CN107699041A - A kind of household china silica gel stamp-pad ink and household china silica gel ink and preparation method thereof - Google Patents

A kind of household china silica gel stamp-pad ink and household china silica gel ink and preparation method thereof Download PDF

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Publication number
CN107699041A
CN107699041A CN201710993498.XA CN201710993498A CN107699041A CN 107699041 A CN107699041 A CN 107699041A CN 201710993498 A CN201710993498 A CN 201710993498A CN 107699041 A CN107699041 A CN 107699041A
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silica gel
household china
weight
ink
parts
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CN201710993498.XA
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Inventor
郑周
王斌
黄月文
鲁道欢
姜智聪
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Guangzhou Chemical Co Ltd of CAS
Nanxiong Material Production Base of Guangzhou Chemical Co Ltd of CAS
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Guangzhou Chemical Co Ltd of CAS
Nanxiong Material Production Base of Guangzhou Chemical Co Ltd of CAS
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Priority to CN201710993498.XA priority Critical patent/CN107699041A/en
Publication of CN107699041A publication Critical patent/CN107699041A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5025Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with ceramic materials
    • C04B41/5042Zirconium oxides or zirconates; Hafnium oxides or hafnates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/87Ceramics
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/06Printing inks based on fatty oils

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention provides a kind of household china silica gel stamp-pad ink and household china silica gel ink and preparation method thereof.Described household china silica gel stamp-pad ink includes the thickener of the parts by weight of the following raw material 10~15, the wetting agent of 4~10 parts by weight, the finish of 0.5~1 parts by weight, the water of 71~86 parts by weight, the liquefacient of 0.1~2 parts by weight, the emulsifying agent of 1~5 parts by weight, the defoamer of 0.01~0.1 parts by weight and the preservative of 0~0.5 parts by weight.The household china silica gel stamp-pad ink of the present invention is combined with toner, obtain household china silica gel ink of the present invention, the household china silica gel ink of gained possesses good amphipathic property and uphangs buoyancy, ink both can be stable in masterplate, Silica Surface coating during stamp, bat printing is stable, ungauged regions, sun-dried mud brick particle and frit particles can be firmly adsorbed again, and meet glazing requirement, possess good application prospect in ceramic field.

