CN107699712A - A kind of metallurgy of megnesium stove and Smelting magnesium method - Google Patents

A kind of metallurgy of megnesium stove and Smelting magnesium method Download PDF

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Publication number
CN107699712A
CN107699712A CN201710892855.3A CN201710892855A CN107699712A CN 107699712 A CN107699712 A CN 107699712A CN 201710892855 A CN201710892855 A CN 201710892855A CN 107699712 A CN107699712 A CN 107699712A
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China
Prior art keywords
furnace body
flow tube
charging flow
magnesium
stove
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CN201710892855.3A
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Chinese (zh)
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CN107699712B (en
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李运雄
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Hami Shengmei Magnesium Industry Co ltd
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Individual
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/20Obtaining alkaline earth metals or magnesium
    • C22B26/22Obtaining magnesium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B5/00General methods of reducing to metals
    • C22B5/02Dry methods smelting of sulfides or formation of mattes
    • C22B5/04Dry methods smelting of sulfides or formation of mattes by aluminium, other metals or silicon

Abstract

The invention discloses a kind of metallurgy of megnesium stove, include furnace body, charging flow tube and separable bell, bell is located above furnace body, the bottom of charging flow tube is connected with the bottom of furnace body, slag-drip opening is provided with the side wall of the bottom of furnace body, interface is provided with the side wall at the top of furnace body, coil is surrounded with the lateral wall of furnace body.Metallurgy of megnesium stove proposed by the present invention, have it is simple in construction, build the advantages that facilitating, can efficiently smelt magnesium using the metallurgy of megnesium stove.The present invention also provides a kind of Smelting magnesium method, the high temperature solution directly come out by the use of mine heat furnace smelting is used as raw material reduction-oxidation magnesium, high temperature solution adds from the bottom of furnace body, make full use of the physical thermal of liquid ferrosilicon, energy consumption substantially reduces, and has reaction abundant, consumption is low, the advantages that production efficiency is high, and labor intensity is small.

