CN107810979A - A kind of hygienic insecticide of containing fipronil and oil of badian - Google Patents
A kind of hygienic insecticide of containing fipronil and oil of badian Download PDFInfo
- Publication number
- CN107810979A CN107810979A CN201711002379.XA CN201711002379A CN107810979A CN 107810979 A CN107810979 A CN 107810979A CN 201711002379 A CN201711002379 A CN 201711002379A CN 107810979 A CN107810979 A CN 107810979A
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- CN
- China
- Prior art keywords
- badian
- oil
- ethiprole
- hygienic insecticide
- cockroach
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Pest Control & Pesticides (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of containing fipronil and the hygienic insecticide of oil of badian, it is made up of the active ingredient and phagostimulant, excipient, preservative, NMF, the uniform mixture of water that are formed with ethiprole and oil of badian, the weight ratio of ethiprole and oil of badian is 3:1~1:5.It is high-efficiency low-toxicity of the present invention, safe and reliable, it can effectively control the cockroach in the indoor place such as residence, dining room, hotel, office to endanger.
Description
Technical field
The present invention relates to daily chemical product, hygienic insecticide, more particularly to a kind of containing fipronil and oil of badian
Hygienic insecticide.
Background technology
Blattaria (being commonly called as cockroach) likes appearing in the place of human lives, and the health hazard to the mankind is serious, and it takes everywhere
Eat, creeping spreads disease, cockroach can also be from a kind of grease of special stench be secreted, in food and tableware and day in vivo in addition
Peculiar smell and multiple pathogens are left when being creeped on conventional tool, it has also become maximum city insect.
At present, the preventing and treating of cockroach is still based on chemical prevention, and ethiprole (fipronil) is used as most of Cockroach-killing drugs
The main component of agent, because of long-term single use, there are urban reflection cockroach resistance increase, the phenomenon that drug effect reduces.
Therefore the resistance of cockroach how is delayed, extend ethiprole is a reality and asking urgently as the life cycle of hygienic insecticide
Topic.
With reference to the characteristics of chemical prevention, compounded by using the composition of different mechanism of action, be to solve chemical pesticide resistance
One quick and simple approach of problem.Screened by formulation of pesticide, draw and mixed in certain ratio range between heterogeneity
With with synergistic function, it is possible to increase actual prevention effect, be the important means for administering pest and disease damage resistance.
Oil of badian be Magnoliacea plant Chinese anise (Illicium verum Hook.f.) fresh branches and leaves or into
The volatile oil that ripe fruit obtains through steam distillation, it is a kind of conventional Chinese medicine.Oil of badian has certain insecticidal activity, such as specially
Sharp application number：2008100735360 point out that oil of badian has good deterrent effect to grain storage pest, must also smoke
Steam, action of contace poison.
At present, related report is not shown in the research for ethiprole being used to prevent and treat to sanitary insect pest to oil of badian mixture also
Road.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of hygienic insecticide of containing fipronil and oil of badian, its
It is high-efficiency low-toxicity, safe and reliable, it can effectively control the cockroach in the indoor place such as residence, dining room, hotel, office to endanger.
The present invention uses following technical scheme：A kind of hygienic insecticide of containing fipronil and oil of badian, by with fluorine worm
The active ingredient and the uniform mixture of phagostimulant, excipient, preservative, NMF, water of nitrile and oil of badian composition are made, fluorine worm
The weight of nitrile and oil of badian ratio is 3:1~1:5.
Preferably, the weight of ethiprole and oil of badian ratio is 1:2.
Described hygienic insecticide, the percentage by weight of ethiprole are 0.02-0.1%, the weight percent of oil of badian
Than for 0.02-0.2%.
Described phagostimulant is selected from one or more combinations of fish meal, cracker meal, analysis for soybean powder, corn flour, starch, white sugar.
One or more combinations of the excipient in guar gum, hydroxyethyl cellulose.
