CN107771837A - A kind of bactericidal composition and its application containing pyraziflumid - Google Patents
A kind of bactericidal composition and its application containing pyraziflumid Download PDFInfo
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- CN107771837A CN107771837A CN201610715052.6A CN201610715052A CN107771837A CN 107771837 A CN107771837 A CN 107771837A CN 201610715052 A CN201610715052 A CN 201610715052A CN 107771837 A CN107771837 A CN 107771837A
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- Prior art keywords
- pyraziflumid
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- fluoxastrobin
- disease
- trifloxystrobin
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
Abstract
The invention discloses a kind of bactericidal composition containing pyraziflumid, contain active ingredient A and active component B in composition, active components A is pyraziflumid, active component B is a kind of methoxy acrylic bactericide, any one of methoxy acrylic bactericide in Fluoxastrobin, pyraclostrobin, kresoxim-methyl, trifloxystrobin, ZEN 90160, SYP-3375, Enestroburin, fluoxastrobin, ZJ0712, SSF 126 or alkene oxime amine, and active components A and active component B mass ratio are 80:1~1:80.The multiple diseases that the present composition can be used in the various crops such as preventing and treating vegetables, fruit tree, flowers, the disease such as powdery mildew, scab, gray mold particularly as caused by higher fungus, there is good prevention effect, have the characteristics that wide sterilization spectrum, dosage are low, synergistic effect is obvious.
Description
Technical field
The present invention relates to a kind of composition pesticide, more particularly to a kind of bactericidal composition containing pyraziflumid and its
Application in crop disease, belongs to technical field of pesticide.
Background technology
Pyraziflumid (test code number NNF-0721) is the SDHI series bactericidal agents of Nihon Nihyaku Co., Ltd's exploitation, right
Powdery mildew, scab, gray mold, sclerotiniose, ring spot on rice, fruits and vegetables etc. have good prevention effect, structure
Formula is as follows:
In actual production, preventing and treating pest and disease damage is easiest to generate the problem that resistance.Different cultivars composition carries out compounding
Prevent and treat the very common method of resistance pest and disease damage.Heterogeneity is compounded, and is to judge certain compounding according to practical application effect
Synergy, addition or antagonism.In most cases, the compounding effect of agricultural chemicals is all summation action, really there is synergy work
Compounding is seldom, and the particularly particularly apparent compounding of synergistic effect is just less.
The content of the invention
It is an object of the invention to provide the composition that a kind of synergistic effect is obvious, preventing and treating spectrum is wide and its application.
To reach goal of the invention, the technical solution adopted by the present invention is:
A kind of bactericidal composition, it is containing active components A and active component B, active components A in composition
Pyraziflumid, active component B are a kind of methoxy acrylic bactericide, and methoxy acrylic bactericide is selected from
Fluoxastrobin, pyraclostrobin, kresoxim-methyl, trifloxystrobin, ZEN 90160, SYP-3375, Enestroburin, fluoxastrobin, ZJ0712,
Any one in SSF 126 or alkene oxime amine, active components A and active component B mass ratio are 80:1~1:80, preferably
Mass ratio is 20:1~1:20.
Disease of the present composition particularly suitable for preventing and treating crops, described crops include cereal crops, beans
Crop, oil crops, fibre crops, sugar crop, melon crop, fruits crop, dry fruit crop, root crop, flower
Grass crop, medicinal crop, crop, green manure pasture crop.
Described disease includes:Target spot, canker, blight dis-ease, rust, ring spot, sclerotiniose, smut, full rot,
Root rot, gray mold, damping-off, banded sclerotial blight, bakanae disease, droop, sclerotiniose, poliosis, downy mildew, samping off, brown spot,
Powdery mildew, anthracnose, early blight, leaf mold, leaf spot, scab, tar spot, shot hole, epidemic disease, bacterial wilt, base rot disease,
Verticillium wilt, clubroot.Etc. a variety of fungal diseases.
Insecticide-applying way can use spraying, pouring root, leaching root, soak seed, gets rid of and apply, spread fertilizer over the fields, ditch spread, spreading manuer in holes, preventing and treating soil-borne disease
Preferred ditch spread during evil, spread manuer in holes, the soil treatment such as pouring root or leaching root, seed soaking, seed pelleting processing.
The present composition can be used in mixed way with other compounds with weeding, bactericidal property, can also be with desinsection
Agent, nematicide, protective agent, growth regulator, nutrient for plants or soil conditioner are used in mixed way.
The present composition compared with the existing technology, can at least produce following beneficial effect:
After 1. two kinds of active components compound according to the above ratio in composition, there is notable synergistic and lasting effect;
2. field dosage and times for spraying can be greatly decreased, production and use cost are reduced, it is dirty effectively to reduce environment
Dye and residues of pesticides, reduce the harm to beneficial organism;
3. expand fungicidal spectrum:To all kinds of true on crops after two kinds of active components is compounded in the ratio in composition
Fungal disease can play a part of it is simultaneous control, and significant effect;
4. composition is made up of the active ingredient of different mechanism of action, action site increase, be advantageous to overcome and delay disease
The drug-fast generation of bacterium.
