CN107651855A - A kind of wear-resisting glass fibre and preparation method thereof - Google Patents
A kind of wear-resisting glass fibre and preparation method thereof Download PDFInfo
- Publication number
- CN107651855A CN107651855A CN201711177167.5A CN201711177167A CN107651855A CN 107651855 A CN107651855 A CN 107651855A CN 201711177167 A CN201711177167 A CN 201711177167A CN 107651855 A CN107651855 A CN 107651855A
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- parts
- glass fibre
- wear
- resisting
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C13/00—Fibre or filament compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B37/00—Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
- C03B37/01—Manufacture of glass fibres or filaments
- C03B37/02—Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor
- C03B37/022—Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor from molten glass in which the resultant product consists of different sorts of glass or is characterised by shape, e.g. hollow fibres, undulated fibres, fibres presenting a rough surface
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
The invention discloses a kind of wear-resisting glass fibre, include the component of following mass parts：00 ~ 130 part of silica 1,2 ~ 8 parts of boron oxide, 2 ~ 5 parts of sodium oxide molybdena, 10 ~ 15 parts of AES resins, 5 ~ 8 parts of sodium tripolyphosphate, 6 ~ 12 parts of ethyl trimethoxy silane, 2 ~ 5 parts of weather resisting agent, 5 ~ 8 parts of grinding aid.The invention discloses a kind of wear-resisting glass fibre, is selected by specific component and content, so as to possess outside the advantages that high temperature resistant, corrosion-resistant, intensity is high, also with wear-resisting feature.The present invention also provides the preparation method of the glass fibre, and this method step is simple, and requirement on devices is low, and cost is low, is adapted to promote the use of.
Description
Technical field
The present invention relates to glass fibre preparing technical field, more particularly to a kind of wear-resisting glass fibre and its preparation side
Method.
Background technology
Glass fibre is higher than organic fiber heatproof, non-ignitable, anti-corruption, heat-insulated, sound-proofing is good, and tensile strength is high, electrical insulating property
It is good.Glass fibre is extraordinary metal material alternative materials, and with developing rapidly for market economy, glass fibre, which turns into, to be built
Build, traffic, electronics, electrically, chemical industry, metallurgy, environmental protection, the essential raw material of industry such as national defence.Due in multiple necks
Domain is used widely, and therefore, glass fibre is increasingly subject to the attention of people.But glass fibre also has some shortcomings, such as
The property said is crisp, and wearability is poor, and this also constrains its application.
The content of the invention
The deficiency for more than, the present invention provide a kind of wear-resisting glass fibre, and the glass fibre is possessing high temperature resistant, corrosion resistant
Outside erosion, the advantages that intensity is high, also with wear-resisting feature.The present invention also provides the preparation method of the glass fibre.
To reach above-mentioned purpose, the present invention adopts the following technical scheme that：
A kind of wear-resisting glass fibre, include the component of following mass parts：00 ~ 130 part of silica 1,2 ~ 8 parts of boron oxide, oxygen
2 ~ 5 parts of sodium of change, 10 ~ 15 parts of AES resins, 5 ~ 8 parts of sodium tripolyphosphate, 6 ~ 12 parts of ethyl trimethoxy silane, 2 ~ 5 parts of weather resisting agent,
5 ~ 8 parts of grinding aid.
Further, the component of following mass parts is included：20 parts of silica 1,4 parts of boron oxide, 3 parts of sodium oxide molybdena, AES trees
12 parts of fat, 6 parts of sodium tripolyphosphate, 10 parts of ethyl trimethoxy silane, 4 parts of weather resisting agent, 6 parts of grinding aid.
Further, the weather resisting agent is one in phenyl salicylate, ultra-violet absorber UV-9 and light stabilizer HPT
Kind.
Further, the grinding aid is one kind in polyalcohol amine, triethanolamine and triisopropanolamine.
