CN103360652B - A kind of uvioresistant cable jacket material and preparation method thereof - Google Patents
A kind of uvioresistant cable jacket material and preparation method thereof Download PDFInfo
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- CN103360652B CN103360652B CN201310253371.6A CN201310253371A CN103360652B CN 103360652 B CN103360652 B CN 103360652B CN 201310253371 A CN201310253371 A CN 201310253371A CN 103360652 B CN103360652 B CN 103360652B
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- 239000000463 material Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- -1 polypropylene Polymers 0.000 claims abstract description 24
- 239000000843 powder Substances 0.000 claims abstract description 21
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 8
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 claims abstract description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004593 Epoxy Substances 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004743 Polypropylene Substances 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229940037003 alum Drugs 0.000 claims abstract description 7
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 7
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 7
- 239000011651 chromium Substances 0.000 claims abstract description 7
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000428 dust Substances 0.000 claims abstract description 7
- 239000010433 feldspar Substances 0.000 claims abstract description 7
- 239000011521 glass Substances 0.000 claims abstract description 7
- 239000010445 mica Substances 0.000 claims abstract description 7
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 7
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 claims abstract description 7
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001155 polypropylene Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 230000036571 hydration Effects 0.000 claims abstract description 4
- 238000006703 hydration reaction Methods 0.000 claims abstract description 4
- 102220040412 rs587778307 Human genes 0.000 claims abstract description 4
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 4
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 3
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 3
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 230000000630 rising effect Effects 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 5
- 230000032683 aging Effects 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- 238000002485 combustion reaction Methods 0.000 abstract description 3
- 239000003921 oil Substances 0.000 description 3
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
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Abstract
The invention discloses a kind of uvioresistant cable jacket material, it is characterized in that what it was made up of the raw material of following weight parts: neoprene M-40? 100-110, polypropylene T30S? 12-15, nano diatomite 8-10, feldspar powder 10-15, glass dust 5-7, mica powder 20-25, dolomol 5-6, phthalic acid ester 4-5, epoxy tetrahydro-2-ethylhexyl phthalate 3-4, alum powder 1-3, hydration zinc borate 2-3, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane 1-2, diisopropyl sodium naphthalene sulfonate 1-2, aluminium isopropoxide 0.3-0.6, chromium boride 1-2, irgasfos 168? 1-2, absolute ethyl alcohol 3-4, ultra-violet absorber UV-9? 0.2-0.3, Imarcaptoacetate dioctyltin 0.8-1, three ammonium molybdate 0.8-1, vulcanizing agent DCBP0.6-1. the cable jacket material that the present invention produces has good physical and mechanical properties, oil resistant, heat-resisting, resistance to combustion, resistance to daylight, resistance to ozone, ageing-resistant, acid and alkali-resistance, anti-ultraviolet property excellence, by add particle of the present invention in preparation, strengthen the compatibility of each stock yard, further strengthened tearing toughness, tensile strength.
Description
Technical field
The present invention relates generally to a kind of protective cover material, relates in particular to a kind of uvioresistant cable jacket material and preparation method thereof.
Background technology
The combination property of neoprene is good, natural rubber and other synthetic rubber are all incomparable in a lot of performances, there is good physical and mechanical properties, oil resistant, heat-resisting, resistance to combustion, resistance to daylight, resistance to ozone, ageing-resistant, acid and alkali-resistance, chemical-resistant reagent, therefore be used as widely cable jacket material, and CABLE MATERIALS is higher for the requirement of performance, want to accept to be for a long time exposed to the sun, wind and rain, high temperature, low cold etc., corrosion-resistant for it, the performance requirement of the each side such as fire-retardant is all higher, therefore need a kind of new method to improve and strengthen the overall performance of neoprene, development for cable cause is necessary.
