CN104946089A - Preparation method for composite resin-type anti-static paint - Google Patents
Preparation method for composite resin-type anti-static paint Download PDFInfo
- Publication number
- CN104946089A CN104946089A CN201510454873.4A CN201510454873A CN104946089A CN 104946089 A CN104946089 A CN 104946089A CN 201510454873 A CN201510454873 A CN 201510454873A CN 104946089 A CN104946089 A CN 104946089A
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- CN
- China
- Prior art keywords
- parts
- preparation
- potassium titanate
- mixture
- crystal whisker
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- 239000003973 paint Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000002131 composite material Substances 0.000 title abstract 4
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 239000000805 composite resin Substances 0.000 claims abstract description 8
- 229920000123 polythiophene Polymers 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 15
- 239000013078 crystal Substances 0.000 claims description 13
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 10
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 6
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000003822 epoxy resin Substances 0.000 claims description 5
- 229920000647 polyepoxide Polymers 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 4
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 3
- 239000013530 defoamer Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000004841 bisphenol A epoxy resin Substances 0.000 abstract 1
- 229920001225 polyester resin Polymers 0.000 abstract 1
- 239000004645 polyester resin Substances 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention discloses a preparation method for composite resin-type anti-static paint, and particularly relates to the composite resin-type anti-static paint high in electrical conductivity and corrosion resistance as well as a preparation method. The composite resin-type anti-static paint high in electrical conductivity and corrosion resistance is prepared by combining composite resin with electro-conductive potassium titanate whiskers and zinc oxide whiskers, wherein the composite resin comprises bisphenol A epoxy resin, polythiophene resin and polyester resin.
Description
Technical field
The present invention relates to a kind of preparation method of composite resin type Antistatic Paint.
Background technology
Electrically conducting coating refers to and is applied on non-conductive substrates, makes it the coating of the ability having conduction current and get rid of stored charge, is called electrically conducting coating.Antistatic Paint is a kind of new coating developed rapidly for nearly ten years, but, although a lot of antistatic coating can reach certain preservative activity, but under the irradiation of sunlight or the wearing and tearing of external force, be difficult to reach rot-resistant object lastingly, in addition, due to coating industry, the problem of environmental protection is also a very important factor.Road sign, guideboard, billboard etc. are all placed on open air, and spray paint application and ordinary powder coating of its surface in the past employing is main, thus how long does not cross after spraying, be generally some months, just there will be variable color, efflorescence, burn into come off, constantly change, waste talent material resources.
Summary of the invention
The present invention is directed to the problems referred to above, provide a kind of composite resin type Antistatic Paint and the preparation method with superior electrical conductivity energy and corrosion resisting property.By using bisphenol A type epoxy resin, Polythiophene resin, the compound resin of vibrin and the combination of electroconductibility potassium titanate crystal whisker and ZnOw, obtain the Antistatic Paint with superior electrical conductivity energy and corrosion resisting property.
Object of the present invention is achieved by once technical scheme:
A preparation method for composite resin type Antistatic Paint, comprises the steps:
A: with weight parts, gets bisphenol A type epoxy resin 15 parts, Polythiophene resin 8 parts, 15 parts, vibrin, thinner 4 parts, sheet mica 10 parts, and titanium dioxide 8 parts, is uniformly mixed 1 hour, obtains mixture A.
B: with weight parts, takes ethyl acetate 10 parts respectively, n-butyl acetate 10 parts, pimelinketone 5 parts, potassium titanate crystal whisker 15 parts, ZnOw 15 parts, adds successively in mixture A under whipped state, after all adding, continue stirring 1 hour, obtain mixture B.
C: with weight parts, takes 0.5 part, wear Protection wax respectively, dispersion agent EL-6425 0.5 part, defoamer EL-2706 0.5 part, and cobalt blue 15 parts adds in mixture B successively, abundant stir about 30-60 minute.
D: the mixture obtained by step c to add in three-roll grinder fully grinding 1 hour, and after through 400 object strainer filterings, obtain Antistatic Paint product.
The preparation method of described potassium titanate crystal whisker is: take K by certain molfraction
2cO
3, TiO
2, boric acid, water glass and silicon oxide, each raw material is added in ball grinder, adds agate ball, with rotating speed 500r/min, ball milling 2 hours, is then placed in crucible by the batch mixing after ball milling, crucible is put into resistance furnace, the mode of temperature programming is adopted to be warming up to 900 DEG C, be incubated 2 hours, be cooled to room temperature, pulverize, sieve, obtain potassium titanate crystal whisker.
