CN105017933A - Preparation method of antistatic paint - Google Patents
Preparation method of antistatic paint Download PDFInfo
- Publication number
- CN105017933A CN105017933A CN201510455248.1A CN201510455248A CN105017933A CN 105017933 A CN105017933 A CN 105017933A CN 201510455248 A CN201510455248 A CN 201510455248A CN 105017933 A CN105017933 A CN 105017933A
- Authority
- CN
- China
- Prior art keywords
- parts
- preparation
- antistatic paint
- potassium titanate
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003973 paint Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims abstract description 14
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003822 epoxy resin Substances 0.000 claims abstract description 6
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 6
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 15
- 239000013078 crystal Substances 0.000 claims description 13
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 6
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000004593 Epoxy Substances 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 4
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 3
- 239000013530 defoamer Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 5
- 239000000805 composite resin Substances 0.000 abstract description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 125000003700 epoxy group Chemical group 0.000 abstract 1
- 229920001225 polyester resin Polymers 0.000 abstract 1
- 239000004645 polyester resin Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 4
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a preparation method of an antistatic paint, and in particular relates to a composite resin type antistatic paint with excellent electric conductivity and corrosion resistance and a preparation method of the antistatic paint. The antistatic paint with excellent electric conductivity and corrosion resistance is obtained by combining composite resin of bisphenol A type epoxy resin, end epoxy group modified polyurethane resin and polyester resin with conductive potassium titanate whiskers and zinc oxide whiskers.
Description
Technical field
The present invention relates to a kind of preparation method of Antistatic Paint.
Background technology
Electrically conducting coating refers to and is applied on non-conductive substrates, makes it the coating of the ability having conduction current and get rid of stored charge, is called electrically conducting coating.Antistatic Paint is a kind of new coating developed rapidly for nearly ten years, but, although a lot of antistatic coating can reach certain preservative activity, but under the irradiation of sunlight or the wearing and tearing of external force, be difficult to reach rot-resistant object lastingly, in addition, due to coating industry, the problem of environmental protection is also a very important factor.Road sign, guideboard, billboard etc. are all placed on open air, and spray paint application and ordinary powder coating of its surface in the past employing is main, thus how long does not cross after spraying, be generally some months, just there will be variable color, efflorescence, burn into come off, constantly change, waste talent material resources.
Summary of the invention
The present invention is directed to the problems referred to above, provide a kind of composite resin type Antistatic Paint and the preparation method with superior electrical conductivity energy and corrosion resisting property.By using bisphenol A type epoxy resin, epoxy terminated modified polyurethane resin, the compound resin of vibrin and the combination of electroconductibility potassium titanate crystal whisker and ZnOw, obtain the Antistatic Paint with superior electrical conductivity energy and corrosion resisting property.
Object of the present invention is achieved by once technical scheme:
A preparation method for Antistatic Paint, comprises the steps:
A: with weight parts, gets bisphenol A type epoxy resin 10 parts, epoxy terminated modified polyurethane resin 10 parts, 10 parts, vibrin, thinner 5 parts, sheet mica 15 parts, and titanium dioxide 10 parts, is uniformly mixed 1 hour, obtains mixture A.
B: with weight parts, takes ethyl acetate 10 parts respectively, n-butyl acetate 10 parts, pimelinketone 5 parts, potassium titanate crystal whisker 15 parts, ZnOw 15 parts, adds successively in mixture A under whipped state, after all adding, continue stirring 1 hour, obtain mixture B.
C: with weight parts, takes 0.5 part, wear Protection wax respectively, dispersion agent EL-6425 0.5 part, defoamer EL-2706 0.5 part, and cobalt blue 15 parts adds in mixture B successively, abundant stir about 30-60 minute.
D: the mixture obtained by step c to add in three-roll grinder fully grinding 1 hour, and after through 400 object strainer filterings, obtain Antistatic Paint product.
