CN107780252A - 一种用于猪毛印染的防静电染料 - Google Patents

一种用于猪毛印染的防静电染料 Download PDF

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CN107780252A
CN107780252A CN201710978852.1A CN201710978852A CN107780252A CN 107780252 A CN107780252 A CN 107780252A CN 201710978852 A CN201710978852 A CN 201710978852A CN 107780252 A CN107780252 A CN 107780252A
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杨荣能
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Wuwei County High Honour Bristle Brush Products Co Ltd
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Abstract

本发明公开了一种用于猪毛印染的防静电染料，其原料包括偶氮二异丁腈、硫酸钠、碳纤维、氨基邻甲酚、乙二醇硬脂酸酯、辛基酚聚氧乙烯醚、邻苯二甲酸二酯、碳酸钠、对氨基苯甲酸、间苯二胺、十二醇硫酸钠、单甘脂、对甲基苯胺、防静电助剂、耐热改性助剂和水。本发明的猪毛印染染料具有优异的防静电性能。

Description

一种用于猪毛印染的防静电染料
技术领域
本发明涉及染料的技术领域，尤其涉及一种用于猪毛印染的防静电染料。
背景技术
有机染料由有机化合物制成的一类染料。染料特性包括耐晒、耐水浸、耐酸、耐碱、耐有机溶剂、耐热、晶型稳定、分散性和遮盖力等。有机染料通常具有较高的着色力，颗粒容易研磨和分散、不易沉淀，色彩也较鲜艳，但耐晒、耐热、耐候性能较差。有机颜料普遍用于油墨、涂料、橡胶制品、塑料制品、文教用品和建筑材料等物料的着色。猪毛在印染时所使用的染料，防静电性能无法满足实际使用时的需求，故此亟需开发一种用于猪毛印染的防静电染料来解决现有技术中的问题。
发明内容
为解决背景技术中存在的技术问题，本发明提出一种用于猪毛印染的防静电染料，具有优异的防静电性能。
本发明提出的一种用于猪毛印染的防静电染料，其原料按重量份包括：偶氮二异丁腈10-20份、硫酸钠5-15份、碳纤维4-8份、氨基邻甲酚3-9份、乙二醇硬脂酸酯2-5份、辛基酚聚氧乙烯醚1-5份、邻苯二甲酸二酯3-8份、碳酸钠2-8份、对氨基苯甲酸1-5份、间苯二胺3-9份、十二醇硫酸钠2-5份、单甘脂1-4份、对甲基苯胺3-9份、防静电助剂4-8份、耐热改性助剂6-12份、水10-20份。
优选地，防静电助剂的原料按重量份包括：去离子水10-20份、叔丁醇5-15份、2,3-环氧丙基三甲基氯化铵4-9份、异丙醇2-6份、纳米硅藻土1-5份、氢氧化镁3-9份、氧化铝2-6份、蒙脱土1-4份、纳米硼酸锌4-8份、碳化硅2-7份、氟化碳1-5份、硅微粉2-9份、石英粉1-4份、钼酸钠3-9份、陶瓷微粉4-9份、白玉刚粉2-9份、苯乙烯1-5份、丙烯酸异辛酯4-9份、硅酸乙酯2-6份、有机硅单体1-6份、乙烯基硅油2-8份、二氧化硅气凝胶3-9份、二甲基甲酰胺1-5份、质量分数为5-15％的过硫酸钾溶液4-9份。
