CN107828531B - Organic bacteriostatic laundry detergent for infants and preparation method thereof - Google Patents
Organic bacteriostatic laundry detergent for infants and preparation method thereof Download PDFInfo
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- CN107828531B CN107828531B CN201711043583.6A CN201711043583A CN107828531B CN 107828531 B CN107828531 B CN 107828531B CN 201711043583 A CN201711043583 A CN 201711043583A CN 107828531 B CN107828531 B CN 107828531B
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- 239000003599 detergent Substances 0.000 title claims abstract description 51
- 230000003385 bacteriostatic effect Effects 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 239000000284 extract Substances 0.000 claims abstract description 91
- 238000003756 stirring Methods 0.000 claims abstract description 80
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 41
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 41
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 40
- 239000000203 mixture Substances 0.000 claims abstract description 37
- 238000002156 mixing Methods 0.000 claims abstract description 34
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 31
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 14
- 239000011780 sodium chloride Substances 0.000 claims abstract description 14
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract description 14
- 229940057950 sodium laureth sulfate Drugs 0.000 claims abstract description 13
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 12
- 238000001816 cooling Methods 0.000 claims abstract description 12
- 150000007524 organic acids Chemical class 0.000 claims abstract description 9
- 241000628997 Flos Species 0.000 claims abstract description 8
- 239000003899 bactericide agent Substances 0.000 claims abstract description 8
- 229940077388 benzenesulfonate Drugs 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 7
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims abstract 2
- 239000011259 mixed solution Substances 0.000 claims description 88
- 239000000839 emulsion Substances 0.000 claims description 48
- 244000075850 Avena orientalis Species 0.000 claims description 47
- 235000007319 Avena orientalis Nutrition 0.000 claims description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 40
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims description 37
- 244000042664 Matricaria chamomilla Species 0.000 claims description 37
- 235000007232 Matricaria chamomilla Nutrition 0.000 claims description 37
- 239000007864 aqueous solution Substances 0.000 claims description 35
- 235000007866 Chamaemelum nobile Nutrition 0.000 claims description 28
- 235000010489 acacia gum Nutrition 0.000 claims description 25
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims description 24
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 24
- 229940114496 olive leaf extract Drugs 0.000 claims description 24
- 239000001593 sorbitan monooleate Substances 0.000 claims description 24
- 235000011069 sorbitan monooleate Nutrition 0.000 claims description 24
- 229940035049 sorbitan monooleate Drugs 0.000 claims description 24
- 238000001694 spray drying Methods 0.000 claims description 23
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 13
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical group CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 11
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 240000000560 Citrus x paradisi Species 0.000 claims description 9
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical group [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 9
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 9
- -1 sodium alkyl benzene Chemical class 0.000 claims description 8
- CWVRJTMFETXNAD-JUHZACGLSA-N chlorogenic acid Chemical compound O[C@@H]1[C@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-JUHZACGLSA-N 0.000 claims description 7
- CWVRJTMFETXNAD-FWCWNIRPSA-N 3-O-Caffeoylquinic acid Natural products O[C@H]1[C@@H](O)C[C@@](O)(C(O)=O)C[C@H]1OC(=O)\C=C\C1=CC=C(O)C(O)=C1 CWVRJTMFETXNAD-FWCWNIRPSA-N 0.000 claims description 6
- PZIRUHCJZBGLDY-UHFFFAOYSA-N Caffeoylquinic acid Natural products CC(CCC(=O)C(C)C1C(=O)CC2C3CC(O)C4CC(O)CCC4(C)C3CCC12C)C(=O)O PZIRUHCJZBGLDY-UHFFFAOYSA-N 0.000 claims description 6
- CWVRJTMFETXNAD-KLZCAUPSSA-N Neochlorogenin-saeure Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O CWVRJTMFETXNAD-KLZCAUPSSA-N 0.000 claims description 6
- FFQSDFBBSXGVKF-KHSQJDLVSA-N chlorogenic acid Natural products O[C@@H]1C[C@](O)(C[C@@H](CC(=O)C=Cc2ccc(O)c(O)c2)[C@@H]1O)C(=O)O FFQSDFBBSXGVKF-KHSQJDLVSA-N 0.000 claims description 6
- 229940074393 chlorogenic acid Drugs 0.000 claims description 6
- 235000001368 chlorogenic acid Nutrition 0.000 claims description 6
- BMRSEYFENKXDIS-KLZCAUPSSA-N cis-3-O-p-coumaroylquinic acid Natural products O[C@H]1C[C@@](O)(C[C@@H](OC(=O)C=Cc2ccc(O)cc2)[C@@H]1O)C(=O)O BMRSEYFENKXDIS-KLZCAUPSSA-N 0.000 claims description 6
- 229940074391 gallic acid Drugs 0.000 claims description 6
- 235000004515 gallic acid Nutrition 0.000 claims description 6
- LXAHHHIGZXPRKQ-UHFFFAOYSA-N 5-fluoro-2-methylpyridine Chemical compound CC1=CC=C(F)C=N1 LXAHHHIGZXPRKQ-UHFFFAOYSA-N 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 235000005979 Citrus limon Nutrition 0.000 claims description 2
- 244000131522 Citrus pyriformis Species 0.000 claims description 2
- 244000178870 Lavandula angustifolia Species 0.000 claims description 2
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 2
- 125000005233 alkylalcohol group Chemical group 0.000 claims description 2
- 239000001102 lavandula vera Substances 0.000 claims description 2
- 235000018219 lavender Nutrition 0.000 claims description 2
- HEBRGEBJCIKEKX-UHFFFAOYSA-M sodium;2-hexadecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HEBRGEBJCIKEKX-UHFFFAOYSA-M 0.000 claims description 2
- 238000005406 washing Methods 0.000 abstract description 20
- 239000000686 essence Substances 0.000 abstract description 16
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 abstract description 11
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 abstract description 10
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 10
- 239000000419 plant extract Substances 0.000 abstract description 5
- 230000000638 stimulation Effects 0.000 abstract description 5
- 238000005202 decontamination Methods 0.000 abstract description 4
- 230000003588 decontaminative effect Effects 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 150000004996 alkyl benzenes Chemical class 0.000 abstract description 2
- 239000008236 heating water Substances 0.000 abstract description 2
- 238000011160 research Methods 0.000 abstract description 2
- 239000008367 deionised water Substances 0.000 description 21
- 229910021641 deionized water Inorganic materials 0.000 description 21
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 16
- ASEFUFIKYOCPIJ-UHFFFAOYSA-M sodium;2-dodecoxyethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOS([O-])(=O)=O ASEFUFIKYOCPIJ-UHFFFAOYSA-M 0.000 description 12