Description

A kind of metallurgy of megnesium stove and Smelting magnesium method
Technical field
The present invention relates to metal smelt technical field, more particularly to a kind of metallurgy of megnesium stove and Smelting magnesium method.
Background technology
At present, the smelting of magnesium mainly has two kinds of techniques:Electrolysis and ferrosilicon process.Anhydrous chlorination is needed to use in electrolysis Magnesium, but it is big due to producing anhydrous magnesium chloride preparation difficulty, therefore constrain the use of electrolysis.Ferrosilicon process is by ferrosilicon and oxidation Magnesium powder is broken, loads after stirring in tank, then takes the air in tank away, and fills inert gas, is finally added with coal etc. Hot tank body, silicon and magnesia are in inert gas(Oxygen-free environment)With reaction generation magnesium vapor under conditions of high temperature, magnesium vapor condensation Magnesium melt has just been obtained afterwards, with regard to that can obtain magnesium ingot after cast.This technology high energy consumption, ferrosilicon reaction is insufficient, and consumption is high, production Efficiency is low, and charging and cleaning residue are difficult, and labor intensity is big.
The content of the invention
The deficiency for more than, the present invention provide a kind of metallurgy of megnesium stove that can efficiently smelt magnesium.
To reach above-mentioned purpose, the present invention adopts the following technical scheme that:
A kind of metallurgy of megnesium stove, include furnace body, charging flow tube and separable bell, the bell and be located at the furnace body Above, the bottom of the charging flow tube is connected with the bottom of the furnace body, is set in the side wall of the bottom of the furnace body There is slag-drip opening, interface is provided with the side wall at the top of the furnace body, line is surrounded with the lateral wall of the furnace body Circle.
Further, the bottom of the charging flow tube is connected with the bottom of the furnace body, including:The charging flow tube It is arranged on the outside of the furnace body, the charging flow tube is L-shaped, and Upper vertical is set, and lower horizontal is set, the feed streams In side wall of the bottom of pipe through the furnace body and the bottom positioned at the furnace body, or, the charging flow tube is arranged at On the inside of the furnace body, the charging flow tube is integrally vertically arranged, and the top of the charging flow tube passes the bell, described to add The bottom of stream pipe is located in the bottom of the furnace body.
Further, the charging flow tube and the communicating position of the furnace body are higher than the set location of the slag-drip opening.
Further, the charging flow tube is by clay fire resistant materials or high alumina refractories or magnesia refractories system Into;The inside sidewalls of the furnace body are made up of carbonaceous refractory or high alumina refractories or magnesia refractories, outside It is made up of clay fire resistant materials;The bell is formed from steel, inner side filling clay fire resistant materials or high alumina refractories Or magnesia refractories.
The present invention also provides a kind of Smelting magnesium method, and this method uses above-mentioned metallurgy of megnesium stove, includes following steps:
1)Block the slag-drip opening, toward the furnace body inside add molten iron to exceeding the slag-drip opening and the feed streams The communicating position of pipe and the furnace body;
2)Lime and burned magnesium oxide sand are added inside toward the furnace body, some or all of molten iron is in lime and oxidation Solidified in the presence of magnesia, then cover the bell and gap sealing between the bell and the furnace body is good;
3)By the interface to carrying out vacuumize process inside the furnace body, exhaust after air again by the interface to institute Filling inert gas inside furnace body is stated, until the air pressure inside the furnace body balances with atmospheric pressure;
4)The coil is connected with the mains, under electromagnetic induction effect, the molten iron of solidification is heated fusing;
5)By ferrosilicon liquation, either Si-Ca-Ba liquation or monocrystalline melted silicon are added in the furnace body by the charging flow tube Portion, to allow ferrosilicon, either Si-Ca-Ba or monocrystalline silicon and magnesia react under high temperature and inert gas environment and obtain magnesium vapor, Magnesium vapor enters magnesium vapor condenser by the interface, and magnesium melt is can obtain after condensation.
