CN107815255A - A kind of preparation method of kitchen and bath's waterproof gasket cement - Google Patents
A kind of preparation method of kitchen and bath's waterproof gasket cement Download PDFInfo
- Publication number
- CN107815255A CN107815255A CN201711099933.0A CN201711099933A CN107815255A CN 107815255 A CN107815255 A CN 107815255A CN 201711099933 A CN201711099933 A CN 201711099933A CN 107815255 A CN107815255 A CN 107815255A
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- CN
- China
- Prior art keywords
- kitchen
- bath
- preparation
- waterproof gasket
- polyester resins
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Abstract
The present invention relates to a kind of preparation method of kitchen and bath's waterproof gasket cement.By weight, isophthalic polyester resins, the hydroxybutyl of acrylic acid 4, polydimethylsiloxane are added in a kettle, perfluorocyclohexyl methyl acrylate, 2,2,4, the silane of 4,5,51,3 dioxy of hexamethyl, 2 ring penta, lysine Sepharose gel, microcrystalline cellulose glue, [base of 4 (base of 2 methyl, 3 butylene 2) 1H imidazoles 5] methanol, 3 chlorine 5,6,7,8 tetrahydrochysenes and pyridine [3,4 C] pyridazine, IPD.Heating, stirs, that is, obtains marine glue product.
Description
Technical field
The present invention relates to a kind of preparation method of kitchen and bath's waterproof gasket cement.
Background technology
Fluid sealant refers to deform with sealing surface shape, is not easy to trickle, the encapsulant for having certain caking property.It is for filling out
Fill configuration gap, to play the adhesive of sealing function.Acted on anti-leak, waterproof, vibration proof and sound insulation, heat-insulated etc..
CN106085329A discloses a kind of fluid sealant, including weight ratio is 3~7:2~5:4~8:1~3 fish oil, egg
White matter glue, polyester resin and modified polypropylene resin.The present invention has advantages below：Using natural biological raw material, substitute completely
The use of traditional glue containing aldehyde, formaldehydeless release, it is adapted to the processing technology of particieboard, there is excellent adhesive strength and hold
Follow closely power, good machining property.
CN103937432A discloses a kind of fluid sealant, including epoxy resin and curing agent, it is characterised in that also includes increasing
Tough dose；The percentage by weight of the fluid sealant each component is respectively：Epoxy resin 5%~70%, curing agent 0.5%~45%,
Toughener 1%~50%.Fluid sealant provided by the invention, bi-component fluid sealant is avoided using the process for preceding needing mixing, can be straight
Connect use and reach the adhesive sealing effect of high quality, have the advantages that it is easy to use, be easy to store；Overcome existing list simultaneously
Component sealing gum poor heat resistance, water absorption rate are high, mechanical strength is low, pliability is poor, bin stability is low, preparation technology is complicated etc. lacks
Point.Disclosure is particularly well suited to as liquid crystal display cell edge sealing adhesive.
The fluid sealant used in kitchen and bath, it is used for filling, glues and stick, waterproof leakproof, existing fluid sealant product has easily
Turn yellow, the shortcomings that producing slight crack, influence the service life of sealer and attractive in appearance.
The content of the invention
The purpose of the present invention is：There is provided a kind of manufacture method of kitchen and bath's marine glue, it is characterised in that following steps：
Isophthalic polyester resins, acrylic acid 4- hydroxybutyls, polydimethylsiloxane, perfluor ring are added in a kettle
Hexyl methyl acrylate, 2,2,4,4,5,5- vegolysens, the silane of 3- dioxy -2- rings penta, lysine Sepharose gel, crystallite are fine
Plain glue is tieed up, [4- (2- methyl -3- butene-2s-yl) -1H- imidazoles -5- bases] methanol, 3- chloro- 5,6,7,8- tetrahydrochysenes and pyridine [3,4-
C] pyridazine, IPD, white oil, 60-80 DEG C is heated to, 3-8h is stirred with 100-200rpm rotating speed, that is, obtains waterproof
Glue product.
Described acrylic acid 4- hydroxybutyls, its quality dosage are the 5-10% of isophthalic polyester resins.