- 244000012254 Canarium album Species 0.000 description 10
- 235000009103 Canarium album Nutrition 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- 240000007817 Olea europaea Species 0.000 description 8
- 230000001580 bacterial effect Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 6
- 239000000725 suspension Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 239000000645 desinfectant Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 238000002835 absorbance Methods 0.000 description 3
- 239000001963 growth medium Substances 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- QKNYBSVHEMOAJP-UHFFFAOYSA-N 2-amino-2-(hydroxymethyl)propane-1,3-diol;hydron;chloride Chemical compound Cl.OCC(N)(CO)CO QKNYBSVHEMOAJP-UHFFFAOYSA-N 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 2
- 241000222122 Candida albicans Species 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- 239000001888 Peptone Substances 0.000 description 2
- 108010080698 Peptones Proteins 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- 235000015278 beef Nutrition 0.000 description 2
- 229940095731 candida albicans Drugs 0.000 description 2
- 238000012258 culturing Methods 0.000 description 2
- 230000000249 desinfective effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000019319 peptone Nutrition 0.000 description 2
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000012488 sample solution Substances 0.000 description 2
- 210000000582 semen Anatomy 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 210000004666 bacterial spore Anatomy 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229940070641 chamomile flowers Drugs 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229960004106 citric acid Drugs 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000007760 free radical scavenging Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011081 inoculation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 239000013642 negative control Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- BHTJEPVNHUUIPV-UHFFFAOYSA-N pentanedial;hydrate Chemical compound O.O=CCCCC=O BHTJEPVNHUUIPV-UHFFFAOYSA-N 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an organic bacteriostatic laundry detergent for infants and a preparation method thereof, wherein the preparation method comprises the following steps: (1) heating water to 65-85 ℃, sequentially adding sodium laureth sulfate, sodium alkyl benzene sulfonate, fatty alcohol-polyoxyethylene ether, sodium polyacrylate and organic acid, and uniformly stirring and mixing to obtain a mixture; (2) cooling the mixture to 45-55 deg.C, sequentially adding herba Avenae Fatuae kernel extract, folium Canarii albi extract, flos Matricariae Chamomillae/leaf/stem extract, sodium chloride, disodium EDTA, potassium hydroxide, essence, and bactericide, stirring, and mixing. The organic bacteriostatic laundry detergent for infants prepared by the invention is reasonably adjusted in a formula system through a large amount of researches, and is mild in performance, safe and free of stimulation; various plant extracts are added into the laundry detergent, so that the laundry effect is promoted, the decontamination capability is strong, and the bacteriostatic effect is good; no chemical residue is caused in the using process, and the washing machine is particularly suitable for washing infant clothes.
Description
Technical Field
The invention relates to the technical field of laundry detergents, in particular to an organic bacteriostatic laundry detergent for infants and a preparation method thereof.
Background
With the development of the integration and trade globalization of the world economy, the cultural background, the technical level and the environmental protection regulations gradually become three major driving forces for the globalization development of the washing products, the global washing products tend to be diversified, but the products which are energy-saving, water-saving, efficient, mild, convenient to use and meet the requirements of safety and environmental protection are the mainstream direction for the development of the current and future washing products.
The laundry detergent replaces anhydrous sodium sulphate serving as a filling agent in the washing powder with water which is rich in resources and low in price, solves the problem of dust pollution caused by the washing powder in the using process, is simple in preparation process, has no stimulation to skin, is mild in performance, and becomes the first choice of household washing products. In order to ensure no stimulation in the use process, the use amount of some effective components with strong decontamination capability in the laundry detergent is reduced, so that the disadvantage of weak decontamination effect of the laundry detergent is caused.
With the increasing awareness of health, the cleaning of clothes cannot meet the mere cleaning effect, and the sterilization and disinfection of clothes while cleaning becomes the first choice of consumers. The skin of the baby is fragile and sensitive, the body resistance is low, and common washing powder and laundry detergent can remain on clothes and cause irritation and damage to the skin of the baby, so that when the baby laundry detergent is selected, on the premise of ensuring the cleaning function of the baby laundry detergent, the baby laundry detergent needs to be carefully selected, and products which do not irritate the skin of the baby and have a certain protection effect are selected. The laundry detergent has antibacterial and disinfecting functions on the market, but the disinfecting components commonly added in the laundry detergent are chlorine-containing disinfectants, oxygen-containing disinfectants or alcohol-containing disinfectants, and both surfactants and disinfectants adopted in the laundry detergent have unpleasant pungent odor; it is irritant and corrosive to fabric and skin; the stability is poor; the compatibility with other raw materials is poor; the environment is not friendly, and the health of the baby is easily damaged.
Most of the current commercially available infant washing products have poor washing effect for reducing irritation and toxicity of residues; or similar to the components of adult washing products, but the concentration is reduced, the washing effect cannot be improved, and the irritation to the skin of the infant cannot be reduced. With the improvement of the requirements on the quality of life, the market demand of the baby detergent is gradually increased, so that the development of the green environment-friendly baby detergent which is safer and has no stimulation and ensures good washing effect is very necessary.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides an organic bacteriostatic laundry detergent for infants and a preparation method thereof, which improve the washing performance and bacteriostatic effect and are suitable for washing infant clothes.
