌防霉整理剂，其特征在于，硫脲、尿素、钛酸丁酯的重量比为15-23：15-21：110-150。
4.根据权利要求2或3所述羊毛帽子专用抗菌防霉整理剂，其特征在于，壳聚糖、改性纳米二氧化钛、戊二醛的重量比为15-35：3-10：0.5-2.5。
5.根据权利要求1-4中任一项所述羊毛帽子专用抗菌防霉整理剂，其特征在于，所述杜仲提取液为杜仲乙醇提取液；所述竹叶提取液为竹叶乙醇提取液；所述白鲜皮提取液为白鲜皮乙醇提取液；所述石榴皮提取液为石榴皮乙醇提取液；所述紫草提取液为紫草乙醇提取液。
6.根据权利要求1-5中任一项所述羊毛帽子专用抗菌防霉整理剂，其特征在于，所述亲水性表面活性剂为烷基苯磺酸钠、十六烷基三甲基溴化铵、聚乙二醇、羧甲基纤维素、聚乙烯吡咯烷酮中的一种或者多种的混合物。
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108893983A (zh) * | 2018-06-08 | 2018-11-27 | 惠州南旋毛织厂有限公司 | 一种羊毛织物专用整理剂及其制备方法 |
| CN108951131A (zh) * | 2018-07-23 | 2018-12-07 | 含山县海达服饰有限公司 | 一种提升羊毛面料抗菌性能的处理方法 |
| CN111235880A (zh) * | 2020-03-24 | 2020-06-05 | 朱红英 | 具有抑菌功能的防护帽及其制备方法 |
| CN111391040A (zh) * | 2019-09-12 | 2020-07-10 | 绿城装饰工程集团有限公司 | 一种无机硅酸钙复合板的制备方法 |
| CN111607959A (zh) * | 2020-06-11 | 2020-09-01 | 南通大学 | 一种自清洁抗菌消臭涤纶织物及其整理方法 |
| CN111636193A (zh) * | 2020-06-11 | 2020-09-08 | 南通大学 | 一种复合功能涤纶织物及其整理方法 |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103981694A (zh) * | 2014-04-23 | 2014-08-13 | 桐乡市濮院毛针织技术服务中心 | 一种壳聚糖/TiO2复合整理羊毛织物的方法 |
| CN103981702A (zh) * | 2014-04-23 | 2014-08-13 | 桐乡市濮院毛针织技术服务中心 | 一种羊毛织物的复合整理方法 |
| CN105568679A (zh) * | 2016-03-11 | 2016-05-11 | 湖州宏鑫绸厂 | 一种羊毛混纺织物防臭整理方法 |
| CN105568678A (zh) * | 2016-03-11 | 2016-05-11 | 湖州宏鑫绸厂 | 一种羊毛织物抗菌整理方法 |
| CN105696336A (zh) * | 2016-03-11 | 2016-06-22 | 湖州宏鑫绸厂 | 一种羊毛织物防霉整理方法 |
| CN105862404A (zh) * | 2016-06-02 | 2016-08-17 | 湖州市菱湖重兆金辉丝织厂 | 一种羊毛织物抗菌防霉整理剂 |
| CN106637922A (zh) * | 2016-12-06 | 2017-05-10 | 浙江兰宝毛纺集团有限公司 | 羊毛纤维的表面改性方法 |
-
2017
- 2017-11-30 CN CN201711236326.4A patent/CN107829295A/zh not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103981694A (zh) * | 2014-04-23 | 2014-08-13 | 桐乡市濮院毛针织技术服务中心 | 一种壳聚糖/TiO2复合整理羊毛织物的方法 |
| CN103981702A (zh) * | 2014-04-23 | 2014-08-13 | 桐乡市濮院毛针织技术服务中心 | 一种羊毛织物的复合整理方法 |
| CN105568679A (zh) * | 2016-03-11 | 2016-05-11 | 湖州宏鑫绸厂 | 一种羊毛混纺织物防臭整理方法 |
| CN105568678A (zh) * | 2016-03-11 | 2016-05-11 | 湖州宏鑫绸厂 | 一种羊毛织物抗菌整理方法 |
| CN105696336A (zh) * | 2016-03-11 | 2016-06-22 | 湖州宏鑫绸厂 | 一种羊毛织物防霉整理方法 |
| CN105862404A (zh) * | 2016-06-02 | 2016-08-17 | 湖州市菱湖重兆金辉丝织厂 | 一种羊毛织物抗菌防霉整理剂 |
| CN106637922A (zh) * | 2016-12-06 | 2017-05-10 | 浙江兰宝毛纺集团有限公司 | 羊毛纤维的表面改性方法 |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108893983A (zh) * | 2018-06-08 | 2018-11-27 | 惠州南旋毛织厂有限公司 | 一种羊毛织物专用整理剂及其制备方法 |
| CN108951131A (zh) * | 2018-07-23 | 2018-12-07 | 含山县海达服饰有限公司 | 一种提升羊毛面料抗菌性能的处理方法 |
| CN111391040A (zh) * | 2019-09-12 | 2020-07-10 | 绿城装饰工程集团有限公司 | 一种无机硅酸钙复合板的制备方法 |
| CN111391040B (zh) * | 2019-09-12 | 2022-02-11 | 绿城装饰工程集团有限公司 | 一种无机硅酸钙复合板的制备方法 |
| CN111235880A (zh) * | 2020-03-24 | 2020-06-05 | 朱红英 | 具有抑菌功能的防护帽及其制备方法 |
| CN111607959A (zh) * | 2020-06-11 | 2020-09-01 | 南通大学 | 一种自清洁抗菌消臭涤纶织物及其整理方法 |
| CN111636193A (zh) * | 2020-06-11 | 2020-09-08 | 南通大学 | 一种复合功能涤纶织物及其整理方法 |
| CN111648126A (zh) * | 2020-06-11 | 2020-09-11 | 南通大学 | 一种基于改性纳米TiO2的多功能涤纶织物及整理方法 |
| CN111648126B (zh) * | 2020-06-11 | 2021-05-14 | 南通大学 | 一种基于改性纳米TiO2的多功能涤纶织物及整理方法 |
| CN111607959B (zh) * | 2020-06-11 | 2021-05-14 | 南通大学 | 一种自清洁抗菌消臭涤纶织物及其整理方法 |
| CN111636193B (zh) * | 2020-06-11 | 2021-05-14 | 南通大学 | 一种复合功能涤纶织物及其整理方法 |
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