CN107771833A - A kind of bactericidal composition and its application containing Boscalid and Propamocarb - Google Patents
A kind of bactericidal composition and its application containing Boscalid and Propamocarb Download PDFInfo
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- CN107771833A CN107771833A CN201610766838.0A CN201610766838A CN107771833A CN 107771833 A CN107771833 A CN 107771833A CN 201610766838 A CN201610766838 A CN 201610766838A CN 107771833 A CN107771833 A CN 107771833A
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- Prior art keywords
- propamocarb
- boscalid
- bactericidal composition
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- 0 C/*=C(\CCC1(CC[N+]C)C2C1)/C2S Chemical compound C/*=C(\CCC1(CC[N+]C)C2C1)/C2S 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Abstract
The invention discloses a kind of bactericidal composition containing Boscalid and Propamocarb and its application.The bactericidal composition is using Boscalid and Propamocarb as principle active component, and wherein the mass ratio of Boscalid and Propamocarb is 1:50~70:1.The bactericidal composition can be applied to prevent and treat Cereal, fruit tree, vegetable disease, has higher synergistic function, overcomes and delayed the resistance to the action of a drug of germ, and sterilization speed is fast, the lasting period is long, reduces application cost, and prevention effect is substantially better than the use of its single dose.The present invention can be used for preventing and treating the fungal disease on crops, it is particularly possible to which, for preventing and treating the fungal diseases such as powdery mildew, gray mold, sclerotiniose, rot, downy mildew, samping off, epidemic disease, late blight, balck shank, effect is better than single dose use.
Description
Technical field：
It is especially a kind of using Boscalid and Propamocarb to be main living the present invention relates to a kind of bactericidal composition and application thereof
The bactericidal composition of property composition and its application.
Background technology
Boscalid (Boscalid), be BASF Aktiengesellschaft exploitation new nicotine acid amide fungicides, chemical name
Claim：The chloro- N- of 2- (4'- chlordiphenyl -2- bases) niacinamide, molecular formula：C18H12Cl2N2O.Structural formula is as follows：
The bactericide fungicidal spectrum is wider, almost all active to all types of fungal diseases, to preventing and treating powdery mildew, grey mold
Disease, sclerotiniose and various rots etc. are highly effective and also effective to the resistance bacterium of other medicaments, for rape, beans, ball
Stem vegetables, leaf mustard, carrot, apple, lettuce, peanut, potato, drupe, strawberry, nut, wild cabbage, cucumber, peppermint, pea, root
The preventing and treating of the disease such as class vegetables, sunflower, grape, lawn, other fruit trees, vegetables, field crop；Due to its distinctive effect machine
Reason is not likely to produce cross resistance, is the new of significant in addition to crop safety and favourable toxicity data and ecological effect
Nicotinamide bactericide.
Propamocarb (Propamocarb), chemical name：N- [3- (dimethylaminopropyl) amino] propyl formate.Structure
Formula：
Propamocarb is a kind of safe and efficient carbamate fungicide, the main phosphatide for suppressing germ cell membrane component
With the biosynthesis of aliphatic acid, suppress the formation and sprouting of mycelial growth, sporangium.Propamocarb category uptake and translocation bactericide,
When as soil treatment, it can be absorbed quickly by root and be conveyed upwards into whole plant；, can be quickly when acting on cauline leaf process
Absorbed and be distributed in blade by blade, can be played a protective role in 30 minutes, because of its mechanism of action and other bactericide not
Together, with other medicament no interactions resistances, especially prevent and treat effective to the germ to have been developed immunity to drugs using bactericide.It is true to Oomycete
Bacterium has special efficacy, can effectively prevent and treat the seed of various crop, seedling, root, disease such as downy mildew caused by leaves and stemses Oomycete, damping off
The diseases such as disease, epidemic disease, late blight, balck shank.
The difficulty of prevention and cure of phytopathogen is increasing at present, on the one hand, with the change of pattern of farming, melon fruits and vegetables etc.
Industrial crops cultivated area progressively expands, and disease occurrence degree, generation quantity increase, and difficulty increases in preventing and treating；Separately
On the one hand, the resistance of pathogen rises year by year under lasting medicament selection pressure, and the prevention effect of single dose is had a greatly reduced quality, plant
Disease control is faced with significant challenge.
The content of the invention：
The purpose of the present invention be for above-mentioned technical problem provide it is a kind of it is applied widely, cost is low, effect is good contains pyridine
The plant bactericidal composition of acyl bacterium amine and Propamocarb.