优选地，防静电助剂按如下工艺进行制备：将去离子水、叔丁醇、2,3-环氧丙基三甲基氯化铵、异丙醇、纳米硅藻土、氢氧化镁、氧化铝、蒙脱土、纳米硼酸锌、碳化硅、氟化碳、硅微粉、石英粉、钼酸钠、陶瓷微粉和白玉刚粉末投入反应釜中混合均匀，加热，保温，冷却至室温得到物料a；然后将苯乙烯、丙烯酸异辛酯、硅酸乙酯和有机硅单体加入物料a中搅拌均匀，升温，保温，冷却至室温得到物料b；将乙烯基硅油、二氧化硅气凝胶及二甲基甲酰胺加入物料b中，搅拌，得到物料c；向物料c中加入质量分数为5-15％的过硫酸钾溶液，然后升温，保温，冷却至室温，得到物料d；然后用氨水调解物料d的pH值至中性，过滤出料，得到防静电助剂。
优选地，防静电助剂按如下工艺进行制备：将去离子水、叔丁醇、2,3-环氧丙基三甲基氯化铵、异丙醇、纳米硅藻土、氢氧化镁、氧化铝、蒙脱土、纳米硼酸锌、碳化硅、氟化碳、硅微粉、石英粉、钼酸钠、陶瓷微粉和白玉刚粉末投入反应釜中混合均匀，加热至60-70℃，保温1-2h，冷却至室温得到物料a；然后将苯乙烯、丙烯酸异辛酯、硅酸乙酯和有机硅单体加入物料a中搅拌均匀，升温至80-90℃，保温1-3h，冷却至室温得到物料b；将乙烯基硅油、二氧化硅气凝胶及二甲基甲酰胺加入物料b中，搅拌20-50min，得到物料c；向物料c中加入质量分数为5-15％的过硫酸钾溶液，然后升温至60-65℃，保温20-30min，冷却至室温，得到物料d；然后用氨水调解物料d的pH值至中性，过滤出料，得到防静电助剂。
优选地，耐热改性助剂的原料按重量份包括：纳米碳管10-20份、二氯乙烷2-6份、亚硫酰氯1-5份、2-丙烯-1-醇3-9份、聚丙烯2-9份、纳米氢氧化铝1-5份、多聚磷酸铝2-8份、聚四氟乙烯4-9份、纳米石墨3-9份、炭黑2-5份、重晶石粉1-5份、纳米二氧化硅4-8份、云母粉3-8份、滑石粉2-5份、季戊四醇三丙烯酸酯3-9份、硅烷偶联剂KH-570 4-9份。
优选地，耐热改性助剂按如下工艺进行制备：将纳米碳管和二氯乙烷混合均匀，超声处理，接着加入亚硫酰氯混合均匀，磁力搅拌，接着升温，回流20-30h，冷却至室温后加入2-丙烯-1-醇混合均匀，接着升温，搅拌，洗涤，离心分离后，将固体干燥，冷却至室温得到物料A；将聚丙烯、纳米氢氧化铝和多聚磷酸铝混合均匀，加热，保温，冷却至常温，然后加入聚四氟乙烯球磨，得物料B；将纳米石墨、炭黑、重晶石粉、纳米二氧化硅、云母粉和滑石粉混合均匀，加热，保温，然后加入季戊四醇三丙烯酸酯和硅烷偶联剂KH-570搅拌至常温得到物料b，然后将物料A和物料B混合均匀，烘干，研磨，冷却至室温得到耐热改性助剂。
优选地，耐热改性助剂按如下工艺进行制备：将纳米碳管和二氯乙烷混合均匀，超声处理1-3h，接着加入亚硫酰氯混合均匀，磁力搅拌20-40min，接着升温至80-90℃，回流20-30h，冷却至室温后加入2-丙烯-1-醇混合均匀，接着升温至45-55℃，搅拌22-26h，洗涤1-4次，离心分离后，将固体于40-50℃干燥6-12h，冷却至室温得到物料A；将聚丙烯、纳米氢氧化铝和多聚磷酸铝混合均匀，加热至450-500℃，保温10-20min，冷却至常温，然后加入聚四氟乙烯球磨8-16min，得物料B；将纳米石墨、炭黑、重晶石粉、纳米二氧化硅、云母粉和滑石粉混合均匀，加热至70-90℃，保温5-15min，然后加入季戊四醇三丙烯酸酯和硅烷偶联剂KH-570搅拌至常温得到物料b，然后将物料A和物料B混合均匀，烘干，研磨，冷却至室温得到耐热改性助剂。
