CN103173065B - A kind of flexographic ink and preparation method thereof - Google Patents
A kind of flexographic ink and preparation method thereof Download PDFInfo
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- CN103173065B CN103173065B CN201310138784.XA CN201310138784A CN103173065B CN 103173065 B CN103173065 B CN 103173065B CN 201310138784 A CN201310138784 A CN 201310138784A CN 103173065 B CN103173065 B CN 103173065B
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Abstract
The invention provides a kind of flexographic ink and preparation method thereof, belong to offset printing field.Described flexographic ink is made up of 65 ~ 80 parts of binders, 1 ~ 2 part of slack wax, 15 ~ 25 parts of pigment, 0.1 ~ 0.3 part of anti skinning agent, 1 ~ 10 part of other auxiliary agent A, described slack wax comprises oleum lini, mineral oil and beeswax, beeswax is both containing polarity and non-polar group, carbon chain lengths is not etc., therefore, described slack wax has internal lubrication effect and external lubrication effect concurrently; The more important thing is, the application finds under the acting in conjunction of oleum lini, mineral oil and beeswax, prepared slack wax can balance inside and outside lubrication, under the prerequisite not affecting gelation, effective solution flexographic ink sticks the problem of ink roller, effectively can improve printing quality, reduce the cleaning maintenance cost of printing press, improve the working efficiency of printing press; And preparation process is simple, process costs is low.
Description
Technical field
The present invention relates to a kind of flexographic ink and preparation method thereof, belong to offset printing field.
Background technology
Along with the progress of Printing industry, the constantly perfect and raising of printing technology and printing equipment, offset printing is with its distinctive advantage, as make a plate quick and convenient, with low cost, printing quality is high, paper use range is wide, printing number contractibility is large etc. is subject to the favor of domestic and international printing factory, thus obtain developing fast and widely, dominate in international Printing industry then, flexographic ink also obtains thereupon and develops faster.
Ink, as most important a kind of printing material of information regeneration, should have good printability in printing process.Flexographic ink is mainly made up of materials such as colored pigment (dyestuff etc.), binder, stopping composition and auxiliary agents, when preparing by the requirement of printing according to certain ratio mix and blend, and process rolls and rolls that black technique makes.
Colored pigment is the water insoluble solid, powdery material being also insoluble to oil or binder, having certain color.It is not only solid moiety main in ink, is also to print to visible chromoplastid part on object, determines the color of ink, rare performance such as thick, fast light to a great extent.
Binder is the heart of ink, belongs to gluing shape fluid; In ink, the material mixing such as the pigment of powdery can link up by it, make it after grinding distribution, form the adherent with certain degree of mobilization and viscosity, thus play link effect.Binder is fluid moiety main in ink, determines the degree of mobilization of ink, viscosity, dryness and printability etc.
Stopping composition is white, transparent, translucent or opaque flour, is also the solid integral part of ink, mainly plays filling effect.Suitably select stopping composition, except reducing amount of pigment, outside reducing costs, it also can regulate the character of ink, as rare thick, degree of mobilization etc.
Auxiliary agent is the supplementary component in ink, also as the additional material of ink finished product, can change or improve some character of ink as printing auxiliary, as: drying property, rub resistance etc.
In offset printing process, flexographic ink will, through point ink of tens ink rollers, even ink and string ink, finally could be transferred on forme by flexographic ink; The phenomenon that flexographic ink sticks on ink roller is a problem very important in flexographic ink formula R&D process.Once flexographic ink sticks on ink roller; along with the dry gradually conjunctiva of flexographic ink; fundamentally will change physical dimension and the printability of ink roller; the transfer of flexographic ink is more and more worsened; not only can affect printing quality, ink consumption amount is large; and stop cleaning of having to, add the cost of the daily cleaning maintenance of printing press, reduce the working efficiency of printing press.The carbochain of PE wax is longer, does not have polar group, can improve the external lubricity of flexographic ink, and therefore, technician can add the problem that slack wax that PE wax and high-boiling point kerosene be mixed with sticks on ink roller to reduce flexographic ink usually in flexographic ink.But exactly because PE wax does not have polar group, carbochain longer, so PE slack wax is only suitable for using as exterior lubricant, do not possess the effect of internal lubrication, this just causes using PE slack wax easily to cause inside and outside lubrication uneven, outside over-lubrication, thus make ink occur the phenomenon that gelation is slow; Therefore, adding a small amount of PE slack wax, when ensureing flexographic ink normal gel, effectively cannot solve the problem that flexographic ink sticks ink roller, so research and development ink roller degree of sticking flexographic ink that is low, excellent performance becomes one of offset printing field problem demanding prompt solution.