The present invention also provides the preparation method of above-mentioned wear-resisting glass fibre, comprises the following steps：
1）Silica, boron oxide, sodium oxide molybdena, AES resins, sodium tripolyphosphate and ethyl trimethoxy silane are put into and ground according to quantity
Ground in grinding machine, obtain mixed-powder；
2）The mixed-powder is added etc. to the water of quality, magnetic agitation is carried out, is put into after stirring in autoclave, 200 ~
60 ~ 120 minutes are incubated at a temperature of 280 DEG C；
3）Step 2 is obtained into material and is together put into glass melter fusing with weather resisting agent and grinding aid, fusion temperature is 850 ~ 1100
DEG C, the time is 2 ~ 3 hours；
4）Wire drawing process is carried out to the material after fusing, wire-drawing temperature is 1200 ~ 1350 DEG C, and the type of cooling is water cooling, after cooling
Obtain wear-resisting glass fibre.
Further, step 1）Described in mixed-powder granularity be 50 ~ 500 μm.
Further, step 2）The rotating speed of middle magnetic agitation is 1600 ~ 2200rpm.
Compared with prior art, the beneficial effects of the invention are as follows：The invention discloses a kind of wear-resisting glass fibre, pass through
Specific component and content selection, so as to possess outside the advantages that high temperature resistant, corrosion-resistant, intensity is high, also with wear-resisting feature.This
Invention also provides the preparation method of the glass fibre, and this method step is simple, and requirement on devices is low, and cost is low, is adapted to promote the use of.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below.Obviously, described implementation
Example only part of the embodiment of the present invention, rather than whole embodiments.It is common based on the embodiment in the present invention, this area
The every other embodiment that technical staff is obtained under the premise of creative work is not made, belong to the model that the present invention protects
Enclose.
Embodiment 1
The present embodiment provides a kind of wear-resisting glass fibre, includes the component of following mass parts：00 part of silica 1, boron oxide 2
Part, 2 parts of sodium oxide molybdena, 10 parts of AES resins, 5 parts of sodium tripolyphosphate, 6 parts of ethyl trimethoxy silane, 2 parts of phenyl salicylate, polymerization
5 parts of hydramine.
The preparation method of the wear-resisting glass fibre of embodiment 1 is prepared, is comprised the following steps：
1）Silica, boron oxide, sodium oxide molybdena, AES resins, sodium tripolyphosphate and ethyl trimethoxy silane are put into and ground according to quantity
Ground in grinding machine, obtain mixed-powder, the granularity of mixed-powder is 50 μm；
2）By the water of the quality such as mixed-powder addition, magnetic agitation is carried out, the rotating speed of magnetic agitation is 1600rpm, stirring
After be put into autoclave, be incubated 120 minutes at a temperature of 200 DEG C；
3）Step 2 is obtained into material and is together put into glass melter fusing with weather resisting agent and grinding aid, fusion temperature is 850 DEG C, when
Between be 3 hours；
4）Wire drawing process is carried out to the material after fusing, wire-drawing temperature is 1200 DEG C, and the type of cooling is water cooling, is obtained after cooling resistance to
The glass fibre of mill.
Embodiment 2
The present embodiment provides a kind of wear-resisting glass fibre, includes the component of following mass parts：30 parts of silica 1, boron oxide 8
Part, 5 parts of sodium oxide molybdena, 15 parts of AES resins, 8 parts of sodium tripolyphosphate, 12 parts of ethyl trimethoxy silane, ultra-violet absorber UV-9
5 parts, 8 parts of triethanolamine.
The preparation method of the wear-resisting glass fibre of embodiment 2 is prepared, is comprised the following steps：
1）Silica, boron oxide, sodium oxide molybdena, AES resins, sodium tripolyphosphate and ethyl trimethoxy silane are put into and ground according to quantity
Ground in grinding machine, obtain mixed-powder, the granularity of mixed-powder is 500 μm；
2）By the water of the quality such as mixed-powder addition, magnetic agitation is carried out, the rotating speed of magnetic agitation is 2200rpm, stirring
After be put into autoclave, be incubated 120 minutes at a temperature of 280 DEG C；
3）Step 2 is obtained into material and is together put into glass melter fusing, fusing temperature with ultra-violet absorber UV-9 and triethanolamine
Spend for 1100 DEG C, the time is 2 hours；
4）Wire drawing process is carried out to the material after fusing, wire-drawing temperature is 1350 DEG C, and the type of cooling is water cooling, is obtained after cooling resistance to
The glass fibre of mill.
