CN107683045A - Method for producing shell, housing and electronic equipment - Google Patents

Method for producing shell, housing and electronic equipment Download PDF

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Publication number
CN107683045A
CN107683045A CN201711036404.6A CN201711036404A CN107683045A CN 107683045 A CN107683045 A CN 107683045A CN 201711036404 A CN201711036404 A CN 201711036404A CN 107683045 A CN107683045 A CN 107683045A
Authority
CN
China
Prior art keywords
automatically cleaning
protective layer
cleaning particle
housing
base material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201711036404.6A
Other languages
Chinese (zh)
Other versions
CN107683045B (en
Inventor
杨光明
张涛
孙文峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Oppo Mobile Telecommunications Corp Ltd
Original Assignee
Guangdong Oppo Mobile Telecommunications Corp Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong Oppo Mobile Telecommunications Corp Ltd filed Critical Guangdong Oppo Mobile Telecommunications Corp Ltd
Priority to CN201711036404.6A priority Critical patent/CN107683045B/en
Publication of CN107683045A publication Critical patent/CN107683045A/en
Application granted granted Critical
Publication of CN107683045B publication Critical patent/CN107683045B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K5/00Casings, cabinets or drawers for electric apparatus
    • H05K5/02Details
    • H05K5/0217Mechanical details of casings
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • C03C17/009Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5072Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with oxides or hydroxides not covered by C04B41/5025
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Composite Materials (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Casings For Electric Apparatus (AREA)

Abstract

The embodiment of the present application discloses a kind of method for producing shell, housing and electronic equipment; by in base material towards forming protective layer on the surface on the outside of electronic equipment; the protective layer includes automatically cleaning particle; the automatically cleaning particle is exposed to the surface of the protective layer; the automatically cleaning particle occurs light-catalyzed reaction, organic matter is decomposed into carbon dioxide and water when receiving light irradiation; namely the oils degradation that will attach in the fingerprint of surface of shell, so as to reach the automatic purpose for eliminating fingerprint.

Description

Method for producing shell, housing and electronic equipment
Technical field
The application is related to technical field of electronic equipment, and in particular to a kind of method for producing shell, housing and electronic equipment.
Background technology
At present, electronic equipment, for example mobile phone, the housing outer surface of tablet personal computer easily glue fingerprint.
The content of the invention
The embodiment of the present application provides a kind of method for producing shell, housing and electronic equipment, can be with automated cleaning housing appearance The fingerprint in face.
The embodiment of the present application provides a kind of method for producing shell, and the housing is applied to electronic equipment, and the housing makes Method includes:
There is provided a base material, the base material includes first surface and second surface, and the first surface is towards in electronic equipment Side, second surface is towards on the outside of electronic equipment;And
Protective layer is set in the second surface of the base material, the protective layer includes automatically cleaning particle, the automatically cleaning Particle is exposed to the surface of the protective layer, and when receiving light irradiation light-catalyzed reaction degraded occurs for the automatically cleaning particle Organic matter.
The embodiment of the present application also provides a kind of housing, and applied to electronic equipment, the housing includes a base material and a protection Layer, the base material include first surface and second surface, and the first surface is electric towards electronic equipment inner side, second surface direction On the outside of sub- equipment, the protective layer is arranged at the second surface of the base material, and the protective layer includes automatically cleaning particle, described Automatically cleaning particle is exposed to the surface of the protective layer, and when receiving light irradiation photocatalysis occurs for the automatically cleaning particle anti- Answer degradation of organic substances.
The embodiment of the present application additionally provides a kind of electronic equipment, including housing, and the housing includes a base material and a protection Layer, the base material include first surface and second surface, and the first surface is electric towards electronic equipment inner side, second surface direction On the outside of sub- equipment, the protective layer is arranged at the second surface of the base material, and the protective layer includes automatically cleaning particle, described Automatically cleaning particle is exposed to the surface of the protective layer, and when receiving light irradiation photocatalysis occurs for the automatically cleaning particle anti- Answer degradation of organic substances.
The method for producing shell that the embodiment of the present application provides, by base material towards being formed on the surface on the outside of electronic equipment Protective layer, the protective layer include automatically cleaning particle, and the automatically cleaning particle is exposed to the surface of the protective layer, it is described from Particle is cleaned when receiving light irradiation, light-catalyzed reaction occurs, organic matter is decomposed into carbon dioxide and water, will also be adhered to Oils degradation in the fingerprint of surface of shell, so as to reach the automatic purpose for eliminating fingerprint.
