CN108893862A - A kind of corrosion resistant glass fiber mesh and preparation method thereof - Google Patents
A kind of corrosion resistant glass fiber mesh and preparation method thereof Download PDFInfo
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- CN108893862A CN108893862A CN201810768237.2A CN201810768237A CN108893862A CN 108893862 A CN108893862 A CN 108893862A CN 201810768237 A CN201810768237 A CN 201810768237A CN 108893862 A CN108893862 A CN 108893862A
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- glass fiber
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- fibre
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Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4209—Inorganic fibres
- D04H1/4218—Glass fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/062—Load-responsive characteristics stiff, shape retention
Abstract
The invention discloses a kind of corrosion resistant glass fiber mesh, raw material forms by weight：40-60 parts of polytetrafluoroethylene fibre, 25-35 parts of Saran, 15-30 parts of phenolic fibre, 10-20 parts of carbon fiber and 15-18 parts of fiber surface coating, 20-30 parts of vinyl cyanide class monomer, 25-30 parts of nano zirconia particles, 10-18 parts of graphene, 10-15 parts of sodium tripolyphosphate, 15-18 parts of ethyl trimethoxy silane, 25-36 parts of PS resin, 17-23 parts of sodium pyrophosphate and 13-18 parts of hydrochloric acid solution.Insulation and high IR absorbent properties are had both using the adhesive layer that the technology for being divided into sedimentation reaction is prepared in the present invention, so that the glass fiber material prepared can improve the corrosion resistance of glass fiber material by being chemically modified to fiberglass surfacing on the basis of the original glass fibre of reservation excellent physical property.
Description
Technical field
The present invention relates to high strength fibre field, specifically a kind of corrosion resistant glass fiber mesh and preparation method thereof.
Background technique
Glass fibre is a kind of inorganic non-metallic material haveing excellent performance, and insulating properties, heat resistance and corrosion resistance are good, machine
Tool intensity is high, and the resistance to acid and alkali of existing glass fiber compound material, rigid, anti-aging, antioxygenic property is all to be improved, in crowd
In more polymer composites, fibre reinforced composites are because it is with excellent comprehensive performance, and glass fibre is with good
Good corrosion-resistant, heat resistance, good mechanical strength, the advantages that along with cheap cost of material, be widely used aquatic products
Cultivation is the production activity of the lower breeding of artificial control, cultivation and harvest aquatic animals and plants.It is commonly included under artificial feeding management
The overall process of aquatic products is formed from seed.It broadly may also comprise Enhancement of fishery resources.It is wherein needed in aquaculture practical big
The isolating strainer of amount, effect is that cultured product is isolated with natural water, feeds and manages convenient for concentrating and avoids escaping,
Use environment of the separation net in water body is complicated, is easy to be corroded, stabilization is poor, and the cost for not only expending replacement can also often be made
At the loss of aquaculture.
Since composite material is to be mixed to be combined together obtained, material by householder method by two or more material
Between often because heterogeneity and there are phase interface, will ultimately result in because interface shearing strength between layers change cause it is multiple
The performance of condensation material is bad, so needing to invent a kind of corrosion resistant fiber net to meet requirement.
Summary of the invention
The purpose of the present invention is to provide a kind of corrosion resistant glass fiber mesh and preparation method thereof, to solve above-mentioned background
The problem of being proposed in technology.
To achieve the above object, the present invention provides the following technical solutions：
A kind of corrosion resistant glass fiber mesh is made of by weight the following raw material：40-60 parts of polytetrafluoroethylene fibre,
25-35 parts of Saran, 15-30 parts of phenolic fibre, 10-20 parts of carbon fiber and 15-18 parts of fiber surface coating, cyanogen
Change vinyl monomer 20-30 parts, 25-30 parts of nano zirconia particles, 10-18 parts of graphene, 10-15 parts of sodium tripolyphosphate, second
15-18 parts of base trimethoxy silane, 25-36 parts of PS resin, 17-23 parts of sodium pyrophosphate and 13-18 parts of hydrochloric acid solution.