The invention is realized by the following technical scheme:
a preparation method of an organic bacteriostatic laundry detergent for infants comprises the following steps:
(1) heating water to 65-85 ℃, sequentially adding sodium laureth sulfate, sodium alkyl benzene sulfonate, fatty alcohol-polyoxyethylene ether, sodium polyacrylate and organic acid, and uniformly stirring and mixing to obtain a mixture;
(2) cooling the mixture to 45-55 deg.C, sequentially adding extract of semen Avenae Fatuae (AVENA SATIVA), extract of folium Canarii albi (Canarium ALBUM), extract of flower/leaf/stem of flos Matricariae Chamomillae (Chamomilla RECUTITA), sodium chloride, disodium EDTA, potassium hydroxide, essence, and bactericide, stirring, and mixing.
A preparation method of an organic bacteriostatic laundry detergent for infants comprises the following steps:
(1) heating 95-105 parts by weight of water to 65-85 ℃, sequentially adding 5-9 parts by weight of sodium laureth sulfate, 1-3 parts by weight of sodium alkyl benzene sulfonate, 4-8 parts by weight of fatty alcohol-polyoxyethylene ether, 2-5 parts by weight of sodium polyacrylate and 0.1-0.7 part by weight of organic acid, and uniformly mixing by stirring at the rotation speed of 200-;
(2) cooling the mixture to 45-55 deg.C, sequentially adding 0.5-1 weight part of semen Avenae Fatuae (AVENA SATIVA) extract, 0.4-0.9 weight part of folium Canarii albi (Canarium ALBUM) extract, 0.4-0.9 weight part of flos Matricariae Chamomillae (Chamomilla) flower/leaf/stem extract, 0.5-1 weight part of sodium chloride, 0.1-0.5 weight part of disodium EDTA, 0.1-0.3 weight part of potassium hydroxide, 0.02-0.04 weight part of essence, 0.01-0.03 weight part of bactericide, stirring at a rotation speed of 200-.
As an improved technical scheme, the preparation method of the organic bacteriostatic laundry detergent for infants comprises the following steps:
(1) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the water are mixed according to the mass ratio of (0.4-0.9): (3-8): (93-97) uniformly mixing to obtain a mixed solution; adding the oat (AVENA SATIVA) kernel extract into the mixed solution, and stirring for 60-90 seconds at the rotating speed of 11000 and 13000 r/min, wherein the mass ratio of the oat (AVENA SATIVA) kernel extract to the mixed solution is (0.1-0.15): 1, obtaining an emulsion; spray drying the emulsion to obtain microencapsulated oat (AVENASATIVA) kernel extract;
(2) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the water are mixed according to the mass ratio of (0.4-0.9): (3-8): (93-97) uniformly mixing to obtain a mixed solution; adding the extract of the leaves of the olive (Canarium ALBUM) into the mixed solution, stirring for 60-90 seconds at the rotation speed of 11000 and 13000 revolutions/minute, wherein the mass ratio of the extract of the leaves of the olive (Canarium ALBUM) to the mixed solution is (0.1-0.15): 1, obtaining an emulsion; spray drying the emulsion to obtain microencapsulated olive (Canarium ALBUM) leaf extract;
(3) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the water are mixed according to the mass ratio of (0.4-0.9): (3-8): (93-97) uniformly mixing to obtain a mixed solution; adding flos Matricariae Chamomillae (Chamomilla RECUTITA) flower/leaf/stem extract into the mixed solution, stirring at rotation speed of 11000 and 13000 r/min for 60-90 s, wherein the mass ratio of flos Matricariae Chamomillae (Chamomilla RECUTITA) flower/leaf/stem extract to the mixed solution is (0.1-0.15): 1, obtaining an emulsion; spray drying the emulsion to obtain microencapsulated flos Matricariae Chamomillae (CHAMOMILLA RECUTITA) flower/leaf/stem extract;
(4) heating 95-105 parts by weight of water to 65-85 ℃, sequentially adding 5-9 parts by weight of sodium laureth sulfate, 1-3 parts by weight of sodium alkyl benzene sulfonate, 4-8 parts by weight of fatty alcohol-polyoxyethylene ether, 2-5 parts by weight of sodium polyacrylate and 0.1-0.7 part by weight of organic acid, and uniformly mixing by stirring at the rotation speed of 200-;
(5) cooling the mixture to 45-55 deg.C, sequentially adding 0.5-1 weight parts of microencapsulated oat (AVENASATIVA) kernel extract, 0.4-0.9 weight parts of microencapsulated olive (CANARIUM ALBUM) leaf extract, 0.4-0.9 weight parts of microencapsulated chamomile (CHAMOMILLA RECUTITA) flower/leaf/stem extract, 0.5-1 weight parts of sodium chloride, 0.1-0.5 weight parts of EDTA disodium, 0.1-0.3 weight parts of potassium hydroxide, 0.02-0.04 weight parts of essence, 0.01-0.03 weight parts of bactericide, stirring at a rotation speed of 200 and 500 revolutions/minute for 10-30min, and mixing uniformly to obtain the final product.
