CN107683863A - Composite is sterilized with high-efficiency sustained-release in a kind of lobster pond - Google Patents
Composite is sterilized with high-efficiency sustained-release in a kind of lobster pond Download PDFInfo
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- CN107683863A CN107683863A CN201710634037.3A CN201710634037A CN107683863A CN 107683863 A CN107683863 A CN 107683863A CN 201710634037 A CN201710634037 A CN 201710634037A CN 107683863 A CN107683863 A CN 107683863A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/16—Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
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- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aliphatically bound aldehyde or keto groups, or thio analogues thereof; Derivatives thereof, e.g. acetals
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- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/02—Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
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- A—HUMAN NECESSITIES
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- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/06—Unsaturated carboxylic acids or thio analogues thereof; Derivatives thereof
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- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
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- A—HUMAN NECESSITIES
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- A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
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- A01N61/00—Biocides, pest repellants or attractants, or plant growth regulators containing substances of unknown or undetermined composition, e.g. substances characterised only by the mode of action
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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Abstract
The invention discloses a kind of lobster pond composite is sterilized with high-efficiency sustained-release, its raw material includes modified filler A, modified filler B, methyl-isothiazol beautiful jade ketone, glutaraldehyde, sorbate, benzoic acid, fixastive, benzalkonium bromide, starch, isobutylaldehyde, benzoate, chlorhexidine acetate, sodium acetate, disodium ethylene diamine tetraacetate, Sodium Polyacrylate, cetyldimethylethylambromide bromide ammonium, glyceryl linoleate, propane diols, AEO, sodium chloride, polyethylene glycol, oxalic acid, asarone, Sitosterolum, sodium humate, fulvic acid, photosynthetic bacteria and deionized water.The sustained release sterilization composite of the present invention is used for the sterilization in lobster pond, and there is excellent bactericide sustained release performance, abundant inorganic growth element can be provided after into pond for the vegetation of pond bottom, while ensureing efficiently high-quality sterilization, also improve the maintenance ability to pond ecosystem.
Description
Technical field
The present invention relates to the technical field of aquatic products sterilization material, more particularly to a kind of lobster pond to be sterilized again with high-efficiency sustained-release
Condensation material.
Background technology
China is aquaculture big country, and breed variety is numerous, and cultured output accounts for the 70% of whole world aquaculture total amount
Left and right.But the environmental pollution transfinited and be on the rise along with the rapid expansion of cultivation scale, regional carrying capacity, causes
Domestic breeding ecological environment deteriorates increasingly, is degenerated plus the germplasm of many traditional breed varieties, premunition declines, and causes to cultivate again
The disease incidence of thing increasingly increases, and its cause of disease is more based on bacteriosis, and above-mentioned disease has turned into restriction China's aquatic products and supported
An important factor for growing sound development.For the harm to anti-disease, antibiotic, disinfectant were used more to aquaculture thing in the past
Etc. being prevented and treated.Antibiotic using effect early stage is preferable, but drug effect can fade away with access times, and main cause is that biology is resistance to
The property of medicine.Disinfectant is the Common drugs of existing aquatic products disease prevention and cure, huge number, and application method is different.But prior art
In the Continuous sterilization effect that enters in water of common bactericide it is poor, its mostly because the dilution or evaporation of water and the sterilization that disappears disappears
The effect of poison, and another key factor for influenceing culture pond environment is exactly oxygen content, using while bactericide also to bottom of pond
Water plant cause serious infringement, and some sterilization elements will also cause Plant death, the heavy damage ecology in pond
Balance, so need a kind of lobster pond of design badly sterilizes composite to solve the problems of the prior art with high-efficiency sustained-release.
The content of the invention
To solve technical problem present in background technology, it is multiple that the present invention proposes that a kind of lobster pond is sterilized with high-efficiency sustained-release
Condensation material, for the sterilization in lobster pond, and there is excellent bactericide sustained release performance, into pond after can be pond bottom
Vegetation abundant inorganic growth element is provided, while ensureing efficiently high-quality sterilization, also improve the dimension to pond ecosystem
Hold ability.
Composite is sterilized in a kind of lobster pond proposed by the present invention with high-efficiency sustained-release, and its raw material includes by weight：Change
Property filler A 20-40 parts, modified filler B 15-35 parts, methyl-isothiazol beautiful jade ketone 2-5 parts, glutaraldehyde 1-4 parts, sorbate 3-6
Part, benzoic acid 4-8 parts, fixastive 2-5 parts, benzalkonium bromide 1-3 parts, starch 2-6 parts, isobutylaldehyde 3-6 parts, benzoate 2-5 parts,
Chlorhexidine acetate 3-6 parts, sodium acetate 3-6 parts, disodium ethylene diamine tetraacetate 2-5 parts, Sodium Polyacrylate 2-4 parts, cetyl two
Methylethyl ammonium bromide 3-6 parts, glyceryl linoleate 3-4 parts, propane diols 5-15 parts, AEO 1.5-2.5 parts,
Sodium chloride 1-3 parts, polyethylene glycol 3-5 parts, oxalic acid 5-8 parts, asarone 2-5 parts, cupreol 1-4 parts, sodium humate 2-5 parts,
Fulvic acid 1-3 parts, photosynthetic bacteria 2-6 parts, deionized water 10-20 parts.