本发明的一种用于猪毛印染的防静电染料，其原料包括偶氮二异丁腈、硫酸钠、碳纤维、氨基邻甲酚、乙二醇硬脂酸酯、辛基酚聚氧乙烯醚、邻苯二甲酸二酯、碳酸钠、对氨基苯甲酸、间苯二胺、十二醇硫酸钠、单甘脂、对甲基苯胺、防静电助剂、耐热改性助剂和水，其中以偶氮二异丁腈为主料，以硫酸钠、碳纤维、氨基邻甲酚、乙二醇硬脂酸酯、辛基酚聚氧乙烯醚、邻苯二甲酸二酯、碳酸钠、对氨基苯甲酸、间苯二胺、十二醇硫酸钠、单甘脂和对甲基苯胺为主料的增强料，以防静电助剂和耐热改性助剂为补强改性助剂，通过主料、主料增强料和补强改性助剂配合，得到的猪毛印染染料具有优异的防静电性能。其中，防静电助剂通过将去离子水、叔丁醇、2,3-环氧丙基三甲基氯化铵、异丙醇、纳米硅藻土、氢氧化镁、氧化铝、蒙脱土、纳米硼酸锌、碳化硅、氟化碳、硅微粉、石英粉、钼酸钠、陶瓷微粉和白玉刚粉末投入反应釜中混合均匀，加热，保温，冷却至室温得到物料a；然后将苯乙烯、丙烯酸异辛酯、硅酸乙酯和有机硅单体加入物料a中搅拌均匀，升温，保温，冷却至室温得到物料b；将乙烯基硅油、二氧化硅气凝胶及二甲基甲酰胺加入物料b中，搅拌，得到物料c；向物料c中加入质量分数为5-15％的过硫酸钾溶液，然后升温，保温，冷却至室温，得到物料d；然后用氨水调解物料d的pH值至中性，过滤出料，得到防静电助剂，运用到本发明中，使得本发明的猪印染染料具有优异的防静电性能。其中，耐热改性助剂通过将纳米碳管和二氯乙烷混合均匀，超声处理，接着加入亚硫酰氯混合均匀，磁力搅拌，接着升温，回流20-30h，冷却至室温后加入2-丙烯-1-醇混合均匀，接着升温，搅拌，洗涤，离心分离后，将固体干燥，冷却至室温得到物料A；将聚丙烯、纳米氢氧化铝和多聚磷酸铝混合均匀，加热，保温，冷却至常温，然后加入聚四氟乙烯球磨，得物料B；将纳米石墨、炭黑、重晶石粉、纳米二氧化硅、云母粉和滑石粉混合均匀，加热，保温，然后加入季戊四醇三丙烯酸酯和硅烷偶联剂KH-570搅拌至常温得到物料b，然后将物料A和物料B混合均匀，烘干，研磨，冷却至室温得到耐热改性助剂，运用到本发明中，使得本发明的猪毛印染染料具有优异的耐热性能。本发明的猪毛印染染料具有优异的防静电性能。
具体实施方式
下面结合具体实施例对本发明做出详细说明，应当了解，实施例只用于说明本发明，而不是用于对本发明进行限定，任何在本发明基础上所做的修改、等同替换等均在本发明的保护范围内。
实施例1
本发明提出的一种用于猪毛印染的防静电染料，其原料按重量份包括：偶氮二异丁腈15份、硫酸钠10份、碳纤维6份、氨基邻甲酚6份、乙二醇硬脂酸酯3.5份、辛基酚聚氧乙烯醚3份、邻苯二甲酸二酯5.5份、碳酸钠5份、对氨基苯甲酸3份、间苯二胺6份、十二醇硫酸钠3.5份、单甘脂2.5份、对甲基苯胺6份、防静电助剂6份、耐热改性助剂9份、水15份。
防静电助剂按如下工艺进行制备：按重量份将15份去离子水、10份叔丁醇、6.5份2,3-环氧丙基三甲基氯化铵、4份异丙醇、3份纳米硅藻土、6份氢氧化镁、4份氧化铝、2.5份蒙脱土、6份纳米硼酸锌、4.5份碳化硅、3份氟化碳、5.5份硅微粉、2.5份石英粉、6份钼酸钠、6.5份陶瓷微粉和5.5份白玉刚粉末投入反应釜中混合均匀，加热至65℃，保温1.5h，冷却至室温得到物料a；然后将3份苯乙烯、6.5份丙烯酸异辛酯、4份硅酸乙酯和3.5份有机硅单体加入物料a中搅拌均匀，升温至85℃，保温2h，冷却至室温得到物料b；将5份乙烯基硅油、6份二氧化硅气凝胶及3份二甲基甲酰胺加入物料b中，搅拌35min，得到物料c；向物料c中加入6.5份质量分数为10％的过硫酸钾溶液，然后升温至62.5℃，保温25min，冷却至室温，得到物料d；然后用氨水调解物料d的pH值至中性，过滤出料，得到防静电助剂。
