CN106316208A - Novel concrete modifying agent and concrete thereof - Google Patents

Novel concrete modifying agent and concrete thereof Download PDF

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Publication number
CN106316208A
CN106316208A CN201610702293.7A CN201610702293A CN106316208A CN 106316208 A CN106316208 A CN 106316208A CN 201610702293 A CN201610702293 A CN 201610702293A CN 106316208 A CN106316208 A CN 106316208A
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CN
China
Prior art keywords
parts
concrete
modifying agent
agent
bentonite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610702293.7A
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Chinese (zh)
Inventor
陆应生
王君
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUILIN XINYI REFRIGERATION EQUIPMENT Co Ltd
Original Assignee
GUILIN XINYI REFRIGERATION EQUIPMENT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUILIN XINYI REFRIGERATION EQUIPMENT Co Ltd filed Critical GUILIN XINYI REFRIGERATION EQUIPMENT Co Ltd
Priority to CN201610702293.7A priority Critical patent/CN106316208A/en
Publication of CN106316208A publication Critical patent/CN106316208A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/90Electrical properties
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Sealing Material Composition (AREA)

Abstract

The invention discloses a novel concrete modifying agent and concrete thereof, and belongs to the technical field of concrete. The concrete modifying agent is prepared from the following raw materials in parts by weight: 6-10 parts of bentonite, 3-5 parts of organosilicon waterproofing agent, 3-5 parts of water reducing agent, 4-10 parts of dimethyl siloxane, 4-10 parts of 4-p-pheynylphenol, 4-8 parts of polyamide epoxy chloropropane resin, 4-8 parts of 4-tert-butyl phenol, 6-10 parts of sodium tripolyphosphate, 3-5 parts of zinc sulfate, 6-8 parts of sodium borate and 4-8 parts of acetyl tridioctyl citrate. The novel concrete modifying agent disclosed by the invention is capable of improving the toughness, the compressive strength and the service life of the concrete; the concrete made of the novel concrete modifying agent is good in tensile property, fracture resistance and anti-cracking ability; the modifying agent is low in cost, simple in production process, low in cost and suitable for large-scale production.