The length of described potassium titanate crystal whisker is 10-30 μm.
The length of described ZnOw is 20-30 μm.
beneficial effect
Antistatic Paint of the present invention is on the basis of traditional electroconductive resin Antistatic Paint, by using the conductive resin compound of particular combination and the combination of bisphenol A type epoxy resin, Polythiophene resin and vibrin, in coating, also use the potassium titanate crystal whisker and ZnOw with superior electrical conductivity energy simultaneously, organic/inorganic electro-conductive material in coating is cooperatively interacted, and each raw material adopts specific proportioning, the coating obtained thus not only has excellent static electricity resistance, has good solidity to corrosion simultaneously.
Embodiment
Below in conjunction with concrete embodiment, composite resin type Antistatic Paint of the present invention and preparation method thereof is described in detail, object is in order to the public better understands the technology contents of the present patent application, instead of the restriction to described technology contents, in fact, with identical or approximate principle, to the improvement that described Antistatic Paint and preparation and application thereof carry out, comprise increase and decrease and the replacement of each component in described Antistatic Paint, and the improvement of different technology conditions in its preparation and application, all within the present patent application technical scheme required for protection.
embodiment 1
The preparation of potassium titanate crystal whisker: take K by certain molfraction
2cO
3, TiO
2, boric acid, water glass and silicon oxide, each raw material is added in ball grinder, adds agate ball, with rotating speed 500r/min, ball milling 2 hours, is then placed in crucible by the batch mixing after ball milling, crucible is put into resistance furnace, the mode of temperature programming is adopted to be warming up to 900 DEG C, be incubated 2 hours, be cooled to room temperature, pulverize, sieve, obtain potassium titanate crystal whisker.
The preparation of Antistatic Paint: with weight parts, gets bisphenol A type epoxy resin 15 parts, Polythiophene resin 8 parts, 15 parts, vibrin, thinner 4 parts, sheet mica 10 parts, and titanium dioxide 8 parts, is uniformly mixed 1 hour, obtains mixture A; ; With weight parts, take ethyl acetate 10 parts respectively, n-butyl acetate 10 parts, pimelinketone 5 parts, length is the potassium titanate crystal whisker 15 parts of 10-30 μm, and length is the ZnOw 15 parts of 20-30 μm, add successively under whipped state in mixture A, after all adding, continue stirring 1 hour, obtain mixture B; With weight parts, take 0.5 part, wear Protection wax respectively, dispersion agent EL-6425 0.5 part, defoamer EL-2706 0.5 part, cobalt blue 15 parts, add in mixture B successively, abundant stir about 30-60 minute; The mixture obtained to be added in three-roll grinder fully grinding 1 hour, and after through 400 object strainer filterings, obtain Antistatic Paint product.
The technical indicator of the Antistatic Paint obtained by embodiment 1 is as follows:
Claims (3)
1. a preparation method for composite resin type Antistatic Paint, is characterized in that, comprises the steps:
A: with weight parts, gets bisphenol A type epoxy resin 15 parts, Polythiophene resin 8 parts, 15 parts, vibrin, thinner 4 parts, sheet mica 10 parts, and titanium dioxide 8 parts etc., are uniformly mixed 1 hour, obtain mixture A;
B: with weight parts, takes ethyl acetate 10 parts respectively, n-butyl acetate 10 parts, pimelinketone 5 parts, potassium titanate crystal whisker 15 parts, ZnOw 15 parts, adds successively in mixture A under whipped state, after all adding, continue stirring 1 hour, obtain mixture B;
C: with weight parts, takes 0.5 part, wear Protection wax respectively, dispersion agent EL-6425 0.5 part, defoamer EL-2706 0.5 part, and cobalt blue 15 parts adds in mixture B successively, abundant stir about 30-60 minute;
D: the mixture obtained by step c to add in three-roll grinder fully grinding 1 hour, and after through 400 object strainer filterings, obtain Antistatic Paint product;
The preparation method of described potassium titanate crystal whisker is: take K by certain molfraction
2cO
3, TiO
2, boric acid, water glass and silicon oxide, each raw material is added in ball grinder, adds agate ball, with rotating speed 500r/min, ball milling 2 hours, is then placed in crucible by the batch mixing after ball milling, crucible is put into resistance furnace, the mode of temperature programming is adopted to be warming up to 900 DEG C, be incubated 2 hours, be cooled to room temperature, pulverize, sieve, obtain potassium titanate crystal whisker.
2. the preparation method of Antistatic Paint as claimed in claim 1, is characterized in that: the length of described potassium titanate crystal whisker is 10-30 μm.
