CN105601129A - Reinforced soakage agent for basalt fibers - Google Patents
Reinforced soakage agent for basalt fibers Download PDFInfo
- Publication number
- CN105601129A CN105601129A CN201510979756.XA CN201510979756A CN105601129A CN 105601129 A CN105601129 A CN 105601129A CN 201510979756 A CN201510979756 A CN 201510979756A CN 105601129 A CN105601129 A CN 105601129A
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- CN
- China
- Prior art keywords
- emulsion
- agent
- basalt fibre
- water
- consumption
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/36—Epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/323—Polyesters, e.g. alkyd resins
Abstract
The invention discloses a soakage agent for basalt fibers and a preparation method of the soakage agent. The soakage agent is prepared from 2%-8% of water-soluble epoxy resin, 1%-5% of a polyester emulsion, 2%-4% of a vinyl resin emulsion, 0.5%-1.0% of a coupling agent, 0.2%-0.8% of an antistatic agent, 0.6%-1.2% of a plasticizer, 0.08%-0.25% of a pH regulator and the balance of deionized water. The soakage agent which is prepared in the rated weight ratio and used for surface modification of the basalt fibers can be directly applied to the surfaces of the basalt fibers in the production and drawing process of the basalt fibers, surface modification can be completed after drying, the soakage agent is more convenient to use, and an aqueous solution of the soakage agent has good adhesion and film-forming properties.
Description
Technical field:
The present invention relates to a kind of enhanced fiber size and preparation method thereof, belong to size technical field.
Background technology:
Basalt fibre be basalt building stones after 1450 DEG C～1500 DEG C meltings, the continuous fiber forming by platinum-rhodium alloy bushing high speed pulling,Intensity is suitable with high strength S glass fibre. Basalt fibre has good mechanical strength, high temperature resistant, resistance to chemical attack, heat insulation, sound insulation, goodGood wave transparent absorbing property and environmental-protecting performance, be a kind of novel inorganic environment-friendly and green high performance fibre material, be also current China give priority to novelOne of high-performance fiber.
In the drawing process of fiber, apply a kind of surface conditioning agent taking organic matter emulsion as main body, i.e. fiber size at fiber surface. MakeCan effectively change the processing characteristics of inorfil with size; In the forming process of inorfil reinforcing material, size can be given fibre instituteEssential technical performance. Size not only directly affects the presentation quality of finished product yarn, and more can affect the performance quality of finished product yarn.
Basalt fibre and glass fibre process technology have similarity, but difference in chemical composition has directly caused both in performance and processedDifference in journey. Each fiber product has special size to coordinate with it, especially the wherein film forming agent of key component of conduct. Conventional is profoundMilitary rock fiber size has three kinds of epoxy emulsion, polyaminoester emulsion and polyester emulsions, and research shows, existing three kinds of basalt fibre sizes are in realityWhile application, also there is certain limitation in border. A kind of film forming agent uses separately filming performance poor, and following process easily produces and flies silk and filoplume phenomenon, with treeFat adhesion is poor.
Summary of the invention:
The present invention is directed to basalt fibre size and have the problems referred to above, aim to provide one and be applicable to basalt fibre fiber size for reinforcemeent. The present inventionBe applicable to the enhancing textile size that basalt strengthens thermosetting phenolic epoxy resin, polyester resin composite material, textile is good and can promote the Black WarriorThe adhesion of rock fiber and the thermosetting polymer polymer that is enhanced.
For achieving the above object, described basalt size batching percentage is as follows:
Described epoxy emulsion film forming agent is aqueous epoxy resin emulsion, and the trade mark is GE-95, purchased from Shanghai Aishibo Organosilicon Material Co., Ltd..Described polyester emulsion model is BH-933, and purchased from wide Tonghua, Dongguan work Products Co., Ltd, described vinylite emulsion model is BH-961, purchasesWide Tonghua work Products Co., Ltd from Dongguan; Vinylite emulsion, what described antistatic additive was selected is inorganic matter lithium nitrate; Amino silane couplingAgent is KH560, and the trade mark is Z-6040, purchased from DOW CORNING.