Summary of the invention
For this reason, to be solved by this invention is that in prior art, flexographic ink, easily in the problem that ink roller sticks, provides a kind of excellent performance, flexographic ink that ink roller degree of sticking is low and preparation method thereof.
For solving the problems of the technologies described above, the technical solution used in the present invention is as follows:
A kind of flexographic ink of the present invention, described flexographic ink comprises the component of following parts by weight:
Binder 65 ~ 80 parts;
Slack wax 1 ~ 2 part;
Pigment 15 ~ 25 parts;
Anti skinning agent 0.1 ~ 0.3 part;
Other auxiliary agent A 1 ~ 10 part;
Wherein, described slack wax is made up of the component of following parts by weight:
Oleum lini 3 ~ 8 parts;
55 ~ 75 parts, mineral oil;
20 ~ 40 parts, beeswax.
Described binder is made up of the component of following parts by weight:
40 ~ 50 parts, Abietyl modified octyl phenol resol;
Oleum lini 20 ~ 30 parts;
25 ~ 35 parts, mineral oil;
Sylvic oil 1 ~ 2 part;
Tetradecyl alcohol 0.1 ~ 0.3 part;
Auxiliary agent B 0.1 ~ 1 part.
Other auxiliary agent A described comprises one or more the combination in viscosity-controlling agent, emulsion resistance auxiliary agent, dispersion agent, anti-wear agent, siccative or soft resin oil.
Described auxiliary agent B comprises fluid gelling agent and/or oxidation inhibitor.
Described siccative is cobalt liquid drier and/or manganese liquid drier.
The preparation method of flexographic ink of the present invention, comprises the steps:
S1, weigh Abietyl modified octyl phenol resol, oleum lini, mineral oil, sylvic oil, tetradecyl alcohol and auxiliary agent B according to selected parts by weight, mineral oil is divided into 3 parts, first part of mineral oil and every other component are placed in reactor and stir, add second part of mineral oil, continue to stir and isothermal holding after being warming up to 200 ~ 280 DEG C, use the 3rd part of mineral oil adjusting viscosity again, obtained binder is for subsequent use;
S2, oleum lini, mineral oil and beeswax be placed in reactor stir, and isothermal holding after being warming up to 100 ~ 150 DEG C, obtained slack wax is for subsequent use;
S3, to weigh binder that step S1 obtains, step S2 obtained slack wax, pigment, anti skinning agent and other auxiliary agent A according to selected parts by weight and be placed in reactor and stir, the work in-process of obtained described flexographic ink;
S4, described work in-process obtained in step S3 to be ground, obtained described flexographic ink.
In step S1, the temperature of heating step is 220 ~ 240 DEG C.
In step S2, the temperature of heating step is 120 ~ 140 DEG C.
In step S4, after described grinding steps, the fineness of described flexographic ink is 12 ~ 15 microns.
Technique scheme of the present invention has the following advantages compared to existing technology:
1, flexographic ink of the present invention is made up of binder, slack wax, pigment, anti skinning agent and other auxiliary agent A, described slack wax comprises oleum lini, mineral oil and beeswax, beeswax is primarily of lipid, free acids, free alcohols and hydrocarbon composition, both containing polar group and non-polar group, and, carbon chain lengths be C24 ~ C34 not etc., therefore, described slack wax has internal lubrication effect and external lubrication effect concurrently; The more important thing is, the application finds under the acting in conjunction of oleum lini, mineral oil and beeswax, prepared slack wax can balance inside and outside lubrication, under the prerequisite not affecting gelation, effective solution flexographic ink sticks the problem of ink roller, effectively can improve printing quality, reduce the cleaning maintenance cost of printing press, improve the working efficiency of printing press;
In addition, in described flexographic ink, be added with anti skinning agent, can prevent described flexographic ink from by top layer during ink roller, oxypolymerization effect occurring further, form skinning and stick on ink roller.
2, flexographic ink of the present invention, described binder only selects Abietyl modified octyl phenol resol as resin, and molecular weight is large, has splendid mineral oil solvability, gives the splendid water resisting property of described flexographic ink and light permanency.
3, flexographic ink of the present invention, described binder only selects oleum lini as vegetable oil component, and dryness is moderate, effectively solves the problem of the too fast internal stress of resin skewness brought of dryness, gives the sticking power that described flexographic ink is splendid.
4, flexographic ink of the present invention, other auxiliary agent A described comprises one or more the combination in viscosity-controlling agent, emulsion resistance auxiliary agent, dispersion agent, siccative or soft resin oil, effectively can improve the printability of described flexographic ink.