As another improved technical scheme, the preparation method of the organic bacteriostatic laundry detergent for infants comprises the following steps:
(1) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the water are mixed according to the mass ratio of (0.4-0.9): (3-8): (93-97) uniformly mixing to obtain a mixed solution; adding the oat (AVENA SATIVA) kernel extract into the mixed solution, stirring for 60-90 seconds at the rotating speed of 11000-13000 r/min, then adding a glutaraldehyde aqueous solution with the mass fraction of 20-30%, stirring for 15-25 minutes at the rotating speed of 500-900 r/min, wherein the mass ratio of the oat (AVENA SATIVA) kernel extract to the mixed solution is (0.1-0.15): 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 20-30% to the mixed solution is (0.02-0.05): 1, obtaining an emulsion; spray drying the emulsion to obtain microencapsulated oat (AVENA SATIVA) kernel extract;
(2) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the water are mixed according to the mass ratio of (0.4-0.9): (3-8): (93-97) uniformly mixing to obtain a mixed solution; adding the olive (Canarium ALBUM) leaf extract into the mixed solution, stirring for 60-90 seconds at the rotation speed of 11000 rotation/minute and 13000 rotation/minute, then adding a glutaraldehyde aqueous solution with the mass fraction of 20-30%, stirring for 15-25 minutes at the rotation speed of 500 rotation/minute and 900 rotation/minute, wherein the mass ratio of the olive (Canarium ALBUM) leaf extract to the mixed solution is (0.1-0.15): 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 20-30% to the mixed solution is (0.02-0.05): 1, obtaining an emulsion; spray drying the emulsion to obtain microencapsulated olive (Canarium ALBUM) leaf extract;
(3) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the water are mixed according to the mass ratio of (0.4-0.9): (3-8): (93-97) uniformly mixing to obtain a mixed solution; adding the flower/leaf/stem extract of the chamomile (CHAMOMILLA RECUTITA) into the mixed solution, stirring for 60-90 seconds at the rotating speed of 11000 and 13000 r/min, then adding a glutaraldehyde aqueous solution with the mass fraction of 20-30%, stirring for 15-25 minutes at the rotating speed of 500 and 900 r/min, wherein the mass ratio of the flower/leaf/stem extract of the chamomile (CHAMOMILLA RECUTITA) to the mixed solution is (0.1-0.15): 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 20-30% to the mixed solution is (0.02-0.05): 1, obtaining an emulsion; spray drying the emulsion to obtain microencapsulated flos Matricariae Chamomillae (CHAMOMILLA RECUTITA) flower/leaf/stem extract;
(4) heating 95-105 parts by weight of water to 65-85 ℃, sequentially adding 5-9 parts by weight of sodium laureth sulfate, 1-3 parts by weight of sodium alkyl benzene sulfonate, 4-8 parts by weight of fatty alcohol-polyoxyethylene ether, 2-5 parts by weight of sodium polyacrylate and 0.1-0.7 part by weight of organic acid, and uniformly mixing by stirring at the rotation speed of 200-;
(5) cooling the mixture to 45-55 deg.C, sequentially adding 0.5-1 weight parts of microencapsulated oat (AVENASATIVA) kernel extract, 0.4-0.9 weight parts of microencapsulated olive (CANARIUM ALBUM) leaf extract, 0.4-0.9 weight parts of microencapsulated chamomile (CHAMOMILLA RECUTITA) flower/leaf/stem extract, 0.5-1 weight parts of sodium chloride, 0.1-0.5 weight parts of EDTA disodium, 0.1-0.3 weight parts of potassium hydroxide, 0.02-0.04 weight parts of essence, 0.01-0.03 weight parts of bactericide, stirring at a rotation speed of 200 and 500 revolutions/minute for 10-30min, and mixing uniformly to obtain the final product.
The sodium alkyl benzene sulfonate is sodium dodecyl benzene sulfonate or sodium hexadecyl benzene sulfonate.
The essence is lemon essence, lavender essence and grapefruit essence.
The organic acid is one or more of citric acid, chlorogenic acid and gallic acid. In one embodiment of the invention, the organic acid consists of 8-12 wt% chlorogenic acid and 88-92 wt% gallic acid.
The bactericide is methylisothiazolinone.
The fatty alcohol polyoxyethylene ether is C12-18 alkyl alcohol polyoxyethylene ether.
The invention also provides an organic bacteriostatic laundry detergent for infants, which is prepared by adopting the method.
The organic bacteriostatic laundry detergent for infants prepared by the invention is reasonably adjusted in a formula system through a large amount of researches, and is mild in performance, safe and free of stimulation; various plant extracts are added into the laundry detergent, so that the laundry effect is promoted, the decontamination capability is strong, and the bacteriostatic effect is good; no chemical residue is caused in the using process, and the washing machine is particularly suitable for washing infant clothes.
Detailed Description
Free radical scavenging test:
the organic bacteriostatic laundry detergent for infants is prepared into a sample solution with the mass concentration of 0.5% by using water, and an experiment is carried out. 4.5mL of Tris-HCl buffer (0.05 mol/L, pH 8.2) was preheated in a water bath at 25 ℃ for 20 min. Then adding 1mL of sample solution and 0.4mL of 25mmol/L pyrogallol solution, mixing uniformly, reacting in a water bath at 25 ℃ for 5min, and adding 1.0mL of 8mol/L HCl to terminate the reaction. Absorbance values were measured at 299nm with Tris-HCl buffer as a reference. Blank replaced the sample with 1mL of water. The clearance (D) was calculated according to equation (2).
Superoxide anion radical clearance (%) [1- (a2/a1) ] × 100%.
In the formula: a1 is the absorbance value of the blank; a2 is the absorbance value of the sample.
And (3) testing the antibacterial performance:
the beef extract peptone agar culture medium for bacterial culture has the following specific formula: 3.0g of beef extract, 10g of peptone, 5.0g of sodium chloride, 20g of agar and 1000mL of water are heated to melt, and the pH value is adjusted to 7.5. Subpackaging, and sterilizing under high pressure and moist heat (121 deg.C, 20min) for use.
Strain: escherichia coli (ATCC8739), Candida albicans (ATCC 10231).
Transferring the test strains to corresponding test tube slant culture medium, and repeating the strain inoculation. The bacteria are cultured in a biochemical incubator at 37 ℃ for 24h, and the mould is cultured at 28 ℃ for 48 h. 2 strains were used for the experiment, and the rest were refrigerated for further use.