Embodiment
For the object, technical solutions and advantages of the present invention are more clearly understood, with reference to embodiment in the present invention
Appearance is described further, but the present invention is limited to absolutely not these examples.Specific embodiment is only used for explaining the present invention, is not used to limit
The fixed present invention.Any modifications, equivalent replacements and improvementsmade within the spirit and principles of the invention, etc., should be included in
Within protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
The present invention can be prepared into the formulation of suitable agricultural use with known method, and composition can be according to required preventing and treating
Crop, local environment condition, prevention and controls, the various factors such as cost accounting, by active ingredient and auxiliary agent and carrier (filler)
Any one acceptable formulation in pesticides application is processed into together, and preferred dosage form is suspension seed-coating agent, granule, micro-capsule hang
Floating agent, microemulsion, aqueous emulsion, suspending agent, wettable powder, water dispersible granules or missible oil.Adjuvant used, carrier and process technology
Using known component.In above-mentioned various formulations, in composition the gross mass percentage composition of active ingredient be 0.5%~
85%, for example, when pyraziflumid and Fluoxastrobin weight/mass percentage composition are respectively 10%, 10%, gross mass percentage contains
Measure as 20%.
First, preparation processing formulation Example
Embodiment 1:30%pyraziflumid Fluoxastrobin suspending agents (pyraziflumid:Fluoxastrobin=1:1)
It is made according to common process, wherein pyraziflumid 15g, Fluoxastrobin 15g, sodium lignin sulfonate (dispersant)
4g, lauryl sodium sulfate (wetting agent) 2g, ethylene glycol (antifreeze) 4g, bentonite (thickener) 0.15g, organic silicone (disappear
Infusion) 0.4g, deionized water mended to 100g.
The part by weight of pyraziflumid and Fluoxastrobin can be 20 in the present embodiment:1~1:Change between 20, both
Weight/mass percentage composition can change between 5%~80%, be also adjusted accordingly, formed new therewith using the proportioning of auxiliary agent
Embodiment.
Fluoxastrobin can also be substituted for pyraclostrobin, kresoxim-methyl, trifloxystrobin, ZEN 90160, SYP-3375, alkene oxime bacterium
Ester, fluoxastrobin, ZJ0712, SSF 126 or alkene oxime amine form new embodiment.
Embodiment 2:60%pyraziflumid pyraclostrobin water dispersible granules (pyraziflumid:Pyrazoles ether bacterium
Ester=5:1)
It is made according to common process, wherein pyraziflumid 50g, pyraclostrobin 10g, Negel is (scattered
Agent) 5g, sodium lignin sulfonate (dispersant) 7g, lauryl sodium sulfate (wetting agent) 2g, ammonium sulfate (disintegrant) 5g, lightweight carbon
Sour calcium (filler) complements to 100g.
The part by weight of pyraziflumid and pyraclostrobin can be 20 in the present embodiment:1~1:Change between 20,
Both weight/mass percentage compositions can change between 1%~85%, be also adjusted accordingly therewith using the proportioning of auxiliary agent, be formed
New embodiment.
Pyraclostrobin can also be substituted for Fluoxastrobin, kresoxim-methyl, trifloxystrobin, ZEN 90160, SYP-3375, alkene oxime bacterium
Ester, fluoxastrobin, ZJ0712, SSF 126 or alkene oxime amine form new embodiment.
Embodiment 3:42%pyraziflumid kresoxim-methyl wettable powders (pyraziflumid:Kresoxim-methyl=1:20)
It is made according to common process, wherein pyraziflumid 2g, kresoxim-methyl 40g, lauryl sodium sulfate (wetting agent)
2g, sodium lignin sulfonate (dispersant) 3g, NNO (dispersant) 5g, kaolin complement to 100g.
The part by weight of pyraziflumid and kresoxim-methyl can be 20 in the present embodiment:1~1:Change between 20, both
Weight/mass percentage composition can change between 1%~85%, be also adjusted accordingly, formed new therewith using the proportioning of auxiliary agent
Embodiment.
Kresoxim-methyl can also be substituted for Fluoxastrobin, pyraclostrobin, trifloxystrobin, ZEN 90160, SYP-3375, alkene oxime bacterium
Ester, fluoxastrobin, ZJ0712, SSF 126 or alkene oxime amine form new embodiment.
Embodiment 4:6%pyraziflumid trifloxystrobin microemulsions (pyraziflumid:Trifloxystrobin=1:5)
It is made according to common process, wherein pyraziflumid 1g, trifloxystrobin 5g, 1-METHYLPYRROLIDONE (solvent)
10g, isopropanol (solvent) 5g, No. 500 (emulsifying agent) 5g of agriculture breast, No. 1601 (emulsifying agent) 5g of agriculture breast, deionized water complement to
100g。
Pyraziflumid and the part by weight of trifloxystrobin can be 20 in the present embodiment:1~1:Change between 20, both
Weight/mass percentage composition can change between 1%~30%, be also adjusted accordingly, formed new therewith using the proportioning of auxiliary agent
Embodiment.
Trifloxystrobin can also be substituted for Fluoxastrobin, pyraclostrobin, kresoxim-methyl, ZEN 90160, SYP-3375, alkene oxime bacterium
Ester, fluoxastrobin, ZJ0712, SSF 126 or alkene oxime amine form new embodiment.
Embodiment 5:11%pyraziflumid ZEN 90160 microcapsule suspending agents (pyraziflumid:ZEN 90160=
1:10)
It is made according to common process, wherein pyraziflumid 1g, ZEN 90160 10g, cyclohexanone (solvent) 1g, polyisocyanate
Cyanate (curing agent) 0.4g, ethylene glycol (antifreezing agent) 0.4g, Arabic gum (thickener) 1g, deionized water complement to 100g.