Brief description of the drawings
In order to illustrate more clearly of the technical scheme in the embodiment of the present application, make required in being described below to embodiment Accompanying drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the present application, for For those skilled in the art, on the premise of not paying creative work, it can also be obtained according to these accompanying drawings other attached Figure.
Fig. 1 is the structural representation for the electronic equipment that the embodiment of the present application provides.
Fig. 2 is the structural representation for the housing that the embodiment of the present application provides.
Fig. 3 is the structural representation for the bonnet that the embodiment of the present application provides.
Fig. 4 is profiles of the Fig. 3 in the first embodiment in A-A directions.
Fig. 5 is profiles of the Fig. 3 in second of embodiment in A-A directions.
Fig. 6 is profiles of the Fig. 3 in the third embodiment in A-A directions.
Fig. 7 is another structural representation for the housing that the embodiment of the present application provides.
Fig. 8 is another structural representation for the bonnet that the embodiment of the present application provides.
Fig. 9 is another structural representation for the electronic equipment that the embodiment of the present application provides.
Figure 10 is the first schematic flow sheet for the bonnet preparation method that the embodiment of the present application provides.
Figure 11 is second of schematic flow sheet of the bonnet preparation method that the embodiment of the present application provides.
Figure 12 is the third schematic flow sheet for the bonnet preparation method that the embodiment of the present application provides.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present application, the technical scheme in the embodiment of the present application is carried out clear, complete Site preparation describes.Obviously, described embodiment is only some embodiments of the present application, rather than whole embodiments.It is based on Embodiment in the application, the every other implementation that those skilled in the art are obtained under the premise of creative work is not made Example, belong to the scope of the application protection.
In the description of the present application, it is to be understood that term " " center ", " longitudinal direction ", " transverse direction ", " length ", " width ", " thickness ", " on ", " under ", "front", "rear", "left", "right", " vertical ", " level ", " top ", " bottom ", " interior ", " outer ", " up time The orientation or position relationship of the instruction such as pin ", " counterclockwise " are based on orientation shown in the drawings or position relationship, are for only for ease of Describe the application and simplify to describe, rather than indicate or imply that signified device or element must have specific orientation, Yi Te Fixed azimuth configuration and operation, therefore it is not intended that limitation to the application.In addition, term " first ", " second " are only used for Purpose is described, and it is not intended that instruction or hint relative importance or the implicit quantity for indicating indicated technical characteristic. Thus, " first " is defined, the feature of " second " can be expressed or implicitly includes one or more feature. In the description of the present application, " multiple " are meant that two or more, unless otherwise specifically defined.
, it is necessary to illustrate in the description of the present application, unless otherwise clearly defined and limited, term " installation ", " phase Even ", " connection " should be interpreted broadly, for example, it may be being fixedly connected or being detachably connected, or be integrally connected;Can To be mechanical connection or electrical connection or can mutually communicate;Can be joined directly together, can also be by between intermediary Connect connected, can be connection or the interaction relationship of two elements of two element internals.For the ordinary skill of this area For personnel, the concrete meaning of above-mentioned term in this application can be understood as the case may be.
In this application, unless otherwise clearly defined and limited, fisrt feature second feature it " on " or it " under " Can directly it be contacted including the first and second features, it is not directly to contact but pass through it that can also include the first and second features Between other characterisation contact.Moreover, fisrt feature second feature " on ", " top " and " above " to include first special Sign is directly over second feature and oblique upper, or is merely representative of fisrt feature level height and is higher than second feature.Fisrt feature exists Second feature " under ", " lower section " and " following " fisrt feature that includes are immediately below second feature and obliquely downward, or be merely representative of Fisrt feature level height is less than second feature.
Following disclosure provides many different embodiments or example is used for realizing the different structure of the application.In order to Simplify disclosure herein, hereinafter the part and setting of specific examples are described.Certainly, they are only example, and And purpose does not lie in limitation the application.In addition, the application can in different examples repeat reference numerals and/or reference letter, This repetition is for purposes of simplicity and clarity, between itself not indicating discussed various embodiments and/or setting Relation.In addition, this application provides various specific techniques and material examples, but those of ordinary skill in the art can be with Recognize the application of other techniques and/or the use of other materials.