Selecting colony, inoculating into plate, culturing bacteria for 24 hr, eluting with sterile normal saline, and making into 10-containing bacteria7CFU/mL of bacterial suspension. The preparation method comprises the following steps: respectively selecting a small amount of bacterial spores, washing with sterile normal saline, scattering glass beads, making into bacterial suspension, and adjusting the concentration of the bacterial suspension to 107CFU/mL, spare.
And (3) carrying out dry heat sterilization on a circular blank filter paper sheet with the diameter of 3cm at 160 ℃, and storing the blank filter paper sheet for later use under the aseptic condition. 0.1mL of the activated experimental bacterial suspension with the adjusted bacterial liquid concentration is sucked by a sterile pipettor and added into a culture dish poured with the culture medium, and the bacterial suspension is uniformly coated by a self-made glass coater sterilized by dry heat. And then, clamping the filter paper sheets by using sterile tweezers, putting the filter paper sheets on different bacteria-containing culture dishes, sucking 10 mu L of the organic infant bacteriostatic laundry detergent onto each filter paper sheet by using a sterile pipettor, and preparing two dishes for each kind of bacteria in parallel. The corresponding extraction solvent was then used as a negative control. Culturing the bacteria in a biochemical incubator at a constant temperature of 37 ℃ for 24h, measuring the diameter of a bacteriostatic circle by a cross method, and taking an average value.
In the embodiment, the polyoxyethylene sorbitan monooleate is polyoxyethylene sorbitan monooleate with the model number of T-80 provided by Jining Baichuan chemical company Limited.
Examples gum arabic, CAS number: 9000-01-5.
Examples glutaraldehyde, CAS number: 111-30-8.
In the examples, olive leaf extract was provided by the Sichuan Biotech limited.
Sodium dodecylbenzenesulfonate, CAS number: 25155-30-0.
In the embodiment, the fatty alcohol polyoxyethylene ether is the polyoxyethylene lauryl ether with the model of AEO-9 provided by Federal Fine chemical Co., Ltd.
In the embodiment, the sodium polyacrylate is food-grade sodium polyacrylate provided by Zhejiang Zhongyuan biotechnology Co.
Chlorogenic acid in examples, CAS No.: 327-97-9.
Examples gallic acid, CAS No.: 149-91-7.
Citric acid in the examples, CAS number: 77-92-9.
Examples potassium hydroxide, CAS number: 1310-58-3.
Sodium chloride in the examples, CAS No.: 7647-14-5.
Disodium EDTA, i.e. disodium EDTA, CAS number: 139-33-3.
In the examples grapefruit essence is supplied by Shanghai Lanfeng flavor Co., Ltd and is a light colored liquid in appearance.
Examples methylisothiazolinone, i.e. 2-methyl-4-isothiazolin-3-one, CAS number: 2682-20-4.
In the examples, the oat kernel extract is provided by Shaanxi forest Freund natural products Co., Ltd, and the extraction ratio is 10: 1 (i.e. 1g oat kernel extract per 10g oat kernel).
In the examples, extracts of chamomile flowers/leaves/stems were provided by Shanxi pannier Biotech limited.
Sodium laureth sulfate, CAS number: 9004-82-4, available from Chongqing Liangjie brand chemical products, Inc.
Example 1
The preparation method of the organic bacteriostatic laundry detergent for the infants comprises the following steps:
(1) heating 100 parts by weight of deionized water to 75 ℃, sequentially adding 7 parts by weight of sodium laureth sulfate, 2 parts by weight of sodium dodecyl benzene sulfonate, 6 parts by weight of fatty alcohol-polyoxyethylene ether, 3 parts by weight of sodium polyacrylate and 0.2 part by weight of citric acid, stirring at the rotating speed of 300 revolutions per minute for 20min, and uniformly mixing to obtain a mixture;
(2) cooling the mixture to 50 ℃, and then sequentially adding 0.8 weight part of oat kernel extract, 0.6 weight part of olive leaf extract, 0.6 weight part of chamomile/leaf/stem extract, 0.7 weight part of sodium chloride, 0.2 weight part of EDTA disodium, 0.15 weight part of potassium hydroxide, 0.03 weight part of grapefruit essence and 0.015 weight part of methylisothiazolinone, stirring at the rotating speed of 300 revolutions per minute for 20min, and uniformly mixing to obtain the organic baby bacteriostatic laundry detergent.
Example 2
The preparation method of the organic bacteriostatic laundry detergent for the infants comprises the following steps:
(1) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding the oat kernel extract into the mixed solution, and stirring for 70 seconds at the rotating speed of 12000 rpm, wherein the mass ratio of the oat kernel extract to the mixed solution is 0.12: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3The micro-encapsulated oat kernel extract is obtained at the speed of 300 revolutions per minute and the feeding speed of 40 mL/min;
(2) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding the olive leaf extract into the mixed solution, and stirring at 12000 rpm for 70 s, wherein the mass ratio of the olive leaf extract to the mixed solution is 0.12: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3Min, the feeding speed is 40mL/min, and the rotating speed of an atomizer is 300 revolutions per minute, so as to obtain the microencapsulated olive leaf extract;
(3) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding the chamomile flower/leaf/stem extract into the mixed solution, and stirring for 70 seconds at the rotating speed of 12000 rpm, wherein the mass ratio of the chamomile flower/leaf/stem extract to the mixed solution is 0.12: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3Min, the feeding speed is 40mL/min, and the rotating speed of an atomizer is 300 revolutions per minute, so as to obtain a microencapsulated chamomile flower/leaf/stem extract;
(4) heating 100 parts by weight of deionized water to 75 ℃, sequentially adding 7 parts by weight of sodium laureth sulfate, 2 parts by weight of sodium dodecyl benzene sulfonate, 6 parts by weight of fatty alcohol-polyoxyethylene ether, 3 parts by weight of sodium polyacrylate and 0.2 part by weight of citric acid, stirring at the rotating speed of 300 revolutions per minute for 20min, and uniformly mixing to obtain a mixture;
(5) cooling the mixture to 50 ℃, and then sequentially adding 0.8 weight part of microencapsulated oat kernel extract, 0.6 weight part of microencapsulated olive leaf extract, 0.6 weight part of microencapsulated chamomile/leaf/stem extract, 0.7 weight part of sodium chloride, 0.2 weight part of disodium EDTA, 0.15 weight part of potassium hydroxide, 0.03 weight part of grapefruit essence and 0.015 weight part of methylisothiazolinone, stirring for 20min at the rotating speed of 300 revolutions per minute, and uniformly mixing to obtain the organic infant bacteriostatic laundry detergent.