The part by weight of pyraziflumid and ZEN 90160 can be 20 in the present embodiment:1~1:Change between 20, two
The weight/mass percentage composition of person can change between 1%~60%, be also adjusted accordingly therewith using the proportioning of auxiliary agent, be formed new
Embodiment.
ZEN 90160 can also be substituted for Fluoxastrobin, pyraclostrobin, kresoxim-methyl, trifloxystrobin, SYP-3375, alkene oxime bacterium
Ester, fluoxastrobin, ZJ0712, SSF 126 or alkene oxime amine form new embodiment.
Embodiment 6:22%pyraziflumid SYP-3375 aqueous emulsions (pyraziflumid:SYP-3375=10:1)
It is made according to common process, wherein pyraziflumid 20g, SYP-3375 2g, calcium dodecyl benzene sulfonate (breast
Agent) 2.1g, phenethyl phenol polyethenoxy ether (emulsifying agent) 1.5g, cyclohexanone (solvent) 10.1g, loose base ester vegetable oil (solvent)
10.2g, xanthans (thickener) 0.5g, deionized water complement to 100g.
The part by weight of pyraziflumid and SYP-3375 can be 20 in the present embodiment:1~1:Change between 20, two
The weight/mass percentage composition of person can change between 1%~60%, be also adjusted accordingly therewith using the proportioning of auxiliary agent, be formed new
Embodiment.
SYP-3375 can also be substituted for Fluoxastrobin, pyraclostrobin, kresoxim-methyl, trifloxystrobin, ZEN 90160, alkene oxime bacterium
Ester, fluoxastrobin, ZJ0712, SSF 126 or alkene oxime amine form new embodiment.
Embodiment 7:21%pyraziflumid Enestroburin granules (pyraziflumid:Enestroburin=20:1)
It is made according to common process, wherein pyraziflumid 20g, Enestroburin 1g, cornstarch (dispersing aid)
0.5g, polyethylene glycol (binding agent) 0.1g, polyvinyl alcohol (sustained release agent) 0.1g, kaolin (filler) complement to 100g.
The part by weight of pyraziflumid and Enestroburin can be 20 in the present embodiment:1~1:Change between 20, two
The weight/mass percentage composition of person can change between 0.5%~85%, be also adjusted accordingly therewith using the proportioning of auxiliary agent, be formed
New embodiment.
Enestroburin can also be substituted for Fluoxastrobin, pyraclostrobin, kresoxim-methyl, trifloxystrobin, ZEN 90160, cloves bacterium
Ester, fluoxastrobin, ZJ0712, SSF 126 or alkene oxime amine form new embodiment.
Embodiment 8:10%pyraziflumid fluoxastrobin seed treatment suspending agents (pyraziflumid:The phonetic bacterium of fluorine
Ester=1:1)
It is made according to common process, wherein pyraziflumid 5g, fluoxastrobin 5g, naphthalenesulfonate formaldehyde condensation compound (point
Powder) 1.4g, lauryl sodium sulfate (wetting agent) 0.5g, AEO (bleeding agent) 0.5g, xanthans (thickening
Agent) 0.2g, organosilicon (defoamer) 0.1g, ethylene glycol (antifreezing agent) 0.3g, acid scarlet (warning coloration) 0.5g, deionized water benefit
Enough to 100g.
The part by weight of pyraziflumid and fluoxastrobin can be 20 in the present embodiment:1~1:Change between 20, two
The weight/mass percentage composition of person can change between 0.5%~80%, be also adjusted accordingly therewith using the proportioning of auxiliary agent, be formed
New embodiment.
Fluoxastrobin can also be substituted for Fluoxastrobin, pyraclostrobin, kresoxim-methyl, trifloxystrobin, ZEN 90160, cloves bacterium
Ester, Enestroburin, ZJ0712, SSF 126 or alkene oxime amine form new embodiment.
Embodiment 9:15%pyraziflumid ZJ0712 suspension seed-coating agents (pyraziflumid:ZJ0712=
1:1)
It is made according to common process, wherein pyraziflumid 7.5g, ZJ0712 7.5g, lignosulfonates are (scattered
Agent) 5g, dioctyl sulfosuccinate (bleeding agent) 2g, starch (film forming agent) 3g, carboxymethyl cellulose (film forming agent) 2g are organic
Silicon (defoamer) 0.08g, propane diols (antifreezing agent) 2g, acid scarlet (warning coloration) 3g, deionized water complement to 100g.
The part by weight of pyraziflumid and ZJ0712 can be 20 in the present embodiment:1~1:Change between 20, two
The weight/mass percentage composition of person can change between 0.5~80%, be also adjusted accordingly therewith using the proportioning of auxiliary agent, be formed new
Embodiment.
ZJ0712 can also be substituted for Fluoxastrobin, pyraclostrobin, kresoxim-methyl, trifloxystrobin, ZEN 90160, cloves bacterium
Ester, Enestroburin, fluoxastrobin, SSF 126 or alkene oxime amine form new embodiment.
Embodiment 10:30%pyraziflumid SSF 126 suspending agents (pyraziflumid:SSF 126=1:5)
It is made according to common process, wherein pyraziflumid 5g, Fluoxastrobin 25g, sodium lignin sulfonate (dispersant)
4g, lauryl sodium sulfate (wetting agent) 2g, ethylene glycol (antifreeze) 4g, bentonite (thickener) 0.12g, organic silicone (disappear
Infusion) 0.4g, deionized water mended to 100g.