5, flexographic ink preparation method of the present invention, prepares binder and slack wax first respectively, and then the components such as described binder, slack wax, pigment, anti skinning agent, other auxiliary agent A is carried out mixing, grinding, and preparation process is simple, and process costs is low; In the preparation process of described binder, the technique adopting mineral oil substep to throw in, effectively can improve the viscosity of described binder; In the preparation process of described slack wax, strict temperature control is at 100 ~ 150 DEG C, at such a temperature, the amalgamation that each component merges improves, and belongs to carboxyl and the hydroxylic moiety generation condensation reaction of polar group together, balances the ratio of polar group and non-polar group further, make the inside and outside lubrication balance of described slack wax, during printing, under the prerequisite of flexographic ink normal gel, the degree of sticking of described flexographic ink on ink roller is low.
Embodiment
In order to make the object, technical solutions and advantages of the present invention clearly, will be described in further detail embodiments of the present invention below.
Abietyl modified octyl phenol resol described in following embodiment is purchased from this ink material company limited of Ruili, Tianjin, and product type is 8320; Described oleum lini is purchased from the sharp grease of gold (Suzhou) company limited; Described mineral oil is purchased from south, Shaoxing County petrochemical industry company limited, and product type is 280; Described high-boiling point kerosene is purchased from south, Shaoxing County petrochemical industry company limited; Described sylvic oil to be increased income resin processing plant purchased from Taicang decorated archway, and product type is 139; Described tetradecyl alcohol is purchased from Shanghai Yuan Xiang Chemicals company limited; Described oxidation inhibitor is 2,6 di tert butyl 4 methyl phenol (BHT), purchased from Huayuan Chemical Co., Ltd. of Shanghai Huayi Group; Described fluid gelling agent, purchased from Tai'an, Tianjin Chemical Co., Ltd., product type is TN-series of fluids gelifying agent; Beeswax is purchased from orchard, Dongguang County wax work company limited; In described pigment, precious red 6BN is purchased from Shandong sunlight pigment Chemical Co., Ltd., precious red 8B and 178-1 is yellow purchased from Longkou associating Chemical Co., Ltd., 94817 orchids and barba hispanica are purchased from Hebei MERIDA limited-liability company, MA-11 is black in Shanghai Hao Yang industry development company limited, and 306A carbon black is purchased from brightness powder body material company limited of Maanshan City; Described viscosity-controlling agent is transparent calcium, purchased from the remarkable chemical science and technology Development Co., Ltd in Shanghai; Described non-emulsifying agent is purchased from ShangHai SanZheng polymer Materials Co., Ltd, and model is CH-35; Described flow promotor is purchased from ShangHai SanZheng polymer Materials Co., Ltd, and model is CH-5; Described PE wax is purchased from Nanjing Tianshi Experimental Micro Powder Ltd., and model is PEW-0301; Described anti-wear agent is purchased from Nanjing Tianshi Experimental Micro Powder Ltd., and model is WL-5; Described soft resin oil to be increased income resin processing plant purchased from Taicang decorated archway; Described cobalt liquid drier and manganese liquid drier are purchased from Shanghai Heng Tian novel material Science and Technology Ltd..
Embodiment 1
Magenta ink described in the present embodiment, its component is:
Binder 73.775 kilograms;
Slack wax 1.5 kilograms;
It is 13 kilograms that pigment comprises precious red 6BN, and precious red 8B is 5.5 kilograms, totally 18.5 kilograms;
Anti skinning agent 0.15 kilogram;
Other auxiliary agent A comprises viscosity-controlling agent 4.5 kilograms, emulsion resistance auxiliary agent 0.5 kilogram, flow promotor 0.3 kilogram, anti-wear agent 0.5 kilogram, cobalt liquid drier 0.025 kilogram, manganese liquid drier 0.25 kilogram, totally 6.075 kilograms.
Described binder, its component and each ingredients weight parts are:
44 parts, Abietyl modified octyl phenol resol;
Oleum lini 24 parts;
30 parts, mineral oil;
Sylvic oil 1.1 parts;
Tetradecyl alcohol 0.2 part;
Auxiliary agent B comprises fluid gelling agent 0.6 part, BHT0.1 part, totally 0.7 part.
Described slack wax, its component and each ingredients weight parts are:
Oleum lini 5.4 parts;
67.4 parts, mineral oil;
27.2 parts, beeswax.
The concrete preparation process of described flexographic ink is:
S1, weigh Abietyl modified octyl phenol resol, oleum lini, mineral oil, sylvic oil, tetradecyl alcohol and auxiliary agent B according to selected parts by weight, mineral oil is divided into 3 parts: 20%, 70% and 10%, the mineral oil of 20% and every other component are placed in reactor and stir, add the mineral oil of 70% again, continue to stir, and be incubated 1 hour after within 100 minutes, being warming up to 230 DEG C, then add the mineral oil adjusting viscosity of 10%, obtained binder is for subsequent use;
S2, to weigh oleum lini, mineral oil and beeswax be placed in reactor and stir according to selected parts by weight, be incubated 40 minutes after within 1 hour, being warming up to 130 DEG C, obtained slack wax is for subsequent use;
S3, to weigh according to selected parts by weight binder that step S1 obtains, step S2 obtained slack wax, pigment, anti skinning agent and other auxiliary agent A to be placed in reactor 500 ~ 1000 turns per hour, stir 40 ~ 60 minutes, the work in-process of obtained described flexographic ink after stirring;
Described work in-process obtained in step S3 grind by S4, use ball mill, and obtained described flexographic ink, the fineness of described flexographic ink is 12 ~ 15 microns.