Preferably in modified filler A raw material includes by weight：Bentonite 15-25 parts, ferric chloride solution 4-8 parts, work
Property charcoal 3-6 parts, montmorillonite 2-5 parts, aluminum oxide 1-4 parts, zeolite 2-5 parts, bentonite 1-5 parts, Silane coupling reagent KH-570 2-6 parts,
PLA 3-9 parts, urea 4-8 parts.
Preferably, modified filler A is prepared by following technique：Dried after bentonite is washed, then add iron chloride
Solution is well mixed, heating water bath, is cooled to room temperature, is then washed with deionized, then calcines, and is cooled to room temperature and is obtained thing
Expect A；Activated carbon and montmorillonite are well mixed, is stirred, is then dried, then calcine, aluminum oxide, boiling are added after being cooled to room temperature
Stone and bentonite are well mixed, and then grinding sieving, is subsequently added into Silane coupling reagent KH-570 and is well mixed, and are stirred,
Then material A, PLA and urea are added to be well mixed, is heated up, insulation, is followed by stirring for, is cooled to room temperature and obtains modified filler
A。
Preferably, modified filler A is prepared by following technique：Dried after bentonite is washed, then add iron chloride
Solution is well mixed, and in 80-100 DEG C of heating water bath 8-12h, is cooled to room temperature, is then washed with deionized, be then warming up to
250-350 DEG C of calcining 4-6h, is cooled to room temperature and obtains material A；Activated carbon and montmorillonite are well mixed, in 450-550r/min
Rotating speed stirs 20-40min, then in 80-120 DEG C of dry 1-3h, then calcines 20-40min in 700-900 DEG C, is cooled to room
Aluminum oxide, zeolite and bentonite are added after temperature to be well mixed, then ground 30-50 mesh sieves, be subsequently added into silane idol
Connection agent KH-570 is well mixed, and is stirred 20-40min in 650-850r/min rotating speeds, is then added material A, PLA and urea
It is well mixed, 130-150 DEG C is warming up to, is incubated 20-40min, then stirs 20-40min in 1500-2500r/min rotating speeds, it is cold
But modified filler A is obtained to room temperature.
Preferably, modified filler B raw material includes by weight：Stalk 5-15 parts, mulberry tree branch 8-16 parts, liquor zinci chloridi
1-5 parts, stearic acid 2-4 parts, dibutyl tin laurate 1-4 parts, polypropylene 3-6 parts, dibutyl carboxyl toluene 2-5 parts, diethyl
Alkene triamine 3-5 parts, potassium chloride 2-5 parts, ammonium nitrate 1-4 parts, ammonium molybdate 3-6 parts, potassium sulfate 2-6 parts, borax 1-4 parts, manganese sulfate
3-5 parts, zinc sulfate 2-5 parts, potassium dihydrogen phosphate 1-4 parts, dipotassium hydrogen phosphate 3-6 parts, vermiculite 5-15 parts.
Preferably, modified filler B is prepared by following technique：Stalk and mulberry tree branch are cut into small pieces drying, Ran Houjia
Enter liquor zinci chloridi to be well mixed, stir, impregnate, then heat up at room temperature, sinter, be cooled to room temperature material a；By stearic acid,
Dibutyl tin laurate, polypropylene and dibutyl carboxyl toluene are well mixed, heat up, insulation, be subsequently added into diethylenetriamine,
Potassium chloride, ammonium nitrate, ammonium molybdate, potassium sulfate, borax, manganese sulfate, zinc sulfate, potassium dihydrogen phosphate, dipotassium hydrogen phosphate and vermiculite mix
Close uniformly, continue to heat up, be incubated, stirring, be cooled to room temperature and obtain modified filler B.
Preferably, modified filler B is prepared by following technique：Stalk and mulberry tree branch are cut into small pieces in 100-110 DEG C
20-40min is dried, liquor zinci chloridi is then added and is well mixed, stirs 10-20min in 650-850r/min rotating speeds, at room temperature
10-14h is impregnated, then heats to 500-700 DEG C, 0.5-1.5h is sintered, is cooled to room temperature material a；By stearic acid, tin dilaurate
Dibutyl tin, polypropylene and dibutyl carboxyl toluene are well mixed, and are warming up to 90-110 DEG C, are incubated 10-20min, are subsequently added into
Diethylenetriamine, potassium chloride, ammonium nitrate, ammonium molybdate, potassium sulfate, borax, manganese sulfate, zinc sulfate, potassium dihydrogen phosphate, phosphoric acid hydrogen two
Potassium and vermiculite are well mixed, and are continuously heating to 120-130 DEG C, are incubated 2-3h, and 20- is stirred in 1250-1450r/min rotating speeds
40min, it is cooled to room temperature and obtains modified filler B.