3. the preparation method of Antistatic Paint as claimed in claim 1, is characterized in that: the length of described ZnOw is 20-30 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510454873.4A CN104946089B (en) | 2015-07-30 | 2015-07-30 | A kind of preparation method of composite resin type anti-static coatings |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510454873.4A CN104946089B (en) | 2015-07-30 | 2015-07-30 | A kind of preparation method of composite resin type anti-static coatings |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104946089A true CN104946089A (en) | 2015-09-30 |
| CN104946089B CN104946089B (en) | 2018-05-04 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510454873.4A Active CN104946089B (en) | 2015-07-30 | 2015-07-30 | A kind of preparation method of composite resin type anti-static coatings |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104946089B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105176359A (en) * | 2015-10-29 | 2015-12-23 | 刘广利 | Environment-friendly antistatic anti-corrosion paint and preparation method thereof |
| CN108290383A (en) * | 2015-11-26 | 2018-07-17 | 新日铁住金株式会社 | Coated metal plate |
| CN112226142A (en) * | 2020-10-22 | 2021-01-15 | 湖北博宇粉末科技有限公司 | Weather-resistant powder coating |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101144186A (en) * | 2006-09-12 | 2008-03-19 | 上海秀普复合材料有限公司 | Method for synthesizing potassium hexatitanate crystal whisker |
| CN101993647A (en) * | 2009-08-20 | 2011-03-30 | 杨紫萱 | Heat-resistant antistatic coating |
| CN102876102A (en) * | 2012-04-30 | 2013-01-16 | 长兴化学工业股份有限公司 | Conductive Coating Composition |
| CN104212241A (en) * | 2014-09-01 | 2014-12-17 | 江苏格美高科技发展有限公司 | High-thermal-conductivity polymer conductive ink and production process thereof |
-
2015
- 2015-07-30 CN CN201510454873.4A patent/CN104946089B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101144186A (en) * | 2006-09-12 | 2008-03-19 | 上海秀普复合材料有限公司 | Method for synthesizing potassium hexatitanate crystal whisker |
| CN101993647A (en) * | 2009-08-20 | 2011-03-30 | 杨紫萱 | Heat-resistant antistatic coating |
| CN102876102A (en) * | 2012-04-30 | 2013-01-16 | 长兴化学工业股份有限公司 | Conductive Coating Composition |
| CN104212241A (en) * | 2014-09-01 | 2014-12-17 | 江苏格美高科技发展有限公司 | High-thermal-conductivity polymer conductive ink and production process thereof |
Non-Patent Citations (2)
| Title |
|---|
| 天津化工研究设计院: "《无机精细化学品手册》", 31 January 2001 * |
| 孙秋菊: "《无机晶须填充改性聚合物的应用》", 31 December 2012 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105176359A (en) * | 2015-10-29 | 2015-12-23 | 刘广利 | Environment-friendly antistatic anti-corrosion paint and preparation method thereof |
| CN108290383A (en) * | 2015-11-26 | 2018-07-17 | 新日铁住金株式会社 | Coated metal plate |
| CN108290383B (en) * | 2015-11-26 | 2020-05-05 | 日本制铁株式会社 | Coated metal sheet |
| CN112226142A (en) * | 2020-10-22 | 2021-01-15 | 湖北博宇粉末科技有限公司 | Weather-resistant powder coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104946089B (en) | 2018-05-04 |
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| CB03 | Change of inventor or designer information |
Inventor after: Liu Zhanchuan Inventor after: Mei Shaofeng Inventor after: Dong Lizhi Inventor after: Hu Zhongyuan Inventor after: Liu Cun Inventor before: Li Mengyan |
|
| CB03 | Change of inventor or designer information | ||
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| TA01 | Transfer of patent application right |
Effective date of registration: 20180125 Address after: 071000 Hebei city of Baoding province Xushui Chenyang Street No. 1 Applicant after: HEBEI CHENYANG INDUSTRY&TRADE Group Ltd. Address before: 311813, No. 188, North Road, Jiyang street, Zhuji, Zhejiang, Shaoxing Applicant before: Li Mengyan |
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Effective date of registration: 20200929 Granted publication date: 20180504 |
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| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20150930 Assignee: Chenyang Environmental Protection New Material Co.,Ltd. Assignor: HEBEI CHENYANG INDUSTRY&TRADE Group Ltd. Contract record no.: X2023980033290 Denomination of invention: Preparation method of a composite resin type antistatic coating Granted publication date: 20180504 License type: Common License Record date: 20230303 |
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