The embodiment of the present application provides a kind of method for producing shell, housing and electronic equipment.It will carry out respectively below detailed Explanation.
In the present embodiment, will be described from the angle of bonnet preparation method, the method for producing shell can be formed Housing, the housing can be set in the electronic device, such as mobile phone, tablet personal computer, palm PC (Personal Digital Assistant, PDA) etc..
Refer to the structural representation that 1, Fig. 1 is the electronic equipment that the embodiment of the present application provides.The electronic equipment 1 includes Housing 10, display screen 20, printed circuit board 30, battery 40.
Referring to Fig. 2, Fig. 2 is the structural representation for the housing that the embodiment of the present application provides.
Wherein, the housing 10 can include cover plate 11, center 12 and bonnet 13.The cover plate 11, the and of the center 12 The bonnet 13 is mutually combined to form the housing 10.The housing 10, which has, passes through the cover plate 11, the center 12 and institute A confined space of the formation of bonnet 13 is stated, to accommodate the devices such as display screen 20, printed circuit board 30, battery 40.
In certain embodiments, the lid of cover plate 11 is set on the center 12.The lid of bonnet 13 is set to the center On 12.The cover plate 11 and bonnet 13 are located at the opposite face of the center 12.The cover plate 11 and bonnet 13 are oppositely arranged.It is described The confined space of housing 10 is between the cover plate 11 and bonnet 13.
The cover plate 11 can be transparent glass cover plate.In some embodiments, the cover plate 11 can be with such as Glass cover-plate made of the materials such as sapphire.
The center 12 can be metal shell, such as aluminium alloy center 12.It should be noted that in the embodiment of the present application The material of frame 12 is not limited to this, can also use other manner, such as:The center 12 can ceramic center, glass center. For another example:The center 12 can be plastic cement center.Also such as:The center 12 can be the knot that metal and plastic cement cooperate Structure, plastic portions and being molded on sheet metal can be formed.
The bonnet 13 can be with metal back cover, such as aluminium alloy bonnet, stainless steel bonnet.The bonnet 13 can also be glass Glass bonnet or ceramic bonnet.
Also referring to Fig. 3, Fig. 3 is the structural representation for the bonnet that the embodiment of the present application provides.
The bonnet 13 can include inner surface 131 and the outer surface 132 being oppositely arranged.The inner surface of the bonnet 13 131 close to center 12 and cover plate 11, forms a part for the inner surface of the housing 10.The outer surface 132 of the bonnet 13 is remote From center 12 and cover plate 11, a part for the outer surface of the housing 10 is formed.The bonnet 13 can also include through hole 133, The through hole 133 can be used for installing camera.
Also referring to Fig. 4, Fig. 4 is profiles of the Fig. 3 in A-A directions.
For purposes of illustration only, housing is illustrated by taking bonnet 13 as an example below.
The bonnet 13 can include a base material 134 and a protective layer 135.The protective layer 135 is arranged at the bonnet 13 surfaces away from cover plate 11.
Wherein, the base material 134 can use aluminium, such as aluminium alloy, can also use stainless steel, can also use glass Glass, ceramics etc..
The base material 134 includes first surface 1341 and second surface 1342.The first surface 1341 is set towards electronics Standby inner side, second surface 1342 is towards on the outside of electronic equipment.In one embodiment, the first surface 1341 is towards cover plate 11 Set with the direction of center 12.The first surface 1341 can be the inner surface 131 of bonnet 13.The first surface 1341 is The inner surface of the housing 11.The second surface 1342 faces away from cover plate 11 and the direction of center 12 is set.Described second Surface 1342 is the outer surface of the housing 11.
The protective layer 135 is arranged at the second surface 1342 of the base material 134.The protective layer 135 is included from clear Clean particle 136, the automatically cleaning particle 136 are exposed to the surface of the protective layer 135.The automatically cleaning particle 136 is receiving When light irradiates, light-catalyzed reaction degradation of organic substances occurs.
The protective layer 136 can use celluloid paint.
In one embodiment, in order that the protective layer 135 can more be firmly adhered to the of the base material 134 Two surfaces 1342, the second surface 1342 of the base material 134 can be processed by shot blasting, to increase the of the base material 134 The flatness on the surface on two surfaces 1342, so as to add second surface 1342 of the protective layer 135 in the base material 134 Adhesive force, and then the protective layer 135 is firmly adhered to the second surface 1342 of the base material 134.