Composite is sterilized in a kind of lobster pond of the present invention with high-efficiency sustained-release, and its raw material includes modified filler A, modification is filled out
Expect B, methyl-isothiazol beautiful jade ketone, glutaraldehyde, sorbate, benzoic acid, fixastive, benzalkonium bromide, starch, isobutylaldehyde, benzoic acid
Salt, chlorhexidine acetate, sodium acetate, disodium ethylene diamine tetraacetate, Sodium Polyacrylate, cetyldimethylethylambromide bromide ammonium, Asia
Olein, propane diols, AEO, sodium chloride, polyethylene glycol, oxalic acid, asarone, cupreol, humic
Sour sodium, fulvic acid, photosynthetic bacteria and deionized water.Then modified filler A adds iron chloride by being dried after bentonite is washed
Solution is well mixed, heating water bath, is cooled to room temperature, is then washed with deionized, then calcines, and is cooled to room temperature and is obtained thing
Expect A；Activated carbon and montmorillonite are well mixed, is stirred, is then dried, then calcine, aluminum oxide, boiling are added after being cooled to room temperature
Stone and bentonite are well mixed, and then grinding sieving, is subsequently added into Silane coupling reagent KH-570 and is well mixed, and are stirred,
Then material A, PLA and urea are added to be well mixed, is heated up, insulation, is followed by stirring for, is cooled to room temperature and obtains modified filler
A, it is by the way that using aluminum oxide, bentonite, zeolite, activated carbon and montmorillonite as porous substrate, trivalent is supplemented with ferric chloride solution
Iron ion, using bentonite as expanding material, and add degradable PLA and urea carries out facilitating moulding mixture, obtained modified filler
A can provide more attachment sites for raw bactericidal material, and can effectively improve the release efficiency and quality of raw bactericidal material, moreover it is possible to
Plant enough for bottom of pond provides abundant nitrogen, promotes the growth of bottom of pond plant.Modified filler B is by by stalk and mulberry tree
Branch is cut into small pieces drying, then adds liquor zinci chloridi and is well mixed, stir, impregnate, then heat up at room temperature, sinters, cooling
To room temperature material a；Stearic acid, dibutyl tin laurate, polypropylene and dibutyl carboxyl toluene are well mixed, heated up, is protected
Temperature, it is subsequently added into diethylenetriamine, potassium chloride, ammonium nitrate, ammonium molybdate, potassium sulfate, borax, manganese sulfate, zinc sulfate, biphosphate
Potassium, dipotassium hydrogen phosphate and vermiculite are well mixed, and continue to heat up, and are incubated, and stirring, are cooled to room temperature and are obtained modified filler B, it is with straw
Stalk and mulberry tree branch are as base-material, with stearic acid, dibutyl tin laurate, polypropylene, diethylenetriamine and dibutyl carboxyl first
Benzene as shaping raw material, with potassium chloride, ammonium nitrate, ammonium molybdate, potassium sulfate, borax, manganese sulfate, zinc sulfate, potassium dihydrogen phosphate and
Dipotassium hydrogen phosphate provides abundant auxin as bottom of pond plant, and vermiculite is filled out as porous base-material, the obtained modification of preparation
Material B is applied in the sterilization composite of the present invention, can not only further enhance the release efficiency of raw bactericidal material, additionally it is possible to be
The plant of bottom of pond provides abundant auxin.The sustained release sterilization composite of the present invention is used for the sterilization in lobster pond, and has
Excellent bactericide sustained release performance, into pond after abundant inorganic growth element can be provided for the vegetation of pond bottom, ensure
While efficient high-quality sterilization, the maintenance ability to pond ecosystem is also improved.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
In embodiment, modified filler A parts by weight can be 20 parts, 25 parts, 30 parts, 35 parts, 40 parts；Modification is filled out
Expect B parts by weight can be 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts,
27 parts, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts；The parts by weight of methyl-isothiazol beautiful jade ketone can be 2 parts,
2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of glutaraldehyde can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5
Part, 4 parts；The parts by weight of sorbate can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of benzoic acid
It can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of fixastive can be 2 parts, 2.5
Part, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of benzalkonium bromide can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；Starch
Parts by weight can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts；The parts by weight of isobutylaldehyde can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5
Part, 5.5 parts, 6 parts；The parts by weight of benzoate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Acetic acid chlorine oneself
Fixed parts by weight can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of sodium acetate can be 3 parts, 3.5
Part, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of disodium ethylene diamine tetraacetate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts,
4 parts, 4.5 parts, 5 parts；The parts by weight of Sodium Polyacrylate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；Hexadecyldimethyl benzyl ammonium
The parts by weight of ethyl phosphonium bromide ammonium can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The weight of glyceryl linoleate
Part can be 3 parts, 3.1 parts, 3.2 parts, 3.3 parts, 3.4 parts, 3.5 parts, 3.6 parts, 3.7 parts, 3.8 parts, 3.9 parts, 4 parts；Propane diols
Parts by weight can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；Fatty alcohol polyoxy second
The parts by weight of alkene ether can be 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts, 2.0 parts, 2.1 parts, 2.2 parts, 2.3 parts, 2.4
Part, 2.5 parts；The parts by weight of sodium chloride can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The parts by weight of polyethylene glycol can be 3
Part, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of oxalic acid can be 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；Carefully
The parts by weight of octyl ether can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of cupreol can be 1
Part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of sodium humate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4
Part, 4.5 parts, 5 parts；The parts by weight of fulvic acid can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The parts by weight of photosynthetic bacteria can be with
For 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of deionized water can be 10 parts, 11
Part, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts.