Cause answering on fungal disease in preventing and treating plant epiphyte it is a still further object of the present invention to provide the bactericidal composition
With especially in preventing and treating powdery mildew, gray mold, sclerotiniose, rot, downy mildew, samping off, epidemic disease, late blight, balck shank etc.
Purposes on fungal disease.
The purpose of the present invention is to be achieved through the following technical solutions：
A kind of bactericidal composition containing Boscalid and Propamocarb, the bactericidal composition is based on Boscalid and Propamocarb
Active ingredient is wanted, the wherein mass ratio of Boscalid and Propamocarb is 1:50~70:1, wherein effective ingredient in bactericidal composition
It is present in enhancing effective amount in composition.
The mass ratio of described bactericidal composition, wherein Boscalid and Propamocarb is preferably 1:20~50:1, further
Preferably 1:20~1:2、2.5:1~50:1.Still more preferably it is：1:10、5:1~30:1.
In bactericidal composition of the present invention, the weight/mass percentage composition that both Boscalid and Propamocarb account for composition is 2%
~80%.It is preferred that 10%~40%.
Described bactericidal composition, wherein using Boscalid and Propamocarb as principle active component and known auxiliary agent and tax
Shape agent is re-dubbed any one formulation allowed on agricultural chemicals.These known auxiliary agents, excipients have dispersant, diffusant, defoaming
Agent, wetting agent, disintegrant etc., calcium dodecyl benzene sulfonate, APES, benzyl phenol polyethenoxy can be used
Ether, phenethyl phenol polyethenoxy ether, AEO and its similar products, aliphatic amine polyoxyethylene ether, aliphatic acid ring
Oxidative ethane addition product, polyoxyethylene polyoxy propylene block compound, castor oil polyoxyethylene ether, NPE, tell
Warm series, AEO, polyethylene glycol series, Sulfonates, carboxylate, sulfate, phosphate, phosphite,
One or more of lignosulfonates, xanthans, phenol formaldehyde condensate, ammonium salt, quaternary etc. combine, and excipient includes
Cyclohexanone, dimethylbenzene, various solvent naphthas, water, antifreezing agent (such as propane diols), deionized water.Above auxiliary agent, excipient and other
Auxiliary material can be with alone or be used in combination.
Described bactericidal composition, its formulation are that missible oil, wettable powder, suspending agent, aqueous emulsion, microemulsion or moisture dissipate
Granule.
Application of the described bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared.Especially in preventing and treating cereal
Class, fruit tree, the application in vegetable crop disease.
Above-mentioned fungal diseases of plants is powdery mildew, gray mold, sclerotiniose, rot, downy mildew, samping off, epidemic disease, evening
At least one of epidemic disease and balck shank.
Beneficial effects of the present invention：
1st, the Boscalid used in the present invention is pyridine series bactericidal agent, and Propamocarb is that safe and efficient carbamates kills
Microbial inoculum, the mechanism of action are different, mutual mixture will not produce it is low touch, can Synergistic, reduce dosage, reduce cost.
2nd, the present composition scope of application increase, suitable for preventing and treating Cereal, fruit tree, vegetables refractory fungal disease,
Particularly preventing and treating powdery mildew, gray mold, sclerotiniose, rot, downy mildew, samping off, epidemic disease, late blight, balck shank etc. has
Significant effect.Bactericidal composition of the present invention has anti-well to sac fungus, basidiomycetes, Fungi Imperfecti and Oomycete fungal disease
Control effect；And suppress the drug-fast generation of insect or fungi to unitary agent (Boscalid and Propamocarb are any).The present invention
Bactericidal composition can produce higher synergistic function, and the dosage of the amount ratio independent reactive compound of the mixture is big
Big to reduce, i.e., the activity of mixture is more than the activity of independent component.
Beneficial effects of the present invention compared with prior art：(1) compared with single dose, said composition antagonism fungal disease is such as
The fungal diseases such as powdery mildew, gray mold, sclerotiniose, rot, downy mildew, samping off, epidemic disease, late blight, balck shank have substantially
Synergistic function, overcome and delayed the resistance to the action of a drug, expand preventing and treating spectrum, hence it is evident that improve prevention effect；(2) preventing and treating is reduced to use
Work, drug cost；(3) alternative routine and the agricultural chemicals for being also easy to produce resistance；(4) compared with single dose, production and use cost reduce；
(5) the drug-fast generation of fungi is suppressed, its positive effect uses higher than its single dose.
Embodiment
The invention will be further described with reference to embodiments, and the preparation method of formulation is conventional side in embodiment
Method, " % " of the present invention is mass percent.