The automatically cleaning particle 136 can use TiO2、SiO2、ZnO、CdS、WO3、Fe2O3Deng.The automatically cleaning particle 136 can also use the TiO of metal ion mixing2、SiO2、ZnO、CdS、WO3、Fe2O3Deng.The metal ion for doping Can be silver ion, copper ion etc..
The automatically cleaning particle 136 can use physical vapour deposition (PVD) (PVD), chemical vapor deposition (CVD), collosol and gel The methods of method or hydro-thermal method, is formed.
In one embodiment, when forming the automatically cleaning particle 136 using the method for chemical vapor deposition, can adopt Use TiCl4And O2, by the control to temperature and pressure, generate TiO2Nano particle, namely form the automatically cleaning particle 136.
In one embodiment, when forming the automatically cleaning particle 136 using sol-gal process, forerunner can first be prepared Body colloidal sol, pass through the control to PH, additive and temperature etc., gel of the generation with certain space structure, by gel It is dried and calcines, forms nano particle, namely form the automatically cleaning particle 136.
In one embodiment, metal alkoxide can be used for raw material, add solvent, water, catalyst etc., by hydrolysis and Polymerisation obtains precursor sol.The metal alkoxide can use Ti (OC2H5)4、Ti(OC3H7 i)4、Ti(OC4H9 n)4Deng.
In one embodiment, when forming the protective layer 135 using hydro-thermal method, precursor solution is first prepared, is passed through Control to temperature and pressure, nano particle is generated, namely form the automatically cleaning particle 136.
It should be noted that referring to Fig. 5-6, in certain embodiments, the protective layer 135 includes at least two colorings Area 1351/1352, the color of each colour attaching area 1351/1352 is different, and the colour attaching area 1351/1352 of different colours uses color not Same automatically cleaning particle 1361/1362.
For example, the protective layer 135 includes the first colour attaching area 1351 and the second colour attaching area 1352.First colour attaching area 1351 can use the first automatically cleaning particle 1361.The first automatically cleaning particle 1361 can be white.Described first from clearly Clean particle 1361 can use TiO2, ZnO etc..Second colour attaching area 1352 can use the second automatically cleaning particle 1362.Institute It can be yellow to state the second automatically cleaning particle 1362.The second automatically cleaning particle 1362 can use CdS, BiVO4Deng.Example again Such as, the protective layer 135 can also include the 3rd colour attaching area 1353.3rd colour attaching area 1353 uses the 3rd automatically cleaning particle 1363.The 3rd automatically cleaning particle 1363 can be rufous.The 3rd automatically cleaning particle 1363 can use Fe2O3
In one embodiment, the thickness of the protective layer 135 is more than 10 microns.When the thickness of the protective layer 135 is small When 10 microns, because the thickness of the protective layer 135 is smaller, photopermeability is high, is easily done by the self color of base material 134 Disturb, it is bad to the utilization rate of the automatically cleaning particle 136 of the protective layer 135 color of itself, simultaneously as the protective layer 135 thickness is smaller, easily punches protective layer 135 in polishing process, is unfavorable for the formation of protective layer 135.A kind of real Apply in mode, the thickness of the protective layer 135 can be more than 100 microns.
In one embodiment, the diameter of the automatically cleaning particle 136 is less than 500 nanometers, to cause the automatically cleaning Grain 136 has good photocatalytic, meanwhile, user can't experience the automatically cleaning on its surface when touching the housing Particle 136.In one embodiment, the diameter of the automatically cleaning particle 136 can be 50 nanometers -100 nanometers.When described from clear When the diameter of clean particle 136 is less than 50nm, because the diameter of the automatically cleaning particle 136 is smaller, cause manufacturing cost higher, make Make complex process;When the diameter of the automatically cleaning particle 136 is more than 100nm, due to the automatically cleaning particle 136 diameter compared with Greatly, cause the photocatalytic of the automatically cleaning particle 136 weaker.
It should be noted that the structure of the embodiment of the present application housing is not limited to this, such as, referring to Fig. 7, Fig. 7 is this Apply for another structural representation for the housing that embodiment provides.
The housing 10a includes cover plate 16 and bonnet 17.In certain embodiments, the cover plate 16 directly lid is set to described On bonnet 17.The cover plate 16 and the bonnet 17 are mutually combined to form the housing 10a.The housing 10a, which has, passes through institute The confined space that cover plate 16 and bonnet 17 are formed is stated, to accommodate the devices such as display screen 20, printed circuit board 30, battery 40.