Description

A kind of new concrete modifying agent and concrete thereof
Technical field
The present invention relates to a kind of new concrete modifying agent and concrete thereof, belong to technical field of concrete.
Background technology
Concrete, referred to as " concrete ", it is common that referring to make Binder Materials with cement, sand, masonry gather materials, with water by a certain percentage Coordinate, agitated gained.Concrete has abundant raw material, cheap, the simple feature of production technology so that it is range ten Divide extensively, not only use in various civil engineerings, it is simply that shipbuilding industry, mechanical industry, the exploitation of ocean, geothermal engineering etc., mixed Solidifying soil is also important material.
During concrete is applied in Practical Project, it is commonly exposed to the harshest various environment, as environment is corroded Property medium intrusion, the change of ambient temperature and humidity, freeze-thaw cycle destroy and part concrete works often in heavy load grind Damaging, these external conditions will have a strong impact on the service life of concrete.Accordingly, it would be desirable to add protective agent pair in concrete Concrete carries out protective effect, and existing concrete modifying agent exists function singleness, the technology poor to the maintenance effect of concrete Not enough.
Summary of the invention
It is an object of the invention to make up the deficiencies in the prior art, it is provided that a kind of new concrete modifying agent and concrete thereof. The new concrete modifying agent of the present invention can improve the toughness of concrete, comprcssive strength and service life, and the employing present invention's is new The concrete that type concrete modifying agent is made, tension, anti-folding, cracking resistance are good.
The technical scheme is that a kind of new concrete modifying agent, by following weight The raw material of number is made: bentonite 6~10 parts, waterproofing agent of organosilicon 3~5 parts, water reducer 3~5 parts, dimethyl siloxane 4~ 10 parts, 4-4-hydroxydiphenyl 4~10 parts, polyamine epichlorohydrin resin 4~8 parts, 4-tertiary butyl phenol 4~8 parts, sodium tripolyphosphate 6~10 parts, zinc sulfate 3~5 parts, sodium borate 6~8 parts and ATOC 4~8 parts.
On the basis of technique scheme, the present invention can also do following improvement.
Further, be made up of the raw material of following parts by weight: bentonite 8 parts, waterproofing agent of organosilicon 4 parts, water reducer 4 parts, Dimethyl siloxane 7 parts, 4-4-hydroxydiphenyl 7 parts, polyamine epichlorohydrin resin 6 parts, 4-tertiary butyl phenol 6 parts, tripolyphosphate 8 parts of sodium, 4 parts of zinc sulfate, sodium borate 7 parts and ATOC 6 parts.
Further, described bentonite is sodium bentonite.
Further, described waterproofing agent of organosilicon is octyltri-ethoxysilane with poly-MTES by weight It it is the mixture of 4: 1 compositions.
Further, described water reducer is ferroso-ferric oxide, dihydric phosphate, dibasic alkaliine, tartaric acid, amino trimethylene first One or more in base phosphoric acid.
A kind of concrete, comprises concrete modifying agent as above.
On the basis of technique scheme, the present invention can also do following improvement.
Further, the quality of described concrete modifying agent is the 4~8wt% of concrete quality.
The invention has the beneficial effects as follows:
(1) the new concrete modifying agent of the present invention, can improve the toughness of concrete, comprcssive strength and service life.
(2) the concrete tension that the new concrete modifying agent of the employing present invention is made, anti-folding, cracking resistance are good.
(3) cheap, the production technology of the present invention is simple, low cost, is suitable for large-scale production.
Detailed description of the invention
Being described principle and the feature of the present invention below in conjunction with specific embodiment, example is served only for explaining this Bright, it is not intended to limit the scope of the present invention.
Embodiment 1:
A kind of new concrete modifying agent, is made up of the raw material of following parts by weight: bentonite 6 parts, waterproofing agent of organosilicon 5 Part, water reducer 3 parts, dimethyl siloxane 10 parts, 4-4-hydroxydiphenyl 4 parts, polyamine epichlorohydrin resin 8 parts, the tertiary fourth of 4- 4 parts of phenol, sodium tripolyphosphate 10 parts, 3 parts of zinc sulfate, sodium borate 8 parts and ATOC 4 parts, wherein, described bentonite For sodium bentonite, described waterproofing agent of organosilicon is that octyltri-ethoxysilane is by weight with poly-MTES The mixture of 4: 1 compositions, described water reducer is ferroso-ferric oxide.
A kind of concrete, comprises concrete modifying agent as above.
The quality of described concrete modifying agent is the 4wt% of concrete quality.
Utilize concrete resistivity analyzer that the concrete obtained in embodiment 1 is tested, obtain its dampness Lower resistivity is 0.46 Ω m, and under drying regime, resistivity is 1.62 Ω m.
According to GB/T19856.1, the concrete obtained in embodiment 1 is tested, obtain its dash current tolerance Δ R%=2.7%.
Carry out the resistance to tested person of power current to embodiment 2 obtains concrete, obtain its power current tolerance Δ R%= 10.8%.
Utilize TYE-20 agent on crack resistance of concrete folding compression testing machine that the concrete obtained in embodiment 2 is tested, obtain it Rupture strength is 8.2MPa, and comprcssive strength is 41.5MPa.
Embodiment 2:
A kind of new concrete modifying agent, is made up of the raw material of following parts by weight: bentonite 8 parts, waterproofing agent of organosilicon 4 Part, water reducer 4 parts, dimethyl siloxane 7 parts, 4-4-hydroxydiphenyl 7 parts, polyamine epichlorohydrin resin 6 parts, 4-tertiary butyl phenol 6 parts, sodium tripolyphosphate 8 parts, 4 parts of zinc sulfate, sodium borate 7 parts and ATOC 6 parts, wherein, described bentonite is Sodium bentonite, described waterproofing agent of organosilicon is octyltri-ethoxysilane and poly-MTES is 4 by weight: The mixture of 1 composition, described water reducer is the mixture of dihydric phosphate and dibasic alkaliine, is respectively 2 parts.
A kind of concrete, comprises concrete modifying agent as above.
The quality of described concrete modifying agent is the 6wt% of concrete quality.
Utilize concrete resistivity analyzer that the concrete obtained in embodiment 2 is tested, obtain its dampness Lower resistivity is 0.52 Ω m, and under drying regime, resistivity is 1.64 Ω m.
According to GB/T19856.1, the concrete obtained in embodiment 2 is tested, obtain its dash current tolerance Δ R%=2.7%.
Carry out the resistance to tested person of power current to embodiment 2 obtains concrete, obtain its power current tolerance Δ R%= 11.1%.
Utilize TYE-20 agent on crack resistance of concrete folding compression testing machine that the concrete obtained in embodiment 2 is tested, obtain it Rupture strength is 8.4MPa, and comprcssive strength is 43.5MPa.
Embodiment 3:
A kind of new concrete modifying agent, is made up of the raw material of following parts by weight: bentonite 10 parts, waterproofing agent of organosilicon 3 parts, water reducer 5 parts, dimethyl siloxane 4 parts, 4-4-hydroxydiphenyl 10 parts, polyamine epichlorohydrin resin 4 parts, the tertiary fourth of 4- 8 parts of phenol, sodium tripolyphosphate 6 parts, 5 parts of zinc sulfate, sodium borate 6 parts and ATOC 8 parts, wherein, described bentonite For sodium bentonite, described waterproofing agent of organosilicon is that octyltri-ethoxysilane is by weight with poly-MTES The mixture of 4: 1 compositions, described water reducer be dihydric phosphate, dibasic alkaliine, tartaric acid, aminotrimethylene phosphoric acid mixed Compound, is respectively 1 part.
A kind of concrete, comprises concrete modifying agent as above.
The quality of described concrete modifying agent is the 8wt% of concrete quality.
Utilize concrete resistivity analyzer that the concrete obtained in embodiment 3 is tested, obtain its dampness Lower resistivity is 0.49 Ω m, and under drying regime, resistivity is 1.58 Ω m.
According to GB/T19856.1, the concrete obtained in embodiment 3 is tested, obtain its dash current tolerance Δ R%=2.5%.
Carry out the resistance to tested person of power current to embodiment 2 obtains concrete, obtain its power current tolerance Δ R%= 10.8%.
Utilize TYE-20 agent on crack resistance of concrete folding compression testing machine that the concrete obtained in embodiment 3 is tested, obtain it Rupture strength is 8.2MPa, and comprcssive strength is 41.8MPa.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and Within principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.