The preparation method for the corrosion-resistant fiberglass net that the aquaculture uses the specific steps are：
A, by polytetrafluoroethylene fibre, phenolic fibre, fiber surface coating, nano zirconia particles, sodium tripolyphosphate and
The mixing of PS resin is placed in the stirring of blender high speed, and heating temperature is 75-85 DEG C, mixing speed 500-800r/min, then
Wire drawing is carried out, material one is obtained；
B, Saran, vinyl cyanide class monomer, graphene and ethyl trimethoxy silane liquid are placed in stirring
It stirring and heats in machine, temperature is 65-85 DEG C, the hydrochloric acid solution that mass fraction is 25-30% added, 30-40min is reacted,
Obtain material two；
C, material one is mixed with material two and is placed in melting 4-6h in melting machine, stirred under the revolving speed of 150-300r/min
35-60min obtains material three；
D, material three is placed in baking oven at 100-110 DEG C and dries 15-30min, then condensed rapidly with freezing machine to
Room temperature is placed in organic solvent again impregnates 2-5h, and finished product can be obtained after drying.
Compared with prior art, the beneficial effects of the invention are as follows：Glass fiber material of the present invention has good acid and alkali-resistance
Characteristic, while it is also equipped with good, anti-aging, the oxidation resistant advantage of rigidity, the use that can meet numerous users well is wanted
It asks, promotes industrial expansion；The cost of raw material of the invention is cheap, from a wealth of sources, and preparation method of the present invention is simple, easily grasps
Work, preparation flow are short, therefore are suitble to industrialization large-scale production manufacture；Using the technology preparation for being divided into sedimentation reaction in the present invention
Adhesive layer out has both insulation and high IR absorbent properties, so that the glass fiber material prepared can retain original glass
Glass fiber material is improved by being chemically modified to fiberglass surfacing on the basis of the excellent physical property of glass fiber
Corrosion resistance.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, the described embodiments are only some of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of corrosion resistant glass fiber mesh is as follows, and in parts by weight, 40 parts of polytetrafluoroethylene fibre, Vingon are fine
25 parts of dimension, 15 parts of phenolic fibre, 10 parts of carbon fiber and 15 parts of fiber surface coating, 20 parts of vinyl cyanide class monomer, nano oxygen
Change 25 parts of zirconium particle, 10 parts of graphene, 10 parts of sodium tripolyphosphate, 15 parts of ethyl trimethoxy silane, 25 parts of PS resin, pyrophosphoric acid
17 parts and 13 parts of hydrochloric acid solution of sodium.The preparation method for the corrosion-resistant fiberglass net that the aquaculture uses the specific steps are：
A, by polytetrafluoroethylene fibre, phenolic fibre, fiber surface coating, nano zirconia particles, sodium tripolyphosphate and
The mixing of PS resin is placed in the stirring of blender high speed, and heating temperature is 75-85 DEG C, mixing speed 500-800r/min, then
Wire drawing is carried out, material one is obtained；
B, Saran, vinyl cyanide class monomer, graphene and ethyl trimethoxy silane liquid are placed in stirring
It stirring and heats in machine, temperature is 65-85 DEG C, the hydrochloric acid solution that mass fraction is 25-30% added, 30-40min is reacted,
Obtain material two；
C, material one is mixed with material two and is placed in melting 4-6h in melting machine, stirred under the revolving speed of 150-300r/min
35-60min obtains material three；
D, material three is placed in baking oven at 100-110 DEG C and dries 15-30min, then condensed rapidly with freezing machine to
Room temperature is placed in organic solvent again impregnates 2-5h, and finished product can be obtained after drying
Embodiment 2
A kind of corrosion resistant glass fiber mesh is as follows, and in parts by weight, 60 parts of polytetrafluoroethylene fibre, Vingon are fine
35 parts of dimension, 30 parts of phenolic fibre, 20 parts of carbon fiber and 18 parts of fiber surface coating, 30 parts of vinyl cyanide class monomer, nano oxygen
Change 30 parts of zirconium particle, 18 parts of graphene, 15 parts of sodium tripolyphosphate, 18 parts of ethyl trimethoxy silane, 36 parts of PS resin, pyrophosphoric acid
23 parts and 18 parts of hydrochloric acid solution of sodium.It is described produce the preparation method of corrosion-resistant fiberglass net that cultivation uses the specific steps are：
A, by polytetrafluoroethylene fibre, phenolic fibre, fiber surface coating, nano zirconia particles, sodium tripolyphosphate and