Embodiment 3
The present embodiment provides a kind of wear-resisting glass fibre, includes the component of following mass parts：20 parts of silica 1, boron oxide 4
Part, 3 parts of sodium oxide molybdena, 12 parts of AES resins, 6 parts of sodium tripolyphosphate, 10 parts of ethyl trimethoxy silane, 5 parts of light stabilizer HPT,
8 parts of triisopropanolamine.
The preparation method of the wear-resisting glass fibre of embodiment 2 is prepared, is comprised the following steps：
1）Silica, boron oxide, sodium oxide molybdena, AES resins, sodium tripolyphosphate and ethyl trimethoxy silane are put into and ground according to quantity
Ground in grinding machine, obtain mixed-powder, the granularity of mixed-powder is 200 μm；
2）By the water of the quality such as mixed-powder addition, magnetic agitation is carried out, the rotating speed of magnetic agitation is 2000rpm, stirring
After be put into autoclave, be incubated 100 minutes at a temperature of 260 DEG C；
3）Step 2 is obtained into material and is together put into glass melter fusing, fusion temperature with light stabilizer HPT and triisopropanolamine
For 900 DEG C, the time is 2.5 hours；
4）Wire drawing process is carried out to the material after fusing, wire-drawing temperature is 1300 DEG C, and the type of cooling is water cooling, is obtained after cooling resistance to
The glass fibre of mill.
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any
Those familiar with the art the invention discloses technical scope in, the change or replacement that can readily occur in, all should
It is included within the scope of the present invention.Therefore, protection scope of the present invention should using the scope of the claims as
It is accurate.
Claims (7)
1. a kind of wear-resisting glass fibre, it is characterised in that include the component of following mass parts：00 ~ 130 part of silica 1, oxygen
2 ~ 8 parts of boron of change, 2 ~ 5 parts of sodium oxide molybdena, 10 ~ 15 parts of AES resins, 5 ~ 8 parts of sodium tripolyphosphate, 6 ~ 12 parts of ethyl trimethoxy silane,
2 ~ 5 parts of weather resisting agent, 5 ~ 8 parts of grinding aid.
2. wear-resisting glass fibre according to claim 1, it is characterised in that include the component of following mass parts：Dioxy
120 parts of SiClx, 4 parts of boron oxide, 3 parts of sodium oxide molybdena, 12 parts of AES resins, 6 parts of sodium tripolyphosphate, 10 parts of ethyl trimethoxy silane,
4 parts of weather resisting agent, 6 parts of grinding aid.
3. wear-resisting glass fibre according to claim 1, it is characterised in that the weather resisting agent is phenyl salicylate, purple
One kind in ultraviolet absorbers UV-9 and light stabilizer HPT.
4. wear-resisting glass fibre according to claim 1, it is characterised in that the grinding aid is polyalcohol amine, three second
One kind in hydramine and triisopropanolamine.
5. the preparation method of the wear-resisting glass fibre according to Claims 1-4, it is characterised in that comprise the following steps：
1）Silica, boron oxide, sodium oxide molybdena, AES resins, sodium tripolyphosphate and ethyl trimethoxy silane are put into and ground according to quantity
Ground in grinding machine, obtain mixed-powder；
2）The mixed-powder is added etc. to the water of quality, magnetic agitation is carried out, is put into after stirring in autoclave, 200 ~
60 ~ 120 minutes are incubated at a temperature of 280 DEG C；
3）Step 2 is obtained into material and is together put into glass melter fusing with weather resisting agent and grinding aid, fusion temperature is 850 ~ 1100
DEG C, the time is 2 ~ 3 hours；
4）Wire drawing process is carried out to the material after fusing, wire-drawing temperature is 1200 ~ 1350 DEG C, and the type of cooling is water cooling, after cooling
Obtain wear-resisting glass fibre.
