CN112094526A - Water-based glue for producing ceramic printing color ink and application - Google Patents
Water-based glue for producing ceramic printing color ink and application Download PDFInfo
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- CN112094526A CN112094526A CN202011003100.1A CN202011003100A CN112094526A CN 112094526 A CN112094526 A CN 112094526A CN 202011003100 A CN202011003100 A CN 202011003100A CN 112094526 A CN112094526 A CN 112094526A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
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- Decoration By Transfer Pictures (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
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Abstract
The invention relates to the field of ceramic decoration, in particular to water-based glue for producing ceramic printing color ink and an application thereof, wherein the water-based glue is prepared from the following raw materials in parts by weight: 0.1-80 parts of film-forming auxiliary agent, 0.1-90 parts of humectant, 0-40 parts of water, 0-5 parts of dispersing agent, 0.1-9.9 parts of thickening agent, 0.01-0.5 part of defoaming agent and 0-0.5 part of preservative. The water-based glue can be applied to the production of ink. The formula of the water-based glue is prepared by selecting appropriate raw materials and matching the raw materials in proportion, so that the cost is low, the process route is simple, and the water-based glue can be mixed with pigments; the ink prepared by the water-based glue has high transfer rate from the gravure dipping to the transfer printing silica gel and high transfer rate from the transfer printing silica gel to the mud blank; and the ink prepared by the water-based glue has good moisture retention and slow volatilization speed.
Description
Technical Field
The invention relates to the field of ceramic decoration, in particular to water-based glue for producing ceramic printing color ink and application thereof.
Background
The decoration technology of daily-used porcelain is divided into three types according to the position relation between color and glaze, namely overglaze color, overglaze color and underglaze color. The underglaze color is the color below the environment-friendly glaze, so that the food is isolated from being contacted with the color pigment, and the underglaze color is the safest and healthier of the three. The traditional underglaze decoration method for domestic ceramics is a paper-sticking technique, and is characterized by that firstly, the pattern of colour pigment is printed on special paper, then the paper is stuck on the clay blank by means of adhesive, then the clay blank is coated with glaze water, and then the above-mentioned material is roasted at high temperature so as to obtain the invented product.
With the development of industrial automation degree, the decoration method of daily ceramics increasingly uses automatic equipment. The ceramic color printing machine (CN206678553U, CN206968180U) changes the traditional decoration method of underglaze color, omits the process of manual paper pasting, can directly scrape ink in intaglio patterns, dips the ink through pad printing silica gel of the color printing machine, presses the ink on bowl-shaped or disc-shaped clay blanks, and finally realizes the transfer of the ink in the intaglio to the clay blanks. The process change inevitably brings the change of materials. The oily glue and glaze water generate the phenomenon of 'oil-water incompatibility', and the glaze water cannot cover the dry place of the oily glue, so that only aqueous glue can be selected to prepare the ink. The common water-based glue material can not meet the requirements of the ceramic color press, and has the following problems and disadvantages:
(1) the transfer rate of ink dipped from the intaglio onto the pad printing silica gel is low: ink with certain viscosity can be dipped by the pad printing silica gel, but the traditional glue has high water content and large surface tension, and the ink is not easy to be adsorbed on the silica gel due to the hydrophobicity of the pad printing silica gel, so that the dipped ink volume is low;
(2) the transfer rate of the ink desorbed from the transfer printing silica gel to the mud blank is low: because the mud blank has certain hydroscopicity, the ink with high water content is dried on the mud blank too fast, the viscosity is increased, when the pad printing silica gel is separated from the mud blank, the ink can not be desorbed, even the mud powder of the mud blank is taken away, and the pattern blank is caused.
(3) The ink has high volatilization and drying speed, an ink tray of the ceramic color printing machine is exposed in the air, and the ink viscosity is increased and the color printing cannot be normally carried out when the machine runs for 24 hours.
Disclosure of Invention
In order to solve the technical problems, the invention provides the water-based glue for producing the ceramic color printing ink and the application thereof.
The invention relates to water-based glue for producing ceramic printing color ink, which is characterized by being prepared from the following raw materials in parts by weight: 0.1-80 parts of film-forming auxiliary agent, 0.1-90 parts of humectant, 0-20 parts of water, 0-5 parts of dispersing agent, 0.1-9.9 parts of thickening agent, 0.01-0.5 part of defoaming agent and 0-0.5 part of preservative.