Described polydimethylsiloxane, its quality dosage are the 4-12% of isophthalic polyester resins.
Described perfluorocyclohexyl methyl acrylate, its quality dosage are the 2-6% of isophthalic polyester resins.
Described 2,2,4,4,5,5- vegolysens, the silane of 3- dioxy -2- rings penta, its quality dosage are gathered for M-phthalic acid
The 0.5-1.5% of ester resin.
Described lysine Sepharose gel, its quality dosage are the 1-2.5% of isophthalic polyester resins.
Described microcrystalline cellulose glue, its quality dosage are the 1.5-4% of isophthalic polyester resins.
Described [4- (2- methyl -3- butene-2s-yl) -1H- imidazoles -5- bases] methanol, its quality dosage is isophthalic diformazan
The 1-3% of acid polyester resin.
Described 3- chloro- 5,6,7,8- tetrahydrochysenes and pyridine [3,4-C] pyridazine, its quality dosage is isophthalic polyester tree
The 0.1-1% of fat.
Described IPD, its quality dosage are the 2-5% of isophthalic polyester resins.
Described white oil, its quality dosage are the 20-50% of isophthalic polyester resins.
Described isophthalic polyester resins are commercially available prod, the product produced such as Tianmo Group Co., Ltd., Changzhou；
Acrylic acid 4- hydroxybutyls are commercially available prod, the product produced such as Hangzhou great Yang Chemical Co., Ltd.s；Polydimethylsiloxane is city
Product is sold, the product produced such as Shanxi West Asia chemical industry Co., Ltd；Perfluorocyclohexyl methyl acrylate is commercially available prod, such as
The product of regent biochemical technology Co., Ltd of Shenzhen production；2,2,4,4,5,5- vegolysens, the silane of 3- dioxy -2- rings penta are
Commercially available prod, the product produced such as Beijing Heng Yezhongyuan Chemical Co., Ltd.s；Lysine Sepharose gel is commercially available prod, as above
The product of Hai Yuanye bio tech ltd production；Microcrystalline cellulose glue is commercially available prod, as chemistry is newly hoped in Huzhou City water chestnut lake
The product of Co., Ltd's production；[4- (2- methyl -3- butene-2s-yl) -1H- imidazoles -5- bases] methanol is commercially available prod, such as Hangzhou
The product of Shang Jie Chemical Co., Ltd.s production；3- chloro- 5,6,7,8- tetrahydrochysenes and pyridine [3,4-C] pyridazine are commercially available prod, such as south
The product of Jing Aikang Chemical Co., Ltd.s production；IPD is commercially available prod, as Shanghai Mike's woods biochemical technology is limited
The product of company's production.
The beneficial effects of the invention are as follows：The marine glue that the present invention is produced has the advantages of mechanical property is strong, non-aging,
And there is long-acting antimycotic effect.Adhesive property is excellent, difficult for drop-off, is not likely to produce slight crack, can remain intact the long period outer
See and performance is played effectiveness.
Embodiment
Following instance is only to further illustrate the present invention, is not limitation the scope of protection of the invention.
Embodiment 1
In a kettle, isophthalic polyester resins 100Kg, acrylic acid 4- hydroxybutyl 7.5Kg, poly dimethyl are added
Silicone 8Kg, perfluorocyclohexyl methyl acrylate 4Kg, 2,2,4,4,5,5- vegolysens, the silane 1Kg of 3- dioxy -2- rings penta, rely
Propylhomoserin Ago-Gel 1.7Kg, microcrystalline cellulose glue 2.7Kg, [4- (2- methyl -3- butene-2s-yl) -1H- imidazoles -5- bases] first
Alcohol 2Kg, 3- chloro- 5,6,7,8- tetrahydrochysenes and pyridine [3,4-C] pyridazine 0.5Kg, IPD 3.5Kg, white oil 35Kg, heating
To 70 DEG C, 5.5h is stirred with 150rpm rotating speed, that is, obtains marine glue product.