Compared to the housing 10 shown in Fig. 2, Fig. 7 housing 10a does not include center, or perhaps by the center in Fig. 2 12 and bonnet 13 be integrally formed to form the structure of a bonnet 17.
Specifically, referring to Fig. 8, Fig. 8 is another structural representation for the bonnet that the embodiment of the present application provides.
In certain embodiments, bonnet 17 includes inner surface 171 and outer surface 172, inner surface 171 and the phase of outer surface 172 To setting, the whole surface of bonnet 17 is formed.Each Rotating fields of the bonnet 17 can refer to bonnet 13, will not be repeated here.
The printed circuit board 30 is installed in the housing 10, and the printed circuit board 30 can be the mainboard of electronic equipment 1, Antenna, motor, microphone, camera, light sensor, receiver and processor etc. can be integrated with printed circuit board 30 Functional unit.In certain embodiments, the printed circuit board 30 is fixed in housing 10.Specifically, the printed circuit board 30 can be screwed on center 12 by screw, can also be fitted on using card by the way of buckle on center 12.It should be noted that The mode that the embodiment of the present application printed circuit board 30 is specifically fixed on center 12 is not limited to this, can with other manner, than Such as by way of buckle and screw are fixed jointly.
The battery 40 is installed in the housing 10, and battery 40 is electrically connected with the printed circuit board 30, with to electronics Equipment 1 provides power supply.Housing 10 can be as the battery cover of battery 40.Housing 10 covers battery 40 to protect battery 40, specifically Be that bonnet 13 covers battery 40 to protect battery 40, reduce battery 40 due to electronic equipment 1 collision, fall etc. and be subject to Damage.
The display screen 20 is installed in the housing 10, meanwhile, the display screen 20 is electrically connected on printed circuit board 30, with Form the display surface of electronic equipment 1.The display screen 20 includes viewing area 14 and non-display area 15.The viewing area 14 It can be used for showing the picture of electronic equipment 1 or carry out touching manipulation etc. for user.The top region of the non-display area 15 Domain opens up the perforate for sound and light conduction, and fingerprint module, touch controlled key can be set on the bottom of non-display area 15 Deng functional unit.Wherein described cover plate 11 is installed on display screen 20, to cover display screen 20, is formed and the identical of display screen 20 Viewing area and non-display area, it can specifically refer to viewing area and the non-display area of display screen 20.
It should be noted that the structure of the display screen 20 is not limited to this.For example the display screen can be to shield comprehensively Or opposite sex screen, specifically, referring to Fig. 9, Fig. 9 is another structural representation for the electronic equipment that the embodiment of the present application provides.Fig. 9 In electronic equipment and Fig. 1 in the difference of electronic equipment be:The non-display area 15a is formed directly into display screen 20a On, for example in display screen 20a non-display area 15a it is arranged to transparent configuration, so that optical signal passes through, or directly showing Screen 20a non-display area is opened up for structures such as the perforate of light conduction or breach, can be by front camera, photoelectric sensor Etc. being arranged at non-display area position, so that front camera takes pictures, photoelectric sensor detection.The viewing area 14a is paved with Electronic equipment 1a whole surfaces.It should be noted that housing 10, printed circuit board 30 and battery 40 in the electronic equipment 1a Above content can be referred to Deng device, will not be repeated here.
The present invention also provides a kind of preparation method of housing.
It should be noted that illustrated below by taking bonnet as an example, but the embodiment of the present application method for producing shell is not It is limited to bonnet.
Also referring to Figure 10, Figure 10 is the schematic flow sheet for the bonnet preparation method that the embodiment of the present application provides.It is described Method for producing shell comprises the following steps:
Step S101 a, there is provided base material 134, the base material 134 includes first surface 1341 and second surface 1342, described First surface 1341 is towards on the inside of electronic equipment, and second surface 1342 is towards on the outside of electronic equipment.
The base material 134 can be metal material, such as aluminium, further, such as aluminium alloy.It should be noted that The base material 134 can be directly commercially available, and sheet fabrication can also be obtained, for example, aluminum alloy plate materials are forged and pressed, when The PROCESS FOR TREATMENTs such as effect obtain.The base material 134 can also use glass, ceramics etc..