The mixing of PS resin is placed in the stirring of blender high speed, and heating temperature is 75-85 DEG C, mixing speed 500-800r/min, then
Wire drawing is carried out, material one is obtained；
B, Saran, vinyl cyanide class monomer, graphene and ethyl trimethoxy silane liquid are placed in stirring
It stirring and heats in machine, temperature is 65-85 DEG C, the hydrochloric acid solution that mass fraction is 25-30% added, 30-40min is reacted,
Obtain material two；
C, material one is mixed with material two and is placed in melting 4-6h in melting machine, stirred under the revolving speed of 150-300r/min
35-60min obtains material three；
D, material three is placed in baking oven at 100-110 DEG C and dries 15-30min, then condensed rapidly with freezing machine to
Room temperature is placed in organic solvent again impregnates 2-5h, and finished product can be obtained after drying
Embodiment 3
A kind of corrosion resistant glass fiber mesh is as follows, and in parts by weight, 50 parts of polytetrafluoroethylene fibre, Vingon are fine
30 parts of dimension, 20 parts of phenolic fibre, 15 parts of carbon fiber and 16 parts of fiber surface coating, 27 parts of vinyl cyanide class monomer, nano oxygen
Change 26 parts of zirconium particle, 17 parts of graphene, 13 parts of sodium tripolyphosphate, 17 parts of ethyl trimethoxy silane, 29 parts of PS resin, pyrophosphoric acid
21 parts and 14 parts of hydrochloric acid solution of sodium.The preparation method for the corrosion-resistant fiberglass net that the aquaculture uses the specific steps are：
A, by polytetrafluoroethylene fibre, phenolic fibre, fiber surface coating, nano zirconia particles, sodium tripolyphosphate and
The mixing of PS resin is placed in the stirring of blender high speed, and heating temperature is 75-85 DEG C, mixing speed 500-800r/min, then
Wire drawing is carried out, material one is obtained；
B, Saran, vinyl cyanide class monomer, graphene and ethyl trimethoxy silane liquid are placed in stirring
It stirring and heats in machine, temperature is 65-85 DEG C, the hydrochloric acid solution that mass fraction is 25-30% added, 30-40min is reacted,
Obtain material two；
C, material one is mixed with material two and is placed in melting 4-6h in melting machine, stirred under the revolving speed of 150-300r/min
35-60min obtains material three；
D, material three is placed in baking oven at 100-110 DEG C and dries 15-30min, then condensed rapidly with freezing machine to
Room temperature is placed in organic solvent again impregnates 2-5h, and finished product can be obtained after drying.
It is tested by correlation test, obtains following test result：
Table 1：The present embodiment test result
Insulation and high IR are had both using the adhesive layer that the technology for being divided into sedimentation reaction is prepared in the new material
Absorbent properties, so that the glass fiber material prepared can be logical on the basis of the original glass fibre of reservation excellent physical property
It crosses and fiberglass surfacing is chemically modified to improve the corrosion resistance of glass fiber material.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (5)
1. a kind of corrosion resistant glass fiber mesh, which is characterized in that in parts by weight, including：Polytetrafluoroethylene fibre 40-60
Part, 25-35 parts of Saran, 15-30 parts of phenolic fibre, 10-20 parts of carbon fiber and fiber surface coating 15-18
Part, 20-30 parts of vinyl cyanide class monomer, 25-30 parts of nano zirconia particles, 10-18 parts of graphene, sodium tripolyphosphate 10-15
Part, 15-18 parts of ethyl trimethoxy silane, 25-36 parts of PS resin, 17-23 parts of sodium pyrophosphate and 13-18 parts of hydrochloric acid solution.
2. a kind of corrosion resistant glass fiber mesh according to claim 1, which is characterized in that in parts by weight, polytetrafluoro
40 parts of vinyl fiber, 25 parts of Saran, 15 parts of phenolic fibre, 10 parts of carbon fiber and 15 parts of fiber surface coating,
20 parts of vinyl cyanide class monomer, 25 parts of nano zirconia particles, 10 parts of graphene, 10 parts of sodium tripolyphosphate, ethyl trimethoxy
15 parts of silane, 25 parts of PS resin, 17 parts of sodium pyrophosphate and 13 parts of hydrochloric acid solution.
3. a kind of corrosion resistant glass fiber mesh according to claim 1, which is characterized in that in parts by weight, polytetrafluoro
60 parts of vinyl fiber, 35 parts of Saran, 30 parts of phenolic fibre, 20 parts of carbon fiber and 18 parts of fiber surface coating,
30 parts of vinyl cyanide class monomer, 30 parts of nano zirconia particles, 18 parts of graphene, 15 parts of sodium tripolyphosphate, ethyl trimethoxy
18 parts of silane, 36 parts of PS resin, 23 parts of sodium pyrophosphate and 18 parts of hydrochloric acid solution.