Embodiment 2
Middle yellow ink described in the present embodiment, its component is:
Binder 75.845 kilograms;
Slack wax 1.5 kilograms;
Pigment is that 178-1 is yellow, 18.5 kilograms;
Anti skinning agent 0.15 kilogram;
Other auxiliary agent A comprises viscosity-controlling agent 2.5 kilograms, emulsion resistance auxiliary agent 0.5 kilogram, flow promotor 0.3 kilogram, anti-wear agent 0.5 kilogram, cobalt liquid drier 0.03 kilogram, manganese liquid drier 0.175 kilogram, totally 4.005 kilograms.
Described binder, its component and each ingredients weight parts are:
40 parts, Abietyl modified octyl phenol resol;
Oleum lini 30 parts;
28 parts, mineral oil;
Sylvic oil 1.8 parts;
Tetradecyl alcohol 0.1 part;
Auxiliary agent B is fluid gelling agent 0.1 part, totally 0.1 part.
Described slack wax, its component and each ingredients weight parts are:
Oleum lini 3 parts;
75 parts, mineral oil;
22 parts, beeswax.
The concrete preparation process of described flexographic ink is:
S1, weigh Abietyl modified octyl phenol resol, oleum lini, mineral oil, sylvic oil, tetradecyl alcohol and auxiliary agent B according to selected parts by weight, mineral oil is divided into 3 parts: 20%, 70% and 10%, the mineral oil of 20% and every other component are placed in reactor and stir, add the mineral oil of 70% again, continue to stir, and be incubated 1 hour after within 100 minutes, being warming up to 200 DEG C, then add the mineral oil adjusting viscosity of 10%, obtained binder is for subsequent use;
S2, to weigh oleum lini, mineral oil and beeswax according to selected parts by weight and be placed in reactor and stir, 1 little be warming up to 100 DEG C after insulation 40 minutes, obtained slack wax is for subsequent use;
S3, to weigh according to selected parts by weight binder that step S1 obtains, step S2 obtained slack wax, pigment, anti skinning agent and other auxiliary agent A to be placed in reactor 500 ~ 1000 turns per hour, stir 40 ~ 60 minutes, the work in-process of obtained described flexographic ink after stirring;
Described work in-process obtained in step S3 grind by S4, use ball mill, and obtained described flexographic ink, the fineness of described flexographic ink is 12 ~ 15 microns.
Embodiment 3
Sky blue ink described in the present embodiment, its component is:
Binder 78.775 kilograms;
Slack wax 2 kilograms;
Pigment is 17.5 kilograms, 94817 orchid;
Anti skinning agent 0.15 kilogram;
Other auxiliary agent A comprises emulsion resistance auxiliary agent 0.5 kilogram, flow promotor 0.3 kilogram, anti-wear agent 0.6 kilogram, cobalt liquid drier 0.025 kilogram, manganese liquid drier 0.15 kilogram, totally 1.575 kilograms.
Described binder, its component and each ingredients weight parts are:
50 parts, Abietyl modified octyl phenol resol;
Oleum lini 20 parts;
27 parts, mineral oil;
Sylvic oil 1.7 parts;
Tetradecyl alcohol 0.3 part;
Auxiliary agent B comprises fluid gelling agent 0.7 part, BHT0.3 part, totally 1 part.
Described slack wax, its component and each ingredients weight parts are:
Oleum lini 8 parts;
72 parts, mineral oil;
20 parts, beeswax.
The concrete preparation process of described flexographic ink is:
S1, weigh Abietyl modified octyl phenol resol, oleum lini, mineral oil, sylvic oil, tetradecyl alcohol and auxiliary agent B according to selected parts by weight, mineral oil is divided into 3 parts: 20%, 75% and 5%, the mineral oil of 20% and every other component are placed in reactor and stir, add the mineral oil of 75% again, continue to stir, and be incubated 1 hour after within 100 minutes, being warming up to 280 DEG C, then add the mineral oil adjusting viscosity of 5%, obtained binder is for subsequent use;
S2, to weigh oleum lini, mineral oil and beeswax be placed in reactor and stir according to selected parts by weight, be incubated 40 minutes after within 1 hour, being warming up to 120 DEG C, obtained slack wax is for subsequent use;
S3, to weigh according to selected parts by weight binder that step S1 obtains, step S2 obtained slack wax, pigment, anti skinning agent and other auxiliary agent A to be placed in reactor 500 ~ 1000 turns per hour, stir 40 ~ 60 minutes, the work in-process of obtained described flexographic ink after stirring;
Described work in-process obtained in step S3 grind by S4, use ball mill, and obtained described flexographic ink, the fineness of described flexographic ink is 12 ~ 15 microns.