One or more combinations of the preservative in Nipagin complex esters, potassium sorbate, sodium benzoate.
One or more combinations of the NMF in glycerine, propane diols, polyethylene glycol.
Described hygienic insecticide prepares glue bait formulation common in any art, and compound method is：According to recipe requirements, divide
Also known as take active ingredient, phagostimulant, excipient, preservative, the weight of NMF.Excipient and NMF are thoroughly mixed
Scattered 30 minutes, addition water fully dissolves standby；Phagostimulant, preservative, active ingredient are put into the solution above prepared again
In, then stir, produce the cockroach-killing gel bait of the present invention.
Compared with prior art, the present invention possesses following technique effect：
(1) active ingredient of the invention is used with rational ratio range, and Synergistic is notable, can greatly improve medicine
Effect, pesticide cost is reduced, is advantageous to delay pest resistance to develop, extend Life Cycle of the ethiprole in health pest control field
Phase.
(2) palatability of the present invention is good, and allure is strong, safe, and outward appearance is fine and smooth, is unlikely to deteriorate and distributes unhappy gas
Taste.
Embodiment
Below in conjunction with embodiment, the present invention is further detailed explanation, and percentage of the present invention is
Percentage by weight.
First, embodiment is prepared
Embodiment 1：0.06% ethiprole oil of badian cockroach-killing gel bait
Formula：Ethiprole 0.02%, oil of badian 0.04%, Nipagin complex esters 0.2g, ethoxy fibre are weighed according to quantity
Dimension element 0.4%, glycerine 18.0%, starch 12.0%, white sugar 5.0%, water complements to 100%.
Embodiment 2：0.15% ethiprole oil of badian cockroach-killing gel bait
Formula：Weigh ethiprole 0.05% according to quantity, oil of badian 0.1%, potassium sorbate 0.2g, guar gum 0.5%, third
Glycol 15.0%, fish meal 12.0%, white sugar 3.0%, water complements to 100%.
Embodiment 3：0.3% ethiprole oil of badian cockroach-killing gel bait
Formula：Ethiprole 0.1%, oil of badian 0.2%, sodium benzoate 0.5g, hydroxyethyl cellulose are weighed according to quantity
0.5%, polyethylene glycol 10.0%, cracker meal 15.0%, white sugar 2.0%, water complements to 100%.
Embodiment 4：0.04% ethiprole oil of badian cockroach-killing gel bait
Formula：Ethiprole 0.02%, oil of badian 0.02%, Nipagin complex esters 0.2g, ethoxy fibre are weighed according to quantity
Dimension element 0.5%, glycerine 12.0%, analysis for soybean powder 10.0%, corn flour 5.0%, water complements to 100%.
The preparation method of the cockroach-killing gel bait of the present invention is as follows：According to the part by weight of above-mentioned each raw material, weigh respectively effectively
Composition, phagostimulant, excipient, preservative, the weight of NMF.Excipient and NMF are thoroughly mixed scattered 30 points
Clock, addition water fully dissolve standby；Phagostimulant, preservative, active ingredient are put into the solution above prepared again, then fully
Stir, produce the cockroach-killing gel bait of the present invention.
2nd, Toxicity Determination is tested
Embodiment 1：The indoor pharmacodynamic test of ethiprole, oil of badian and its mixture to Groton bug
Experimental design：Indoor pharmacodynamic test, using stomach toxicity method, square box device.The valid density of each medicament is determined through prerun
After scope, ethiprole, oil of badian and its mixture are pressed into 5 concentration of active constituent content gradient dilution as glue bait medicine to be measured
Agent.120 Groton bugs are put into the square box device for being turned off door by putting worm channel, stoppers and puts worm channel.Treat that test worm recovers normal
After activity, glue bait medicament to be measured is placed respectively in case inner opposite angle line, center, which is placed, fills immersion cotton balls culture dish.Day by day observation examination
Worm death condition, and dead test worm taken out, numeration, the 12nd day after Continuous Observation to bait throwing in.If using chow diet raising as sky
White control.Each off-test, clean experimental rig.