The preparation of the aqueous glue is not limited too much, and the aqueous glue is prepared by adopting a conventional process, for example, the film-forming auxiliary agent, the humectant, the thickener and water are put into a stirring cylinder and stirred into a uniform system, and then the dispersant, the defoamer and the preservative are added and stirred continuously and uniformly to obtain the product aqueous glue.
Wherein, the preferred scheme is as follows:
the film-forming assistant is one or more of alcohol ester dodeca, dipropylene glycol methyl ether or diethylene glycol butyl ether. The film forming assistant aims at adjusting the surface tension of a glue system, so that the ink can form a smooth film on the pad printing silica gel, and the transfer rate of the ink dipped is improved.
The humectant is a polyhydric alcohol humectant. The humectant aims to reduce the volatilization and drying speed of the ink on the ink tray and improve the moisture retention of the glue.
The polyalcohol humectant is one or more of ethylene glycol, propylene glycol, glycerol, dipropylene glycol, diethylene glycol, triethylene glycol or tetraethylene glycol.
The water is selected from one or more of distilled water, purified water or deionized water.
The dispersing agent is Colkino 5040 and/or BYK-190. The dispersing agent aims to improve the dispersibility of the pigment in an ink system when the glue is mixed with the pigment.
The thickening agent is one or more of xanthan gum, polyvidone, cellulose ether, alginic acid inorganic salt or propylene glycol alginate. Thickeners are intended to increase the viscosity of the system.
The defoaming agent is digao 825 and/or BYK-024. The defoaming agent is intended to reduce the surface tension of the glue, eliminate the original foam and inhibit the regeneration of foam formation.
The preservative is isothiazolinone and/or sodium lactate. Preservatives are intended to prevent bacterial contamination of the glue, resulting in viscosity loss, spoilage, gas generation, emulsion breaking and other deleterious physical and chemical changes.
The invention also provides the application of the water-based glue in ink production. Specifically, the pigment and the water-based glue are mixed according to the weight ratio of 9-11: 8, stirring and mixing uniformly to obtain the ink.
The innovation points of the invention are as follows:
(1) the mud embryo structure has certain adsorbability due to the existence of micropores, and the components of the mud embryo have hydrophilicity. According to the invention, a proper hydrophilic mixed solvent is selected to meet the water absorption and hydrophilicity of the mud embryo; meanwhile, the reasonable solvent system formula is designed, so that the permeation speed of the solvent on the surface of the mud blank, namely the drying speed of the ink on the mud blank, is effectively controlled, and the ink can be smoothly desorbed from the silica gel and adsorbed on the mud blank.
(1) The appropriate film-forming assistant is selected, the surface chemical property of the water-based glue is optimized, the hydrophobicity of the silicon-oxygen group of the transferred silica gel is compatible, the ink is easy to adsorb and spread on the silica gel, and the ink can be smoothly dipped on the silica gel from the ink tray.
(3) The reasonable addition amount of the moisturizing auxiliary agent reduces the volatilization speed of the ink due to the hygroscopicity of the moisturizing auxiliary agent, and ensures the continuous work of the ink in the exposed air.
The invention has the advantages that: (1) the formula of the water-based glue is prepared by selecting appropriate raw materials and matching the raw materials in proportion, so that the cost is low, the process route is simple, and the water-based glue can be mixed with pigments; (2) the ink prepared by the water-based glue has high transfer rate from the gravure dipping to the pad printing silica gel; (3) the transfer rate of ink prepared by the water-based glue in desorption from the transfer printing silica gel to mud embryos is high; (4) the ink prepared by the water-based glue has good moisture retention and slow volatilization speed.
Detailed Description
The present invention is further illustrated by the following examples.
Example 1:
the water-based glue for producing the ceramic printing color ink is prepared from the following raw materials in parts by weight: 60.0 parts of diethylene glycol butyl ether, 27.0 parts of diethylene glycol, 10.0 parts of deionized water, BYK-1901.5 parts, 1.0 part of xanthan gum, 8250.3 parts of digao and 0.2 part of sodium lactate.