Claims (7)

1. a new concrete modifying agent, it is characterised in that be made up of the raw material of following parts by weight: bentonite 6~10 parts, Waterproofing agent of organosilicon 3~5 parts, water reducer 3~5 parts, dimethyl siloxane 4~10 parts, 4-4-hydroxydiphenyl 4~10 parts, polyamides Amine epichlorohydrin resin 4~8 parts, 4-tertiary butyl phenol 4~8 parts, sodium tripolyphosphate 6~10 parts, zinc sulfate 3~5 parts, sodium borate 6 ~8 parts and ATOC 4~8 parts.
A kind of new concrete modifying agent the most according to claim 1, it is characterised in that by the raw material of following parts by weight Make: bentonite 8 parts, waterproofing agent of organosilicon 4 parts, water reducer 4 parts, dimethyl siloxane 7 parts, 4-4-hydroxydiphenyl 7 parts, polyamides Amine epichlorohydrin resin 6 parts, 4-tertiary butyl phenol 6 parts, sodium tripolyphosphate 8 parts, 4 parts of zinc sulfate, sodium borate 7 parts and acetyl tributyl citrate Three monooctyl esters 6 parts.
A kind of new concrete modifying agent the most according to claim 1 and 2, it is characterised in that described bentonite is sodio Bentonite.
A kind of new concrete modifying agent the most according to claim 1 and 2, it is characterised in that described waterproofing agent of organosilicon It is the mixture of 4: 1 compositions by weight for octyltri-ethoxysilane and poly-MTES.
A kind of new concrete modifying agent the most according to claim 1 and 2, it is characterised in that described water reducer is four oxygen Change one or more in three-iron, dihydric phosphate, dibasic alkaliine, tartaric acid, aminotrimethylene phosphoric acid.
6. a concrete, it is characterised in that comprise the concrete modifying agent described in claim 1-5 any one.
Concrete the most according to claim 6, it is characterised in that the quality of described concrete modifying agent is concrete quality 4~8wt%.
CN201610702293.7A 2016-08-22 2016-08-22 Novel concrete modifying agent and concrete thereof Pending CN106316208A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107973543A (en) * 2017-11-27 2018-05-01 陈啟文 A kind of concrete modifying agent and its concrete
CN108947320A (en) * 2018-08-10 2018-12-07 徐州和合新型建材有限公司 A kind of concrete additive and preparation method

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101172803A (en) * 2007-10-26 2008-05-07 北京工业大学 Composite additive improving self-contraction of concrete
CN103601395A (en) * 2013-10-20 2014-02-26 青岛海伴诚远塑业有限公司 Concrete modifier
CN103626420A (en) * 2013-11-04 2014-03-12 青岛汇而通商贸有限公司 Anti-crack modifier for concrete
CN103641378A (en) * 2013-11-04 2014-03-19 青岛汇而通商贸有限公司 Concrete waterproof modifier
CN103641376A (en) * 2013-11-04 2014-03-19 青岛汇而通商贸有限公司 Concrete crack resistance modifier
CN105174800A (en) * 2015-09-11 2015-12-23 王嘉文 Novel concrete modifier and concrete thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101172803A (en) * 2007-10-26 2008-05-07 北京工业大学 Composite additive improving self-contraction of concrete
CN103601395A (en) * 2013-10-20 2014-02-26 青岛海伴诚远塑业有限公司 Concrete modifier
CN103626420A (en) * 2013-11-04 2014-03-12 青岛汇而通商贸有限公司 Anti-crack modifier for concrete
CN103641378A (en) * 2013-11-04 2014-03-19 青岛汇而通商贸有限公司 Concrete waterproof modifier
CN103641376A (en) * 2013-11-04 2014-03-19 青岛汇而通商贸有限公司 Concrete crack resistance modifier
CN105174800A (en) * 2015-09-11 2015-12-23 王嘉文 Novel concrete modifier and concrete thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107973543A (en) * 2017-11-27 2018-05-01 陈啟文 A kind of concrete modifying agent and its concrete
CN108947320A (en) * 2018-08-10 2018-12-07 徐州和合新型建材有限公司 A kind of concrete additive and preparation method

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