Embodiment 4
Tusche ink described in the present embodiment, its component is:
Binder 68.7 kilograms;
Slack wax 2 kilograms;
Pigment comprises black 10 kilograms of MA-11,306A carbon black 11 kilograms, barba hispanica 1.5 kilograms, totally 22.5 kilograms;
Anti skinning agent 0.15 kilogram;
Other auxiliary agent A comprises emulsion resistance auxiliary agent 0.6 kilogram, flow promotor 0.3 kilogram, anti-wear agent 0.5 kilogram, cobalt liquid drier 0.05 kilogram, manganese liquid drier 0.2 kilogram, soft resin oil 5 kilograms, totally 6.65 kilograms.
Described binder, its component and each ingredients weight parts are:
45 parts, Abietyl modified octyl phenol resol;
Oleum lini 27 parts;
25 parts, mineral oil;
Sylvic oil 2 parts;
Tetradecyl alcohol 0.2 part;
Auxiliary agent B comprises fluid gelling agent 0.5 part, BHT0.3 part.
Described slack wax, its component and each ingredients weight parts are:
Oleum lini 5 parts;
55 parts, mineral oil;
40 parts, beeswax.
The concrete preparation process of described flexographic ink is:
S1, weigh Abietyl modified octyl phenol resol, oleum lini, mineral oil, sylvic oil, tetradecyl alcohol and auxiliary agent B according to selected parts by weight, mineral oil is divided into 3 parts: 20%, 75% and 5%, the mineral oil of 20% and every other component are placed in reactor and stir, add the mineral oil of 75% again, continue to stir, and be incubated 1 hour after within 100 minutes, being warming up to 220 DEG C, then add the mineral oil adjusting viscosity of 5%, obtained binder is for subsequent use;
S2, to weigh oleum lini, mineral oil and beeswax be placed in reactor and stir according to selected parts by weight, be incubated 40 minutes after within 1 hour, being warming up to 150 DEG C, obtained slack wax is for subsequent use;
S3, to weigh according to selected parts by weight binder that step S1 obtains, step S2 obtained slack wax, pigment, anti skinning agent and other auxiliary agent A to be placed in reactor 500 ~ 1000 turns per hour, stir 40 ~ 60 minutes, the work in-process of obtained described flexographic ink after stirring;
Described work in-process obtained in step S3 grind by S4, use ball mill, and obtained described flexographic ink, the fineness of described flexographic ink is 12 ~ 15 microns.
Embodiment 5
Sky blue ink described in the present embodiment, its component is:
Binder 65 kilograms;
Slack wax 1 kilogram;
Pigment is 94817 orchids, 25 kilograms;
Anti skinning agent 0.3 kilogram;
Other auxiliary agent A comprises emulsion resistance auxiliary agent 0.3 kilogram, flow promotor 0.6 kilogram, anti-wear agent 0.5 kilogram, cobalt liquid drier 0.1 kilogram, soft resin oil 7.2 kilograms, totally 8.7 kilograms.
Wherein, described binder, its component and each ingredients weight parts are:
41 parts, Abietyl modified octyl phenol resol;
Oleum lini 22 parts;
35 parts, mineral oil;
Sylvic oil 1.1 parts;
Tetradecyl alcohol 0.2 part;
Auxiliary agent B is fluid gelling agent, 0.7 part.
Wherein, described slack wax, its component and each ingredients weight parts are:
Oleum lini 5.4 parts;
67.4 parts, mineral oil;
27.2 parts, beeswax.
The concrete preparation process of described flexographic ink is:
S1, weigh Abietyl modified octyl phenol resol, oleum lini, mineral oil, sylvic oil, tetradecyl alcohol and auxiliary agent B according to selected parts by weight, mineral oil is divided into 3 parts: 25%, 65% and 10%, the mineral oil of 25% and every other component are placed in reactor and stir, add the mineral oil of 65% again, continue to stir, and be incubated 1 hour after within 100 minutes, being warming up to 240 DEG C, then add the mineral oil adjusting viscosity of 10%, obtained binder is for subsequent use;
S2, to weigh oleum lini, mineral oil and beeswax be placed in reactor and stir according to selected parts by weight, be incubated 40 minutes after within 1 hour, being warming up to 140 DEG C, obtained slack wax is for subsequent use;
S3, to weigh according to selected parts by weight binder that step S1 obtains, step S2 obtained slack wax, pigment, anti skinning agent and other auxiliary agent A to be placed in reactor 500 ~ 1000 turns per hour, stir 40 ~ 60 minutes, the work in-process of obtained described flexographic ink after stirring;
Described work in-process obtained in step S3 grind by S4, use ball mill, and obtained described flexographic ink, the fineness of described flexographic ink is 12 ~ 15 microns.