Further, Smelting magnesium method is further comprising the steps of:
6)After the completion for the treatment of ferrosilicon and oxidation reactive magnesium, magnesium vapor condenser is closed, the slag-drip opening is opened, due in electromagnetic induction Under effect, the heated fusing of clinker for reacting generation has mobility, therefore clinker and molten iron or copper water or manganese water can pass through institute State slag-drip opening discharge.
Further, Smelting magnesium method is further comprising the steps of:
7)By the interface to inert gas is filled inside the furnace body, the air pressure inside the furnace body is improved, so that Obtain clinker and molten iron or copper water or manganese water is arranged more thorough;After the completion of deslagging inside the furnace body remaining magnesium vapor from the row Cinder notch is discharged and burnt.
Further, Smelting magnesium method is further comprising the steps of:
8)After the drained rear, magnesium vapor of clinker no longer burns, block the slag-drip opening and purge the charging flow tube, and further Remove magnesium vapor inside the furnace body.
Further, Smelting magnesium method is further comprising the steps of:
9)Open the bell and clear up the furnace body internal residual clinker.
Compared with prior art, the beneficial effects of the invention are as follows:The present invention proposes a kind of metallurgy of megnesium stove, has structure letter It is single, the advantages that facilitating is built, can efficiently smelt magnesium using the metallurgy of megnesium stove.The present invention also provides a kind of Smelting magnesium method, directly Connect by the use of the high temperature solution that mine heat furnace smelting comes out as raw material reduction-oxidation magnesium, high temperature solution and added from the bottom of furnace body, So as to make full use of the physical thermal of liquid ferrosilicon, energy consumption substantially reduces, and has reaction abundant, and consumption is low, and production efficiency is high, work The advantages that intensity is small.
Brief description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, required use in being described below to embodiment Accompanying drawing be briefly described.
Fig. 1 is the schematic front view of metallurgy of megnesium stove;
Fig. 2 is the schematic top plan view of metallurgy of megnesium stove;
Fig. 3 be Fig. 2 in AA to sectional view.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation describes.Obviously, described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other under the premise of creative work is not made Embodiment, belong to the scope of protection of the invention.
Fig. 1 to Fig. 3 is refer to, the present invention provides a kind of metallurgy of megnesium stove, includes furnace body 1, charging flow tube 3 and can divide From bell 2;Bell 2 is located above furnace body 1, and the bottom of charging flow tube 3 is connected with the bottom of furnace body 1, specially adds Stream pipe 3 is arranged at the outside of furnace body 1, and charging flow tube 3 is L-shaped, and Upper vertical is set, and lower horizontal is set, and feed flow tube 3 Bottom through furnace body 1 side wall and positioned at furnace body 1 bottom in;Deslagging is provided with the side wall of the bottom of furnace body 1 The communicating position of mouth 4, charging flow tube 3 and furnace body 1 is higher than the set location of slag-drip opening 4;Set in the side wall at the top of furnace body 1 It is equipped with interface 5, interface 5 can be connected with vavuum pump, magnesium vapor condenser and the inert gas tank of outside etc.;Outside furnace body 1 Coil 6 is surrounded with side wall, when coil 6 is powered, in the presence of electromagnetic induction, molten iron is heated fusing and has flowing Property.Wherein, charging flow tube 3 is made up of clay fire resistant materials;The inside sidewalls of furnace body 1 are made up of carbonaceous refractory, outside Side is made up of clay fire resistant materials;Bell 2 is formed from steel, inner side filling clay fire resistant materials.Clay fire resistant materials energy It is enough to ensure that the present invention sustains high temperature without damaging during Smelting magnesium.
The charging flow tube 3 that " L " type is set can facilitate fluid(Ferrosilicon liquation etc.)Into inside furnace body 1, stove is arranged at The cleaning and maintenance of charging flow tube 3 are also easy to outside body 1.Charging flow tube 3 and the communicating position of furnace body 1 are higher than slag-drip opening 4 Set location, this set can conveniently smelt after the completion of deslagging.