Using the logarithm value of drug concentration (mg/kg) as independent variable x, using the probit value of corrected mortality as y, with DPS softwares
Calculate LC50And virulence regression equation, the co-toxicity coefficient (CTC) of each mixed ratio is obtained using Sun Yunpei method, and evaluate two
When the synergistic effect that person uses with, i.e. co-toxicity coefficient (CTC) >=120, composition shows as synergistic effect；As CTC≤80, combination
Thing shows as antagonism；As 80 ＜ CTC ＜ 120, composition shows as summation action.
3rd, result of the test is shown in Table 1.
The Toxicity Determination table of the ethiprole of table 1, oil of badian and mixture to Groton bug
| Reagent agent | Proportioning | LD50(mg/kg) | Survey toxicity index | Theoretical toxicity index | Co-toxicity coefficient (CTC) |
| Ethiprole (A) | / | 0.72 | 482.39 | / | / |
| Oil of badian (B) | / | 3.48 | 100.00 | / | / |
| A:B | 3:1 | 0.70 | 493.51 | 386.79 | 127.6 |
| A:B | 2:1 | 0.73 | 476.57 | 354.92 | 134.3 |
| A:B | 1:1 | 0.71 | 489.56 | 291.19 | 168.1 |
| A:B | 1:2 | 0.64 | 539.92 | 227.46 | 237.4 |
| A:B | 1:3 | 1.02 | 342.37 | 195.60 | 175.0 |
| A:B | 1:5 | 1.30 | 268.01 | 163.73 | 163.7 |
| A:B | 10:1 | 1.02 | 341.25 | 447.62 | 76.2 |
The joint toxicity measuring result of table 1 shows, ethiprole and oil of badian are 3 in weight ratio:1~1:Mixed in the range of 5
The co-toxicity coefficient (CTC) of pairing Groton bug is all higher than 120, has synergistic function；When ethiprole and oil of badian
Weight ratio is 1:When 2, co-toxicity coefficient is maximum, is 237.4, and synergy is more notable, well should have in the preventing and treating of sanitary insect pest
With value.
3rd, field efficacy experiment is simulated
Embodiment 1：Prepare preparation (0.06% ethiprole oil of badian cockroach-killing gel bait) the preventing and treating moral of the gained of embodiment 1
The small Lian of state simulation field efficacy experiment
Experimental design：Simulation sets cockroach to conceal place in scene.100 Groton bugs of the same size are discharged in simulation
In scene.After test worm recovers normal activity, to be measured kill diagonally is placed in the room for recommending dosage throughout to manage according to the present invention
In roach glue bait medicament and two culture dishes, the culture dish of cockroach feed is contained in another diagonal placement, is placed in parallel by each culture dish
One culture dish for filling immersion cotton balls.The method and weight of the launched cockroach-killing gel bait of each processing are consistent, close the doors and windows, and count
When.Check daily and record dead borer population, 12d after Continuous Observation to bait throwing in.
The medicament of the cockroach-killing gel bait respectively handled is as follows：
Handle 1#：Prepare the preparation of the gained of embodiment 1, i.e. 0.06% ethiprole oil of badian cockroach-killing gel bait.
Handle 2#：0.06% ethiprole cockroach-killing gel bait.
Handle 3#：0.15% oil of badian cockroach-killing gel bait.
Handle 4#：Blank control (CK), not delivering medicament.
Result of the test is shown in Table 2.
Table 2：Test of pesticide effectiveness statistical form of the 0.06% ethiprole oil of badian cockroach-killing gel bait to Groton bug
From indoor harmacological effect result (table 2), tried according to GB/T 13917.7-2009 agriculture chemical registration with hygienic insecticide in
The test of pesticide effectiveness and evaluation criterion, the indoor medicine of 0.06% ethiprole oil of badian cockroach-killing gel bait of the invention to Groton bug
Imitate as A levels.The synergistic effect of two kinds of compositions of the invention simultaneously, help to reduce the dosage of chemical composition ethiprole.