Description

A kind of household china silica gel stamp-pad ink and household china silica gel ink and preparation method thereof
Technical field
The invention belongs to ceramic field, more particularly to a kind of household china silica gel stamp-pad ink and household china silica gel ink and its preparation Method.
Background technology
China is the cradle of ceramic technology and ceramic art, the extensive use of printing technology, greatly improves ceramics The efficiency and quality of decoration;Traditional household china stamp is mainly decal paper technology, i.e., the graph text information for stamp is passed through common Be printed on special paper, paper be printed on ceramic sun-dried mud brick surface by binding agent, but decal paper technology artificial and Many negative factors such as paper cost and its low production efficiency brought, paper material consumption, can not meet social environment to pottery The requirement of porcelain industry, limit the development of ceramic industry.Ceramic printing machine is to have been coated with printing inks by using soft silica gel extruding Pattern steel plate, after soft silica gel adsorb curing ink after, then by extrude be desorbed, ink is printed on ceramic sun-dried mud brick, so as to complete Stamp;Whole process eliminates decal paper and the process for making marble paper, has not only reduced cost but also has improved production efficiency;Now printing inks It is the key of printing technique in the carrier as graph text information.
The most water-based or oiliness of existing market stamp-pad ink, is prepared into the problems that ink still faces:(1) have with soft silica gel Certain repulsion and contraction, after being printed on sun-dried mud brick, the defects of the deformation of the lines of formation or missing;(2) suspension is bad, stamp process In occur reuniting or lamination is, it is necessary to constantly re-mix;(3) cohesive force is not strong after ink trace is dried, in production operation Easily it is damaged or comes off in journey;(4) oiliness is excessive can not glazing etc..Therefore, how to obtain the more excellent ink of performance turns into Technical problem urgently to be resolved hurrily in the industry at present.
The content of the invention
The shortcomings that primary and foremost purpose of the present invention is to overcome prior art and deficiency, there is provided a kind of household china silica gel stamp-pad ink.
Another object of the present invention is to provide the preparation method of described household china silica gel stamp-pad ink.
A further object of the present invention is to provide a kind of household china silica gel ink.
It is still another object of the present invention to provide the preparation method of described household china silica gel ink.
The purpose of the present invention is achieved through the following technical solutions:
A kind of household china silica gel stamp-pad ink, its raw material include by weight ratio:
Described thickener is sodium carboxymethylcellulose, sodium carboxymethyl starch, methylcellulose, hydroxypropyl methyl fiber Element, peach gum, sodium alginate, melon and one kind in glue or at least two.
Described wetting agent is propane diols, D-sorbite, one kind in glycerine or at least two.
Described finish is one kind in castor oil, white oil, palm oil, hydroxyl endblocked polydimethylsiloxane, paraffin oil Or at least two.
Described liquefacient is sodium tripolyphosphate, sodium metasilicate, Sodium Polyacrylate, one kind in ammonium polyacrylate or at least Two kinds;The proportioning of described liquefacient is more preferably 1~2 parts by weight.
Described emulsifying agent is polysorbas20, Tween 80, one kind in this Pan 60, AEO or at least two Kind.
Described defoamer is polyoxyethylene polyoxy propyl alcohol amidogen ether, polyoxyethylene polyoxypropylene pentaerythrite ether, polyethers-silicon One kind in siloxane copolymers or at least two.
Described preservative is in methyl p-hydroxybenzoate, ethyl-para-hydroxybenzoate, potassium sorbate, natrium nitrosum One kind or at least two.
Described water is preferably deionized water, pure water, distilled water or ultra-pure water.
The preparation method of described household china silica gel stamp-pad ink, comprises the following steps:
(1) thickener, wetting agent, finish and water are added by proportioning, heating is mixed to being completely dissolved, and obtains mixed liquor;
(2) liquefacient, emulsifying agent, defoamer, preservative are added in the mixed liquor obtained in step (1), is well mixed, Produce described household china silica gel stamp-pad ink.
The temperature of heating described in step (1) is preferably 75 DEG C~85 DEG C;More preferably 80 DEG C.
A kind of household china silica gel ink, its raw material include by weight ratio:
The parts by weight of toner 40~55
The described parts by weight of household china silica gel stamp-pad ink 45~60
Described household china silica gel ink, its raw material preferably include by weight ratio:The toner of 45 parts by weight, 55 weight The described household china silica gel stamp-pad ink of part.
Described toner is ceramic high temperature pigment and one kind in colouring agent or at least two.
Described ceramic high temperature pigment is preferably one or both of dark blue zirconium oxide and indigo-blue zirconium oxide;Described Toner is preferably iron oxide red.
Described toner is preferably the toner that granularity D50 is 5 μm.
The viscosity of described household china silica gel ink is preferably 3500~4500cps/10min.
The preparation method of described household china silica gel ink, comprises the following steps:Toner and described daily is taken by proportioning Porcelain silica gel stamp-pad ink, it is well mixed, produces described household china silica gel ink.
Described mixing is preferably mixed by ball milling;The time of mixing is preferably 8~15 minutes;More preferably 10 minutes.