The first surface 1341 is set towards the direction of cover plate 11 and center 12.After the first surface 1341 can be The inner surface 131 of lid 13.The first surface 1341 is the inner surface of the housing 11.The second surface 1342 faces away from The direction of cover plate 11 and center 12 is set.The second surface 1342 is the outer surface of the housing 11.
Step S102, protective layer 135 is set in the second surface 1342 of the base material 134, the protective layer 135 includes Automatically cleaning particle 136, the automatically cleaning particle 136 are exposed to the surface of the protective layer 135, and the automatically cleaning particle 135 exists When receiving light irradiation, light-catalyzed reaction degradation of organic substances occurs.
In one embodiment, Figure 11 is referred to, the step S102 may include:
Step S1021:The second surface 1342 of the base material 134 is processed by shot blasting;And
Step S1022:In the second surface 1342 of the base material 134 of polishing, protective layer 135, the guarantor are set Sheath 135 includes automatically cleaning particle 136, and the automatically cleaning particle 136 is exposed to the surface of the protective layer 135, it is described from Particle 135 is cleaned when receiving light irradiation, light-catalyzed reaction degradation of organic substances occurs.
Wherein, in order that the protective layer 135 can more be firmly adhered to the second surface of the base material 134 1342, the second surface 1342 of the base material 134 can be processed by shot blasting, to increase the second surface of the base material 134 The flatness on 1342 surface, so as to add attachment of the protective layer 135 in the second surface 1342 of the base material 134 Power, and then the protective layer 135 is firmly adhered to the second surface 1342 of the base material 134.
In certain embodiments, can be by the way of machinery, chemistry, electrochemistry or ultrasonic wave etc. to the base material 134 Second surface 1342 realize polishing.To cause the roughness of second surface 1342 of the base material 134 to reduce, with obtain it is bright, The second surface 1342 of the base material 134 of flat surface.Wherein, chemical polishing mode is the second table to the base material 134 Face 1342 carries out regular dissolving and reaches smooth.Wherein, electrochemical polish mode is by the second surface of the base material 134 1342 conduct anodes, insoluble petal are negative electrode, and the two poles of the earth are immersed in electrolytic cell simultaneously, are led to direct current and are produced selective sun Pole solution, so that the brightness of second surface 1342 increase of the base material 134 is big.The mode wherein mechanically polished is by cutting Cut the second surface 1342 of the base material 134 so that after the plastic deformation of second surface 1342 of the base material 134 removes polishing Convex portion and obtain even surface.The mode of wherein ultrasonic polishing is that the base material 134 is put into abrasive suspension and put together In ultrasound field, by the oscillation action of ultrasonic wave, make abrasive material in the grinding-polishing of second surface 1342 of the base material 134.
In certain embodiments, can be first right before being processed by shot blasting to the second surface 1342 of the base material 134 The second surface 1342 of the base material 134 carries out grinding process, then again to the second table of the base material 134 after grinding process Face 1342 is processed by shot blasting, makes polishing better so that the second surface 1342 of the base material 134 is more smooth. Here, it should be noted that the grinding process can be understood as to the roughing before polishing.I.e., it is possible to first to bonnet Outer surface carries out once thick polishing, then is once carefully polished, and completes polishing.
The protective layer 136 can use celluloid paint.
The automatically cleaning particle 136 can use TiO2、SiO2、ZnO、CdS、WO3、Fe2O3Deng.The automatically cleaning particle 136 can also use the TiO of metal ion mixing2、SiO2、ZnO、CdS、WO3、Fe2O3Deng.The metal ion for doping Can be silver ion, copper ion etc..
The automatically cleaning particle 136 can use physical vapour deposition (PVD) (PVD), chemical vapor deposition (CVD), collosol and gel The methods of method or hydro-thermal method, is formed.
In one embodiment, when forming the automatically cleaning particle 136 using the method for chemical vapor deposition, can adopt Use TiCl4And O2, by the control to temperature and pressure, generate TiO2Nano particle, namely form the automatically cleaning particle 136.
In one embodiment, when forming the automatically cleaning particle 136 using sol-gal process, forerunner can first be prepared Body colloidal sol, pass through the control to PH, additive and temperature etc., gel of the generation with certain space structure, by gel It is dried and calcines, forms nano particle, namely form the automatically cleaning particle 136.
In one embodiment, metal alkoxide can be used for raw material, add solvent, water, catalyst etc., by hydrolysis and Polymerisation obtains precursor sol.The metal alkoxide can use Ti (OC2H5)4、Ti(OC3H7 i)4、Ti(OC4H9 n)4Deng.