Embodiment 6
Middle yellow ink described in the present embodiment, its component is:
Binder 80 kilograms;
Slack wax 2 kilograms;
Pigment is that 178-1 is yellow, 15 kilograms;
Anti skinning agent 0.1 kilogram;
Other auxiliary agent A comprises emulsion resistance auxiliary agent 0.5 kilogram, flow promotor 0.7 kilogram, anti-wear agent 0.9 kilogram, cobalt liquid drier 0.1 kilogram, manganese liquid drier 0.5 kilogram, totally 2.9 kilograms.
Described binder, its component and each ingredients weight parts are:
44 parts, Abietyl modified octyl phenol resol;
Oleum lini 24 parts;
30 parts, mineral oil;
Sylvic oil 1.1 parts;
Tetradecyl alcohol 0.2 part;
Auxiliary agent B comprises fluid gelling agent 0.6 part, BHT0.1 part, totally 0.7 part.
Described slack wax, its component and each ingredients weight parts are:
Oleum lini 3 parts;
75 parts, mineral oil;
22 parts, beeswax.
The concrete preparation process of described flexographic ink is:
S1, weigh Abietyl modified octyl phenol resol, oleum lini, mineral oil, sylvic oil, tetradecyl alcohol and auxiliary agent B according to selected parts by weight, mineral oil is divided into 3 parts: 20%, 70% and 10%, the mineral oil of 20% and every other component are placed in reactor and stir, add the mineral oil of 70% again, continue to stir, and be incubated 1 hour after within 100 minutes, being warming up to 220 DEG C, then add the mineral oil adjusting viscosity of 10%, obtained binder is for subsequent use;
S2, to weigh oleum lini, mineral oil and beeswax be placed in reactor and stir according to selected parts by weight, be incubated 40 minutes after within 1 hour, being warming up to 130 DEG C, obtained slack wax is for subsequent use;
S3, to weigh according to selected parts by weight binder that step S1 obtains, step S2 obtained slack wax, pigment, anti skinning agent and other auxiliary agent A to be placed in reactor 500 ~ 1000 turns per hour, stir 40 ~ 60 minutes, the work in-process of obtained described flexographic ink after stirring;
Described work in-process obtained in step S3 grind by S4, use ball mill, and obtained described flexographic ink, the fineness of described flexographic ink is 12 ~ 15 microns.
Embodiment 7
Sky blue ink described in the present embodiment, its component is:
Binder 76 kilograms;
Slack wax 1.8 kilograms;
Pigment is 21 kilograms, 94817 orchid;
Anti skinning agent 0.2 kilogram;
Other auxiliary agent A comprises emulsion resistance auxiliary agent 0.2 kilogram, flow promotor 0.4 kilogram, anti-wear agent 0.1 kilogram, manganese liquid drier 0.3 kilogram, totally 1 kilogram.
Described binder, its component and each ingredients weight parts are:
44 parts, Abietyl modified octyl phenol resol;
Oleum lini 24 parts;
30 parts, mineral oil;
Sylvic oil 1.1 parts;
Tetradecyl alcohol 0.2 part;
Auxiliary agent B comprises fluid gelling agent 0.6 part, BHT0.1 part, totally 0.7 part.
Described slack wax, its component and each ingredients weight parts are:
Oleum lini 8 parts;
72 parts, mineral oil;
20 parts, beeswax.
The concrete preparation process of described flexographic ink is:
S1, weigh Abietyl modified octyl phenol resol, oleum lini, mineral oil, sylvic oil, tetradecyl alcohol and auxiliary agent B according to selected parts by weight, mineral oil is divided into 3 parts: 20%, 70% and 10%, the mineral oil of 20% and every other component are placed in reactor and stir, add the mineral oil of 70% again, continue to stir, and be incubated 1 hour after within 100 minutes, being warming up to 230 DEG C, then add the mineral oil adjusting viscosity of 10%, obtained binder is for subsequent use;
S2, to weigh oleum lini, mineral oil and beeswax be placed in reactor and stir according to selected parts by weight, be incubated 40 minutes after within 1 hour, being warming up to 130 DEG C, obtained slack wax is for subsequent use;
S3, to weigh according to selected parts by weight binder that step S1 obtains, step S2 obtained slack wax, pigment, anti skinning agent and other auxiliary agent A to be placed in reactor 500 ~ 1000 turns per hour, stir 40 ~ 60 minutes, the work in-process of obtained described flexographic ink after stirring;
Described work in-process obtained in step S3 grind by S4, use ball mill, and obtained described flexographic ink, the fineness of described flexographic ink is 12 ~ 15 microns.