Household china printing inks of the present invention are that have high activity according to ceramic powder particle table, can with adion, The characteristics of hydrophilic group, the hydroxyl in thickener, wetting agent is adsorbed in by toner particle surface by ball milling mixing, then by emulsifying agent Toner surface is anchored with hydrophilic group in liquefacient, hydrophobic group stretches and adsorbs oiliness molecule while produce steric hindrance.Thus shape Into ink possess and amphipathic property and uphang buoyancy, ink both can be stable in masterplate, Silica Surface coating during stamp, Sun-dried mud brick particle and frit particles can be firmly adsorbed again, and meet glazing.
The present invention is had the following advantages relative to prior art and effect:
(1) present invention shifting printing inks possess bat printing stabilization, ungauged regions feature.As shown in figure 4, ink is coated on silica gel Surface, shooting and initial situation indifference after 30min minutes are placed, compared to printing inks more of the prior art (such as Fig. 5, figure 6), printing inks stamp stability produced by the present invention is higher, and flexibility is stronger.
(2) the high feature of suspension.Ink is placed in graduated glass pipe, 72h is placed and is not layered, and gently after agitation Still keep identical viscosity.
(3) the strong feature of glaze-body bonding power.By ink coated on sun-dried mud brick and after drying, 3~5 times are gently slided with hand, on hand without gluing There is toner;Gently brushed with banister brush 10 times, it is of poor quality to be less than 0.2g.
(4) product produced by the present invention has appropriate amphipathic property, can meet a variety of glazing process.
Brief description of the drawings
Fig. 1 is the printing quality figure of printing inks made from embodiment 1.
Fig. 2 is the printing quality figure of printing inks made from comparative example 1.
Fig. 3 is the printing quality figure of printing inks made from comparative example 2.
Fig. 4 is the photo figure after printing inks silica gel tiling 30min made from embodiment 4.
Fig. 5 is the photo figure after certain import printing inks silica gel tiling 30min.
Fig. 6 is the photo figure after certain domestic printing inks silica gel tiling 30min.
Embodiment
With reference to embodiment and accompanying drawing, the present invention is described in further detail, but embodiments of the present invention are unlimited In this.
Raw materials used can be bought by commercially available approach obtains in embodiment.
Embodiment 1
(1) parts by weight of sodium carboxymethylcellulose (D.S=0.6~0.8) 11 are taken, the parts by weight of propane diols 5, hydroxy-end capped poly- two Methylsiloxane (250~500cps of viscosity) 0.5 parts by weight, the parts by weight of deionized water 83, are heated to 80 DEG C, are stirred to complete Fully dissolved;The parts by weight of sodium tripolyphosphate 1 are added, polysorbas20 parts by weight are 1, the weight of polyoxyethylene polyoxy propyl alcohol amidogen ether 0.05 Part, the parts by weight of methyl p-hydroxybenzoate 0.25, it is uniformly mixed, produces stamp oil.
(2) parts by weight of dark blue zirconium oxide (D50=5 μm) 45 are taken, 55 parts by weight of stamp oil made from step (1), in ball milling Mixed 10 minutes in machine, produce printing inks.It is 3500~4000cps/10min to measure viscosity, wherein viscosity used is calculated as Digital display viscosimeter, the rotor used are No. 2 rotors, and measurement volume is 100mL.72h observations are placed without layering to occur.
(3) first printing inks are evenly applied on steel form, extruded with more than silica gel pressing steel plate 10s, then by silica gel Ceramic more than sun-dried mud brick 10s, then places more than 30min by sun-dried mud brick under normal temperature.The decalcomania obtained is complete, and lines are soft Clearly, as shown in Figure 1 (printing quality of embodiment 2,3,4 is similar to Fig. 1).Gently brushed with banister brush 10 times, of poor quality is 0.08g.
Embodiment 2
(1) parts by weight of sodium carboxymethylcellulose (D.S=0.6~0.8) 15 are taken, the parts by weight of propane diols 10 are hydroxy-end capped poly- Dimethyl siloxane (250~500cps of viscosity) 1 parts by weight, the parts by weight of deionized water 86, are heated to 80 DEG C, are stirred to complete Fully dissolved;The parts by weight of sodium tripolyphosphate 2 are added, polysorbas20 parts by weight are 5, the weight of polyoxyethylene polyoxy propyl alcohol amidogen ether 0.05 Part, the parts by weight of methyl p-hydroxybenzoate 0.25, it is uniformly mixed, produces stamp oil.
(2) parts by weight of dark blue zirconium oxide (D50=5 μm) 45 are taken, 55 parts by weight of stamp oil made from step (1), in ball milling Mixed 10 minutes in machine, produce printing inks.The viscosity for measuring the ink is 4000~4500cps/10min, wherein used Viscosity is calculated as digital display viscosimeter, and the rotor used is No. 2 rotors, and measurement volume is 100mL.72h observations are placed without layering to occur.
(3) first printing inks are evenly applied on steel form, extruded with more than silica gel pressing steel plate 10s, then by silica gel Ceramic more than sun-dried mud brick 10s, sun-dried mud brick is then placed into 30min under normal temperature.The decalcomania obtained is complete, and lines are soft clear It is clear, as shown in Figure 1 (printing quality of the printing inks obtained by the present embodiment is similar to Example 1, can using Fig. 1 as The present embodiment is referred to, and the present embodiment is not listed individually).Gently brushed with banister brush 10 times, of poor quality is 0.1g.
Embodiment 3