Claims (7)
1. the hygienic insecticide of a kind of containing fipronil and oil of badian, it is characterised in that by with ethiprole and oil of badian
The active ingredient and phagostimulant of composition, excipient, preservative, NMF, the uniform mixture of water are made, ethiprole and oil of badian
Weight ratio be 3:1~1:5.
2. hygienic insecticide according to claim 1, it is characterised in that the weight of ethiprole and oil of badian ratio is 1:
2。
3. hygienic insecticide according to claim 1 or 2, it is characterised in that the percentage by weight of ethiprole is 0.02-
0.1%, the percentage by weight of oil of badian is 0.02-0.2%.
4. hygienic insecticide according to claim 1, it is characterised in that described phagostimulant is selected from fish meal, cracker meal, Huang
One or more combinations of bean powder, corn flour, starch, white sugar.
5. hygienic insecticide according to claim 1, it is characterised in that it is fine that the excipient is selected from guar gum, ethoxy
One or more combinations in dimension element.
6. hygienic insecticide according to claim 1, it is characterised in that the preservative is selected from Nipagin complex esters, mountain
One or more combinations in potassium sorbate, sodium benzoate.
7. hygienic insecticide according to claim 1, it is characterised in that the NMF is selected from glycerine, propane diols, poly- second
One or more combinations in glycol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711002379.XA CN107810979A (en) | 2017-10-24 | 2017-10-24 | A kind of hygienic insecticide of containing fipronil and oil of badian |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711002379.XA CN107810979A (en) | 2017-10-24 | 2017-10-24 | A kind of hygienic insecticide of containing fipronil and oil of badian |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107810979A true CN107810979A (en) | 2018-03-20 |
Family
ID=61607531
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711002379.XA Pending CN107810979A (en) | 2017-10-24 | 2017-10-24 | A kind of hygienic insecticide of containing fipronil and oil of badian |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112205397A (en) * | 2020-10-13 | 2021-01-12 | 中国烟草总公司海南省公司 | Ant food attractant and application thereof |
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|---|---|---|---|---|
| CN101248804A (en) * | 2008-04-15 | 2008-08-27 | 广西钦州谷虫净总厂 | Deltamethrin and badian oil insecticidal composition |
| CN101305721A (en) * | 2008-07-17 | 2008-11-19 | 浙江省农业科学院 | Fipronil microcapsule suspension hygienic insecticide and its preparation method |
| CN102036668A (en) * | 2008-03-19 | 2011-04-27 | 蒂拉德克公司 | Pest control compositions and methods |
| CN103734155A (en) * | 2013-12-27 | 2014-04-23 | 广西科技大学 | Cockroach bait gel |
| CN104509545A (en) * | 2013-09-29 | 2015-04-15 | 青岛好利特生物农药有限公司 | Insecticide prepared from fipronil |
-
2017
- 2017-10-24 CN CN201711002379.XA patent/CN107810979A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102036668A (en) * | 2008-03-19 | 2011-04-27 | 蒂拉德克公司 | Pest control compositions and methods |
| CN101248804A (en) * | 2008-04-15 | 2008-08-27 | 广西钦州谷虫净总厂 | Deltamethrin and badian oil insecticidal composition |
| CN101305721A (en) * | 2008-07-17 | 2008-11-19 | 浙江省农业科学院 | Fipronil microcapsule suspension hygienic insecticide and its preparation method |
| CN104509545A (en) * | 2013-09-29 | 2015-04-15 | 青岛好利特生物农药有限公司 | Insecticide prepared from fipronil |
| CN103734155A (en) * | 2013-12-27 | 2014-04-23 | 广西科技大学 | Cockroach bait gel |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112205397A (en) * | 2020-10-13 | 2021-01-12 | 中国烟草总公司海南省公司 | Ant food attractant and application thereof |
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