Example 3
The preparation method of the organic bacteriostatic laundry detergent for the infants comprises the following steps:
(1) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding the oat kernel extract to the mixture at 12000 rpm under stirringStirring for 70 seconds, then adding a glutaraldehyde aqueous solution with the mass fraction of 25%, and stirring for 20 minutes at the rotating speed of 600 revolutions per minute, wherein the mass ratio of the oat kernel extract to the mixed solution is 0.12: 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 25% to the mixed solution is 0.03: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3The micro-encapsulated oat kernel extract is obtained at the speed of 300 revolutions per minute and the feeding speed of 40 mL/min;
(2) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding the olive leaf extract into the mixed solution, stirring for 70 seconds at the rotating speed of 12000 rpm, adding a glutaraldehyde aqueous solution with the mass fraction of 25%, and stirring for 20 minutes at the rotating speed of 600 rpm, wherein the mass ratio of the olive leaf extract to the mixed solution is 0.12: 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 25% to the mixed solution is 0.03: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3Min, the feeding speed is 40mL/min, and the rotating speed of an atomizer is 300 revolutions per minute, so as to obtain the microencapsulated olive leaf extract;
(3) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding the chamomile flower/leaf/stem extract into the mixed solution, stirring for 70 seconds at the rotating speed of 12000 rpm, adding a glutaraldehyde aqueous solution with the mass fraction of 25%, and stirring for 20 minutes at the rotating speed of 600 rpm, wherein the mass ratio of the chamomile flower/leaf/stem extract to the mixed solution is 0.12: 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 25% to the mixed solution is 0.03: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3Min, the feeding speed is 40mL/min, and the rotating speed of an atomizer is 300 revolutions per minute, so as to obtain a microencapsulated chamomile flower/leaf/stem extract;
(4) heating 100 parts by weight of deionized water to 75 ℃, sequentially adding 7 parts by weight of sodium laureth sulfate, 2 parts by weight of sodium dodecyl benzene sulfonate, 6 parts by weight of fatty alcohol-polyoxyethylene ether, 3 parts by weight of sodium polyacrylate and 0.2 part by weight of citric acid, stirring at the rotating speed of 300 revolutions per minute for 20min, and uniformly mixing to obtain a mixture;
(5) cooling the mixture to 50 ℃, and then sequentially adding 0.8 weight part of microencapsulated oat kernel extract, 0.6 weight part of microencapsulated olive leaf extract, 0.6 weight part of microencapsulated chamomile/leaf/stem extract, 0.7 weight part of sodium chloride, 0.2 weight part of disodium EDTA, 0.15 weight part of potassium hydroxide, 0.03 weight part of grapefruit essence and 0.015 weight part of methylisothiazolinone, stirring for 20min at the rotating speed of 300 revolutions per minute, and uniformly mixing to obtain the organic infant bacteriostatic laundry detergent.
Example 4
The preparation method of the organic bacteriostatic laundry detergent for the infants comprises the following steps:
(1) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding the oat kernel extract into the mixed solution, stirring for 70 seconds at the rotating speed of 12000 rpm, adding a glutaraldehyde aqueous solution with the mass fraction of 25%, and stirring for 20 minutes at the rotating speed of 600 rpm, wherein the mass ratio of the oat kernel extract to the mixed solution is 0.12: 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 25% to the mixed solution is 0.03: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3The micro-encapsulated oat kernel extract is obtained at the speed of 300 revolutions per minute and the feeding speed of 40 mL/min;
(2) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding folium Canarii albi extract into the mixed solution, stirring at 12000 rpm for 70 s, adding 25% glutaraldehyde water solution, stirring at 600 rpm for 20min, wherein the mass ratio of folium Canarii albi extract to the mixed solutionIs 0.12: 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 25% to the mixed solution is 0.03: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3Min, the feeding speed is 40mL/min, and the rotating speed of an atomizer is 300 revolutions per minute, so as to obtain the microencapsulated olive leaf extract;
(3) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding the chamomile flower/leaf/stem extract into the mixed solution, stirring for 70 seconds at the rotating speed of 12000 rpm, adding a glutaraldehyde aqueous solution with the mass fraction of 25%, and stirring for 20 minutes at the rotating speed of 600 rpm, wherein the mass ratio of the chamomile flower/leaf/stem extract to the mixed solution is 0.12: 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 25% to the mixed solution is 0.03: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3Min, the feeding speed is 40mL/min, and the rotating speed of an atomizer is 300 revolutions per minute, so as to obtain a microencapsulated chamomile flower/leaf/stem extract;
(4) heating 100 parts by weight of deionized water to 75 ℃, sequentially adding 7 parts by weight of sodium laureth sulfate, 2 parts by weight of sodium dodecyl benzene sulfonate, 6 parts by weight of fatty alcohol-polyoxyethylene ether, 3 parts by weight of sodium polyacrylate and 0.2 part by weight of chlorogenic acid, stirring at the rotating speed of 300 revolutions per minute for 20min, and uniformly mixing to obtain a mixture;
(5) cooling the mixture to 50 ℃, and then sequentially adding 0.8 weight part of microencapsulated oat kernel extract, 0.6 weight part of microencapsulated olive leaf extract, 0.6 weight part of microencapsulated chamomile/leaf/stem extract, 0.7 weight part of sodium chloride, 0.2 weight part of disodium EDTA, 0.15 weight part of potassium hydroxide, 0.03 weight part of grapefruit essence and 0.015 weight part of methylisothiazolinone, stirring for 20min at the rotating speed of 300 revolutions per minute, and uniformly mixing to obtain the organic infant bacteriostatic laundry detergent.