耐热改性助剂按如下工艺进行制备：按重量份将15份纳米碳管和4份二氯乙烷混合均匀，超声处理2h，接着加入3份亚硫酰氯混合均匀，磁力搅拌30min，接着升温至85℃，回流25h，冷却至室温后加入6份2-丙烯-1-醇混合均匀，接着升温至50℃，搅拌24h，洗涤3次，离心分离后，将固体于45℃干燥9h，冷却至室温得到物料A；将5.5份聚丙烯、3份纳米氢氧化铝和5份多聚磷酸铝混合均匀，加热至475℃，保温15min，冷却至常温，然后加入6.5份聚四氟乙烯球磨12min，得物料B；将6份纳米石墨、3.5份炭黑、3份重晶石粉、6份纳米二氧化硅、5.5份云母粉和3.5份滑石粉混合均匀，加热至80℃，保温10min，然后加入6份季戊四醇三丙烯酸酯和6.5份硅烷偶联剂KH-570搅拌至常温得到物料b，然后将物料A和物料B混合均匀，烘干，研磨，冷却至室温得到耐热改性助剂。
实施例2
本发明提出的一种用于猪毛印染的防静电染料，其原料按重量份包括：偶氮二异丁腈10份、硫酸钠15份、碳纤维4份、氨基邻甲酚9份、乙二醇硬脂酸酯2份、辛基酚聚氧乙烯醚5份、邻苯二甲酸二酯3份、碳酸钠8份、对氨基苯甲酸1份、间苯二胺9份、十二醇硫酸钠2份、单甘脂4份、对甲基苯胺3份、防静电助剂8份、耐热改性助剂6份、水20份。
防静电助剂按如下工艺进行制备：按重量份将10份去离子水、15份叔丁醇、4份2,3-环氧丙基三甲基氯化铵、6份异丙醇、1份纳米硅藻土、9份氢氧化镁、2份氧化铝、4份蒙脱土、4份纳米硼酸锌、7份碳化硅、1份氟化碳、9份硅微粉、1份石英粉、9份钼酸钠、4份陶瓷微粉和9份白玉刚粉末投入反应釜中混合均匀，加热至60℃，保温2h，冷却至室温得到物料a；然后将1份苯乙烯、9份丙烯酸异辛酯、2份硅酸乙酯和6份有机硅单体加入物料a中搅拌均匀，升温至80℃，保温3h，冷却至室温得到物料b；将2份乙烯基硅油、9份二氧化硅气凝胶及1份二甲基甲酰胺加入物料b中，搅拌50min，得到物料c；向物料c中加入4份质量分数为15％的过硫酸钾溶液，然后升温至60℃，保温30min，冷却至室温，得到物料d；然后用氨水调解物料d的pH值至中性，过滤出料，得到防静电助剂。
耐热改性助剂按如下工艺进行制备：按重量份将10份纳米碳管和6份二氯乙烷混合均匀，超声处理1h，接着加入5份亚硫酰氯混合均匀，磁力搅拌20min，接着升温至90℃，回流20h，冷却至室温后加入9份2-丙烯-1-醇混合均匀，接着升温至45℃，搅拌26h，洗涤1次，离心分离后，将固体于50℃干燥6h，冷却至室温得到物料A；将9份聚丙烯、1份纳米氢氧化铝和8份多聚磷酸铝混合均匀，加热至450℃，保温20min，冷却至常温，然后加入4份聚四氟乙烯球磨16min，得物料B；将3份纳米石墨、5份炭黑、1份重晶石粉、8份纳米二氧化硅、3份云母粉和5份滑石粉混合均匀，加热至70℃，保温15min，然后加入3份季戊四醇三丙烯酸酯和9份硅烷偶联剂KH-570搅拌至常温得到物料b，然后将物料A和物料B混合均匀，烘干，研磨，冷却至室温得到耐热改性助剂。
实施例3
本发明提出的一种用于猪毛印染的防静电染料，其原料按重量份包括：偶氮二异丁腈20份、硫酸钠5份、碳纤维8份、氨基邻甲酚3份、乙二醇硬脂酸酯5份、辛基酚聚氧乙烯醚1份、邻苯二甲酸二酯8份、碳酸钠2份、对氨基苯甲酸5份、间苯二胺3份、十二醇硫酸钠5份、单甘脂1份、对甲基苯胺9份、防静电助剂4份、耐热改性助剂12份、水10份。