Embodiment 8
Magenta ink described in the present embodiment, its component is:
Binder 68 kilograms;
Slack wax 1.3 kilograms;
It is 15 kilograms that pigment comprises precious red 6BN, and precious red 8B is 5.5 kilograms, totally 20.5 kilograms;
Anti skinning agent 0.2 kilogram;
Other auxiliary agent A comprises viscosity-controlling agent 6.5 kilograms, emulsion resistance auxiliary agent 0.8 kilogram, flow promotor 0.7 kilogram, anti-wear agent 0.9 kilogram, cobalt liquid drier 0.2 kilogram, manganese liquid drier 0.9 kilogram, totally 10 kilograms.
Described binder, its component and each ingredients weight parts are:
44 parts, Abietyl modified octyl phenol resol;
Oleum lini 24 parts;
30 parts, mineral oil;
Sylvic oil 1.1 parts;
Tetradecyl alcohol 0.2 part;
Auxiliary agent B comprises fluid gelling agent 0.6 part, BHT0.1 part, totally 0.7 part.
Described slack wax, its component and each ingredients weight parts are:
Oleum lini 3 parts;
75 parts, mineral oil;
22 parts, beeswax.
The concrete preparation process of described flexographic ink is:
S1, weigh Abietyl modified octyl phenol resol, oleum lini, mineral oil, sylvic oil, tetradecyl alcohol and auxiliary agent B according to selected parts by weight, mineral oil is divided into 3 parts: 20%, 75% and 5%, the mineral oil of 20% and every other component are placed in reactor and stir, add the mineral oil of 75% again, continue to stir, and be incubated 1 hour after within 100 minutes, being warming up to 230 DEG C, then add the mineral oil adjusting viscosity of 5%, obtained binder is for subsequent use;
S2, to weigh oleum lini, mineral oil and beeswax be placed in reactor and stir according to selected parts by weight, be incubated 40 minutes after within 1 hour, being warming up to 130 DEG C, obtained slack wax is for subsequent use;
S3, to weigh according to selected parts by weight binder that step S1 obtains, step S2 obtained slack wax, pigment, anti skinning agent and other auxiliary agent A to be placed in reactor 500 ~ 1000 turns per hour, stir 40 ~ 60 minutes, the work in-process of obtained described flexographic ink after stirring;
Described work in-process obtained in step S3 grind by S4, use ball mill, and obtained described flexographic ink, the fineness of described flexographic ink is 12 ~ 15 microns.
Comparative example
Magenta ink described in this comparative example, its component, with embodiment 1, is uniquely made up of following component unlike described slack wax:
High-boiling point kerosene 72.8 parts;
27.2 parts, PE wax.
The concrete preparation process of described flexographic ink is with embodiment 1, and uniquely unlike step S2, because the fusing point of PE wax is higher, therefore temperature of reaction brings up to 150 DEG C:
S2, to weigh high-boiling point kerosene and PE wax be placed in reactor and stir according to selected parts by weight, be incubated 40 minutes after within 1 hour, being warming up to 150 DEG C, obtained slack wax is for subsequent use.
Tested by the ink roller degree of sticking of flexographic ink obtained in embodiment 1-8 and comparative example, testing tool is Heidelberg print despot GTO52.Described printer uses flexographic ink obtained in embodiment 1-8 after 200 hours, does not occur that ink roller is stained with the phenomenon of ink; And use flexographic ink obtained in comparative example 1 after 100 hours, occur that ink roller is stained with the phenomenon of ink; Therefore flexographic ink of the present invention has the low advantage of ink roller degree of sticking.
Obviously, above-described embodiment is only for clearly example being described, and the restriction not to embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here exhaustive without the need to also giving all embodiments.And thus the apparent change of extending out or variation be still among protection scope of the present invention.
Claims (9)
1. a flexographic ink, is characterized in that, described flexographic ink comprises the component of following parts by weight:
Wherein, described slack wax is made up of the component of following parts by weight:
Oleum lini 3 ~ 8 parts;
55 ~ 75 parts, mineral oil;
20 ~ 40 parts, beeswax;
The preparation method of described slack wax is: the oleum lini of selected parts by weight, mineral oil and beeswax are placed in reactor and stir, and isothermal holding after being warming up to 100 ~ 150 DEG C, obtained.