Embodiment 1
Composite is sterilized in a kind of lobster pond proposed by the present invention with high-efficiency sustained-release, and its raw material includes by weight：Change
30 parts of property filler A, 25 parts of modified filler B, 3.5 parts of methyl-isothiazol beautiful jade ketone, 2.5 parts of glutaraldehyde, 4.5 parts of sorbate, benzene
6 parts of formic acid, 3.5 parts of fixastive, 2 parts of benzalkonium bromide, 4 parts of starch, 4.5 parts of isobutylaldehyde, 3.5 parts of benzoate, chlorhexidine acetate
4.5 parts, 4.5 parts of sodium acetate, 3.5 parts of disodium ethylene diamine tetraacetate, 3 parts of Sodium Polyacrylate, cetyldimethylethylambromide bromide
4.5 parts of ammonium, 3.5 parts of glyceryl linoleate, 10 parts of propane diols, 2 parts of AEO, 2 parts of sodium chloride, polyethylene glycol 4
Part, 6.5 parts of oxalic acid, 3.5 parts of asarone, 2.5 parts of cupreol, 3.5 parts of sodium humate, 2 parts of fulvic acid, 4 parts of photosynthetic bacteria, go
15 parts of ionized water.
Modified filler A is prepared by following technique：Dried after 20 parts of bentonites are washed by weight, then add 6
Part ferric chloride solution is well mixed, and in 90 DEG C of heating water bath 10h, is cooled to room temperature, is then washed with deionized, then heat up
To 300 DEG C of calcining 5h, it is cooled to room temperature and obtains material A；4.5 parts of activated carbons and 3.5 parts of montmorillonites are well mixed, in 500r/
Min rotating speeds stir 30min, then in 100 DEG C of dry 2h, then calcine 30min in 800 DEG C, and 2.5 parts are added after being cooled to room temperature
Aluminum oxide, 3.5 parts of zeolites and 3 parts of bentonite are well mixed, then ground 40 mesh sieve, are subsequently added into 4 parts of silane idols
Connection agent KH-570 is well mixed, and 30min is stirred in 750r/min rotating speeds, is then added material A, 6 parts of PLAs and 6 parts of urea and is mixed
Close uniformly, be warming up to 140 DEG C, be incubated 30min, then stir 30min in 2000r/min rotating speeds, be cooled to room temperature and be modified
Filler A.
Modified filler B is prepared by following technique：By weight by 10 parts of stalks and 12 parts of mulberry tree branches be cut into small pieces in
105 DEG C of dry 30min, then add 3 parts of liquor zinci chloridis and be well mixed, stir 15min in 750r/min rotating speeds, soak at room temperature
Stain 12h, 600 DEG C are then heated to, sinter 1h, be cooled to room temperature material a；By 3 parts of stearic acid, 2.5 parts of di lauric dibutyls
Tin, 4.5 parts of polypropylene and 3.5 parts of dibutyl carboxyl toluene are well mixed, and are warming up to 100 DEG C, are incubated 15min, are subsequently added into 4 parts
Diethylenetriamine, 3.5 parts of potassium chloride, 2.5 parts of ammonium nitrate, 4.5 parts of ammonium molybdates, 4 parts of potassium sulfates, 2.5 parts of boraxs, 4 parts of manganese sulfates,
3.5 parts of zinc sulfate, 2.5 parts of potassium dihydrogen phosphates, 4.5 parts of dipotassium hydrogen phosphates and 10 parts of vermiculites are well mixed, and are continuously heating to 125
DEG C, 2.5h is incubated, 30min is stirred in 1350r/min rotating speeds, is cooled to room temperature and obtains modified filler B.
Embodiment 2
Composite is sterilized in a kind of lobster pond proposed by the present invention with high-efficiency sustained-release, and its raw material includes by weight：Change
20 parts of property filler A, 35 parts of modified filler B, 2 parts of methyl-isothiazol beautiful jade ketone, 4 parts of glutaraldehyde, 3 parts of sorbate, benzoic acid 8
Part, 2 parts of fixastive, 3 parts of benzalkonium bromide, 2 parts of starch, 6 parts of isobutylaldehyde, 2 parts of benzoate, 6 parts of chlorhexidine acetate, sodium acetate 3
Part, 5 parts of disodium ethylene diamine tetraacetate, 2 parts of Sodium Polyacrylate, 6 parts of cetyldimethylethylambromide bromide ammonium, glyceryl linoleate
3 parts, 15 parts of propane diols, 1.5 parts of AEO, 3 parts of sodium chloride, 3 parts of polyethylene glycol, 8 parts of oxalic acid, 2 parts of asarone,
4 parts of cupreol, 2 parts of sodium humate, 3 parts of fulvic acid, 2 parts of photosynthetic bacteria, 20 parts of deionized water.