防静电助剂按如下工艺进行制备：按重量份将20份去离子水、5份叔丁醇、9份2,3-环氧丙基三甲基氯化铵、2份异丙醇、5份纳米硅藻土、3份氢氧化镁、6份氧化铝、1份蒙脱土、8份纳米硼酸锌、2份碳化硅、5份氟化碳、2份硅微粉、4份石英粉、3份钼酸钠、9份陶瓷微粉和2份白玉刚粉末投入反应釜中混合均匀，加热至70℃，保温1h，冷却至室温得到物料a；然后将5份苯乙烯、4份丙烯酸异辛酯、6份硅酸乙酯和1份有机硅单体加入物料a中搅拌均匀，升温至90℃，保温1h，冷却至室温得到物料b；将8份乙烯基硅油、3份二氧化硅气凝胶及5份二甲基甲酰胺加入物料b中，搅拌20min，得到物料c；向物料c中加入9份质量分数为5％的过硫酸钾溶液，然后升温至65℃，保温20min，冷却至室温，得到物料d；然后用氨水调解物料d的pH值至中性，过滤出料，得到防静电助剂。
耐热改性助剂按如下工艺进行制备：按重量份将20份纳米碳管和2份二氯乙烷混合均匀，超声处理3h，接着加入1份亚硫酰氯混合均匀，磁力搅拌40min，接着升温至80℃，回流30h，冷却至室温后加入3份2-丙烯-1-醇混合均匀，接着升温至55℃，搅拌22h，洗涤4次，离心分离后，将固体于40℃干燥12h，冷却至室温得到物料A；将2份聚丙烯、5份纳米氢氧化铝和2份多聚磷酸铝混合均匀，加热至500℃，保温10min，冷却至常温，然后加入9份聚四氟乙烯球磨8min，得物料B；将9份纳米石墨、2份炭黑、5份重晶石粉、4份纳米二氧化硅、8份云母粉和2份滑石粉混合均匀，加热至90℃，保温5min，然后加入9份季戊四醇三丙烯酸酯和4份硅烷偶联剂KH-570搅拌至常温得到物料b，然后将物料A和物料B混合均匀，烘干，研磨，冷却至室温得到耐热改性助剂。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (7)

1.一种用于猪毛印染的防静电染料，其特征在于，其原料按重量份包括：偶氮二异丁腈10-20份、硫酸钠5-15份、碳纤维4-8份、氨基邻甲酚3-9份、乙二醇硬脂酸酯2-5份、辛基酚聚氧乙烯醚1-5份、邻苯二甲酸二酯3-8份、碳酸钠2-8份、对氨基苯甲酸1-5份、间苯二胺3-9份、十二醇硫酸钠2-5份、单甘脂1-4份、对甲基苯胺3-9份、防静电助剂4-8份、耐热改性助剂6-12份、水10-20份。
2.根据权利要求1所述的用于猪毛印染的防静电染料，其特征在于，防静电助剂的原料按重量份包括：去离子水10-20份、叔丁醇5-15份、2,3-环氧丙基三甲基氯化铵4-9份、异丙醇2-6份、纳米硅藻土1-5份、氢氧化镁3-9份、氧化铝2-6份、蒙脱土1-4份、纳米硼酸锌4-8份、碳化硅2-7份、氟化碳1-5份、硅微粉2-9份、石英粉1-4份、钼酸钠3-9份、陶瓷微粉4-9份、白玉刚粉2-9份、苯乙烯1-5份、丙烯酸异辛酯4-9份、硅酸乙酯2-6份、有机硅单体1-6份、乙烯基硅油2-8份、二氧化硅气凝胶3-9份、二甲基甲酰胺1-5份、质量分数为5-15％的过硫酸钾溶液4-9份。
3.根据权利要求1或2所述的用于猪毛印染的防静电染料，其特征在于，防静电助剂按如下工艺进行制备：将去离子水、叔丁醇、2,3-环氧丙基三甲基氯化铵、异丙醇、纳米硅藻土、氢氧化镁、氧化铝、蒙脱土、纳米硼酸锌、碳化硅、氟化碳、硅微粉、石英粉、钼酸钠、陶瓷微粉和白玉刚粉末投入反应釜中混合均匀，加热，保温，冷却至室温得到物料a；然后将苯乙烯、丙烯酸异辛酯、硅酸乙酯和有机硅单体加入物料a中搅拌均匀，升温，保温，冷却至室温得到物料b；将乙烯基硅油、二氧化硅气凝胶及二甲基甲酰胺加入物料b中，搅拌，得到物料c；向物料c中加入质量分数为5-15％的过硫酸钾溶液，然后升温，保温，冷却至室温，得到物料d；然后用氨水调解物料d的pH值至中性，过滤出料，得到防静电助剂。