(1) parts by weight of sodium alginate (technical grade) 15, the parts by weight of glycerine 10, the parts by weight of castor oil 1, deionized water 83 are taken Parts by weight, 80 DEG C are heated to, be stirred to being completely dissolved;The parts by weight of ammonium polyacrylate 2 are added, Tween 80 parts by weight are 5, The parts by weight of polyoxyethylene polyoxy propyl alcohol amidogen ether 0.05, the parts by weight of methyl p-hydroxybenzoate 0.25, are uniformly mixed, produce print Caul-fat.
(2) parts by weight of dark blue zirconium oxide (D50=5 μm) 45 are taken, 55 parts by weight of stamp oil made from step (1), in ball milling Mixed 10 minutes in machine, produce printing inks.The viscosity for measuring the ink is 4000~4500cps/10min, wherein used Viscosity is calculated as digital display viscosimeter, and the rotor used is No. 2 rotors, and measurement volume is 100mL.72h observations are placed without layering to occur.
(3) first printing inks are evenly applied on steel form, extruded with more than silica gel pressing steel plate 10s, then by silica gel Ceramic more than sun-dried mud brick 10s, sun-dried mud brick is then placed into 30min under normal temperature.The decalcomania obtained is complete, and lines are soft clear Clear, (printing quality of the printing inks obtained by the present embodiment is similar to Example 1, can be as this as shown in Figure 1 Embodiment is referred to, and the present embodiment is not listed individually).Gently brushed with banister brush 10 times, of poor quality is 0.05g.
Embodiment 4
(1) parts by weight of guar gum (technical grade) 10, the parts by weight of propane diols 10, palm oil (24 degree) 1 parts by weight, deionization are taken The parts by weight of water 83, are heated to 80 DEG C, are stirred to being completely dissolved;Add the parts by weight of ammonium polyacrylate 2, Tween 80 parts by weight For 5, the parts by weight of polyoxyethylene polyoxy propyl alcohol amidogen ether 0.05, the parts by weight of methyl p-hydroxybenzoate 0.25, it is uniformly mixed, i.e., Obtain stamp oil.
(2) parts by weight of dark blue zirconium oxide (D50=5 μm) 45 are taken, 55 parts by weight of stamp oil made from step (1), in ball milling Mixed 10 minutes in machine, produce printing inks.The viscosity for measuring the ink is 4000~4500cps/10min, wherein used Viscosity is calculated as digital display viscosimeter, and the rotor used is No. 2 rotors, and measurement volume is 100mL.72h observations are placed without layering to occur.
(3) first printing inks are evenly applied on steel form, extruded with more than silica gel pressing steel plate 10s, then by silica gel Ceramic more than sun-dried mud brick 10s, sun-dried mud brick is then placed into 30min under normal temperature.The decalcomania obtained is complete, and lines are soft clear It is clear, as shown in Figure 1 (printing quality of the printing inks obtained by the present embodiment is similar to Example 1, can using Fig. 1 as The present embodiment is referred to, and the present embodiment is not listed individually).Gently brushed with banister brush 10 times, of poor quality is 0.12g.
Printing inks, certain import printing inks and certain domestic printing inks made from the present embodiment are respectively coated in silica gel Surface, observed after placing 30min minutes, as a result as shown in figures 4-6 (tiling effects of embodiment 1,2,3 are similar to Fig. 4).By Fig. 4 Understand, printing inks and the initial situation indifference of the Silica Surface of the printing inks as made from coated with the present embodiment, and Fig. 5 By rapid desufflation after Silica Surface complete application into droplet-like.Fig. 6 is by the after-contraction of silica gel complete application into flow-like.Thus may be used See, printing inks bat printing made from the present embodiment is stable, ungauged regions, and flexibility is strong.
Comparative example 1
The present embodiment is in addition to following difference, and remaining composition of raw materials and preparation process are the same as embodiment 1:
Addition hydroxyl endblocked polydimethylsiloxane is 0.1 parts by weight.
When printing inks are made, product pattern color is overweight, missing deformation, as shown in Figure 2.
Comparative example 2
The present embodiment is in addition to following difference, and remaining composition of raw materials and preparation process are the same as embodiment 1:
It is 20 parts by weight to add dark blue zirconium oxide.
When printing inks are made, color is excessively shallow, and pattern, lines are unintelligible, as shown in Figure 3.
Comparative example 3
The present embodiment is in addition to following difference, and remaining composition of raw materials and preparation process are the same as embodiment 1:
Addition sodium carboxymethylcellulose is 5 parts by weight.
It is of poor quality with the light brush lines of banister brush 10 times when printing inks are made>0.2g.
Comparative example 4
The present embodiment is in addition to following difference, and remaining composition of raw materials and preparation process are the same as embodiment 1:
Addition sodium tripolyphosphate is 0.1 parts by weight.
When printing inks are made, 8000~20000cps/10min of viscosity is measured, is glued wherein viscosity used is calculated as digital display Degree meter, the rotor used is No. 3 rotors, and measurement volume is 100mL.Viscosity is unstable, and suspension is low, can not stamp.
Comparative example 5
The present embodiment is in addition to following difference, and remaining composition of raw materials and preparation process are the same as embodiment 1:
Add oily 30 parts by weight of stamp.
When printing inks are made, viscosity is measured>20000cps/10min, and viscosity is in 20000~50000cps/10min Between change, wherein viscosity used is calculated as digital display viscosimeter, the rotor used is No. 4 rotors, and measurement volume is 100mL.It is viscous Spend greatly, and viscosity is unstable, suspension is low, can not stamp.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification, Equivalent substitute mode is should be, is included within protection scope of the present invention.