When the water-based glue is prepared, at room temperature, putting xanthan gum, diethylene glycol monobutyl ether, diethylene glycol and deionized water into a stirring cylinder, stirring at a high speed, controlling the rotating speed to be 600-800 r/min, adding BYK-190, sodium lactate and digao 825 when the materials are completely dissolved into a uniform system, keeping the rotating speed unchanged, and continuously stirring for 5 min to obtain the water-based glue. According to the pigment: preparing ink by the weight ratio of 10:8 of the water-based glue, wherein the dipping rate of the ink measured by a weight loss method is 86.3 percent, and the transfer rate of the ink desorbed from the silica gel to the clay embryo measured by a clay embryo weight gain method is 99.0 percent; the ink can be continuously operated for 6 hours at room temperature in a non-humidified state.
Example 2:
the water-based glue for producing the ceramic printing color ink is prepared from the following raw materials in parts by weight: 50.0 parts of dipropylene glycol methyl ether, 23.0 parts of glycerol, 16.0 parts of deionized water, BYK-1901.5 parts, 9.0 parts of povidone, 8250.3 parts of digao and 0.2 part of sodium lactate.
When the water-based glue is prepared, at room temperature, povidone, dipropylene glycol methyl ether, glycerol and deionized water are put into a stirring cylinder, stirred at a high speed, the rotating speed is controlled to be 800-1000 r/min, BYK-190, sodium lactate and digao 825 are added after the materials are completely dissolved into a uniform system, the rotating speed is kept unchanged, and stirring is continued for 5 min, so that the water-based glue is obtained. According to the pigment: preparing ink by the weight ratio of 10:8 of the water-based glue, wherein the dipping rate of the ink measured by a weight loss method is 78.8%, and the transfer rate of the ink desorbed from the silica gel to the clay embryo measured by a clay embryo weight gain method is 96.8%; the ink can be continuously operated for 5 hours at room temperature in a non-humidified state.
Example 3:
the water-based glue for producing the ceramic printing color ink is prepared from the following raw materials in parts by weight: 50.0 parts of dipropylene glycol methyl ether, 10.0 parts of alcohol ester, 14.0 parts of dipropylene glycol, 20.0 parts of deionized water, 50401.5 parts of Colo, 4.0 parts of propylene glycol alginate, BYK-0240.2 parts and 0.3 part of isothiazolinone.
When the water-based glue is prepared, at room temperature, putting propylene glycol alginate, dipropylene glycol methyl ether, alcohol ester dodeca, dipropylene glycol and deionized water into a high-speed stirring cylinder, controlling the rotating speed to be 1000-1200 r/min, adding copanol 5040, isothiazolinone and BYK-024 when the materials are completely dissolved into a uniform problem, keeping the rotating speed unchanged, and continuously stirring for 5 min to obtain the water-based glue. According to the pigment: preparing ink by the weight ratio of 10:8 of the water-based glue, wherein the dipping rate of the ink measured by a weight loss method is 80.1%, and the transfer rate of the ink desorbed from the silica gel to the clay embryo measured by a clay embryo weight gain method is 83.0%; the ink can be continuously operated for 3.5 hours at room temperature in a non-humidified state.
Comparative example 1:
the water-based glue for producing the ceramic printing color ink is prepared from the following raw materials in parts by weight: 40.0 parts of diethylene glycol butyl ether, 27.0 parts of diethylene glycol, 30.0 parts of deionized water, BYK-1901.5 parts, 1.0 part of xanthan gum, 8250.3 parts of digao and 0.2 part of sodium lactate.
When the water-based glue is prepared, at room temperature, putting xanthan gum, diethylene glycol monobutyl ether, diethylene glycol and deionized water into a stirring cylinder, stirring at a high speed, controlling the rotating speed to be 600-800 r/min, adding BYK-190, sodium lactate and digao 825 when the materials are completely dissolved into a uniform system, keeping the rotating speed unchanged, and continuously stirring for 5 min to obtain the water-based glue. According to the pigment: preparing ink by the weight ratio of 10:8 of the water-based glue, wherein the dipping rate of the ink measured by a weight loss method is 54.8%, and the transfer rate of the ink desorbed from the silica gel to the clay embryo measured by a clay embryo weight gain method is 67.6%; the ink can be continuously operated for 4 hours at room temperature in a non-humidified state.
