CN109022826A - Reduction refining integration smelting system - Google Patents

Reduction refining integration smelting system Download PDF

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Publication number
CN109022826A
CN109022826A CN201811218687.0A CN201811218687A CN109022826A CN 109022826 A CN109022826 A CN 109022826A CN 201811218687 A CN201811218687 A CN 201811218687A CN 109022826 A CN109022826 A CN 109022826A
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CN
China
Prior art keywords
magnesium
pipeline
heater
reductive jar
argon gas
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CN201811218687.0A
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Chinese (zh)
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CN109022826B (en
Inventor
习朋欢
冯蕾
董泊宁
徐东明
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Xi'an Silver Magnesium Equipment Co Ltd
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Xi'an Silver Magnesium Equipment Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/20Obtaining alkaline earth metals or magnesium
    • C22B26/22Obtaining magnesium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Abstract

The present invention relates to reduction refining integration smelting systems, including reductive jar, vacuum unit, crystallisation by cooling unit, argon gas protection location and magnesium liquid collector unit;Heat insulating block is set in reductive jar top, reductive jar cooling jacket is set outside reductive jar top, the upper opening of reductive jar is sealed by reductive jar upper cover;Reductive jar is connect by magnesium vapor pipeline with crystallisation by cooling unit;Crystallisation by cooling unit includes crystallizer heater upper cover, potassium sodium plate, heater and crystallizer;Vacuum unit includes vacuum line and vacuum pump;Argon gas protection location includes argon gas pipeline and argon gas feed device;Magnesium liquid collector unit includes refractory ceramics valve and magnesium liquid pipeline, and magnesium liquid pipeline is connect with heater, and the outlet of the entrance and magnesium vapor pipeline of magnesium liquid pipeline is arranged in refractory ceramics valve.The present invention solves that prior art magnesium recovery utilization rate is low, seriously polluted, operating environment is dangerous, the low problem of magnesium ingot quality.