Modified filler A is prepared by following technique：Dried after 15 parts of bentonites are washed by weight, then add 8
Part ferric chloride solution is well mixed, and in 80 DEG C of heating water bath 12h, is cooled to room temperature, is then washed with deionized, then heat up
To 250 DEG C of calcining 6h, it is cooled to room temperature and obtains material A；3 parts of activated carbons and 5 parts of montmorillonites are well mixed, turned in 450r/min
Speed stirring 40min, then in 80 DEG C of dry 3h, then calcines 40min in 700 DEG C, and 1 part of aluminum oxide, 5 are added after being cooled to room temperature
Part zeolite and 1 part of bentonite are well mixed, and then ground 50 mesh sieve, is subsequently added into 2 parts of Silane coupling reagent KH-570s
It is well mixed, 20min is stirred in 850r/min rotating speeds, material A, 9 parts of PLAs and 4 parts of urea is then added and is well mixed, rise
Temperature is incubated 20min to 150 DEG C, then stirs 20min in 2500r/min rotating speeds, is cooled to room temperature and obtains modified filler A.
Modified filler B is prepared by following technique：By weight by 5 parts of stalks and 16 parts of mulberry tree branches be cut into small pieces in
100 DEG C of dry 40min, then add 1 part of liquor zinci chloridi and be well mixed, stir 10min in 850r/min rotating speeds, soak at room temperature
Stain 14h, 500 DEG C are then heated to, sinter 1.5h, be cooled to room temperature material a；By 2 parts of stearic acid, 4 parts of di lauric dibutyls
Tin, 3 parts of polypropylene and 5 parts of dibutyl carboxyl toluene are well mixed, and are warming up to 90 DEG C, are incubated 20min, are subsequently added into 3 parts of diethyls
Alkene triamine, 5 parts of potassium chloride, 1 part of ammonium nitrate, 6 parts of ammonium molybdates, 2 parts of potassium sulfates, 4 parts of boraxs, 3 parts of manganese sulfates, 5 parts of zinc sulfate, 1
Part potassium dihydrogen phosphate, 6 parts of dipotassium hydrogen phosphates and 5 parts of vermiculites are well mixed, and are continuously heating to 130 DEG C, 2h are incubated, in 1450r/
Min rotating speeds stir 20min, are cooled to room temperature and obtain modified filler B.
Embodiment 3
Composite is sterilized in a kind of lobster pond proposed by the present invention with high-efficiency sustained-release, and its raw material includes by weight：Change
40 parts of property filler A, 15 parts of modified filler B, 5 parts of methyl-isothiazol beautiful jade ketone, 1 part of glutaraldehyde, 6 parts of sorbate, benzoic acid 4
Part, 5 parts of fixastive, 1 part of benzalkonium bromide, 6 parts of starch, 3 parts of isobutylaldehyde, 5 parts of benzoate, 3 parts of chlorhexidine acetate, sodium acetate 6
Part, 2 parts of disodium ethylene diamine tetraacetate, 4 parts of Sodium Polyacrylate, 3 parts of cetyldimethylethylambromide bromide ammonium, glyceryl linoleate
4 parts, 5 parts of propane diols, 2.5 parts of AEO, 1 part of sodium chloride, 5 parts of polyethylene glycol, 5 parts of oxalic acid, 5 parts of asarone,
1 part of cupreol, 5 parts of sodium humate, 1 part of fulvic acid, 6 parts of photosynthetic bacteria, 10 parts of deionized water.
Modified filler A is prepared by following technique：Dried after 25 parts of bentonites are washed by weight, then add 4
Part ferric chloride solution is well mixed, and in 100 DEG C of heating water bath 8h, is cooled to room temperature, is then washed with deionized, then heat up
To 350 DEG C of calcining 4h, it is cooled to room temperature and obtains material A；6 parts of activated carbons and 2 parts of montmorillonites are well mixed, turned in 550r/min
Speed stirring 20min, then in 120 DEG C of drys 1h, then calcines 20min in 900 DEG C, be cooled to 4 parts of aluminum oxide of addition after room temperature,
2 parts of zeolites and 5 parts of bentonite are well mixed, then ground 30 mesh sieve, are subsequently added into 6 parts of Silane coupling reagent KH-570s
It is well mixed, 40min is stirred in 650r/min rotating speeds, material A, 3 parts of PLAs and 8 parts of urea is then added and is well mixed, rise
Temperature is incubated 40min to 130 DEG C, then stirs 40min in 1500r/min rotating speeds, is cooled to room temperature and obtains modified filler A.
Modified filler B is prepared by following technique：By weight by 15 parts of stalks and 8 parts of mulberry tree branches be cut into small pieces in
110 DEG C of dry 20min, then add 5 parts of liquor zinci chloridis and be well mixed, stir 20min in 650r/min rotating speeds, soak at room temperature
Stain 10h, 700 DEG C are then heated to, sinter 0.5h, be cooled to room temperature material a；By 4 parts of stearic acid, 1 part of di lauric dibutyl
Tin, 6 parts of polypropylene and 2 parts of dibutyl carboxyl toluene are well mixed, and are warming up to 110 DEG C, are incubated 10min, are subsequently added into 5 parts of diethyls
Alkene triamine, 2 parts of potassium chloride, 4 parts of ammonium nitrate, 3 parts of ammonium molybdates, 6 parts of potassium sulfates, 1 part of borax, 5 parts of manganese sulfates, 2 parts of zinc sulfate, 4
Part potassium dihydrogen phosphate, 3 parts of dipotassium hydrogen phosphates and 15 parts of vermiculites are well mixed, and are continuously heating to 120 DEG C, 3h are incubated, in 1250r/
Min rotating speeds stir 40min, are cooled to room temperature and obtain modified filler B.