A kind of Smelting magnesium method provided by the invention, this method coordinate above-mentioned metallurgy of megnesium stove to be used together, included following Step:
1)Block slag-drip opening 4 with stemming, toward furnace body 1 inside add molten iron to exceeding slag-drip opening 4 and charging flow tube 3 and stove The communicating position of body 1.
Wherein, before slag-drip opening 4 is blocked or simultaneously, also early-stage preparations:It is cold that interface 5 is connected into vavuum pump, magnesium vapor Condenser and inert gas tank, pass through the company of Valve controlling interface 5 and vavuum pump, magnesium vapor condenser and inert gas tank It is logical;After the ferrosilicon solution of production and application is by mine heat furnace smelting, it is contained in ladle, and be incubated.
2)Lime and burned magnesium oxide sand, effect of the molten iron in lime and magnesium oxide sand are added inside toward furnace body 1 It is lower to solidify the communicating position for simultaneously blocking charging flow tube 3 and furnace body 1, then cover bell 2 and by bell 2 and furnace body 1 it Between gap sealing it is good.
3)Start vavuum pump, vacuumize process is carried out to the inside of furnace body 1 by interface 5, after exhausting air, opens inertia Gas tank valve is again by interface 5 to filling inert gas inside furnace body 1(Such as argon gas, helium), until inside furnace body 1 Air pressure and atmospheric pressure balance, inert gas tank valve is closed after balance.
4)Coil 6 is connected with the mains, under electromagnetic induction effect, the molten iron of solidification, which is heated, to be melted and have mobility.
5)Ladle is hung into the top of charging flow tube 3, the mouth of a river opens the mouth of a river, ferrosilicon is melted to end entrance in the flow tube 3 that enters to feed Liquid is added inside furnace body 1 by the flow tube 3 that feeds, to allow ferrosilicon and magnesia to react generation under high temperature and inert gas environment Magnesium vapor, silica and molten iron, silica act on forming clinker with lime, and magnesium vapor is cold into magnesium vapor by interface 5 Condenser, magnesium melt is can obtain after condensation.
After U.S. liquation is obtained, in order to realize the cleaning to furnace body 1 and the grade of flow tube 3 that feeds to realize next time Smelt, can also comprise the following steps:
6)After the completion for the treatment of ferrosilicon and oxidation reactive magnesium, magnesium vapor condenser is closed, slag-drip opening 4 is opened, due to making in electromagnetic induction Under, the clinker of silica and lime reaction generation, which is heated fusing, has mobility, therefore clinker and molten iron can pass through row Cinder notch 4 is discharged.The clinker and molten iron that slag-drip opening 4 is discharged can be separated by prior art, and molten iron is used for the production of next stove.
7)Improved using inert gas tank by interface 5 to inert gas is filled inside furnace body 1 inside furnace body 1 Air pressure, to cause clinker and molten iron to arrange more thorough;The remaining magnesium vapor in the inside of furnace body 1 is discharged from slag-drip opening 4 after the completion of deslagging And burn.
8)After the drained rear, magnesium vapor of clinker no longer burns, block slag-drip opening 4 with stemming and purge charging flow tube 3, go forward side by side One step removes the inside magnesium vapor of furnace body 1, prevents from exploding.
9)Open bell 2 and clear up the internal residual clinker of furnace body 1.
Metallurgy of megnesium stove proposed by the present invention, has simple in construction, builds the advantages that facilitating, can be high using the metallurgy of megnesium stove Effect smelts magnesium.Smelting magnesium method provided by the invention, the ferrosilicon of the high-temperature liquid state directly come out by the use of mine heat furnace smelting are used as original Expect reduction-oxidation magnesium, make full use of the physical thermal of liquid ferrosilicon, energy consumption substantially reduces, and has reaction abundant, and consumption is low, production effect The advantages that rate is high, and labor intensity is small.
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any Those familiar with the art the invention discloses technical scope in, the change or replacement that can readily occur in, all should It is included within the scope of the present invention.Therefore, protection scope of the present invention should using the scope of the claims as It is accurate.