Indoor biometricses are tested：
Mycelial growth rate method, EC of the measure different agents to bacterial strain are used indoors50Value, using co-toxicity coefficient calculating side
Method, the co-toxicity coefficient (CTC) of mixture is calculated, determines the building performance of mixture, circular is as follows：
EC (is generally selected as standard agent using a certain single dose in mixture50Junior), calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
The toxicity index of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture
× B single doses proportion in mixture
Survey the EC of toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, is antagonism when CTC is less than 80, CTC exists
It is summation action between 80-120.
According to active ingredient Boscalid (A)：Propamocarb (B) quality proportioning is：70：1、50：1、30：1、20：1、10：1、
5：1、2.5：1、1：1、1：2、1：4、1：6、1：10、1：20、1：30、1：50 are tested, and determine it to Phytophthora infestans germ
The co-toxicity coefficient of (Phytophthora infestans (Mont.) de Bary).
Table 1：Indoor biometricses result of the Boscalid+Propamocarb different ratio to Phytophthora infestans germ
| Medicament | Virulence regression equation | EC50(mg/L) | Co-toxicity coefficient |
| 25% Boscalid SC | Y=1.335X+4.160 | 4.260 | - |
| 72.2% Propamocarb AS | Y=2.046X+3.361 | 6.327 | - |
| A:B=70:1 | Y=1.021X+4.280 | 5.067 | 125.45 |
| A:B=50:1 | Y=2.635X+3.457 | 3.850 | 165.39 |
| A:B=30:1 | Y=1.487X+4.250 | 3.193 | 200.24 |
| A:B=20:1 | Y=1.022X+4.446 | 3.484 | 184.47 |
| A:B=10:1 | Y=2.365X+3.779 | 3.283 | 198.63 |
| A:B=5:1 | Y=2.258X+3.816 | 3.345 | 200.05 |
| A:B=2.5:1 | Y=1.654X+3.966 | 4.220 | 165.35 |
| A:B=1:1 | Y=2.053X+3.510 | 5.318 | 142.21 |
| A:B=1:2 | Y=1.242X+4.146 | 4.870 | 166.08 |
| A:B=1:4 | Y=2.016X+3.506 | 5.512 | 155.41 |
| A:B=1:6 | Y=1.111X+4.178 | 5.489 | 160.11 |
| A:B=1:10 | Y=2.444X+3.318 | 4.877 | 184.52 |
| A:B=1:20 | Y=1.933X+3.573 | 5.472 | 167.84 |
| A:B=1:30 | Y=2.247X+3.049 | 7.384 | 125.25 |
| A:B=1:50 | Y=2.349X+2.994 | 7.148 | 130.22 |
Field control effectiveness test：
The pesticidal preparations preventing and treating tomato late blight experiment made from above-described embodiment.
1st, test process：This test medicine dosage sets three concentration for the treatment of, comparison medicine respectively according to the difference of each composition
Agent is the Propamocarb AS of agricultural chemicals single dose 72.2% and 25% Boscalid SC and blank clean water experiment respectively.
2nd, each plot area of test method is 66.7m2, it is repeated 3 times；Investigation drug effect side after investigating and prevent and treat before dispenser
Method is：5 points of grab sample in test process area, severity Scaling is carried out according to national field test relevant criterion, calculates preventive effect.
Result of the test is shown in Table 2：
The field test results of table 2
Shown by indoor biometricses and field efficacy result, Boscalid has with Propamocarb composition significantly cooperates with increasing
Effect acts on, and the prevention effect of composition is excellent, and prevention effect is better than single dose kind, has application value in agricultural is applied.
Two kinds of reactive compounds can be processed into any one formulation of permission, illustrate two kinds below with specific embodiment
The preparation that active ingredient is processed into, but the preparation that can process of the two kinds of active components be not limited only to it is set forth below.
Embodiment 1：15% Boscalid Propamocarb wettable powder (1:2)
By Boscalid 5g, Propamocarb 10g, detergent LS (to methoxyl group aliphatic acid amido benzene sulfonic acid sodium salt) 2g, diffusant
NNO (sodium methylene bis-naphthalene sulfonate) 4g, white carbon 5g, kaolin add to 100g mixtures carry out air-flow crushing, be made effectively into
It is 15% Boscalid Propamocarb wettable powder to divide mass percent.
Embodiment 2：15% Boscalid Propamocarb wettable powder (1:4)
By Boscalid 3g, Propamocarb 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin
Add to 100g mixtures and carry out air-flow crushing, it is 15% Boscalid Propamocarb wettable that active ingredient mass percent, which is made,
Pulvis.