Embodiment 4
Composite is sterilized in a kind of lobster pond proposed by the present invention with high-efficiency sustained-release, and its raw material includes by weight：Change
25 parts of property filler A, 32 parts of modified filler B, 3 parts of methyl-isothiazol beautiful jade ketone, 3 parts of glutaraldehyde, 4 parts of sorbate, benzoic acid 7
Part, 3 parts of fixastive, 2.5 parts of benzalkonium bromide, 3 parts of starch, 5 parts of isobutylaldehyde, 3 parts of benzoate, 4 parts of chlorhexidine acetate, sodium acetate
5 parts, 3 parts of disodium ethylene diamine tetraacetate, 3.5 parts of Sodium Polyacrylate, 4 parts of cetyldimethylethylambromide bromide ammonium, linoleic acid it is sweet
3.8 parts of grease, 8 parts of propane diols, 2.2 parts of AEO, 1.5 parts of sodium chloride, 4.5 parts of polyethylene glycol, 6 parts of oxalic acid,
4 parts of asarone, 2 parts of cupreol, 4 parts of sodium humate, 1.5 parts of fulvic acid, 5 parts of photosynthetic bacteria, 12 parts of deionized water.
Modified filler A is prepared by following technique：Dried after 18 parts of bentonites are washed by weight, then add 7
Part ferric chloride solution is well mixed, and in 85 DEG C of heating water bath 11h, is cooled to room temperature, is then washed with deionized, then heat up
To 280 DEG C of calcining 5.5h, it is cooled to room temperature and obtains material A；4 parts of activated carbons and 4 parts of montmorillonites are well mixed, in 480r/min
Rotating speed stirs 35min, then in 85 DEG C of dry 2.5h, then calcines 35min in 750 DEG C, and 2 parts of oxidations are added after being cooled to room temperature
Aluminium, 4 parts of zeolites and 2 parts of bentonite are well mixed, then ground 45 mesh sieve, are subsequently added into 3 parts of silane coupler KH-
570 is well mixed, and 25min is stirred in 820r/min rotating speeds, then adds material A, 8 parts of PLAs and 5 parts of urea and is well mixed,
145 DEG C are warming up to, is incubated 25min, then 25min is stirred in 2200r/min rotating speeds, is cooled to room temperature and obtains modified filler A.
Modified filler B is prepared by following technique：By weight by 12 parts of stalks and 9 parts of mulberry tree branches be cut into small pieces in
108 DEG C of dry 25min, then add 4 parts of liquor zinci chloridis and be well mixed, stir 18min in 680r/min rotating speeds, soak at room temperature
Stain 11h, 650 DEG C are then heated to, sinter 0.8h, be cooled to room temperature material a；By 3.5 parts of stearic acid, 2 parts of fourths of tin dilaurate two
Ji Xi, 5 parts of polypropylene and 3 parts of dibutyl carboxyl toluene are well mixed, and are warming up to 105 DEG C, are incubated 12min, are subsequently added into 4.5 parts
Diethylenetriamine, 3 parts of potassium chloride, 3 parts of ammonium nitrate, 4 parts of ammonium molybdates, 5 parts of potassium sulfates, 2 parts of boraxs, 4.5 parts of manganese sulfates, 3 parts of sulphur
Sour zinc, 3 parts of potassium dihydrogen phosphates, 4 parts of dipotassium hydrogen phosphates and 12 parts of vermiculites are well mixed, and are continuously heating to 122 DEG C, are incubated 2.8h,
35min is stirred in 1280r/min rotating speeds, room temperature is cooled to and obtains modified filler B.
Embodiment 5
Composite is sterilized in a kind of lobster pond proposed by the present invention with high-efficiency sustained-release, and its raw material includes by weight：Change
35 parts of property filler A, 18 parts of modified filler B, 4 parts of methyl-isothiazol beautiful jade ketone, 2 parts of glutaraldehyde, 5 parts of sorbate, benzoic acid 5
Part, 4 parts of fixastive, 1.5 parts of benzalkonium bromide, 5 parts of starch, 4 parts of isobutylaldehyde, 4 parts of benzoate, 4 parts of chlorhexidine acetate, sodium acetate
5 parts, 3 parts of disodium ethylene diamine tetraacetate, 3.5 parts of Sodium Polyacrylate, 4 parts of cetyldimethylethylambromide bromide ammonium, linoleic acid it is sweet
3.8 parts of grease, 8 parts of propane diols, 2.2 parts of AEO, 1.5 parts of sodium chloride, 4.5 parts of polyethylene glycol, 6 parts of oxalic acid,
4 parts of asarone, 2 parts of cupreol, 4 parts of sodium humate, 1.5 parts of fulvic acid, 5 parts of photosynthetic bacteria, 12 parts of deionized water.