2. flexographic ink according to claim 1, is characterized in that, described binder is made up of the component of following parts by weight:
3. flexographic ink according to claim 2, is characterized in that, other auxiliary agent A described comprises one or more the combination in viscosity-controlling agent, emulsion resistance auxiliary agent, dispersion agent, anti-wear agent, siccative or soft resin oil.
4. flexographic ink according to claim 3, is characterized in that, described auxiliary agent B comprises fluid gelling agent and/or oxidation inhibitor.
5. flexographic ink according to claim 4, is characterized in that, described siccative is cobalt liquid drier and/or manganese liquid drier.
6. a preparation method for the arbitrary described flexographic ink of claim 1-5, is characterized in that, comprise the steps:
S1, weigh Abietyl modified octyl phenol resol, oleum lini, mineral oil, sylvic oil, tetradecyl alcohol and auxiliary agent B according to selected parts by weight, mineral oil is divided into 3 parts, first part of mineral oil and every other component are placed in reactor and stir, add second part of mineral oil, continue to stir and isothermal holding after being warming up to 200 ~ 280 DEG C, use the 3rd part of mineral oil adjusting viscosity again, obtained binder is for subsequent use;
S2, oleum lini, mineral oil and beeswax be placed in reactor stir, and isothermal holding after being warming up to 100 ~ 150 DEG C, obtained slack wax is for subsequent use;
S3, to weigh binder that step S1 obtains, step S2 obtained slack wax, pigment, anti skinning agent and other auxiliary agent A according to selected parts by weight and be placed in reactor and stir, the work in-process of obtained described flexographic ink;
S4, described work in-process obtained in step S3 to be ground, obtained described flexographic ink.
7. the preparation method of flexographic ink according to claim 6, it is characterized in that, in step S1, the temperature of heating step is 220 ~ 240 DEG C.
8. the preparation method of flexographic ink according to claim 6, it is characterized in that, in step S2, the temperature of heating step is 120 ~ 140 DEG C.
9. according to the preparation method of the arbitrary described flexographic ink of claim 6-8, it is characterized in that, in step S4, after described grinding steps, the fineness of described flexographic ink is 12 ~ 15 microns.
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| CN105802332A (en) * | 2014-12-30 | 2016-07-27 | 天津天女化工集团股份有限公司 | High-speed offset printing phenolic resin printing ink and preparation method thereof |
| CN105713448B (en) * | 2016-04-15 | 2019-03-19 | 浙江科信油墨有限公司 | A kind of offset ink and preparation method thereof |
| CN106280634A (en) * | 2016-07-29 | 2017-01-04 | 重庆爱溢舍文化传播有限公司 | Nanometer mineral matters pigment |
| CN106118231A (en) * | 2016-08-09 | 2016-11-16 | 苏州市博来特油墨有限公司 | A kind of preparation method of high abrasion offset ink |
| CN106221360A (en) * | 2016-08-09 | 2016-12-14 | 苏州市博来特油墨有限公司 | High speed printing adaptive rub resistance environment-friendly ink |
| CN107793830A (en) * | 2016-08-31 | 2018-03-13 | 天津天女化工集团股份有限公司 | A kind of quick-dry type environmental protection rotary ink and preparation method |
| CN107353825B (en) * | 2017-08-07 | 2020-01-14 | 浙江科信油墨有限公司 | High-gloss friction-resistant glazing oil and preparation method thereof |
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| CN101531845A (en) * | 2009-04-15 | 2009-09-16 | 苏州科斯伍德油墨股份有限公司 | Flexographic ink with high degradation rate |
| CN101531844A (en) * | 2009-04-15 | 2009-09-16 | 苏州科斯伍德油墨股份有限公司 | Environment-friendly flexographic ink |
| CN102675974A (en) * | 2012-05-23 | 2012-09-19 | 张家港市双林制墨涂装有限公司 | Connection material for high-viscosity offset printing high-gloss quick drying ink and preparation method thereof |
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| CN101531845A (en) * | 2009-04-15 | 2009-09-16 | 苏州科斯伍德油墨股份有限公司 | Flexographic ink with high degradation rate |
| CN101531844A (en) * | 2009-04-15 | 2009-09-16 | 苏州科斯伍德油墨股份有限公司 | Environment-friendly flexographic ink |
| CN102675974A (en) * | 2012-05-23 | 2012-09-19 | 张家港市双林制墨涂装有限公司 | Connection material for high-viscosity offset printing high-gloss quick drying ink and preparation method thereof |
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Address after: 325600 no.280 Weiqi Road, Yueqing Economic Development Zone, Wenzhou City, Zhejiang Province Patentee after: Kexin Ink Co., Ltd Address before: 325603, Wenzhou City, Zhejiang province Yueqing City North pond town pond Industrial Zone Patentee before: ZHEJIANG KEXIN INK Co.,Ltd. |
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