Embodiment 3：14% Boscalid Propamocarb wettable powder (1:6)
By Boscalid 2g, Propamocarb 12g, lauryl sodium sulfate 3g, dispersing agent NNO 4g, white carbon 5g, kaolin
Add to 100g mixtures and carry out air-flow crushing, it is 14% Boscalid Propamocarb wettable that active ingredient mass percent, which is made,
Pulvis.
Embodiment 4：20% Boscalid Propamocarb suspending agent (1:1)
10g Boscalids, 10g Propamocarbs, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g are weighed, it is yellow
Virgin rubber 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g, in the presence of sand mill with water
It is 20% Boscalid Propamocarb suspending agent that effective ingredient percent, which is made,.
Embodiment 5：55% Boscalid Propamocarb aqueous emulsion (1:10)
Weigh 5g Boscalids, 50g Propamocarbs, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol
APEO 1g, solvent naphtha 13g, adds water to 100g.The method that above raw material is routinely prepared to aqueous emulsion puts into mixing kettle
High speed mixes, and it is 55% Boscalid Propamocarb aqueous emulsion that effective ingredient percent, which is made,.
Embodiment 6：42% Boscalid Propamocarb missible oil (1:20)
Weigh 2g Boscalids, 40g Propamocarbs, calcium dodecyl benzene sulfonate 8g, phenethyl phenol polyethenoxy ether 5g, solvent
Oil is to 100g.Above raw material is routinely prepared and mixed in the method input mixing kettle of missible oil, effective composition quality percentage is made
Than for 42% Boscalid Propamocarb missible oil.
Embodiment 7：70% Boscalid Propamocarb missible oil (2.5:1)
Weigh 50g Boscalids, 20g Propamocarbs, calcium dodecyl benzene sulfonate 5g, phenethyl phenol polyethenoxy ether 2g, castor
Sesame oil APEO 2g, solvent naphtha to 100g.Above raw material is routinely prepared and mixed in the method input mixing kettle of missible oil,
It is 70% Boscalid Propamocarb missible oil that effective ingredient percent, which is made,.
Embodiment 8：18% Boscalid Propamocarb water dispersion granule (5：1)
Weigh 15g Boscalids, 3g Propamocarbs, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, poly- second
Enol 5g, borax 2g, diatomite 28g complement to 100g, and above raw material is formed with into effect into sub-prime by water dispersible granular agent method
Amount percentage is 17% Boscalid Propamocarb water dispersion granule.
Embodiment 9：11% Boscalid Propamocarb missible oil (10:1)
Weigh 10g Boscalids, 1g Propamocarbs, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether 7g, solvent
Oil is to 100g.Above raw material is routinely prepared and mixed in the method input mixing kettle of missible oil, effective composition quality percentage is made
Than for 11% Boscalid Propamocarb missible oil.
Embodiment 10：31.5% Boscalid Propamocarb microemulsion (20:1)
Weigh 30g Boscalids, 1.5g Propamocarbs, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphoric acid
Ester 3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.Above raw material is routinely prepared micro-
Mixed in the method input mixing kettle of emulsion, it is 32% Boscalid Propamocarb micro emulsion that effective ingredient percent, which is made,
Agent.
Embodiment 11：31% Boscalid Propamocarb missible oil (30:1)
Weigh 30g Boscalids, 1g Propamocarbs, calcium dodecyl benzene sulfonate 4g, phenethyl phenol polyethenoxy ether 4g, solvent
Oil is to 100g.Above raw material is routinely prepared and mixed in the method input mixing kettle of missible oil, effective composition quality percentage is made
Than for 31% Boscalid Propamocarb missible oil.
Embodiment 12：51% Boscalid Propamocarb suspending agent (50:1)
Weigh 50g Boscalids, 1g Propamocarbs, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthan
Glue 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, are made in the presence of sand mill
It is 51% Boscalid Propamocarb suspending agent into active ingredient mass percent.
Embodiment 13：32% Boscalid Propamocarb microemulsion (1:15)
Weigh 2g Boscalids, 30g Propamocarbs, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.Above raw material is routinely prepared into micro emulsion
Mixed in the method input mixing kettle of agent, it is 32% Boscalid Propamocarb microemulsion that effective ingredient percent, which is made,.