The part by weight of pyraziflumid and SSF 126 can be 20 in the present embodiment:1~1:Change between 20, two
The weight/mass percentage composition of person can change between 5%~80%, be also adjusted accordingly therewith using the proportioning of auxiliary agent, be formed new
Embodiment.
SSF 126 can also be substituted for pyraclostrobin, kresoxim-methyl, trifloxystrobin, ZEN 90160, SYP-3375, alkene oxime
Bacterium ester, fluoxastrobin, ZJ0712, Fluoxastrobin or alkene oxime amine form new embodiment.
Embodiment 11:30%pyraziflumid alkene oxime amine missible oil (pyraziflumid:Alkene oxime amine=5:1)
It is made according to common process, wherein pyraziflumid 25g, alkene oxime amine 5g, calcium dodecyl benzene sulfonate (breast
Agent) 3g, OPEO (emulsifying agent) 4g, dimethyl sulfoxide (cosolvent) 10g, goes turpentine oil to mend to 100g.
The part by weight of pyraziflumid and alkene oxime amine can be 20 in the present embodiment:1~1:Change between 20, two
The weight/mass percentage composition of person can change between 1%~60%, be also adjusted accordingly therewith using the proportioning of auxiliary agent, be formed new
Embodiment.
Alkene oxime amine can also be substituted for pyraclostrobin, kresoxim-methyl, trifloxystrobin, ZEN 90160, SYP-3375, alkene oxime
Bacterium ester, fluoxastrobin, ZJ0712, Fluoxastrobin or SSF 126 form new embodiment.
2nd, biological activity determination and field control effectiveness test example
Agricultural chemicals is made in the combination of active principles of different agricultural chemicals, is current exploitation and develops novel pesticide and preventing and treating agriculturally
A kind of effective and quick way of resistance pest and disease damage.After the pestsides synthesis of different cultivars, three kinds of type of action are typically exhibited:
Summation action, synergistic effect and antagonism.But it is specially which kind of effect, it is unpredictable, only could really by lot of experiments
It is fixed.
Inventor has found that pyraziflumid sterilizes with a kind of methoxy acrylic by substantial amounts of screening test
Agent, methoxy acrylic bactericide are selected from Fluoxastrobin, pyraclostrobin, kresoxim-methyl, trifloxystrobin, ZEN 90160, cloves bacterium
To multiple diseases after any one compounding in ester, Enestroburin, fluoxastrobin, ZJ0712, SSF 126 or alkene oxime amine
With obvious synergistic function.Thus, present example provides above-mentioned bactericidal composition in preventing and treating powdery mildew of cucumber, banana
The application of scab, effect are not only the simple addition of two kinds of medicaments, are specifically illustrated with following biologicall test example.
One) biological activity determination example
Pyraziflumid and pyraclostrobin, kresoxim-methyl, trifloxystrobin, ZEN 90160, SYP-3375, Enestroburin, fluorine
Fluoxastrobin, ZJ0712, Fluoxastrobin, alkene oxime amine or SSF 126 compounding are tested the joint toxicity measuring of banana freckle
For trying object:Macrophoma musae bacterium (Macrophoma musae (Cooke) Berl.et Vogl.).
Experiment uses mycelial growth rate method:Aqua sterilisa to contain appropriate acetone and Tween-80 is used as control (CK).
Take 4mL decoctions to be added in the conical flask equipped with the hot culture mediums of 36mL (PDA culture medium, 45-50 DEG C), after shaking up, pour into rapidly
Diameter 90mm glass culture dish, each culture dish pour into band medicine culture medium 10mL, each handle 4 repetitions, horizontal rest, cooling
Afterwards flat board.Bacteria cake is cut for examination colony edge from culture 3d with diameter 5mm card punch, with choosing pin by one with mycelia
Face is connected to on malicious culture medium, and all operations carry out sterile working in superclean bench.24 ± 1 DEG C of constant temperature is placed on after processing
Camera bellows culture in sterile culture case, measure the colony diameter of each processing after 5d respectively using crossing method, calculate colony diameter
Average value, mycelial growth inhibition rate.
Mode of application judges to use co-toxicity coefficient (CTC) method.The calculation formula of co-toxicity coefficient is as follows:
Survey toxicity index (ATI)=(standard agent EC50/ reagent agent EC50)×100
In theoretical toxicity index (TTI)=A medicaments ATI × mixture in A percentage composition+B medicaments ATI × mixture B hundred
Divide content
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI)/mixture theoretical toxicity index (TTI)] × 100
When CTC≤80, then composition shows as antagonism, and as 80 < CTC < 120, then composition shows as being added and made
With when CTC >=120, then composition shows as synergistic effect.
Result of the test:Pyraziflumid and pyraclostrobin, kresoxim-methyl, trifloxystrobin, ZEN 90160, SYP-3375, alkene
To the connection of Macrophoma musae bacterium after trifloxystrobin, fluoxastrobin, ZJ0712, Fluoxastrobin, alkene oxime amine or SSF 126 compounding
Close toxicity test and the results are shown in Table 1-11.