Concrete steps of the present invention are:
A preparation method for basalt fibre size, is characterized in that, comprises the steps:
A, respectively water-soluble epoxy resin, mylar, vinylite emulsion are added to the water and are stirred respectively, make abundant dispersion, waterTemperature is 50～70 degree; The consumption of water is that 5～10 times of each emulsion weight are for subsequent use;
B, in deionized water, add PH conditioning agent, regulating pH value is 4～6, under stirring, adds amino silicane coupling agent, then continue stirring 25～35 minutes to till aqueous solution clear; The consumption of water accounts for 1/20 of size gross weight;
C, antistatic additive is dissolved into the aqueous solution according to 20% mass concentration;
D, above-mentioned raw materials is filled up to soft water by proportional quantity, stir and can come into operation.
Beneficial effect of the present invention:
1, the size in the present invention can ensure that basalt fibre wire drawing carries out smoothly, flies a fracture of wire phenomenon few, the basalt fibre friction resistant of drawing,Have good textile performance, ultimate fibre intensity is high.
2, adopting the size in the present invention is pre-treatment size, and the basalt fiber cloth being made into does not need can be used for thermosetting phenol through Overheating TreatmentFormaldehyde epoxy resin composite is manufactured, and soaks into soon, adhesion is strong with matrix resin compound tense.
4, size compound method of the present invention is easy, easily grasps, reproducible.
5, epoxy emulsion film forming agent of the present invention is bisphenol A type epoxy resin, and filming performance is good, processes fibrous woven performance good, obvolvent effectFruit is good.
6, in the present invention, use the metaphenylene polyester resin aqueous dispersion that polyester emulsion is nonionic. Its aqueous solution has good cementability and film formingProperty.
7, the vinylite aqueous dispersion that vinylite emulsion of the present invention is a kind of nonionic, filming performance is good, to fibre cohesionThere is good greasy property by force, simultaneously.
Detailed description of the invention:
A kind of basalt fibre fiber size for reinforcemeent, is made up of following component according to weight percent meter.
Preparation method comprises the steps:
A, respectively water-soluble epoxy resin, mylar, vinylite emulsion are added to the water and are stirred respectively, make abundant dispersion, waterTemperature is 50～70 degree; The consumption of water is that 5～10 times of each emulsion weight are for subsequent use;
B, in deionized water, add PH conditioning agent, regulating pH value is 4～6, under stirring, adds amino silicane coupling agent, then continue stirring 25～35 minutes to till aqueous solution clear; The consumption of water accounts for 1/20 of size gross weight;
C, antistatic additive is dissolved into the aqueous solution according to 20% mass concentration;
D, above-mentioned raw materials is filled up to soft water by proportional quantity, stir and can come into operation.
Embodiment 1:
A kind of basalt fibre fiber size for reinforcemeent, is made up of following component according to weight percent meter:
Preparation method comprises the steps:
A, respectively water-soluble epoxy resin, mylar, vinylite emulsion are added to the water and are stirred respectively, make abundant dispersion, waterTemperature is 50～70 degree; The consumption of water is that 5～10 times of each emulsion weight are for subsequent use;
B, in deionized water, add PH conditioning agent, regulating pH value is 4～6, under stirring, adds amino silicane coupling agent, then continue stirring 25～35 minutes to till aqueous solution clear; The consumption of water accounts for 1/20 of size gross weight;
C, antistatic additive is dissolved into the aqueous solution according to 20% mass concentration;
D, above-mentioned raw materials is filled up to soft water by proportional quantity, stir and can come into operation.
Embodiment 2:
A kind of basalt fibre fiber size for reinforcemeent, is made up of following component according to weight percent meter:
Preparation method comprises the steps:
A, respectively water-soluble epoxy resin, mylar, vinylite emulsion are added to the water and are stirred respectively, make abundant dispersion, waterTemperature is 50～70 degree; The consumption of water is that 5～10 times of each emulsion weight are for subsequent use;
B, in deionized water, add PH conditioning agent, regulating pH value is 4～6, under stirring, adds amino silicane coupling agent, then continue stirring 25～35 minutes to till aqueous solution clear; The consumption of water accounts for 1/20 of size gross weight;
C, antistatic additive is dissolved into the aqueous solution according to 20% mass concentration;
D, above-mentioned raw materials is filled up to soft water by proportional quantity, stir and can come into operation.
Embodiment 3:
A kind of basalt fibre fiber size for reinforcemeent, is made up of following component according to weight percent meter:
Preparation method comprises the steps:
A, respectively water-soluble epoxy resin, mylar, vinylite emulsion are added to the water and are stirred respectively, make abundant dispersion, waterTemperature is 50～70 degree; The consumption of water is that 5～10 times of each emulsion weight are for subsequent use;
B, in deionized water, add PH conditioning agent, regulating pH value is 4～6, under stirring, adds amino silicane coupling agent, then continue stirring 25～35 minutes to till aqueous solution clear; The consumption of water accounts for 1/20 of size gross weight;
C, antistatic additive is dissolved into the aqueous solution according to 20% mass concentration;
D, above-mentioned raw materials is filled up to soft water by proportional quantity, stir and can come into operation.