Embodiment 2
In a kettle, isophthalic polyester resins 100Kg, acrylic acid 4- hydroxybutyl 5Kg, poly dimethyl silicon are added
Ketone 4Kg, perfluorocyclohexyl methyl acrylate 2Kg, 2,2,4,4,5,5- vegolysens, the silane 0.5Kg of 3- dioxy -2- rings penta, rely
Propylhomoserin Ago-Gel 1Kg, microcrystalline cellulose glue 1.5Kg, [4- (2- methyl -3- butene-2s-yl) -1H- imidazoles -5- bases] methanol
1Kg, 3- chloro- 5,6,7,8- tetrahydrochysenes and pyridine [3,4-C] pyridazine 0.1Kg, IPD 2Kg, white oil 20Kg, are warming up to 60
DEG C, 3h is stirred with 100rpm rotating speed, that is, obtains marine glue product.
Embodiment 3
In a kettle, isophthalic polyester resins 100Kg, acrylic acid 4- hydroxybutyl 10Kg, poly dimethyl are added
Silicone 12Kg, perfluorocyclohexyl methyl acrylate 6Kg, 2,2,4,4,5,5- vegolysens, the silane 1.5Kg of 3- dioxy -2- rings penta,
Lysine Sepharose gel 2.5Kg, microcrystalline cellulose glue 4Kg, [4- (2- methyl -3- butene-2s-yl) -1H- imidazoles -5- bases] first
Alcohol 3Kg, 3- chloro- 5,6,7,8- tetrahydrochysenes and pyridine [3,4-C] pyridazine 1Kg, IPD 5Kg, white oil 50Kg, are warming up to 80
DEG C, 8h is stirred with 200rpm rotating speed, that is, obtains marine glue product.
Comparative example 1
2,2,4,4,5,5- vegolysens are added without, the silane of 3- dioxy -2- rings penta, other conditions are the same as embodiment 1.
Comparative example 2
Lysine Sepharose gel is added without, other conditions are the same as embodiment 1.
Comparative example 3
Microcrystalline cellulose glue is added without, other conditions are the same as embodiment 1.
Embodiment 4
Embodiment 1-3 and comparative example 1-4 shear strength, adhesion strength, with ageing resistance are examined respectively.It is shown in Table 1.
Table 1：The shear strength for the marine glue product that different process is produced, adhesive strength, ageing resistance.
Claims (10)
1. a kind of preparation method of kitchen and bath's waterproof gasket cement, it is characterised in that comprise the following steps：Isophthalic is added in a kettle
Dioctyl phthalate polyester resin, acrylic acid 4- hydroxybutyls, polydimethylsiloxane, perfluorocyclohexyl methyl acrylate, 2,2,4,4,5,
5- vegolysens, the silane of 3- dioxy -2- rings penta, lysine Sepharose gel, microcrystalline cellulose glue, [4- (2- methyl -3- butylene -
2- yls) -1H- imidazoles -5- bases] methanol, 3- chloro- 5,6,7,8- tetrahydrochysenes and pyridine [3,4-C] pyridazine, IPD, heating
To 60-80 DEG C, 3-8h is stirred with 100-200rpm rotating speed, that is, obtains marine glue product.
A kind of 2. preparation method of kitchen and bath's waterproof gasket cement according to claim 1, it is characterised in that：Described acrylic acid
4- hydroxybutyls, its quality dosage are the 5-10% of isophthalic polyester resins.
A kind of 3. preparation method of kitchen and bath's waterproof gasket cement according to claim 1, it is characterised in that：Described poly- diformazan
Base silicone, its quality dosage are the 4-12% of isophthalic polyester resins.
A kind of 4. preparation method of kitchen and bath's waterproof gasket cement according to claim 1, it is characterised in that：Described perfluor ring
Hexyl methyl acrylate, its quality dosage are the 2-6% of isophthalic polyester resins.
A kind of 5. preparation method of kitchen and bath's waterproof gasket cement according to claim 1, it is characterised in that：Described 2,2,4,
4,5,5- vegolysens, the silane of 3- dioxy -2- rings penta, its quality dosage are the 0.5-1.5% of isophthalic polyester resins.
A kind of 6. preparation method of kitchen and bath's waterproof gasket cement according to claim 1, it is characterised in that：Described lysine
Ago-Gel, its quality dosage are the 1-2.5% of isophthalic polyester resins.