Description

Reduction refining integration smelting system
Technical field
The invention belongs to magnesium metal smelting technical fields, and in particular to a kind of reduction refining integration smelting system, Meet refining and the ingot casting that magnesium metal crude magnesium is realized under the premise of energy conservation and environmental protection requires.
Background technique
Pidgeon process (vacuum ferrosilicon process) refines magnesium crude magnesium obtained (Crystalline Magnesium) and contains many metal impurities and nonmetallic miscellaneous Matter cause crude magnesium (Crystalline Magnesium) volume it is big, it is loose, be not easy keeping, storage, transport, and these metal impurities can with magnesium formed merchant's method Electrochemical corrosion occurs for Buddhist nun's battery, and magnesium plays anode, and the metal impurities such as iron and nickel play cathodic process, accelerate the corrosion of magnesium.Cause This crude magnesium, which must refine, can be only achieved the requirement that industry directly uses.
Vacuum breaker (air vacuum breaker) takes out crystallizer after production of magnesium by pidgeonprocess obtains Crystalline Magnesium, by Crystalline Magnesium from crystallizer Refining plant is sent into abjection.Refining solvent is added in refining process first in crucible, Crystalline Magnesium is reloaded into, in 750 DEG C of temperature Lower heating and melting is slowly added into Crystalline Magnesium and melting solvent, when the magnesium in crucible reaches the height of crucible dischargeable capacity, makes earthenware Magnesium liquid temperature is maintained at 710 DEG C in crucible, refining solvent is then added, while being stirred (stirring while adding), mixing time is about 10 minutes, then temperature is risen to 740 DEG C (or 720 DEG C), and stand 5 ~ 10 minutes, protected after being cooled to 710 DEG C to magnesium liquid Temperature completes the refining of crude magnesium.Magnesium burns in refining process, need to spread the burning that covering flux prevents magnesium, prevent the oxidation of magnesium Loss.
Continuous casting machine ingot casting is used after refining, and the crucible for filling molten magnesium is hung in into the heat preservation of tipper valve and is two-mand ladle, Tipper tilts, and in the ingot mould in crucible on magnesium liquid injection mould ingot conveyer, during ingot casting, spreads lower sulphur powder, makes sulphur powder It burns on magnesium ingot surface and generates sulfur dioxide gas, prevent the oxidation of magnesium, casting process is completed.
Traditional refining furnace refining crude magnesium and casting process have some disadvantages:
1, traditional method of refining using air vacuum breaker and needs first to refine crude magnesium again from crystallizer taking-up, in reduction furnace Oxygen, nitrogen combustion generate MgO, MgN in magnesium and air during vacuum breaker in crystallizer, reduce Mg yield, produce simultaneously Raw dust polluting environment;2, the rate of recovery of smart magnesium is generally 94% or so (Zhu Danqing brief talks ferrosilicon process magnesium in conventional refining processes Refinery practice and content of magnesium in design, light metal 1996(5) 42-48) refining slag are higher, and waste of resource pollutes environment;3, it refines It needs to pick and place refining copple by driving in the process, operating process is dangerous;4, refining process is discontinuous, and a large amount of Mg are turning Oxidation loss in fortune and fusion process;5, the refining solvent added in refining process is 2# solvent, can be produced in solvent adding procedure Raw poisonous and harmful flue dust, and these flue dust cannot be handled effectively in collection, worker operation environment is poor, seriously polluted;6, casting process Middle Mg is oxidizable, reduces ingot casting quality;Sulphur powder is spread during ingot casting and generates sulfur dioxide gas, pollutes environment;7, solvent essence The magnesium ingot purity that refining casting obtains is only 99.95%, and quality is lower;8, the crystallizer of conventional shaft reduction tank is built in reductive jar In cooling jacket, Crystalline Magnesium purity can be caused low with some impurity in magnesium vapor uphill process.
Summary of the invention
The object of the present invention is to provide a kind of metallic magnesium refining and continuous casting systems, solve and magnesium exists in the prior art Recovery utilization rate is low, seriously polluted, operating environment is dangerous, the low problem of magnesium ingot quality.
In order to achieve the above object, technical scheme is as follows:
A kind of reduction refining integration smelting system, including reductive jar, vacuum unit, crystallisation by cooling unit, argon gas protection location With magnesium liquid collector unit;Heat insulating block is set in the reductive jar top, reductive jar cooling jacket is set outside reductive jar top, also The upper opening of former tank is sealed by reductive jar upper cover;The reductive jar is connected by magnesium vapor pipeline and the crystallisation by cooling unit It connects;Crystallisation by cooling unit includes crystallizer heater upper cover, potassium sodium plate, heater and crystallizer, and the crystallizer setting is adding In hot device, potassium sodium plate is arranged in crystallizer upper end, and heater upper cover is arranged in the upper opening of heater;The vacuum unit includes vacuum Pipeline and vacuum pump, heater connect vacuum pump by vacuum line;The argon gas protection location includes argon gas pipeline and argon gas Feedway, heater argon gas piping connection argon gas feed device;The magnesium liquid collector unit include refractory ceramics valve and Magnesium liquid pipeline, magnesium liquid pipeline connect with heater, and the entrance and magnesium vapor pipeline of magnesium liquid pipeline is arranged in refractory ceramics valve Outlet.
Further, the reductive jar setting is multiple, and the magnesium vapor pipeline includes vertical section and horizontal segment, multiple reduction Tank is connect by pipeline with the vertical section of magnesium vapor pipeline, and the horizontal segment of magnesium vapor pipeline is connect with intermediate frequency furnace.
Further, the crystallizer is made of non electromagnetic induction heating material.
Further, the crystallizer is made of graphite material.
Further, the magnesium liquid protection pipeline, magnesium vapor pipeline include pipeline body, heat-preservation cotton and heating device; The heat-preservation cotton is wrapped in outside pipeline body, and the heating device compartment heats pipeline body.
Further, the heat insulating block is made of aluminosilicate fiberboard.
Beneficial effects of the present invention:
The present invention uses the structure put and (be placed into other than reductive jar) outside crystallizer, and impurity is passing through magnesium vapor pipeline in magnesium vapor When, it carries out playing the role of impurity screening, the crude magnesium quality of crystallization is more preferable from settling.Using argon gas vacuum breaker, crude magnesium is prevented It is contacted with air, avoids the dust and MgO of the production of vacuum breaker process;Crude magnesium on crystallizer directly heats liquid under ar gas environment Change, do not have to addition refining solvent, do not contacted with air, ensure that the quality of magnesium, contamination-free generates and easy to operate;Insulating tube Magnesium liquid in road flows into always casting machine under protection of argon gas, and casts under argon gas protection environment, avoids use Sulphur powder and caused by sulfur dioxide gas body pollution.
Detailed description of the invention
Fig. 1 is reduction refining integration smelting system structural schematic diagram of the present invention;
Fig. 2 is the schematic diagram of magnesium liquid pipeline and magnesium vapor pipeline of the present invention;
In figure, 1- vacuum pump, 2- vacuum line, 3- heater upper cover, 4- potassium sodium plate, 5- heater, 6- crystallizer, 7- high temperature resistant Ceramic valve, 8- magnesium liquid pipeline, 9- argon gas pipeline, 10- argon gas feed device, 11- reductive jar upper cover, 12- reductive jar cooling jacket, 13- heat insulating block, 14- reductive jar, 15- magnesium vapor pipeline, 16- pipeline body, 17- heat-preservation cotton, 18- heating device.
Specific embodiment
Below by specific embodiment combination attached drawing, invention is further described in detail.Wherein different embodiments Middle similar component uses associated similar element numbers.In the following embodiments, many datail descriptions be in order to The application is better understood.However, those skilled in the art can recognize without lifting an eyebrow, part of feature It is dispensed, or can be substituted by other elements, material, method in varied situations.In some cases, this Shen Please it is relevant it is some operation there is no in the description show or describe, this is the core in order to avoid the application by mistake More descriptions are flooded, and to those skilled in the art, these relevant operations, which are described in detail, not to be necessary, they Relevant operation can be completely understood according to the general technology knowledge of description and this field in specification.
A kind of reduction refining integration smelting system shown in Figure 1, including reductive jar 14, vacuum unit, cooling knot Brilliant unit, argon gas protection location and magnesium liquid collector unit;Heat insulating block 13 is set in 14 top of reductive jar, outside 14 top of reductive jar Reductive jar cooling jacket 12 is set, and the upper opening of reductive jar 14 passes through former tank upper cover 11 and seals;Reductive jar 14 passes through magnesium vapor pipe Road 15 is connect with crystallisation by cooling unit;Crystallisation by cooling unit includes crystallizer heater upper cover 3, potassium sodium plate 4, heater 5 and knot Brilliant device 6, crystallizer 6 are arranged in heater 5, and potassium sodium plate 4 is arranged in 6 upper end of crystallizer, and heater is arranged in the upper opening of heater 5 Upper cover 3;Vacuum unit includes vacuum line 2 and vacuum pump 1, and heater 5 connects vacuum pump 1 by vacuum line 2;Argon gas protection Unit includes argon gas pipeline 9 and argon gas feed device 10, and 5 argon gas pipeline 9 of heater connects argon gas feed device 10;Magnesium liquidization is received Collecting unit includes refractory ceramics valve 7 and magnesium liquid pipeline 8, and magnesium liquid pipeline 8 is connect with heater 5, and the setting of refractory ceramics valve 7 exists Magnesium liquid pipeline 8 exports.
Reductive jar 14 is arranged two, and magnesium vapor pipeline 15 includes vertical section and horizontal segment, and two reductive jars 14 pass through threeway Valve is connect with the vertical section of magnesium vapor pipeline 15, and the horizontal segment of magnesium vapor pipeline 15 is connect with heater 5.
Referring to fig. 2, magnesium liquid pipeline 8, magnesium vapor pipeline 15 include pipeline body 16, heat-preservation cotton 17 and heating device 18; The heat-preservation cotton 17 is wrapped in outside pipeline body 16, and 18 compartment of heating device heats pipeline body 16.
The use process of apparatus of the present invention is described below:
The present invention is using the structure put and (be placed into other than reductive jar) outside crystallizer, when reduction reaction carries out, opens magnesium vapor pipe The refractory ceramics valve 7 on road, magnesium vapor enter 6 crystallisation by cooling of crystallizer by magnesium vapor pipeline 15.Impurity is passing through in magnesium vapor When crossing the vertical section of magnesium vapor pipeline 15, carry out playing the role of impurity screening from settling.Reduction reaction terminates, using argon gas Argon gas vacuum breaker in feedway 10, prevents crude magnesium and contacts with air, the dust and MgO for avoiding vacuum breaker process from producing;It is broken true Sky terminates, and closes the refractory ceramics valve 7 on magnesium vapor pipeline 15, opens after opening the refractory ceramics valve 7 on magnesium liquid pipeline 8 Heater 5, the crude magnesium on crystallizer directly heat liquefaction under ar gas environment and enter magnesium liquid pipeline 8, the magnesium liquid in magnesium liquid pipeline 8 It flows into continuous casting machine under protection of argon gas always, and casts under argon gas protection environment, avoid using sulphur powder Sulfur dioxide gas body pollution caused by and.
Present applicant proposes reduction refining integration smelting system to traditional reductive jar and crystal system mainly have with Lower innovative point: 1, reductive jar water jacket height is reduced, and places aluminosilicate fiber cotton in water jacket bottom, prevents magnesium vapor at water jacket Crystallization;2, change crystallizer material, crystallizer cannot be placed on by the material of electromagnetic induction heating by reductive jar using graphite etc. External top makes the impurity in magnesium vapor from settling, play the effect of double purification in the duct, improve the pure of Crystalline Magnesium Degree;3, magnesium vapor/magnesium liquid pipeline is subjected to INSULATION DESIGN, and compartment/continous way is carried out to pipeline using heating device and is heated, Guarantee magnesium liquid/magnesium vapor temperature in pipeline, prevents magnesium from crystallizing or solidifying.
Use above specific case is illustrated the present invention, is merely used to help understand the present invention, not to limit The system present invention.For those skilled in the art, according to the thought of the present invention, can also make several simple It deduces, deform or replaces.