4.根据权利要求1-3任一项所述的用于猪毛印染的防静电染料，其特征在于，防静电助剂按如下工艺进行制备：将去离子水、叔丁醇、2,3-环氧丙基三甲基氯化铵、异丙醇、纳米硅藻土、氢氧化镁、氧化铝、蒙脱土、纳米硼酸锌、碳化硅、氟化碳、硅微粉、石英粉、钼酸钠、陶瓷微粉和白玉刚粉末投入反应釜中混合均匀，加热至60-70℃，保温1-2h，冷却至室温得到物料a；然后将苯乙烯、丙烯酸异辛酯、硅酸乙酯和有机硅单体加入物料a中搅拌均匀，升温至80-90℃，保温1-3h，冷却至室温得到物料b；将乙烯基硅油、二氧化硅气凝胶及二甲基甲酰胺加入物料b中，搅拌20-50min，得到物料c；向物料c中加入质量分数为5-15％的过硫酸钾溶液，然后升温至60-65℃，保温20-30min，冷却至室温，得到物料d；然后用氨水调解物料d的pH值至中性，过滤出料，得到防静电助剂。
5.根据权利要求1-4任一项所述的用于猪毛印染的防静电染料，其特征在于，耐热改性助剂的原料按重量份包括：纳米碳管10-20份、二氯乙烷2-6份、亚硫酰氯1-5份、2-丙烯-1-醇3-9份、聚丙烯2-9份、纳米氢氧化铝1-5份、多聚磷酸铝2-8份、聚四氟乙烯4-9份、纳米石墨3-9份、炭黑2-5份、重晶石粉1-5份、纳米二氧化硅4-8份、云母粉3-8份、滑石粉2-5份、季戊四醇三丙烯酸酯3-9份、硅烷偶联剂KH-570 4-9份。
6.根据权利要求1-5任一项所述的用于猪毛印染的防静电染料，其特征在于，耐热改性助剂按如下工艺进行制备：将纳米碳管和二氯乙烷混合均匀，超声处理，接着加入亚硫酰氯混合均匀，磁力搅拌，接着升温，回流20-30h，冷却至室温后加入2-丙烯-1-醇混合均匀，接着升温，搅拌，洗涤，离心分离后，将固体干燥，冷却至室温得到物料A；将聚丙烯、纳米氢氧化铝和多聚磷酸铝混合均匀，加热，保温，冷却至常温，然后加入聚四氟乙烯球磨，得物料B；将纳米石墨、炭黑、重晶石粉、纳米二氧化硅、云母粉和滑石粉混合均匀，加热，保温，然后加入季戊四醇三丙烯酸酯和硅烷偶联剂KH-570搅拌至常温得到物料b，然后将物料A和物料B混合均匀，烘干，研磨，冷却至室温得到耐热改性助剂。
7.根据权利要求1-6任一项所述的用于猪毛印染的防静电染料，其特征在于，耐热改性助剂按如下工艺进行制备：将纳米碳管和二氯乙烷混合均匀，超声处理1-3h，接着加入亚硫酰氯混合均匀，磁力搅拌20-40min，接着升温至80-90℃，回流20-30h，冷却至室温后加入2-丙烯-1-醇混合均匀，接着升温至45-55℃，搅拌22-26h，洗涤1-4次，离心分离后，将固体于40-50℃干燥6-12h，冷却至室温得到物料A；将聚丙烯、纳米氢氧化铝和多聚磷酸铝混合均匀，加热至450-500℃，保温10-20min，冷却至常温，然后加入聚四氟乙烯球磨8-16min，得物料B；将纳米石墨、炭黑、重晶石粉、纳米二氧化硅、云母粉和滑石粉混合均匀，加热至70-90℃，保温5-15min，然后加入季戊四醇三丙烯酸酯和硅烷偶联剂KH-570搅拌至常温得到物料b，然后将物料A和物料B混合均匀，烘干，研磨，冷却至室温得到耐热改性助剂。
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