4. a kind of corrosion resistant glass fiber mesh according to claim 1, which is characterized in that in parts by weight, polytetrafluoro
50 parts of vinyl fiber, 30 parts of Saran, 20 parts of phenolic fibre, 15 parts of carbon fiber and 16 parts of fiber surface coating,
27 parts of vinyl cyanide class monomer, 26 parts of nano zirconia particles, 17 parts of graphene, 13 parts of sodium tripolyphosphate, ethyl trimethoxy
17 parts of silane, 29 parts of PS resin, 21 parts of sodium pyrophosphate and 14 parts of hydrochloric acid solution.
5. a kind of preparation method for the corrosion-resistant fiberglass net that the aquaculture as described in claim 1-4 is any uses,
It is characterized in that, includes the following steps：
A, by polytetrafluoroethylene fibre, phenolic fibre, fiber surface coating, nano zirconia particles, sodium tripolyphosphate and PS tree
Rouge mixing is placed in the stirring of blender high speed, and heating temperature is 75-85 DEG C, then mixing speed 500-800r/min is carried out
Wire drawing obtains material one；
B, Saran, vinyl cyanide class monomer, graphene and ethyl trimethoxy silane liquid are placed in blender
It stirs and heats, temperature is 65-85 DEG C, adds the hydrochloric acid solution that mass fraction is 25-30%, reacts 30-40min, obtain material
Material two；
C, material one is mixed with material two and is placed in melting 4-6h in melting machine, stir 35- under the revolving speed of 150-300r/min
60min obtains material three；
D, material three is placed in baking oven at 100-110 DEG C and dries 15-30min, then condensed rapidly with freezing machine to room temperature
It is placed in organic solvent again and impregnates 2-5h, finished product can be obtained after drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201810768237.2A CN108893862A (en) | 2018-07-13 | 2018-07-13 | A kind of corrosion resistant glass fiber mesh and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201810768237.2A CN108893862A (en) | 2018-07-13 | 2018-07-13 | A kind of corrosion resistant glass fiber mesh and preparation method thereof |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140047999A1 (en) * | 2010-11-23 | 2014-02-20 | Ivan Ràzl | Acid and high temperature resistant cement composites |
| CN107324661A (en) * | 2017-08-01 | 2017-11-07 | 合肥利裕泰玻璃制品有限公司 | A kind of preparation method of corrosion-resistant fiberglass material |
| CN107492418A (en) * | 2017-08-09 | 2017-12-19 | 安徽杰奥电气有限公司 | A kind of cable corrosion resistant fiber braiding layer |
| CN107651855A (en) * | 2017-11-22 | 2018-02-02 | 桂林全州燎原科技有限责任公司 | A kind of wear-resisting glass fibre and preparation method thereof |
| CN107761249A (en) * | 2017-11-18 | 2018-03-06 | 杭州高烯科技有限公司 | A kind of Graphene glass fibrous composite and preparation method thereof |
| CN108164919A (en) * | 2017-11-27 | 2018-06-15 | 安徽华星电缆集团有限公司 | A kind of computer cable jacket material |
| CN108264322A (en) * | 2018-02-08 | 2018-07-10 | 合肥利裕泰玻璃制品有限公司 | A kind of fiber glass reinforcement and preparation method thereof |
-
2018
- 2018-07-13 CN CN201810768237.2A patent/CN108893862A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140047999A1 (en) * | 2010-11-23 | 2014-02-20 | Ivan Ràzl | Acid and high temperature resistant cement composites |
| CN107324661A (en) * | 2017-08-01 | 2017-11-07 | 合肥利裕泰玻璃制品有限公司 | A kind of preparation method of corrosion-resistant fiberglass material |
| CN107492418A (en) * | 2017-08-09 | 2017-12-19 | 安徽杰奥电气有限公司 | A kind of cable corrosion resistant fiber braiding layer |
| CN107761249A (en) * | 2017-11-18 | 2018-03-06 | 杭州高烯科技有限公司 | A kind of Graphene glass fibrous composite and preparation method thereof |
| CN107651855A (en) * | 2017-11-22 | 2018-02-02 | 桂林全州燎原科技有限责任公司 | A kind of wear-resisting glass fibre and preparation method thereof |
| CN108164919A (en) * | 2017-11-27 | 2018-06-15 | 安徽华星电缆集团有限公司 | A kind of computer cable jacket material |
| CN108264322A (en) * | 2018-02-08 | 2018-07-10 | 合肥利裕泰玻璃制品有限公司 | A kind of fiber glass reinforcement and preparation method thereof |
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