In one embodiment, when forming the protective layer 135 using hydro-thermal method, precursor solution is first prepared, is passed through Control to temperature and pressure, nano particle is generated, namely form the automatically cleaning particle 136.
It should be noted that in certain embodiments, the protective layer 135 includes at least two colour attaching areas 1351/1352, The color of each colour attaching area 1351/1352 is different, and the colour attaching area 1351/1352 of different colours is using the different automatically cleaning of color Grain 1361/1362.
For example, the protective layer 135 includes the first colour attaching area 1351 and the second colour attaching area 1352.First colour attaching area 1351 can use the first automatically cleaning particle 1361.The first automatically cleaning particle 1361 can be white.Described first from clearly Clean particle 1361 can use TiO2, ZnO etc..Second colour attaching area 1352 can use the second automatically cleaning particle 1362.Institute It can be yellow to state the second automatically cleaning particle 1362.The second automatically cleaning particle 1362 can use CdS, BiVO4Deng.Example again Such as, the protective layer 135 can also include the 3rd colour attaching area 1353.3rd colour attaching area 1353 uses the 3rd automatically cleaning particle 1363.The 3rd automatically cleaning particle 1363 can be rufous.The 3rd automatically cleaning particle 1363 can use Fe2O3
In one embodiment, Figure 12 is referred to, methods described can also include:
Step 103:Automatically cleaning particle 136 is uniformly mixed in protective paint and forms predecessor.
The step S102 also includes:
Step S102a:The predecessor is coated on to the second surface 1342 of the base material 134;
Step S102b:The predecessor for drying the second surface 1342 of the base material 134 obtains prefilter layer;
Step S102c:Blasting treatment is carried out to the prefilter layer, exposure automatically cleaning particle 136, forms protective layer 135, institute Automatically cleaning particle 136 is stated when receiving light irradiation, light-catalyzed reaction degradation of organic substances occurs.
In one embodiment, the step 101 can be carried out before step S103, can also be after step s 103 Carry out, can also be carried out simultaneously with step S103.The step S101 and step S103 are respectively positioned on before the step S102.
In one embodiment, the hardness of abrasive material used in the blasting treatment is more than the hardness of the prefilter layer, small In the hardness of the automatically cleaning particle 136.
In one embodiment, the thickness of the protective layer 135 is more than 10 microns.When the thickness of the protective layer 135 is small When 10 microns, because the thickness of the protective layer 135 is smaller, photopermeability is high, is easily done by the self color of base material 134 Disturb, it is bad to the utilization rate of the automatically cleaning particle 136 of the protective layer 135 color of itself, simultaneously as the protective layer 135 thickness is smaller, easily punches protective layer 135 in polishing process, is unfavorable for the formation of protective layer 135.A kind of real Apply in mode, the thickness of the protective layer 135 can be more than 100 microns.
In one embodiment, the diameter of the automatically cleaning particle 136 is less than 500 nanometers, to cause the automatically cleaning Grain 136 has good photocatalytic, meanwhile, user can't experience the automatically cleaning on its surface when touching the housing Particle 136.In one embodiment, the diameter of the automatically cleaning particle 136 can be 50 nanometers -100 nanometers.When described from clear When the diameter of clean particle 136 is less than 50nm, because the diameter of the automatically cleaning particle 136 is smaller, cause manufacturing cost higher, make Make complex process;When the diameter of the automatically cleaning particle 136 is more than 100nm, due to the automatically cleaning particle 136 diameter compared with Greatly, cause the photocatalytic of the automatically cleaning particle 136 weaker.
In summary, the method for producing shell that the embodiment of the present application provides, by base material towards on the outside of electronic equipment Protective layer is formed on surface, the protective layer includes automatically cleaning particle, and the automatically cleaning particle is exposed to the protective layer Surface, the automatically cleaning particle receive light irradiation when, occur light-catalyzed reaction, by organic matter be decomposed into carbon dioxide and Water, namely the oils degradation that will attach in the fingerprint of surface of shell, so as to reach the automatic purpose for eliminating fingerprint.
It will be understood by those skilled in the art that the structure of the electronic equipment 1 shown in Fig. 1 is not formed to electronic equipment 1 Restriction.Electronic equipment 1 can be included than illustrating more or less parts, either combine some parts or different portions Part is arranged.Electronic equipment 1 can also include memory, bluetooth module etc., will not be repeated here.