Modified filler A is prepared by following technique：Dried after 22 parts of bentonites are washed by weight, then add 5
Part ferric chloride solution is well mixed, and in 95 DEG C of heating water bath 9h, is cooled to room temperature, is then washed with deionized, then heat up
To 320 DEG C of calcining 4.5h, it is cooled to room temperature and obtains material A；5 parts of activated carbons and 3 parts of montmorillonites are well mixed, in 520r/min
Rotating speed stirs 25min, then in 115 DEG C of dry 1.5h, then calcines 25min in 850 DEG C, and 3 parts of oxygen are added after being cooled to room temperature
Change aluminium, 3 parts of zeolites and 4 parts of bentonite to be well mixed, then ground 35 mesh sieve, is subsequently added into 5 parts of silane couplers
KH-570 is well mixed, and 35min is stirred in 680r/min rotating speeds, and it is equal then to add material A, 4 parts of PLAs and 7 parts of urea mixing
It is even, 135 DEG C are warming up to, is incubated 35min, then 35min is stirred in 1800r/min rotating speeds, is cooled to room temperature and obtains modified filler
A。
Modified filler B is prepared by following technique：By weight by 12 parts of stalks and 9 parts of mulberry tree branches be cut into small pieces in
108 DEG C of dry 25min, then add 4 parts of liquor zinci chloridis and be well mixed, stir 18min in 680r/min rotating speeds, soak at room temperature
Stain 11h, 650 DEG C are then heated to, sinter 0.8h, be cooled to room temperature material a；By 3.5 parts of stearic acid, 2 parts of fourths of tin dilaurate two
Ji Xi, 5 parts of polypropylene and 3 parts of dibutyl carboxyl toluene are well mixed, and are warming up to 105 DEG C, are incubated 12min, are subsequently added into 4.5 parts
Diethylenetriamine, 3 parts of potassium chloride, 3 parts of ammonium nitrate, 4 parts of ammonium molybdates, 5 parts of potassium sulfates, 2 parts of boraxs, 4.5 parts of manganese sulfates, 3 parts of sulphur
Sour zinc, 3 parts of potassium dihydrogen phosphates, 4 parts of dipotassium hydrogen phosphates and 12 parts of vermiculites are well mixed, and are continuously heating to 122 DEG C, are incubated 2.8h,
35min is stirred in 1280r/min rotating speeds, room temperature is cooled to and obtains modified filler B.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. composite is sterilized in a kind of lobster pond with high-efficiency sustained-release, it is characterised in that its raw material includes by weight：Modification is filled out
Expect A 20-40 parts, modified filler B 15-35 parts, methyl-isothiazol beautiful jade ketone 2-5 parts, glutaraldehyde 1-4 parts, sorbate 3-6 parts,
Benzoic acid 4-8 parts, fixastive 2-5 parts, benzalkonium bromide 1-3 parts, starch 2-6 parts, isobutylaldehyde 3-6 parts, benzoate 2-5 parts, vinegar
Sour Chlorhexidine 3-6 parts, sodium acetate 3-6 parts, disodium ethylene diamine tetraacetate 2-5 parts, Sodium Polyacrylate 2-4 parts, etradecyldimethylamine
Base ethyl phosphonium bromide ammonium 3-6 parts, glyceryl linoleate 3-4 parts, propane diols 5-15 parts, AEO 1.5-2.5 parts, chlorine
Change sodium 1-3 parts, polyethylene glycol 3-5 parts, oxalic acid 5-8 parts, asarone 2-5 parts, cupreol 1-4 parts, sodium humate 2-5 parts, Huang
Rotten sour 1-3 parts, photosynthetic bacteria 2-6 parts, deionized water 10-20 parts.
2. composite is sterilized in lobster pond according to claim 1 with high-efficiency sustained-release, it is characterised in that modified filler A
Raw material include by weight：Bentonite 15-25 parts, ferric chloride solution 4-8 parts, activated carbon 3-6 parts, montmorillonite 2-5 parts, oxidation
Aluminium 1-4 parts, zeolite 2-5 parts, bentonite 1-5 parts, Silane coupling reagent KH-570 2-6 parts, PLA 3-9 parts, urea 4-8 parts.
3. composite is sterilized in lobster pond according to claim 1 or 2 with high-efficiency sustained-release, it is characterised in that modification is filled out
Material A is prepared by following technique：Dried after bentonite is washed, then add ferric chloride solution and be well mixed, heating water bath,
Room temperature is cooled to, is then washed with deionized, is then calcined, room temperature is cooled to and obtains material A；Activated carbon and montmorillonite are mixed
Close uniformly, stirring, then dry, then calcine, addition aluminum oxide, zeolite and bentonite are well mixed after being cooled to room temperature, then
Grinding sieving, be subsequently added into Silane coupling reagent KH-570 and be well mixed, stir, then add material A, PLA and
Urea is well mixed, and is heated up, and insulation, is followed by stirring for, is cooled to room temperature and obtains modified filler A.
4. composite is sterilized in the lobster pond according to claim any one of 1-3 with high-efficiency sustained-release, it is characterised in that changes
Property filler A is prepared by following technique：Dried after bentonite is washed, then add ferric chloride solution and be well mixed, in 80-
100 DEG C of heating water bath 8-12h, are cooled to room temperature, are then washed with deionized, and are then warming up to 250-350 DEG C of calcining 4-6h,
It is cooled to room temperature and obtains material A；Activated carbon and montmorillonite are well mixed, 20-40min is stirred in 450-550r/min rotating speeds,
Then in 80-120 DEG C of dry 1-3h, 20-40min then is calcined in 700-900 DEG C, aluminum oxide, boiling are added after being cooled to room temperature
Stone and bentonite are well mixed, then ground 30-50 mesh sieves, and it is equal to be subsequently added into Silane coupling reagent KH-570 mixing
It is even, 20-40min is stirred in 650-850r/min rotating speeds, material A, PLA and urea is then added and is well mixed, be warming up to
130-150 DEG C, 20-40min is incubated, then 20-40min is stirred in 1500-2500r/min rotating speeds, is cooled to room temperature and is changed
Property filler A.