Joint toxicity measuring result of the test of the composition of table 1 to Macrophoma musae bacterium
Processing | EC50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
pyraziflumid | 0.18 | 100.0 | / | / |
Pyraclostrobin | 2.47 | 7.3 | / | / |
pyraziflumid80:Pyraclostrobin 1 | 0.12 | 150.0 | 98.9 | 151.74 |
pyraziflumid40:Pyraclostrobin 1 | 0.13 | 138.5 | 97.7 | 141.66 |
pyraziflumid20:Pyraclostrobin 1 | 0.08 | 225.0 | 95.6 | 235.39 |
pyraziflumid10:Pyraclostrobin 1 | 0.10 | 180.0 | 91.6 | 196.57 |
pyraziflumid5:Pyraclostrobin 1 | 0.09 | 200.0 | 84.5 | 236.55 |
pyraziflumid1:Pyraclostrobin 1 | 0.15 | 120.0 | 53.6 | 223.70 |
pyraziflumid1:Pyraclostrobin 5 | 0.43 | 41.9 | 22.7 | 184.09 |
pyraziflumid1:Pyraclostrobin 10 | 0.54 | 33.3 | 15.7 | 212.10 |
pyraziflumid1:Pyraclostrobin 20 | 0.81 | 22.2 | 11.7 | 189.90 |
pyraziflumid1:Pyraclostrobin 40 | 1.47 | 12.2 | 9.5 | 128.24 |
pyraziflumid1:Pyraclostrobin 80 | 1.68 | 10.7 | 8.4 | 127.07 |
The result of the co-toxicity of table 1 test shows that pyraziflumid and pyraclostrobin compounding are 80:1~1:80
120 are all higher than to the co-toxicity coefficient CTC of Macrophoma musae bacterium joint toxicity measuring in ratio range, there is synergistic effect.Especially
It is 20:1~1:In 20 ratio range, CTC is all higher than 180, and synergistic effect is notable.
Joint toxicity measuring result of the test of the composition of table 2 to Macrophoma musae bacterium
Processing | EC50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
pyraziflumid | 0.20 | 100.0 | / | / |
Fluoxastrobin | 5.57 | 3.6 | / | / |
pyraziflumid80:Fluoxastrobin 1 | 0.16 | 125.0 | 98.8 | 126.51 |
pyraziflumid40:Fluoxastrobin 1 | 0.17 | 117.6 | 97.6 | 120.48 |
pyraziflumid20:Fluoxastrobin 1 | 0.10 | 200.0 | 95.4 | 209.62 |
pyraziflumid10:Fluoxastrobin 1 | 0.12 | 166.7 | 91.2 | 182.68 |
pyraziflumid5:Fluoxastrobin 1 | 0.08 | 250.0 | 83.9 | 297.86 |
pyraziflumid1:Fluoxastrobin 1 | 0.21 | 95.2 | 51.8 | 183.87 |
pyraziflumid1:Fluoxastrobin 5 | 0.51 | 39.2 | 19.7 | 199.48 |
pyraziflumid1:Fluoxastrobin 10 | 0.68 | 29.4 | 12.4 | 238.05 |
pyraziflumid1:Fluoxastrobin 20 | 1.24 | 16.1 | 8.2 | 197.14 |
pyraziflumid1:Fluoxastrobin 40 | 2.58 | 7.8 | 5.9 | 130.46 |
pyraziflumid1:Fluoxastrobin 80 | 2.87 | 7.0 | 4.8 | 145.76 |
The result of the co-toxicity of table 2 test shows that pyraziflumid and azoxystrobin compound are 80:1~1:80 proportioning
In the range of 120 are all higher than to the co-toxicity coefficient CTC of Macrophoma musae bacterium joint toxicity measuring, there is synergistic effect.Especially
20:1~1:In 20 ratio range, CTC is all higher than 180, and synergistic effect is notable.
Joint toxicity measuring result of the test of the composition of table 3 to Macrophoma musae bacterium
The result of the co-toxicity of table 3 test shows that pyraziflumid and kresoxim-methyl compounding are 80:1~1:80 proportioning
In the range of 120 are all higher than to the co-toxicity coefficient CTC of Macrophoma musae bacterium joint toxicity measuring, there is synergistic effect.Especially
20:1~1:In 20 ratio range, CTC is all higher than 180, and synergistic effect is notable.
Joint toxicity measuring result of the test of the composition of table 4 to Macrophoma musae bacterium
Processing | EC50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
pyraziflumid | 0.21 | 100.0 | / | / |
Trifloxystrobin | 7.14 | 2.9 | / | / |
pyraziflumid80:Trifloxystrobin 1 | 0.16 | 131.3 | 98.8 | 132.84 |
pyraziflumid40:Trifloxystrobin 1 | 0.14 | 150.0 | 97.6 | 153.64 |
pyraziflumid20:Trifloxystrobin 1 | 0.12 | 175.0 | 95.4 | 183.48 |
pyraziflumid10:Trifloxystrobin 1 | 0.11 | 190.9 | 91.2 | 209.38 |
pyraziflumid5:Trifloxystrobin 1 | 0.13 | 161.5 | 83.8 | 192.71 |
pyraziflumid1:Trifloxystrobin 1 | 0.22 | 95.5 | 51.5 | 185.45 |
pyraziflumid1:Trifloxystrobin 5 | 0.57 | 36.8 | 19.1 | 192.71 |
pyraziflumid1:Trifloxystrobin 10 | 0.86 | 24.4 | 11.8 | 207.56 |
pyraziflumid1:Trifloxystrobin 20 | 1.47 | 14.3 | 7.6 | 188.89 |
pyraziflumid1:Trifloxystrobin 40 | 2.65 | 7.9 | 5.3 | 149.28 |
pyraziflumid1:Trifloxystrobin 80 | 3.79 | 5.5 | 4.1 | 133.86 |
The result of the co-toxicity of table 4 test shows that pyraziflumid and trifloxystrobin compounding are 80:1~1:80 proportioning
In the range of 120 are all higher than to the co-toxicity coefficient CTC of Macrophoma musae bacterium joint toxicity measuring, there is synergistic effect.Especially
20:1~1:In 20 ratio range, CTC is all higher than 180, and synergistic effect is notable.