Example 5
The preparation method of the organic bacteriostatic laundry detergent for the infants comprises the following steps:
(1) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding the oat kernel extract into the mixed solution, stirring for 70 seconds at the rotating speed of 12000 rpm, adding a glutaraldehyde aqueous solution with the mass fraction of 25%, and stirring for 20 minutes at the rotating speed of 600 rpm, wherein the mass ratio of the oat kernel extract to the mixed solution is 0.12: 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 25% to the mixed solution is 0.03: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3The micro-encapsulated oat kernel extract is obtained at the speed of 300 revolutions per minute and the feeding speed of 40 mL/min;
(2) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding the olive leaf extract into the mixed solution, stirring for 70 seconds at the rotating speed of 12000 rpm, adding a glutaraldehyde aqueous solution with the mass fraction of 25%, and stirring for 20 minutes at the rotating speed of 600 rpm, wherein the mass ratio of the olive leaf extract to the mixed solution is 0.12: 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 25% to the mixed solution is 0.03: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3Min, the feeding speed is 40mL/min, and the rotating speed of an atomizer is 300 revolutions per minute, so as to obtain the microencapsulated olive leaf extract;
(3) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding the chamomile flower/leaf/stem extract into the mixed solution, stirring for 70 seconds at the rotating speed of 12000 rpm, adding a glutaraldehyde aqueous solution with the mass fraction of 25%, and stirring for 20 minutes at the rotating speed of 600 rpm, wherein the mass ratio of the chamomile flower/leaf/stem extract to the mixed solution is 0.12: 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 25% to the mixed solution is 0.03: 1, obtaining an emulsion; subjecting the emulsion toSpray drying with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3Min, the feeding speed is 40mL/min, and the rotating speed of an atomizer is 300 revolutions per minute, so as to obtain a microencapsulated chamomile flower/leaf/stem extract;
(4) heating 100 parts by weight of deionized water to 75 ℃, sequentially adding 7 parts by weight of sodium laureth sulfate, 2 parts by weight of sodium dodecyl benzene sulfonate, 6 parts by weight of fatty alcohol-polyoxyethylene ether, 3 parts by weight of sodium polyacrylate and 0.2 part by weight of gallic acid, stirring at the rotating speed of 300 revolutions per minute for 20min, and uniformly mixing to obtain a mixture;
(5) cooling the mixture to 50 ℃, and then sequentially adding 0.8 weight part of microencapsulated oat kernel extract, 0.6 weight part of microencapsulated olive leaf extract, 0.6 weight part of microencapsulated chamomile/leaf/stem extract, 0.7 weight part of sodium chloride, 0.2 weight part of disodium EDTA, 0.15 weight part of potassium hydroxide, 0.03 weight part of grapefruit essence and 0.015 weight part of methylisothiazolinone, stirring for 20min at the rotating speed of 300 revolutions per minute, and uniformly mixing to obtain the organic infant bacteriostatic laundry detergent.
Example 6
The preparation method of the organic bacteriostatic laundry detergent for the infants comprises the following steps:
(1) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding the oat kernel extract into the mixed solution, stirring for 70 seconds at the rotating speed of 12000 rpm, adding a glutaraldehyde aqueous solution with the mass fraction of 25%, and stirring for 20 minutes at the rotating speed of 600 rpm, wherein the mass ratio of the oat kernel extract to the mixed solution is 0.12: 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 25% to the mixed solution is 0.03: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3The micro-encapsulated oat kernel extract is obtained at the speed of 300 revolutions per minute and the feeding speed of 40 mL/min;
(2) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring at a rotation speed of 600 rpmUniformly mixing for 10 minutes to obtain a mixed solution; adding the olive leaf extract into the mixed solution, stirring for 70 seconds at the rotating speed of 12000 rpm, adding a glutaraldehyde aqueous solution with the mass fraction of 25%, and stirring for 20 minutes at the rotating speed of 600 rpm, wherein the mass ratio of the olive leaf extract to the mixed solution is 0.12: 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 25% to the mixed solution is 0.03: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3Min, the feeding speed is 40mL/min, and the rotating speed of an atomizer is 300 revolutions per minute, so as to obtain the microencapsulated olive leaf extract;
(3) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the deionized water are mixed according to the mass ratio of 0.65: 5: 95 stirring the mixture for 10 minutes at the rotating speed of 600 revolutions per minute to be uniformly mixed to obtain a mixed solution; adding the chamomile flower/leaf/stem extract into the mixed solution, stirring for 70 seconds at the rotating speed of 12000 rpm, adding a glutaraldehyde aqueous solution with the mass fraction of 25%, and stirring for 20 minutes at the rotating speed of 600 rpm, wherein the mass ratio of the chamomile flower/leaf/stem extract to the mixed solution is 0.12: 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 25% to the mixed solution is 0.03: 1, obtaining an emulsion; spray drying the emulsion with air inlet temperature of 170 deg.C, air outlet temperature of 75 deg.C, and hot air speed of 4m3Min, the feeding speed is 40mL/min, and the rotating speed of an atomizer is 300 revolutions per minute, so as to obtain a microencapsulated chamomile flower/leaf/stem extract;
(4) heating 100 parts by weight of deionized water to 75 ℃, sequentially adding 7 parts by weight of sodium laureth sulfate, 2 parts by weight of sodium dodecyl benzene sulfonate, 6 parts by weight of fatty alcohol-polyoxyethylene ether, 3 parts by weight of sodium polyacrylate, 0.02 part by weight of chlorogenic acid and 0.18 part by weight of gallic acid, stirring at the rotating speed of 300 revolutions per minute for 20min, and uniformly mixing to obtain a mixture;
(5) cooling the mixture to 50 ℃, and then sequentially adding 0.8 weight part of microencapsulated oat kernel extract, 0.6 weight part of microencapsulated olive leaf extract, 0.6 weight part of microencapsulated chamomile/leaf/stem extract, 0.7 weight part of sodium chloride, 0.2 weight part of disodium EDTA, 0.15 weight part of potassium hydroxide, 0.03 weight part of grapefruit essence and 0.015 weight part of methylisothiazolinone, stirring for 20min at the rotating speed of 300 revolutions per minute, and uniformly mixing to obtain the organic infant bacteriostatic laundry detergent. The performance of the antibacterial laundry detergent for organic babies is tested, and the result is as follows: the diameter of a bacteriostasis zone of escherichia coli is 18mm, the diameter of a bacteriostasis zone of candida albicans is 17mm, and the scavenging rate of superoxide anion free radicals is 97.2%.