The preparation method of described potassium titanate crystal whisker is: take K by certain molfraction
2cO
3, TiO
2, boric acid, water glass and silicon oxide, each raw material is added in ball grinder, adds agate ball, with rotating speed 500r/min, ball milling 2 hours, is then placed in crucible by the batch mixing after ball milling, crucible is put into resistance furnace, the mode of temperature programming is adopted to be warming up to 900 DEG C, be incubated 2 hours, be cooled to room temperature, pulverize, sieve, obtain potassium titanate crystal whisker.
The length of described potassium titanate crystal whisker is 10-30 μm.
The length of described ZnOw is 20-30 μm.
beneficial effect
Antistatic Paint of the present invention is on the basis of traditional electroconductive resin Antistatic Paint, by using the conductive resin compound of particular combination and the combination of bisphenol A type epoxy resin, epoxy terminated modified polyurethane resin and vibrin, in coating, also use the potassium titanate crystal whisker and ZnOw with superior electrical conductivity energy simultaneously, organic/inorganic electro-conductive material in coating is cooperatively interacted, and each raw material adopts specific proportioning, the coating obtained thus not only has excellent static electricity resistance, has good solidity to corrosion simultaneously.
Embodiment
Below in conjunction with concrete embodiment; Antistatic Paint of the present invention and preparation method thereof is described in detail; object is in order to the public better understands the technology contents of the present patent application; instead of the restriction to described technology contents; in fact; with identical or approximate principle; to the improvement that described Antistatic Paint and preparation and application thereof carry out; comprise increase and decrease and the replacement of each component in described Antistatic Paint; and the improvement of different technology conditions in its preparation and application, all within the present patent application technical scheme required for protection.
embodiment 1
The preparation of potassium titanate crystal whisker: take K by certain molfraction
2cO
3, TiO
2, boric acid, water glass and silicon oxide, each raw material is added in ball grinder, adds agate ball, with rotating speed 500r/min, ball milling 2 hours, is then placed in crucible by the batch mixing after ball milling, crucible is put into resistance furnace, the mode of temperature programming is adopted to be warming up to 900 DEG C, be incubated 2 hours, be cooled to room temperature, pulverize, sieve, obtain potassium titanate crystal whisker.
The preparation of Antistatic Paint: with weight parts, gets bisphenol A type epoxy resin 10 parts, epoxy terminated modified polyurethane resin 10 parts, 10 parts, vibrin, thinner 5 parts, sheet mica 15 parts, and titanium dioxide 10 parts, is uniformly mixed 1 hour, obtains mixture A; With weight parts, take ethyl acetate 10 parts respectively, n-butyl acetate 10 parts, pimelinketone 5 parts, length is the potassium titanate crystal whisker 15 parts of 10-30 μm, and length is the ZnOw 15 parts of 20-30 μm, add successively under whipped state in mixture A, after all adding, continue stirring 1 hour, obtain mixture B; With weight parts, take 0.5 part, wear Protection wax respectively, dispersion agent EL-6425 0.5 part, defoamer EL-2706 0.5 part, cobalt blue 15 parts, add in mixture B successively, abundant stir about 30-60 minute; The mixture obtained to be added in three-roll grinder fully grinding 1 hour, and after through 400 object strainer filterings, obtain Antistatic Paint product.
The technical indicator of the Antistatic Paint obtained by embodiment 1 is as follows:
Claims (3)
1. a preparation method for Antistatic Paint, is characterized in that, comprises the steps:
A: with weight parts, gets bisphenol A type epoxy resin 10 parts, epoxy terminated modified polyurethane resin 10 parts, 10 parts, vibrin, thinner 5 parts, sheet mica 15 parts, and titanium dioxide 10 parts etc., are uniformly mixed 1 hour, obtain mixture A;
B: with weight parts, takes ethyl acetate 10 parts respectively, n-butyl acetate 10 parts, pimelinketone 5 parts, potassium titanate crystal whisker 15 parts, ZnOw 15 parts, adds successively in mixture A under whipped state, after all adding, continue stirring 1 hour, obtain mixture B;
C: with weight parts, takes 0.5 part, wear Protection wax respectively, dispersion agent EL-6425 0.5 part, defoamer EL-2706 0.5 part, and cobalt blue 15 parts adds in mixture B successively, abundant stir about 30-60 minute;
D: the mixture obtained by step c to add in three-roll grinder fully grinding 1 hour, and after through 400 object strainer filterings, obtain Antistatic Paint product;
The preparation method of described potassium titanate crystal whisker is: take K by certain molfraction
2cO
3, TiO
2, boric acid, water glass and silicon oxide, each raw material is added in ball grinder, adds agate ball, with rotating speed 500r/min, ball milling 2 hours, is then placed in crucible by the batch mixing after ball milling, crucible is put into resistance furnace, the mode of temperature programming is adopted to be warming up to 900 DEG C, be incubated 2 hours, be cooled to room temperature, pulverize, sieve, obtain potassium titanate crystal whisker.