Joint toxicity measuring result of the test of the composition of table 5 to Macrophoma musae bacterium
Processing | EC50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
pyraziflumid | 0.19 | 100.0 | / | / |
ZEN 90160 | 4.78 | 4.0 | / | / |
pyraziflumid80:ZEN 90160 1 | 0.16 | 118.8 | 98.8 | 120.17 |
pyraziflumid40:ZEN 90160 1 | 0.15 | 126.7 | 97.7 | 129.70 |
pyraziflumid20:ZEN 90160 1 | 0.11 | 172.7 | 95.4 | 181.00 |
pyraziflumid10:ZEN 90160 1 | 0.09 | 211.1 | 91.3 | 231.30 |
pyraziflumid5:ZEN 90160 1 | 0.12 | 158.3 | 84.0 | 188.50 |
pyraziflumid1:ZEN 90160 1 | 0.17 | 111.8 | 52.0 | 214.98 |
pyraziflumid1:ZEN 90160 5 | 0.42 | 45.2 | 20.0 | 226.43 |
pyraziflumid1:ZEN 90160 10 | 0.75 | 25.3 | 12.7 | 199.41 |
pyraziflumid1:ZEN 90160 20 | 1.68 | 11.3 | 8.5 | 132.31 |
pyraziflumid1:ZEN 90160 40 | 2.34 | 8.1 | 6.3 | 128.54 |
pyraziflumid1:ZEN 90160 80 | 2.59 | 7.3 | 5.2 | 142.16 |
The result of the co-toxicity of table 5 test shows that pyraziflumid and ZEN 90160 compounding are 80:1~1:80 match somebody with somebody
120 are all higher than to the co-toxicity coefficient CTC of Macrophoma musae bacterium joint toxicity measuring than in the range of, there is synergistic effect.Especially
It is 20:1~1:In 20 ratio range, CTC is all higher than 180, and synergistic effect is notable.
Joint toxicity measuring result of the test of the composition of table 6 to Macrophoma musae bacterium
The result of the co-toxicity of table 6 test shows that pyraziflumid and SYP-3375 compounding are 80:1~1:80 match somebody with somebody
120 are all higher than to the co-toxicity coefficient CTC of Macrophoma musae bacterium joint toxicity measuring than in the range of, there is synergistic effect.Especially
It is 20:1~1:In 20 ratio range, CTC is all higher than 180, and synergistic effect is notable.
Joint toxicity measuring result of the test of the composition of table 7 to Macrophoma musae bacterium
Processing | EC50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
pyraziflumid | 0.18 | 100.0 | / | / |
Enestroburin | 10.25 | 1.8 | / | / |
pyraziflumid80:Enestroburin 1 | 0.15 | 120.0 | 98.8 | 121.47 |
pyraziflumid40:Enestroburin 1 | 0.13 | 138.5 | 97.6 | 141.86 |
pyraziflumid20:Enestroburin 1 | 0.10 | 180.0 | 95.3 | 188.83 |
pyraziflumid10:Enestroburin 1 | 0.09 | 200.0 | 91.1 | 219.61 |
pyraziflumid5:Enestroburin 1 | 0.11 | 163.6 | 83.6 | 195.68 |
pyraziflumid1:Enestroburin 1 | 0.15 | 120.0 | 50.9 | 235.86 |
pyraziflumid1:Enestroburin 5 | 0.52 | 34.6 | 18.1 | 190.93 |
pyraziflumid1:Enestroburin 10 | 0.86 | 20.9 | 10.7 | 195.84 |
pyraziflumid1:Enestroburin 20 | 1.54 | 11.7 | 6.4 | 181.65 |
pyraziflumid1:Enestroburin 40 | 3.12 | 5.8 | 4.2 | 138.94 |
pyraziflumid1:Enestroburin 80 | 4.16 | 4.3 | 3.0 | 145.74 |
The result of the co-toxicity of table 7 test shows that pyraziflumid and Enestroburin compounding are 80:1~1:80 match somebody with somebody
120 are all higher than to the co-toxicity coefficient CTC of Macrophoma musae bacterium joint toxicity measuring than in the range of, there is synergistic effect.Especially
It is 20:1~1:In 20 ratio range, CTC is all higher than 180, and synergistic effect is notable.