Test example 1
The performance of the organic bacteriostatic laundry detergent prepared in the examples 1-5 was tested. The specific test results are shown in table 1.
Table 1: test result table
The plant extract is subjected to microencapsulation treatment, so that the performance of the laundry detergent is remarkably improved, and the reason probably is that the plant extract is prepared into the microcapsule, so that the activity of effective components of the plant extract is favorably kept, the specific surface area of the laundry detergent, which is contacted with a fabric, is increased, and the washing effect is improved.
Claims (6)
1. The preparation method of the organic bacteriostatic laundry detergent for the infants is characterized by comprising the following steps of:
(1) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the water are mixed according to the mass ratio of (0.4-0.9): (3-8): (93-97) uniformly mixing to obtain a mixed solution; adding the oat kernel extract into the mixed solution, stirring for 60-90 seconds at the rotating speed of 11000-13000 rpm, then adding a glutaraldehyde aqueous solution with the mass fraction of 20-30%, stirring for 15-25 minutes at the rotating speed of 500-900 rpm, wherein the mass ratio of the oat kernel extract to the mixed solution is (0.1-0.15): 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 20-30% to the mixed solution is (0.02-0.05): 1, obtaining an emulsion; spray drying the emulsion to obtain microencapsulated oat kernel extract;
(2) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the water are mixed according to the mass ratio of (0.4-0.9): (3-8): (93-97) uniformly mixing to obtain a mixed solution; adding the olive leaf extract into the mixed solution, stirring for 60-90 seconds at the rotating speed of 11000-13000 rpm, adding a glutaraldehyde aqueous solution with the mass fraction of 20-30%, and stirring for 15-25 minutes at the rotating speed of 500-900 rpm, wherein the mass ratio of the olive leaf extract to the mixed solution is (0.1-0.15): 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 20-30% to the mixed solution is (0.02-0.05): 1, obtaining an emulsion; spray drying the emulsion to obtain microencapsulated olive leaf extract;
(3) the sorbitan monooleate polyoxyethylene ether, the Arabic gum and the water are mixed according to the mass ratio of (0.4-0.9): (3-8): (93-97) uniformly mixing to obtain a mixed solution; adding the chamomile/leaf/stem extract into the mixed solution, stirring for 60-90 seconds at the rotation speed of 11000-13000 r/m, then adding a glutaraldehyde aqueous solution with the mass fraction of 20-30%, stirring for 15-25 minutes at the rotation speed of 500-900 r/m, wherein the mass ratio of the chamomile/leaf/stem extract to the mixed solution is (0.1-0.15): 1, the mass ratio of the glutaraldehyde aqueous solution with the mass fraction of 20-30% to the mixed solution is (0.02-0.05): 1, obtaining an emulsion; spray drying the emulsion to obtain microencapsulated flos Matricariae Chamomillae/leaf/stem extract;
(4) heating 95-105 parts by weight of water to 65-85 ℃, sequentially adding 5-9 parts by weight of sodium laureth sulfate, 1-3 parts by weight of sodium alkyl benzene sulfonate, 4-8 parts by weight of fatty alcohol-polyoxyethylene ether, 2-5 parts by weight of sodium polyacrylate and 0.1-0.7 part by weight of organic acid, and uniformly mixing by stirring at the rotation speed of 200-;
(5) cooling the mixture to 45-55 ℃, and then sequentially adding 0.5-1 part by weight of microencapsulated oat kernel extract, 0.4-0.9 part by weight of microencapsulated olive leaf extract, 0.4-0.9 part by weight of microencapsulated chamomile/leaf/stem extract, 0.5-1 part by weight of sodium chloride, 0.1-0.5 part by weight of EDTA disodium, 0.1-0.3 part by weight of potassium hydroxide, 0.02-0.04 part by weight of essence and 0.01-0.03 part by weight of bactericide, stirring at the rotation speed of 200 and 500 revolutions per minute for 10-30min, and uniformly mixing to obtain the oat extract-based bactericidal composition;
the organic acid is mixture of chlorogenic acid and gallic acid.
2. The preparation method of the organic bacteriostatic laundry detergent for infants as claimed in claim 1, which is characterized in that: the sodium alkyl benzene sulfonate is sodium dodecyl benzene sulfonate or sodium hexadecyl benzene sulfonate.
3. The preparation method of the organic bacteriostatic laundry detergent for infants as claimed in claim 1, which is characterized in that: the essence is lemon essence, lavender essence and grapefruit essence.
4. The preparation method of the organic bacteriostatic laundry detergent for infants as claimed in claim 1, which is characterized in that: the bactericide is methylisothiazolinone.
5. The preparation method of the organic bacteriostatic laundry detergent for infants as claimed in claim 1, which is characterized in that: the fatty alcohol polyoxyethylene ether is C12-18 alkyl alcohol polyoxyethylene ether.
6. An organic bacteriostatic laundry detergent for infants, which is prepared by the method of any one of claims 1 to 5.
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