Method for producing shell, housing and the electronic equipment provided above the embodiment of the present application is described in detail, this Apply specific case in text to be set forth the principle and embodiment of the application, the explanation of above example is only intended to Help understands the application.Meanwhile for those skilled in the art, according to the thought of the application, in embodiment and answer With there will be changes in scope, in summary, this specification content should not be construed as the limitation to the application.

Claims (13)

1. a kind of method for producing shell, the housing is applied to electronic equipment, it is characterised in that the method for producing shell bag Include:
One base material is provided, the base material includes first surface and second surface, and the first surface is towards on the inside of electronic equipment, and the Two surfaces are towards on the outside of electronic equipment;And
Protective layer is set in the second surface of the base material, the protective layer includes automatically cleaning particle, the automatically cleaning particle Exposed to the surface of the protective layer, when receiving light irradiation light-catalyzed reaction degraded occurs for the automatically cleaning particle organic Thing.
2. method for producing shell as claimed in claim 1, it is characterised in that protection is set in the second surface of the base material Layer, the protective layer include automatically cleaning particle, and the automatically cleaning particle is exposed to the surface of the protective layer, the automatically cleaning Particle is in addition to equal by automatically cleaning particle before the step of light-catalyzed reaction degradation of organic substances occurs when receiving light irradiation Even is mixed in protective paint the step of forming predecessor.
3. method for producing shell as claimed in claim 2, it is characterised in that protection is set in the second surface of the base material Layer, the protective layer include automatically cleaning particle, and the automatically cleaning particle is exposed to the surface of the protective layer, the automatically cleaning Particle receive light irradiation when, occur light-catalyzed reaction degradation of organic substances the step of in, including:
The predecessor is coated on to the second surface of the base material;
The predecessor for drying the second surface of the base material obtains prefilter layer;And
Blasting treatment is carried out to the prefilter layer, exposure automatically cleaning particle forms protective layer, and the automatically cleaning particle is receiving light When line irradiates, light-catalyzed reaction degradation of organic substances occurs.
4. method for producing shell as claimed in claim 1, it is characterised in that:The protective layer includes at least two colour attaching areas, The color of each colour attaching area is different, and the colour attaching area of different colours is using the different automatically cleaning particle of color.
5. method for producing shell as claimed in claim 1, it is characterised in that:The thickness of the protective layer is more than 10 microns.
6. method for producing shell as claimed in claim 1, it is characterised in that:The diameter of the automatically cleaning particle is received less than 500 Rice.
7. method for producing shell as claimed in claim 1, it is characterised in that:A diameter of 50 nanometers of the automatically cleaning particle- 100 nanometers.
A kind of 8. housing, applied to electronic equipment, it is characterised in that:The housing includes a base material and a protective layer, the base Material includes first surface and second surface, and the first surface is towards on the inside of electronic equipment, and second surface is towards outside electronic equipment Side, the protective layer are arranged at the second surface of the base material, and the protective layer includes automatically cleaning particle, the automatically cleaning Grain is exposed to the surface of the protective layer, and when receiving light irradiation, light-catalyzed reaction degraded occurs to be had the automatically cleaning particle Machine thing.
9. housing as claimed in claim 8, it is characterised in that:The protective layer includes at least two colour attaching areas, each coloring The color in area is different, and the colour attaching area of different colours is using the different automatically cleaning particle of color.
10. housing as claimed in claim 8, it is characterised in that:The thickness of the protective layer is more than 10 microns.
11. housing as claimed in claim 8, it is characterised in that:The diameter of the automatically cleaning particle is less than 500 nanometers.
12. housing as claimed in claim 8, it is characterised in that:A diameter of 50 nanometers -100 nanometers of the automatically cleaning particle.
13. a kind of electronic equipment, it is characterised in that including housing, the housing is as any one of claim 8 to 12 Housing.
CN201711036404.6A 2017-10-30 2017-10-30 Shell manufacturing method, shell and electronic equipment Expired - Fee Related CN107683045B (en)

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CN1900360A (en) * 2006-07-14 2007-01-24 西南大学 Process for preparing magnesium alloy surface function gradient film
CN1900361A (en) * 2006-07-14 2007-01-24 西南大学 Process for preparing neodymium-iron-boron permanent magnetic material surface gradient function coating layer
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