Joint toxicity measuring result of the test of the composition of table 8 to watermelon Fusarium oxysporum
Processing | EC50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
pyraziflumid | 0.22 | 100.0 | / | / |
Fluoxastrobin | 11.46 | 1.9 | / | / |
pyraziflumid80:Fluoxastrobin 1 | 0.16 | 137.5 | 98.8 | 139.19 |
pyraziflumid40:Fluoxastrobin 1 | 0.17 | 129.4 | 97.6 | 132.58 |
pyraziflumid20:Fluoxastrobin 1 | 0.12 | 183.3 | 95.3 | 192.32 |
pyraziflumid10:Fluoxastrobin 1 | 0.13 | 169.2 | 91.1 | 185.80 |
pyraziflumid5:Fluoxastrobin 1 | 0.10 | 220.0 | 83.7 | 262.99 |
pyraziflumid1:Fluoxastrobin 1 | 0.21 | 104.8 | 51.0 | 205.58 |
pyraziflumid1:Fluoxastrobin 5 | 0.65 | 33.8 | 18.3 | 185.29 |
pyraziflumid1:Fluoxastrobin 10 | 0.98 | 22.4 | 10.8 | 207.17 |
pyraziflumid1:Fluoxastrobin 20 | 1.67 | 13.2 | 6.6 | 199.90 |
pyraziflumid1:Fluoxastrobin 40 | 4.18 | 5.3 | 4.3 | 122.06 |
pyraziflumid1:Fluoxastrobin 80 | 5.78 | 3.8 | 3.1 | 121.58 |
The result of the co-toxicity of table 8 test shows that pyraziflumid and fluoxastrobin compounding are 80:1~1:80 match somebody with somebody
120 are all higher than to the co-toxicity coefficient CTC of Macrophoma musae bacterium joint toxicity measuring than in the range of, there is synergistic effect.Especially
It is 20:1~1:In 20 ratio range, CTC is all higher than 180, and synergistic effect is notable.
Joint toxicity measuring result of the test of the composition of table 9 to Macrophoma musae bacterium
The result of the co-toxicity of table 9 test shows that pyraziflumid and ZJ0712 compounding are 80:1~1:80 match somebody with somebody
120 are all higher than to the co-toxicity coefficient CTC of Macrophoma musae bacterium joint toxicity measuring than in the range of, there is synergistic effect.Especially
It is 20:1~1:In 20 ratio range, CTC is all higher than 180, and synergistic effect is notable.
Joint toxicity measuring result of the test of the composition of table 10 to Macrophoma musae bacterium
Processing | EC50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
pyraziflumid | 0.24 | 100.0 | / | / |
Alkene oxime amine | 12.89 | 1.9 | / | / |
pyraziflumid80:Alkene oxime amine 1 | 0.20 | 120.0 | 98.8 | 121.47 |
pyraziflumid40:Alkene oxime amine 1 | 0.19 | 126.3 | 97.6 | 129.41 |
pyraziflumid20:Alkene oxime amine 1 | 0.13 | 184.6 | 95.3 | 193.67 |
pyraziflumid10:Alkene oxime amine 1 | 0.12 | 200.0 | 91.1 | 219.59 |
pyraziflumid5:Alkene oxime amine 1 | 0.14 | 171.4 | 83.6 | 204.95 |
pyraziflumid1:Alkene oxime amine 1 | 0.26 | 92.3 | 50.9 | 181.24 |
pyraziflumid1:Alkene oxime amine 5 | 0.62 | 38.7 | 18.2 | 212.48 |
pyraziflumid1:Alkene oxime amine 10 | 0.98 | 24.5 | 10.8 | 227.10 |
pyraziflumid1:Alkene oxime amine 20 | 1.87 | 12.8 | 6.5 | 196.39 |
pyraziflumid1:Alkene oxime amine 40 | 4.67 | 5.1 | 4.3 | 120.77 |
pyraziflumid1:Alkene oxime amine 80 | 5.38 | 4.5 | 3.1 | 145.14 |
The result of the co-toxicity of table 10 test shows that pyraziflumid and alkene oxime amine compounding are 80:1~1:80 match somebody with somebody
120 are all higher than to the co-toxicity coefficient CTC of Macrophoma musae bacterium joint toxicity measuring than in the range of, there is synergistic effect.Especially
It is 20:1~1:In 20 ratio range, CTC is all higher than 180, and synergistic effect is notable.
Joint toxicity measuring result of the test of the composition of table 11 to Macrophoma musae bacterium
Processing | EC50(μg/mL) | ATI | TTI | Co-toxicity coefficient CTC |
pyraziflumid | 0.17 | 100.0 | / | / |
SSF 126 | 13.65 | 1.2 | / | / |
pyraziflumid80:SSF 126 1 | 0.13 | 130.8 | 98.8 | 132.38 |
pyraziflumid40:SSF 126 1 | 0.12 | 141.7 | 97.6 | 145.16 |
pyraziflumid20:SSF 126 1 | 0.08 | 212.5 | 95.3 | 222.99 |
pyraziflumid10:SSF 126 1 | 0.10 | 170.0 | 91.0 | 186.77 |
pyraziflumid5:SSF 126 1 | 0.07 | 242.9 | 83.5 | 290.70 |
pyraziflumid1:SSF 126 1 | 0.11 | 154.5 | 50.6 | 305.29 |
pyraziflumid1:SSF 126 5 | 0.34 | 50.0 | 17.7 | 282.41 |
pyraziflumid1:SSF 126 10 | 0.85 | 20.0 | 10.2 | 195.64 |
pyraziflumid1:SSF 126 20 | 1.58 | 10.8 | 5.9 | 180.89 |
pyraziflumid1:SSF 126 40 | 3.87 | 4.4 | 3.7 | 120.22 |
pyraziflumid1:SSF 126 80 | 5.40 | 3.1 | 2.5 | 127.73 |
The result of the co-toxicity of table 11 test shows that pyraziflumid and SSF 126 compounding are 80:1~1:80 match somebody with somebody
120 are all higher than to the co-toxicity coefficient CTC of Macrophoma musae bacterium joint toxicity measuring than in the range of, there is synergistic effect.Especially
It is 20:1~1:In 20 ratio range, CTC is all higher than 180, and synergistic effect is notable.