A kind of 7. preparation method of kitchen and bath's waterproof gasket cement according to claim 1, it is characterised in that：Described crystallite is fine
Plain glue is tieed up, its quality dosage is the 1.5-4% of isophthalic polyester resins.
A kind of 8. preparation method of kitchen and bath's waterproof gasket cement according to claim 1, it is characterised in that：Described [4- (2-
Methyl -3- butene-2s-yl) -1H- imidazoles -5- bases] methanol, its quality dosage is the 1-3% of isophthalic polyester resins.
A kind of 9. preparation method of kitchen and bath's waterproof gasket cement according to claim 1, it is characterised in that：Described 3- is chloro-
5,6,7,8- tetrahydrochysenes and pyridine [3,4-C] pyridazine, its quality dosage are the 0.1-1% of isophthalic polyester resins.
A kind of 10. preparation method of kitchen and bath's waterproof gasket cement according to claim 1, it is characterised in that：Described different Buddhist
That ketone diamines, its quality dosage are the 2-5% of isophthalic polyester resins.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711099933.0A CN107815255A (en) | 2017-11-09 | 2017-11-09 | A kind of preparation method of kitchen and bath's waterproof gasket cement |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711099933.0A CN107815255A (en) | 2017-11-09 | 2017-11-09 | A kind of preparation method of kitchen and bath's waterproof gasket cement |
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| Publication Number | Publication Date |
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| CN107815255A true CN107815255A (en) | 2018-03-20 |
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| CN201711099933.0A Pending CN107815255A (en) | 2017-11-09 | 2017-11-09 | A kind of preparation method of kitchen and bath's waterproof gasket cement |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112223466A (en) * | 2020-10-15 | 2021-01-15 | 东易日盛智能家居科技有限公司 | Method for treating plate without formaldehyde release |
| CN112459527A (en) * | 2020-12-03 | 2021-03-09 | 安徽墨砂工程修缮技术有限公司 | Brick-smashing-free toilet leakage repairing method |
| CN115746313A (en) * | 2022-11-10 | 2023-03-07 | 擎天材料科技有限公司 | Polyester resin, powder coating, and preparation method and application thereof |
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| CN103013416A (en) * | 2012-12-19 | 2013-04-03 | 苏州威仕科贸有限公司 | Light sensitive glass film binding agent |
| CN105111946A (en) * | 2015-08-10 | 2015-12-02 | 惠州市杜科新材料有限公司 | Liquid UV curing and sealing agent for replacing solid sealing ring of automobile oil tank cover and preparation method therefor |
| CN106752982A (en) * | 2016-12-11 | 2017-05-31 | 安徽兆利光电科技有限公司 | A kind of LED fluid sealant |
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2017
- 2017-11-09 CN CN201711099933.0A patent/CN107815255A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103013416A (en) * | 2012-12-19 | 2013-04-03 | 苏州威仕科贸有限公司 | Light sensitive glass film binding agent |
| CN105111946A (en) * | 2015-08-10 | 2015-12-02 | 惠州市杜科新材料有限公司 | Liquid UV curing and sealing agent for replacing solid sealing ring of automobile oil tank cover and preparation method therefor |
| CN106752982A (en) * | 2016-12-11 | 2017-05-31 | 安徽兆利光电科技有限公司 | A kind of LED fluid sealant |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112223466A (en) * | 2020-10-15 | 2021-01-15 | 东易日盛智能家居科技有限公司 | Method for treating plate without formaldehyde release |
| CN112459527A (en) * | 2020-12-03 | 2021-03-09 | 安徽墨砂工程修缮技术有限公司 | Brick-smashing-free toilet leakage repairing method |
| CN115746313A (en) * | 2022-11-10 | 2023-03-07 | 擎天材料科技有限公司 | Polyester resin, powder coating, and preparation method and application thereof |
| CN115746313B (en) * | 2022-11-10 | 2024-02-06 | 擎天材料科技有限公司 | Polyester resin, powder coating and preparation method and application thereof |
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Application publication date: 20180320 |
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