6. preparation method according to claim 5, it is characterised in that step 1）Described in mixed-powder granularity for 50 ~
500μm。
7. preparation method according to claim 5, it is characterised in that step 2）The rotating speed of middle magnetic agitation be 1600 ~
2200rpm。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711177167.5A CN107651855A (en) | 2017-11-22 | 2017-11-22 | A kind of wear-resisting glass fibre and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711177167.5A CN107651855A (en) | 2017-11-22 | 2017-11-22 | A kind of wear-resisting glass fibre and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107651855A true CN107651855A (en) | 2018-02-02 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711177167.5A Withdrawn CN107651855A (en) | 2017-11-22 | 2017-11-22 | A kind of wear-resisting glass fibre and preparation method thereof |
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| CN (1) | CN107651855A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108893862A (en) * | 2018-07-13 | 2018-11-27 | 合肥连森裕腾新材料科技开发有限公司 | A kind of corrosion resistant glass fiber mesh and preparation method thereof |
| CN109234876A (en) * | 2018-08-31 | 2019-01-18 | 嘉兴市优泰纺织新材料有限公司 | A kind of Silk Threads of high intensity |
| CN114057396A (en) * | 2021-12-14 | 2022-02-18 | 赵嘉成 | Acid and alkali resistant colorful glass and preparation method thereof |
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| CN104452094A (en) * | 2014-12-06 | 2015-03-25 | 常熟江南玻璃纤维有限公司 | Production process of glass fiber composite |
| CN104452097A (en) * | 2014-12-06 | 2015-03-25 | 常熟江南玻璃纤维有限公司 | Production method of glass fiber composite |
| CN104452096A (en) * | 2014-12-06 | 2015-03-25 | 常熟江南玻璃纤维有限公司 | Production process of glass fiber composite |
| CN104818555A (en) * | 2015-04-28 | 2015-08-05 | 安徽丹凤集团桐城玻璃纤维有限公司 | Composite glass fiber production process |
| CN105086178A (en) * | 2015-07-28 | 2015-11-25 | 安徽丹凤集团桐城玻璃纤维有限公司 | Preparation technology for glass fiber composite material with acid-base resistance |
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2017
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Patent Citations (5)
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| CN104452094A (en) * | 2014-12-06 | 2015-03-25 | 常熟江南玻璃纤维有限公司 | Production process of glass fiber composite |
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| CN104452096A (en) * | 2014-12-06 | 2015-03-25 | 常熟江南玻璃纤维有限公司 | Production process of glass fiber composite |
| CN104818555A (en) * | 2015-04-28 | 2015-08-05 | 安徽丹凤集团桐城玻璃纤维有限公司 | Composite glass fiber production process |
| CN105086178A (en) * | 2015-07-28 | 2015-11-25 | 安徽丹凤集团桐城玻璃纤维有限公司 | Preparation technology for glass fiber composite material with acid-base resistance |
Non-Patent Citations (1)
| Title |
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| 赵彦钊等: "《玻璃工艺学》", 30 April 2015, 化学工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108893862A (en) * | 2018-07-13 | 2018-11-27 | 合肥连森裕腾新材料科技开发有限公司 | A kind of corrosion resistant glass fiber mesh and preparation method thereof |
| CN109234876A (en) * | 2018-08-31 | 2019-01-18 | 嘉兴市优泰纺织新材料有限公司 | A kind of Silk Threads of high intensity |
| CN114057396A (en) * | 2021-12-14 | 2022-02-18 | 赵嘉成 | Acid and alkali resistant colorful glass and preparation method thereof |
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Application publication date: 20180202 |