Embodiment 4:
A kind of basalt fibre fiber size for reinforcemeent, is made up of following component according to weight percent meter:
Preparation method comprises the steps:
A, respectively water-soluble epoxy resin, mylar, vinylite emulsion are added to the water and are stirred respectively, make abundant dispersion, waterTemperature is 50～70 degree; The consumption of water is that 5～10 times of each emulsion weight are for subsequent use;
B, in deionized water, add PH conditioning agent, regulating pH value is 4～6, under stirring, adds amino silicane coupling agent, then continue stirring 25～35 minutes to till aqueous solution clear; The consumption of water accounts for 1/20 of size gross weight;
C, antistatic additive is dissolved into the aqueous solution according to 20% mass concentration;
D, above-mentioned raw materials is filled up to soft water by proportional quantity, stir and can come into operation.
Embodiment 6:
Get 20Kg size of the present invention and carry out wire drawing in 200 hole bushing devices, spinning cake is tested after 25 DEG C of oven dry. Application the present invention drawThe basalt fibre (A sample) of system sees the following form with domestic certain enterprise's basalt fibre (B sample) test data contrast test:
Claims (6)
1. a basalt fibre size, it is characterized in that, described size comprises: epoxy resin latex, polyester emulsion, polyvinyl resin emulsion, coupling agent, plasticizer, antistatic additive, pH adjusting agent, and water, described basalt fibre size comprises the composition of following weight percentage:
Water-soluble epoxy resin consumption is 2%～8%, polyester emulsion consumption is 1%～5%, vinylite emulsion 2%～4%, coupling agent consumption are 0.5%～1.0%, antistatic additive consumption is 0.2%～0.8%, plasticizer consumption is 0.6%～1.2%, pH adjusting agent consumption is 0.08% to 0.25%, and surplus is deionized water.
2. basalt fibre size according to claim 1, is characterized in that, described epoxy resin is water-soluble epoxy resin emulsion.
3. basalt fibre size according to claim 1, is characterized in that the metaphenylene polyester resin aqueous dispersion that described polyester emulsion is nonionic.
4. basalt fibre size according to claim 1, is characterized in that, described coupling agent is amino silicane coupling agent, preferably gamma-aminopropyl-triethoxy-silane coupling agent (KH560).
5. basalt fibre size according to claim 4, is characterized in that, described pH adjusting agent is glacial acetic acid or oxalic acid, and using pH adjusting agent to regulate deionized water pH value is 4～6, and described coupling agent is dissolved in this deionized water, makes solution.
6. basalt fibre size according to claim 1, is characterized in that, described antistatic additive is lithium nitrate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510979756.XA CN105601129A (en) | 2015-12-23 | 2015-12-23 | Reinforced soakage agent for basalt fibers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510979756.XA CN105601129A (en) | 2015-12-23 | 2015-12-23 | Reinforced soakage agent for basalt fibers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105601129A true CN105601129A (en) | 2016-05-25 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510979756.XA Pending CN105601129A (en) | 2015-12-23 | 2015-12-23 | Reinforced soakage agent for basalt fibers |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106366611A (en) * | 2016-09-14 | 2017-02-01 | 四川力久云智知识产权运营有限公司 | Special impregnating agent for polycarbonate material reinforced basalt fibers and preparation method of impregnating agent |
| CN107385915A (en) * | 2016-11-30 | 2017-11-24 | 德阳力久云智知识产权运营有限公司 | A kind of polyformaldehyde material enhancing basalt fibre sizing agent special and preparation method thereof |
| CN111410441A (en) * | 2020-04-28 | 2020-07-14 | 江苏绿材谷新材料科技发展有限公司 | Basalt fiber surface modifier and surface-modified basalt fiber |