Claims (6)

1. reduction refining integration smelting system, it is characterised in that: including reductive jar (14), vacuum unit, crystallisation by cooling list Member, argon gas protection location and magnesium liquid collector unit;Heat insulating block (13) are set in reductive jar (14) top, reductive jar (14) Reductive jar cooling jacket (12) are set outside top, the upper opening of reductive jar (14) is sealed by reductive jar upper cover (11);It is described to go back Former tank (14) is connect by magnesium vapor pipeline (15) with the crystallisation by cooling unit;Crystallisation by cooling unit includes crystallizer heater Upper cover (3), potassium sodium plate (4), heater (5) and crystallizer (6), crystallizer (6) setting is in heater (5), crystallizer (6) heater upper cover (3) are arranged in the upper opening of upper end setting potassium sodium plate (4), heater (5);The vacuum unit includes vacuum Pipeline (2) and vacuum pump (1), heater (5) pass through vacuum line (2) connection vacuum pump (1);The argon gas protection location includes Argon gas pipeline 9 and argon gas feed device (10), heater (5) argon gas pipeline (9) connect argon gas feed device (10);The magnesium liquid Changing collector unit includes refractory ceramics valve (7) and magnesium liquid pipeline (8), and magnesium liquid pipeline (8) is connect with heater (5), high temperature resistant Ceramic valve (7) is arranged in the outlet of the entrance and magnesium vapor pipeline (15) of magnesium liquid pipeline (8).
2. reduction refining integration smelting system according to claim 1, it is characterised in that: reductive jar (14) setting Multiple, the magnesium vapor pipeline (15) includes vertical section and horizontal segment, and multiple reductive jars (14) pass through pipeline and magnesium vapor pipeline (15) vertical section connection, the horizontal segment of magnesium vapor pipeline (15) are connect with intermediate frequency furnace (5).
3. reduction refining integration smelting system according to claim 1 or claim 2, it is characterised in that: the crystallizer (6) is adopted It is made of non electromagnetic induction heating material.
4. reduction refining integration smelting system according to claim 3, it is characterised in that: the crystallizer (6) uses stone Black material is made.
5. reduction refining integration smelting system according to claim 4, it is characterised in that: the magnesium liquid protects pipeline (8), magnesium vapor pipeline (15) includes pipeline body (16), heat-preservation cotton (17) and heating device (18);The heat-preservation cotton (17) It is wrapped in pipeline body (16) outside, heating device (18) compartment heats pipeline body (6).
6. reduction refining integration smelting system according to claim 5, it is characterised in that: the heat insulating block (13) is by silicon Sour aluminum fiberboard is made.
CN201811218687.0A 2018-10-19 2018-10-19 Reduction and refining integrated smelting system Active CN109022826B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110863118A (en) * 2019-11-27 2020-03-06 国科镁业科技(河南)有限公司 Application of nickel-based filter material in gas-phase magnesium purification and production system comprising same
CN111778410A (en) * 2020-07-07 2020-10-16 西安银研镁业装备有限公司 Clean vacuum pyrometallurgical zinc smelting device and zinc smelting method
CN113737019A (en) * 2021-08-25 2021-12-03 西安交通大学 Method and device for continuously extracting crystallized magnesium in Pidgeon magnesium smelting process at high temperature
CN113774235A (en) * 2021-08-25 2021-12-10 西安交通大学 Method and device for intermittently and continuously extracting crystallized magnesium in Pidgeon magnesium smelting