Embodiment 14：6% Boscalid Propamocarb aqueous emulsion (1:5)
1g Boscalids, 5g Propamocarbs, phenethyl phenol polyethenoxy ether phosphate 3g, agriculture breast 33#2g, alkyl phenol is weighed to gather
Oxygen vinethene 1g, solvent naphtha 13g, adds water to 100g.In the method input mixing kettle that above raw material is routinely prepared to aqueous emulsion
Mixed at high speed, it is 6% Boscalid Propamocarb aqueous emulsion that effective ingredient percent, which is made,.
Embodiment 15：62% Boscalid Propamocarb microemulsion (1:30)
Weigh 2g Boscalids, 60g Propamocarbs, calcium dodecyl benzene sulfonate 6g, phenethyl phenol polyethenoxy ether phosphate
3g, agriculture breast 33#2g, APES 1g, isopropanol 10g, add water to 100g.Above raw material is routinely prepared into micro emulsion
Mixed in the method input mixing kettle of agent, it is 62% Boscalid Propamocarb microemulsion that effective ingredient percent, which is made,.
Embodiment 16：51% Boscalid Propamocarb suspending agent (1:50)
Weigh 1g Boscalids, 50g Propamocarbs, lignin 2g, polyoxyethylene poly-oxygen propylene aether and its sulfate 4g, xanthan
Glue 0.15g, ethylene glycol 5g, silica ethane 0.10g, aluminium-magnesium silicate 0.5g, complement to 100g with water, are made in the presence of sand mill
It is 51% Boscalid Propamocarb suspending agent into active ingredient mass percent.
Embodiment 17：7% Boscalid Propamocarb water dispersion granule (1：2.5)
Weigh 2g Boscalids, 5g Propamocarbs, wooden sodium sulfonate 8g, lauryl sodium sulfate 2g, ammonium sulfate 5g, polyethylene
Alcohol 5g, borax 2g, white carbon 3g, diatomite complement to 100g, by above raw material by water dispersible granular agent method be formed with effect into
It is 7% Boscalid Propamocarb water dispersion granule to divide mass percent.
Claims (9)
1. a kind of bactericidal composition containing Boscalid and Propamocarb, it is characterised in that the bactericidal composition is with Boscalid and frost
Mould prestige is principle active component, and wherein the mass ratio of Boscalid and Propamocarb is 1:50~70:1.
2. bactericidal composition according to claim 1, it is characterised in that the mass ratio of the Boscalid and Propamocarb is
1:20~50:1.
3. bactericidal composition according to claim 2, it is characterised in that the mass ratio of the Boscalid and Propamocarb is
1:20~1:2、2.5:1~50:1.
4. bactericidal composition according to claim 1, it is characterised in that both described Boscalids and Propamocarb account for group
The weight/mass percentage composition of compound is 2%~80%.
5. bactericidal composition according to claim 4, it is characterised in that both described Boscalids and Propamocarb account for group
The weight/mass percentage composition of compound is 10%~40%.
6. bactericidal composition according to claim 1, it is characterised in that using Boscalid and Propamocarb as it is main effectively into
Point and insecticides adjuvant, excipients be configured to any one formulation for allowing on agricultural chemicals.
7. bactericidal composition according to claim 6, it is characterised in that the formulation be missible oil, suspending agent, aqueous emulsion, can
WP, microemulsion or water dispersion granule.
8. application of the bactericidal composition on preventing and treating fungal diseases of plants medicine is prepared described in claim 1.
9. application according to claim 8, it is characterised in that described fungal diseases of plants is powdery mildew, gray mold, bacterium
At least one of core disease, rot, downy mildew, samping off, epidemic disease, late blight and balck shank.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610766838.0A CN107771833A (en) | 2016-08-29 | 2016-08-29 | A kind of bactericidal composition and its application containing Boscalid and Propamocarb |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610766838.0A CN107771833A (en) | 2016-08-29 | 2016-08-29 | A kind of bactericidal composition and its application containing Boscalid and Propamocarb |
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| CN107771833A true CN107771833A (en) | 2018-03-09 |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1282215A (en) * | 1997-12-18 | 2001-01-31 | 巴斯福股份公司 | Fungicide mixtures based on carboxamides and pyridine derivatives |
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2016
- 2016-08-29 CN CN201610766838.0A patent/CN107771833A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1282215A (en) * | 1997-12-18 | 2001-01-31 | 巴斯福股份公司 | Fungicide mixtures based on carboxamides and pyridine derivatives |
| EP1228691A2 (en) * | 1997-12-18 | 2002-08-07 | Basf Aktiengesellschaft | Fungicidal mixtures based on pyridine carboxamide compounds |
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Application publication date: 20180309 |