Comparative example 2:
the water-based glue for producing the ceramic printing color ink is prepared from the following raw materials in parts by weight: 67.0 parts of diethylene glycol butyl ether, 30.0 parts of deionized water, BYK-1901.5 parts, 1.0 part of xanthan gum, 8250.3 parts of digao and 0.2 part of sodium lactate.
When the water-based glue is prepared, at room temperature, putting xanthan gum, diethylene glycol and deionized water into a stirring cylinder, stirring at a high speed, controlling the rotating speed at 600-800 rpm, adding BYK-190, sodium lactate and digao 825, keeping the rotating speed unchanged, and continuously stirring for 5 minutes to obtain the water-based glue. According to the pigment: preparing ink by the weight ratio of 10:8 of the water-based glue, wherein the dipping rate of the ink measured by a weight loss method is 77.2%, and the transfer rate of the ink desorbed from the silica gel to the clay blank measured by a clay blank weight gain method is 62.8%; the ink can be continuously operated for 0.5 hour at room temperature in a non-humidified state.
TABLE 1 test results of examples and comparative examples
| Numbering | Example 1 | Example 2 | Example 3 | Comparative example 1 | Comparative example 2 |
| Dipping rate | 86.3％ | 78.8％ | 80.1％ | 54.8％ | 77.2％ |
| Rate of mud embryo adsorption | 99.0％ | 96.8％ | 83.0％ | 67.6％ | 62.8％ |
| Continuous printing time | 6 hours | 5 hours | 3.5 hours | 4 hours | 0.5 hour |
In summary, as shown in table 1, the adsorption rate of the ink of example 3 on the clay embryo is poor in examples 1, 2 and 3 because the water content is relatively highest in example 3, the adsorption drying speed is fast when the small molecular water molecules contact the clay embryo, the ink viscosity increases fast, the desorption is difficult, and the ink residue on the silica gel is observed, so the desorption transfer rate is low. In addition, the evaporation rate of the coalescent in example 3 was relatively high, and the moisturizing performance of the moisturizing aid was relatively poor, resulting in a shorter continuous working time for example 3.
In comparative example 1, the ink pick-up was low because the water content increased to 30%, the film-forming aid was low in proportion to the examples, and the ink was difficult to pick-up due to the hydrophobic nature of the silica gel. In addition, the mud embryo adsorption rate of comparative example 1 is low because the ink dries quickly when contacting the mud embryo due to the increase of the water content, the viscosity increases quickly, and the transfer to the mud embryo is difficult. However, the ink of comparative example 1 was continuously operated for a long time due to the relatively high content of the moisturizing aid. In comparative example 2, the moisture retention aid content was zero while the water content was increased to 30%, so that the continuous operation time was shortened as compared with comparative example 1.
Claims (10)
1. The water-based glue for producing the ceramic printing color ink is characterized by being prepared from the following raw materials in parts by weight: 0.1-80 parts of film-forming auxiliary agent, 0.1-90 parts of humectant, 0-20 parts of water, 0-5 parts of dispersing agent, 0.1-9.9 parts of thickening agent, 0.01-0.5 part of defoaming agent and 0-0.5 part of preservative.
2. The aqueous glue for producing ceramic printing color ink according to claim 1, characterized in that: the film-forming assistant is one or more of alcohol ester dodeca, dipropylene glycol methyl ether or diethylene glycol butyl ether.
3. The aqueous glue for producing ceramic printing color ink according to claim 1, characterized in that: the humectant is a polyhydric alcohol humectant.
4. The aqueous glue for producing ceramic printing color ink according to claim 3, characterized in that: the polyalcohol humectant is one or more of ethylene glycol, propylene glycol, glycerol, dipropylene glycol, diethylene glycol, triethylene glycol or tetraethylene glycol.
5. The aqueous glue for producing ceramic printing color ink according to claim 1, characterized in that: the water is selected from one or more of distilled water, purified water or deionized water.
6. The aqueous glue for producing ceramic printing color ink according to claim 1, characterized in that: the dispersing agent is Colkino 5040 and/or BYK-190.