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CN1827808A (en) * 2006-03-24 2006-09-06 东北大学 Inner resistance heating metallothermic reduction furnace for melting magnesium
CN201942729U (en) * 2010-12-13 2011-08-24 昆明理工大学 Semi-continuous vacuum induction heating magnesium reduction furnace
CN201981246U (en) * 2011-02-25 2011-09-21 王全祥 Reduction furnace device for vacuum-thermal reduction of metallic magnesium
CN105950889A (en) * 2016-06-29 2016-09-21 狄保法 Electric arc furnace vacuum magnesium smelting system and magnesium smelting method thereof
CN106191467A (en) * 2016-07-12 2016-12-07 吉林市润成膜科技有限公司 A kind of method that former Smelting magnesium prepares porous silicon simultaneously
CN108188408A (en) * 2018-01-04 2018-06-22 北京理工大学 A kind of spherical atomization magnesium zinc non-crystaline amorphous metal powder and preparation method thereof
CN209052749U (en) * 2018-10-19 2019-07-02 西安银研镁业装备有限公司 A kind of reduction refining integration smelting system

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1827808A (en) * 2006-03-24 2006-09-06 东北大学 Inner resistance heating metallothermic reduction furnace for melting magnesium
CN201942729U (en) * 2010-12-13 2011-08-24 昆明理工大学 Semi-continuous vacuum induction heating magnesium reduction furnace
CN201981246U (en) * 2011-02-25 2011-09-21 王全祥 Reduction furnace device for vacuum-thermal reduction of metallic magnesium
CN105950889A (en) * 2016-06-29 2016-09-21 狄保法 Electric arc furnace vacuum magnesium smelting system and magnesium smelting method thereof
CN106191467A (en) * 2016-07-12 2016-12-07 吉林市润成膜科技有限公司 A kind of method that former Smelting magnesium prepares porous silicon simultaneously
CN108188408A (en) * 2018-01-04 2018-06-22 北京理工大学 A kind of spherical atomization magnesium zinc non-crystaline amorphous metal powder and preparation method thereof
CN209052749U (en) * 2018-10-19 2019-07-02 西安银研镁业装备有限公司 A kind of reduction refining integration smelting system

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110863118A (en) * 2019-11-27 2020-03-06 国科镁业科技(河南)有限公司 Application of nickel-based filter material in gas-phase magnesium purification and production system comprising same
CN111778410A (en) * 2020-07-07 2020-10-16 西安银研镁业装备有限公司 Clean vacuum pyrometallurgical zinc smelting device and zinc smelting method
CN113737019A (en) * 2021-08-25 2021-12-03 西安交通大学 Method and device for continuously extracting crystallized magnesium in Pidgeon magnesium smelting process at high temperature
CN113774235A (en) * 2021-08-25 2021-12-10 西安交通大学 Method and device for intermittently and continuously extracting crystallized magnesium in Pidgeon magnesium smelting

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