| CN112724466A (en) * | 2020-12-29 | 2021-04-30 | 江苏绿材谷新材料科技发展有限公司 | Impregnating compound for basalt fiber reinforced polyethylene resin and preparation method thereof |
| CN113149464A (en) * | 2020-12-30 | 2021-07-23 | 江苏天龙玄武岩连续纤维股份有限公司 | Treating agent and lipophilic basalt continuous fiber infiltrated with same |
| CN114605091A (en) * | 2022-04-27 | 2022-06-10 | 单县大道玻纤有限公司 | Glass fiber impregnating compound |
| CN114605091B (en) * | 2022-04-27 | 2024-04-19 | 单县大道玻纤有限公司 | Glass fiber impregnating compound |
Citations (6)
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|---|---|---|---|---|
| JPH11293568A (en) * | 1998-04-10 | 1999-10-26 | Nippon Synthetic Chem Ind Co Ltd:The | Sizing of fiber |
| CN101497252A (en) * | 2009-03-06 | 2009-08-05 | 华东理工大学 | Polymer brush structure of polymer-based composite material interface as well as method and application for building the same |
| CN102515570A (en) * | 2011-11-30 | 2012-06-27 | 淄博新力特种纤维科技有限公司 | Pre-processing reinforced type impregnating agent for basalt fiber chopped spun yarn and preparation method of pre-processing reinforced type impregnating agent |
| CN102898044A (en) * | 2012-10-19 | 2013-01-30 | 四川航天拓鑫玄武岩实业有限公司 | Basalt fiber surface modification impregnating compound and preparation method thereof |
| CN104176948A (en) * | 2013-05-21 | 2014-12-03 | 济南大学 | Preparation method and use of nano-SiO2-modified glass fiber film-forming agent emulsion |
| CN104692674A (en) * | 2015-02-10 | 2015-06-10 | 四川省西玄科技有限公司 | Special epoxy impregnating compound for basalt fiber and preparation method of special epoxy impregnating compound |
-
2015
- 2015-12-23 CN CN201510979756.XA patent/CN105601129A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11293568A (en) * | 1998-04-10 | 1999-10-26 | Nippon Synthetic Chem Ind Co Ltd:The | Sizing of fiber |
| CN101497252A (en) * | 2009-03-06 | 2009-08-05 | 华东理工大学 | Polymer brush structure of polymer-based composite material interface as well as method and application for building the same |
| CN102515570A (en) * | 2011-11-30 | 2012-06-27 | 淄博新力特种纤维科技有限公司 | Pre-processing reinforced type impregnating agent for basalt fiber chopped spun yarn and preparation method of pre-processing reinforced type impregnating agent |
| CN102898044A (en) * | 2012-10-19 | 2013-01-30 | 四川航天拓鑫玄武岩实业有限公司 | Basalt fiber surface modification impregnating compound and preparation method thereof |
| CN104176948A (en) * | 2013-05-21 | 2014-12-03 | 济南大学 | Preparation method and use of nano-SiO2-modified glass fiber film-forming agent emulsion |
| CN104692674A (en) * | 2015-02-10 | 2015-06-10 | 四川省西玄科技有限公司 | Special epoxy impregnating compound for basalt fiber and preparation method of special epoxy impregnating compound |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106366611A (en) * | 2016-09-14 | 2017-02-01 | 四川力久云智知识产权运营有限公司 | Special impregnating agent for polycarbonate material reinforced basalt fibers and preparation method of impregnating agent |
| CN106366611B (en) * | 2016-09-14 | 2018-06-19 | 汕头市明达纺织有限公司 | A kind of makrolon material enhancing basalt fibre sizing agent special and preparation method thereof |
| CN107385915A (en) * | 2016-11-30 | 2017-11-24 | 德阳力久云智知识产权运营有限公司 | A kind of polyformaldehyde material enhancing basalt fibre sizing agent special and preparation method thereof |
| CN111410441A (en) * | 2020-04-28 | 2020-07-14 | 江苏绿材谷新材料科技发展有限公司 | Basalt fiber surface modifier and surface-modified basalt fiber |
| CN112724466A (en) * | 2020-12-29 | 2021-04-30 | 江苏绿材谷新材料科技发展有限公司 | Impregnating compound for basalt fiber reinforced polyethylene resin and preparation method thereof |
| CN113149464A (en) * | 2020-12-30 | 2021-07-23 | 江苏天龙玄武岩连续纤维股份有限公司 | Treating agent and lipophilic basalt continuous fiber infiltrated with same |
| CN114605091A (en) * | 2022-04-27 | 2022-06-10 | 单县大道玻纤有限公司 | Glass fiber impregnating compound |
| CN114605091B (en) * | 2022-04-27 | 2024-04-19 | 单县大道玻纤有限公司 | Glass fiber impregnating compound |
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Application publication date: 20160525 |