7. The aqueous glue for producing ceramic printing color ink according to claim 1, characterized in that: the thickening agent is one or more of xanthan gum, polyvidone, cellulose ether, alginic acid inorganic salt or propylene glycol alginate.
8. The aqueous glue for producing ceramic printing color ink according to claim 1, characterized in that: the defoaming agent is digao 825 and/or BYK-024.
9. The aqueous glue for producing ceramic printing color ink according to claim 1, characterized in that: the preservative is isothiazolinone and/or sodium lactate.
10. Use of the aqueous glue of claims 1-9 in the production of an ink.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202011003100.1A CN112094526A (en) | 2020-09-22 | 2020-09-22 | Water-based glue for producing ceramic printing color ink and application |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202011003100.1A CN112094526A (en) | 2020-09-22 | 2020-09-22 | Water-based glue for producing ceramic printing color ink and application |
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105060933A (en) * | 2015-07-17 | 2015-11-18 | 星谊精密陶瓷科技（昆山）有限公司 | Ink for dry-granule printing glaze and application |
| CN105504991A (en) * | 2016-01-28 | 2016-04-20 | 佛山市禅信陶瓷釉料有限公司 | Ink for digital three-dimensional ceramic product printing and technology thereof |
| CN107699041A (en) * | 2017-10-23 | 2018-02-16 | 中科院广州化学有限公司南雄材料生产基地 | A kind of household china silica gel stamp-pad ink and household china silica gel ink and preparation method thereof |
| WO2018093025A1 (en) * | 2016-11-17 | 2018-05-24 | (주)삼광기업 | Method for producing ink for pad printing on ceramic coating layer, and pad printing ink produced by method |
| CN108191242A (en) * | 2018-01-25 | 2018-06-22 | 广东金牌陶瓷有限公司 | A kind of big plate glued surfaces of ceramics protect color glaze and preparation method thereof |
| CN108251048A (en) * | 2018-01-19 | 2018-07-06 | 佛山市陶琦新型材料有限公司 | Dry granular glaze glue, dry granular glaze, dry granular glazed tile and preparation method thereof |
| CN108424111A (en) * | 2018-01-25 | 2018-08-21 | 广东金牌陶瓷有限公司 | A kind of ceramic plate and preparation method thereof greatly of light dry granular polishing |
| CN110128172A (en) * | 2019-04-28 | 2019-08-16 | 东莞市唯美陶瓷工业园有限公司 | A kind of method improving Ceramic Tiles green surface performance of keeping humidity and the Ceramic Tiles using this method preparation |
-
2020
- 2020-09-22 CN CN202011003100.1A patent/CN112094526A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105060933A (en) * | 2015-07-17 | 2015-11-18 | 星谊精密陶瓷科技（昆山）有限公司 | Ink for dry-granule printing glaze and application |
| CN105504991A (en) * | 2016-01-28 | 2016-04-20 | 佛山市禅信陶瓷釉料有限公司 | Ink for digital three-dimensional ceramic product printing and technology thereof |
| WO2018093025A1 (en) * | 2016-11-17 | 2018-05-24 | (주)삼광기업 | Method for producing ink for pad printing on ceramic coating layer, and pad printing ink produced by method |
| CN107699041A (en) * | 2017-10-23 | 2018-02-16 | 中科院广州化学有限公司南雄材料生产基地 | A kind of household china silica gel stamp-pad ink and household china silica gel ink and preparation method thereof |
| CN108251048A (en) * | 2018-01-19 | 2018-07-06 | 佛山市陶琦新型材料有限公司 | Dry granular glaze glue, dry granular glaze, dry granular glazed tile and preparation method thereof |
| CN108191242A (en) * | 2018-01-25 | 2018-06-22 | 广东金牌陶瓷有限公司 | A kind of big plate glued surfaces of ceramics protect color glaze and preparation method thereof |
| CN108424111A (en) * | 2018-01-25 | 2018-08-21 | 广东金牌陶瓷有限公司 | A kind of ceramic plate and preparation method thereof greatly of light dry granular polishing |
| CN110128172A (en) * | 2019-04-28 | 2019-08-16 | 东莞市唯美陶瓷工业园有限公司 | A kind of method improving Ceramic Tiles green surface performance of keeping humidity and the Ceramic Tiles using this method preparation |
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