Claims (9)

1. a kind of metallurgy of megnesium stove, includes furnace body(1), charging flow tube(3)And separable bell(2), the bell(2) Positioned at the furnace body(1)Above, it is characterised in that:The charging flow tube(3)Bottom and the furnace body(1)Bottom phase Connection, the furnace body(1)Bottom side wall on be provided with slag-drip opening(4), the furnace body(1)Top side wall on set It is equipped with interface(5), the furnace body(1)Lateral wall on be surrounded with coil(6).
2. metallurgy of megnesium stove according to claim 1, it is characterised in that:The charging flow tube(3)Bottom and the stove sheet Body(1)Bottom be connected, including:The charging flow tube(3)It is arranged at the furnace body(1)Outside, the charging flow tube(3) L-shaped, Upper vertical is set, and lower horizontal is set, the charging flow tube(3)Bottom pass through the furnace body(1)Side Wall is simultaneously located at the furnace body(1)Bottom in, or, the charging flow tube(3)It is arranged at the furnace body(1)Inner side, institute State charging flow tube(3)Entirety is vertically arranged, the charging flow tube(3)Top pass the bell(2), the charging flow tube (3)Bottom be located at the furnace body(1)Bottom in.
3. metallurgy of megnesium stove according to claim 1, it is characterised in that:The charging flow tube(3)With the furnace body(1)'s Communicating position is higher than the slag-drip opening(4)Set location.
4. metallurgy of megnesium stove according to claim 1, it is characterised in that:The charging flow tube(3)By clay fire resistant materials Or high alumina refractories or magnesia refractories are made;The furnace body(1)Inside sidewalls be made up of carbonaceous refractory, Outside is made up of clay fire resistant materials or high alumina refractories or magnesia refractories;The bell(2)It is formed from steel, it is interior Fill clay fire resistant materials or high alumina refractories or magnesia refractories in side.
5. the Smelting magnesium method that the metallurgy of megnesium stove described in a kind of usage right requirement 1 to 4 is carried out, it is characterised in that include with Lower step:
1)Block the slag-drip opening(4), toward the furnace body(1)Inside adds molten iron to exceeding the slag-drip opening(4)And The charging flow tube(3)With the furnace body(1)Communicating position;
2)Toward the furnace body(1)Inside adds lime and magnesia, and some or all of molten iron is in lime and the work of magnesia With lower solidification, the bell is then covered(2)And by the bell(2)With the furnace body(1)Between gap sealing it is good;
3)Pass through the interface(5)To the furnace body(1)Inside carries out vacuumize process, is connect again by described after exhausting air Mouthful(5)To the furnace body(1)Inside filling inert gas, until the furnace body(1)Internal air pressure balances with atmospheric pressure;
4)By the coil(6)Connect with the mains, under electromagnetic induction effect, the molten iron of solidification is heated fusing;
5)By ferrosilicon liquation, either Si-Ca-Ba liquation or monocrystalline melted silicon pass through the charging flow tube(3)Add the furnace body (1)Inside, to allow ferrosilicon, either Si-Ca-Ba or monocrystalline silicon and magnesia react under high temperature and inert gas environment and obtain magnesium Steam, magnesium vapor pass through the interface(5)Into magnesium vapor condenser, magnesium melt is can obtain after condensation.
6. Smelting magnesium method according to claim 5, it is characterised in that further comprising the steps of:
6)After the completion for the treatment of ferrosilicon and oxidation reactive magnesium, magnesium vapor condenser is closed, opens the slag-drip opening(4), due in electromagnetism Under induction effect, the heated fusing of clinker for reacting generation has mobility, therefore clinker and molten iron can pass through the slag-drip opening (4)Discharge.
7. Smelting magnesium method according to claim 6, it is characterised in that further comprising the steps of:
7)Pass through the interface(5)To the furnace body(1)Inside filling inert gas, improves the furnace body(1)Internal Air pressure, to cause clinker and molten iron to arrange more thorough;The furnace body after the completion of deslagging(1)Internal remaining magnesium vapor is from the row Cinder notch(4)Discharge and burn.
8. Smelting magnesium method according to claim 7, it is characterised in that further comprising the steps of:
8)After the drained rear, magnesium vapor of clinker no longer burns, the slag-drip opening is blocked(4)And purge the charging flow tube(3), and Further remove the furnace body(1)Internal magnesium vapor.
9. Smelting magnesium method according to claim 8, it is characterised in that further comprising the steps of:
9)Open the bell(2)And clear up the furnace body(1)Internal residual clinker.
CN201710892855.3A 2017-09-27 2017-09-27 Magnesium metallurgical furnace and magnesium smelting method Active CN107699712B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110219021A (en) * 2019-06-19 2019-09-10 李运雄 A kind of closing down magnesium electrolysis bath and magnesium eletrolysis technique

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CN104651636A (en) * 2015-02-06 2015-05-27 牛强 Vacuum electrothermal magnesium smelting apparatus with protector
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CN102041398A (en) * 2010-11-19 2011-05-04 重庆大学 Process and device for preparing magnesium by utilizing smelting reduction carbothermy
CN201942729U (en) * 2010-12-13 2011-08-24 昆明理工大学 Semi-continuous vacuum induction heating magnesium reduction furnace
CN202047117U (en) * 2011-04-14 2011-11-23 杨同华 Reducing furnace for smelting magnesium continuously
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Publication number Priority date Publication date Assignee Title
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