Two) field control effectiveness test example
1st, to the field control effectiveness test of powdery mildew of cucumber
Test and carried out in August, 2015 in the green house of vegetables of Shouguang City of Shandong Province one, the greenhouse plants cucumber year after year, during experiment
Lighter, investigation state of an illness radix before medicine occurs for powdery mildew of cucumber, takes at random per cell at 4 points, whole leaves of 2 plants of cucumber of every investigation
Piece, the percentage that every leaf is accounted for leaf area by scab are classified record.
Stage division:
0 grade:Disease-free spot;
1 grade:Lesion area accounts for whole leaf area below 5%;
3 grades:Lesion area accounts for whole below leaf area 6%-10%;
5 grades:Lesion area accounts for whole below leaf area 11%-20%;
7 grades:Lesion area accounts for whole below leaf area 21%-40%;
9 grades:Lesion area accounts for whole more than 40%.
Experiment shares medicine three times, each medication interval 7 days, 14 days investigation results after last time medication.
Calculation formula is as follows:
Prevention effect (%)=(1- (CK0 × PT1)/(CK1 × PT0)) × 100
In formula:CK0Disease index before expression blank district dispenser;
CK1Disease index after expression blank district dispenser;
PT0Disease index before expression chemicals treatment district dispenser;
PT1Disease index after expression chemicals treatment district dispenser.
Data can be drawn from table 12, and the various formulation synergistic effects of composition containing pyraziflumid are obvious;Last
14d after secondary dispenser, each compound drug are also significantly better than single dose to the prevention effect of powdery mildew of cucumber.
Field control effect of the medicaments such as the composition of table 12 to powdery mildew of cucumber
2nd, to the field control effectiveness test of banana freckle
Test first for banana freckle morbidity when in June, 2015 is in the banana base progress of Guangxi Gold fringe company one, experiment
Phase, state of an illness radix is investigated before medicine, take 3 plants of investigation at random per cell, blade investigates every plant and investigates 8 by the order from top down
Leaf.Record the total number of sheets of investigation, the sick number of sheets at different levels.The percentage that every leaf is accounted for leaf area by scab is classified record.
Stage division:
0 grade:Disease-free spot;
1 grade:Lesion area accounts for whole leaf area below 5%;
3 grades:Lesion area accounts for whole below leaf area 6%-10%;
5 grades:Lesion area accounts for whole below leaf area 11%-25%;
7 grades:Lesion area accounts for whole below leaf area 26%-50%;
9 grades:Lesion area accounts for whole more than 50%.
Experiment shares medicine three times, each medication interval 7 days, 10 days investigation results after last time medication.
Calculation formula is as follows:
Prevention effect (%)=(1- (CK0 × PT1)/(CK1 × PT0)) × 100
In formula:CK0Disease index before expression blank district dispenser;
CK1Disease index after expression blank district dispenser;
PT0Disease index before expression chemicals treatment district dispenser;
PT1Disease index after expression chemicals treatment district dispenser.
Data can be drawn from table 13, and the various formulation synergistic effects of composition containing pyraziflumid are obvious;Last
10d after secondary dispenser, each compound drug are also significantly better than single dose to the prevention effect of banana freckle.
Field control effect of the composition containing pyraziflumid of table 13 to banana freckle
Powdery mildew of cucumber, the field control effectiveness test result of banana freckle are seen from the combination containing pyraziflumid, it is each multiple
Dose out powders have good prevention effect to powdery mildew and scab, and preventive effect is significantly better than single dose.Illustrate that there is compounding synergy to make
With the lasting period extends, and can reduce dosage and spraying times, delay the resistance to the action of a drug to produce, while can reduce cost accounting.
These are only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and
All any modification, equivalent and improvement made within principle etc., should be included in the scope of the protection.
Claims (6)
1. a kind of bactericidal composition containing pyraziflumid, contain active components A and active component B, its feature in composition
It is:Active components A and active component B mass ratio are 80:1~1:80, the active components A is pyraziflumid, living
Property composition B be a kind of methoxy acrylic bactericide, methoxy acrylic bactericide is selected from Fluoxastrobin, pyrazoles ether bacterium
Ester, kresoxim-methyl, trifloxystrobin, ZEN 90160, SYP-3375, Enestroburin, fluoxastrobin, ZJ0712, SSF 126 or alkene oxime
Any one in bacterium amine.
2. the bactericidal composition according to claim 1 containing pyraziflumid, it is characterised in that:Active components A and work
Property composition B mass ratio be 20:1~1:20.
3. the bactericidal composition according to claim 1 or 2 containing pyraziflumid, it is characterised in that:Have in composition
The gross mass percentage composition for imitating composition is 0.5%~85%.
4. the bactericidal composition according to claim 3 containing pyraziflumid, it is characterised in that:Composition can be made
Formulation have suspension seed-coating agent, granule, microcapsule suspending agent, microemulsion, aqueous emulsion, suspending agent, wettable powder, water-dispersible grain
Agent or missible oil.
5. the bactericidal composition containing pyraziflumid described in any one of Claims 1-4 is used for the use for preventing and treating crop disease
On the way.
6. purposes according to claim 5, it is characterised in that:Described disease is target spot, canker, blight dis-ease, rust
Disease, ring spot, sclerotiniose, smut, full rot, root rot, gray mold, damping-off, banded sclerotial blight, bakanae disease, droop, sclerotium
Disease, poliosis, downy mildew, samping off, brown spot, powdery mildew, anthracnose, early blight, leaf mold, leaf spot, scab, black mole
Disease, shot hole, epidemic disease, bacterial wilt, base rot disease, verticillium wilt, clubroot.
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