2. the preparation method of Antistatic Paint as claimed in claim 1, is characterized in that: the length of described potassium titanate crystal whisker is 10-30 μm.
3. the preparation method of Antistatic Paint as claimed in claim 1, is characterized in that: the length of described ZnOw is 20-30 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510455248.1A CN105017933B (en) | 2015-07-30 | 2015-07-30 | A kind of preparation method of anti-static coatings |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510455248.1A CN105017933B (en) | 2015-07-30 | 2015-07-30 | A kind of preparation method of anti-static coatings |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105017933A true CN105017933A (en) | 2015-11-04 |
| CN105017933B CN105017933B (en) | 2016-08-03 |
Family
ID=54408252
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510455248.1A Active CN105017933B (en) | 2015-07-30 | 2015-07-30 | A kind of preparation method of anti-static coatings |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105017933B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105315872A (en) * | 2015-11-30 | 2016-02-10 | 成都九十度工业产品设计有限公司 | Anti-static coating |
| CN106243915A (en) * | 2016-07-28 | 2016-12-21 | 苏州明轩地坪涂料有限公司 | A kind of anti-static coatings |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101358099A (en) * | 2008-09-09 | 2009-02-04 | 北京市射线应用研究中心 | Epoxy static conducting anti-corrosive paint |
| CN101906264B (en) * | 2010-08-13 | 2012-12-05 | 华南理工大学 | Insulating coil coating and preparation method thereof |
-
2015
- 2015-07-30 CN CN201510455248.1A patent/CN105017933B/en active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105315872A (en) * | 2015-11-30 | 2016-02-10 | 成都九十度工业产品设计有限公司 | Anti-static coating |
| CN106243915A (en) * | 2016-07-28 | 2016-12-21 | 苏州明轩地坪涂料有限公司 | A kind of anti-static coatings |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105017933B (en) | 2016-08-03 |
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Legal Events
| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Xu Xian Inventor before: Li Mengyan |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160623 Address after: 321081 Jinhua City, Wucheng City West Economic Development Zone, block No. 3 starting Road, No. Applicant after: ZHEJIANG SHENGLIBANG PAINT Co.,Ltd. Address before: 311813, No. 188, North Road, Jiyang street, Zhuji, Zhejiang, Shaoxing Applicant before: Li Mengyan |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Process for preparing static resistant coating Effective date of registration: 20180208 Granted publication date: 20160803 Pledgee: Bank of China Limited by Share Ltd. Development Zone Jinhua subbranch Pledgor: ZHEJIANG SHENGLIBANG PAINT Co.,Ltd. Registration number: 2018330000039 |
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| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230620 Granted publication date: 20160803 Pledgee: Bank of China Limited by Share Ltd. Development Zone Jinhua subbranch Pledgor: ZHEJIANG SHENGLIBANG PAINT Co.,Ltd. Registration number: 2018330000039 |
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| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method of anti-static coating Effective date of registration: 20230628 Granted publication date: 20160803 Pledgee: Bank of Jinhua Limited by Share Ltd. science and Technology Branch Pledgor: ZHEJIANG SHENGLIBANG PAINT Co.,Ltd. Registration number: Y2023980046281 |