5. composite is sterilized in the lobster pond according to claim any one of 1-4 with high-efficiency sustained-release, it is characterised in that changes
Property filler B raw material includes by weight：Stalk 5-15 parts, mulberry tree branch 8-16 parts, liquor zinci chloridi 1-5 parts, stearic acid 2-4
Part, dibutyl tin laurate 1-4 parts, polypropylene 3-6 parts, dibutyl carboxyl toluene 2-5 parts, diethylenetriamine 3-5 parts, chlorination
Potassium 2-5 parts, ammonium nitrate 1-4 parts, ammonium molybdate 3-6 parts, potassium sulfate 2-6 parts, borax 1-4 parts, manganese sulfate 3-5 parts, zinc sulfate 2-5
Part, potassium dihydrogen phosphate 1-4 parts, dipotassium hydrogen phosphate 3-6 parts, vermiculite 5-15 parts.
6. composite is sterilized in the lobster pond according to claim any one of 1-5 with high-efficiency sustained-release, it is characterised in that changes
Property filler B is prepared by following technique：Stalk and mulberry tree branch are cut into small pieces drying, it is equal then to add liquor zinci chloridi mixing
It is even, stirring, impregnate, then heat up at room temperature, sinter, be cooled to room temperature material a；By stearic acid, dibutyl tin laurate, gather
Propylene and dibutyl carboxyl toluene are well mixed, and are heated up, and insulation, are subsequently added into diethylenetriamine, potassium chloride, ammonium nitrate, molybdic acid
Ammonium, potassium sulfate, borax, manganese sulfate, zinc sulfate, potassium dihydrogen phosphate, dipotassium hydrogen phosphate and vermiculite are well mixed, and continue to heat up, and are protected
Temperature, stirring, is cooled to room temperature and obtains modified filler B.
7. composite is sterilized in the lobster pond according to claim any one of 1-6 with high-efficiency sustained-release, it is characterised in that changes
Property filler B is prepared by following technique：Stalk and mulberry tree branch are cut into small pieces in 100-110 DEG C of dry 20-40min, then
Add liquor zinci chloridi to be well mixed, stir 10-20min in 650-850r/min rotating speeds, impregnate 10-14h, Ran Housheng at room temperature
Temperature sinters 0.5-1.5h, is cooled to room temperature material a to 500-700 DEG C；By stearic acid, dibutyl tin laurate, polypropylene and
Dibutyl carboxyl toluene is well mixed, and is warming up to 90-110 DEG C, is incubated 10-20min, be subsequently added into diethylenetriamine, potassium chloride,
Ammonium nitrate, ammonium molybdate, potassium sulfate, borax, manganese sulfate, zinc sulfate, potassium dihydrogen phosphate, dipotassium hydrogen phosphate and vermiculite are well mixed,
120-130 DEG C is continuously heating to, is incubated 2-3h, 20-40min is stirred in 1250-1450r/min rotating speeds, is cooled to room temperature and obtains
Modified filler B.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710634037.3A CN107683863A (en) | 2017-07-29 | 2017-07-29 | Composite is sterilized with high-efficiency sustained-release in a kind of lobster pond |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710634037.3A CN107683863A (en) | 2017-07-29 | 2017-07-29 | Composite is sterilized with high-efficiency sustained-release in a kind of lobster pond |
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| Publication Number | Publication Date |
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| CN107683863A true CN107683863A (en) | 2018-02-13 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023108218A1 (en) * | 2021-12-14 | 2023-06-22 | Robjulz Pty. Ltd. | Plant pathogen composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106614689A (en) * | 2016-12-10 | 2017-05-10 | 钦州学院 | Liquid disinfectant for aquaculture and preparation method thereof |
| CN106745814A (en) * | 2016-12-31 | 2017-05-31 | 新昌县田野泉养殖技术开发有限公司 | Compound improver of water quality for aquaculture and preparation method thereof |
| CN106980005A (en) * | 2017-05-25 | 2017-07-25 | 安徽宏远职业卫生技术服务有限公司 | A kind of water quality detection agent detected for heavy metal element |
-
2017
- 2017-07-29 CN CN201710634037.3A patent/CN107683863A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106614689A (en) * | 2016-12-10 | 2017-05-10 | 钦州学院 | Liquid disinfectant for aquaculture and preparation method thereof |
| CN106745814A (en) * | 2016-12-31 | 2017-05-31 | 新昌县田野泉养殖技术开发有限公司 | Compound improver of water quality for aquaculture and preparation method thereof |
| CN106980005A (en) * | 2017-05-25 | 2017-07-25 | 安徽宏远职业卫生技术服务有限公司 | A kind of water quality detection agent detected for heavy metal element |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023108218A1 (en) * | 2021-12-14 | 2023-06-22 | Robjulz Pty. Ltd. | Plant pathogen composition |
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