Claims (10)

1. a kind of household china silica gel stamp-pad ink, it is characterised in that its raw material includes by weight ratio:
2. household china silica gel stamp-pad ink according to claim 1, it is characterised in that:
Described thickener is sodium carboxymethylcellulose, sodium carboxymethyl starch, methylcellulose, hydroxypropyl methyl cellulose, peach Glue, sodium alginate, melon and one kind in glue or at least two.
3. household china silica gel stamp-pad ink according to claim 1, it is characterised in that:
Described defoamer is polyoxyethylene polyoxy propyl alcohol amidogen ether, polyoxyethylene polyoxypropylene pentaerythrite ether, polyether-silicone One kind in copolymer or at least two.
4. household china silica gel stamp-pad ink according to claim 1, it is characterised in that:
Described liquefacient is sodium tripolyphosphate, sodium metasilicate, Sodium Polyacrylate, one kind in ammonium polyacrylate or at least two Kind;
Described finish is castor oil, white oil, palm oil, hydroxyl endblocked polydimethylsiloxane, one kind in paraffin oil or extremely It is few two kinds.
5. household china silica gel stamp-pad ink according to claim 1, it is characterised in that:
Described emulsifying agent is one kind or at least two in polysorbas20, Tween 80, this Pan 60, AEO;
Described wetting agent is propane diols, D-sorbite, one kind in glycerine or at least two;
Described preservative is one kind in methyl p-hydroxybenzoate, ethyl-para-hydroxybenzoate, potassium sorbate, natrium nitrosum Or at least two.
6. the preparation method of the household china silica gel stamp-pad ink described in any one of Claims 1 to 5, it is characterised in that including following step Suddenly:
(1) thickener, wetting agent, finish and water are added by proportioning, heating is mixed to being completely dissolved, and obtains mixed liquor;
(2) liquefacient, emulsifying agent, defoamer, anti-corrosion are added in the mixed liquor obtained in step (1)
Agent, it is well mixed, produces described household china silica gel stamp-pad ink.
7. a kind of household china silica gel ink, it is characterised in that its raw material includes by weight ratio:
8. household china silica gel ink according to claim 7, it is characterised in that:
Described toner is ceramic high temperature pigment and one kind in colouring agent or at least two.
9. the preparation method of the household china silica gel ink described in claim 7 or 8, it is characterised in that comprise the following steps:
Toner and described household china silica gel stamp-pad ink are taken by proportioning, is well mixed, produces described household china silica gel ink.
10. the preparation method of household china silica gel ink according to claim 9, it is characterised in that:
Described mixing is mixed by ball milling.
CN201710993498.XA 2017-10-23 2017-10-23 A kind of household china silica gel stamp-pad ink and household china silica gel ink and preparation method thereof Pending CN107699041A (en)

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Cited By (4)

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CN110154611A (en) * 2019-05-28 2019-08-23 江苏拜富科技有限公司 A kind of low-temperature nano ceramic water transfer paste marble paper
CN112094526A (en) * 2020-09-22 2020-12-18 贾佳 Water-based glue for producing ceramic printing color ink and application
CN114106628A (en) * 2021-12-29 2022-03-01 淄博科睿特新材料科技有限公司 Efficient and accurate daily porcelain 3D soft silica gel transfer printing ink and application thereof
CN114231084A (en) * 2021-12-29 2022-03-25 贾佳 Ceramic continuous offset printing oil and ink with high adaptability and application thereof

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CN106715608A (en) * 2014-09-19 2017-05-24 司马塞拉姆科公司 Ceramic ink for inkjet printing

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CN110154611A (en) * 2019-05-28 2019-08-23 江苏拜富科技有限公司 A kind of low-temperature nano ceramic water transfer paste marble paper
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CN115340785A (en) * 2021-12-29 2022-11-15 淄博科睿特新材料科技有限公司 Stamp-pad ink of ceramic silica gel transfer printing ink

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