Summary of the invention
The object of the invention is just to provide a kind of uvioresistant cable jacket material and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of uvioresistant cable jacket material, it is made up of the raw material of following weight parts
Neoprene M-40100-110, polypropylene T30S12-15, nano diatomite 8-10, feldspar powder 10-15, glass dust 5-7, mica powder 20-25, dolomol 5-6, phthalic acid ester 4-5, epoxy tetrahydro-2-ethylhexyl phthalate 3-4, alum powder 1-3, hydration zinc borate 2-3, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane 1-2, diisopropyl sodium naphthalene sulfonate 1-2, aluminium isopropoxide 0.3-0.6, chromium boride 1-2, irgasfos 168 1-2, absolute ethyl alcohol 3-4, ultra-violet absorber UV-90.2-0.3, Imarcaptoacetate dioctyltin 0.8-1, three ammonium molybdate 0.8-1, vulcanizing agent DCBP0.6-1.
A preparation method for uvioresistant cable jacket material, comprises the following steps:
Above-mentioned aluminium isopropoxide is mixed with absolute ethyl alcohol, under normal temperature, fully stir, add nano diatomite, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane, at 60-70 DEG C, constant temperature stirs 20-30 minute, add alum powder, chromium boride, three ammonium molybdates, rising temperature, to 80-90 DEG C, is incubated 1-2 hour, be cooled to normal temperature, add diisopropyl sodium naphthalene sulfonate, 700-900 rev/min is disperseed 10-13 minute, ball milling post-drying, sieve, obtain the particle of 2-3 μ m; Above-mentioned neoprene M-40 and polypropylene T30S, dolomol, phthalic acid ester, epoxy tetrahydro-2-ethylhexyl phthalate are mixed to join in banbury, mixing 2-4 minute at 82-90 DEG C, add again particle obtained above and feldspar powder, glass dust, mica powder, irgasfos 168, ultra-violet absorber UV-9, Imarcaptoacetate dioctyltin, be at 85-90 DEG C in temperature, mixing 4-5 minute; Adding the each raw material of residue, is mixing 2-3 minute at 55-60 DEG C in temperature again, and discharging is cooling obtains described uvioresistant cable jacket material.
Advantage of the present invention is:
The cable jacket material that the present invention produces has good physical and mechanical properties, oil resistant, heat-resisting, resistance to combustion, resistance to daylight, resistance to ozone, ageing-resistant, acid and alkali-resistance, anti-ultraviolet property excellence, by add particle of the present invention in preparation, strengthen the compatibility of each stock yard, further strengthened tearing toughness, tensile strength.
Detailed description of the invention
Embodiment 1
A kind of uvioresistant cable jacket material, it by following weight parts (kilogram) raw material form
Neoprene M-40110, polypropylene T30S15, nano diatomite 8, feldspar powder 15, glass dust 5, mica powder 25, dolomol 6, phthalic acid ester 5, epoxy tetrahydro-2-ethylhexyl phthalate 4, alum powder 3, hydration zinc borate 3, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane 2, diisopropyl sodium naphthalene sulfonate 2, aluminium isopropoxide 0.6, chromium boride 1, irgasfos 168 1, absolute ethyl alcohol 4, ultra-violet absorber UV-90.3, Imarcaptoacetate dioctyltin 0.8, three ammonium molybdates 0.8, vulcanizing agent DCBP0.6.
A preparation method for uvioresistant cable jacket material, comprises the following steps:
Above-mentioned aluminium isopropoxide is mixed with absolute ethyl alcohol, under normal temperature, fully stir, add nano diatomite, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane, at 70 DEG C, constant temperature stirs 30 minutes, add alum powder, chromium boride, three ammonium molybdates, rising temperature to 90 DEG C, is incubated 2 hours, be cooled to normal temperature, add diisopropyl sodium naphthalene sulfonate, 900 revs/min are disperseed 13 minutes, ball milling post-drying, sieve, obtain the particle of 3 μ m; Above-mentioned neoprene M-40 and polypropylene T30S, dolomol, phthalic acid ester, epoxy tetrahydro-2-ethylhexyl phthalate are mixed to join in banbury, at 90 DEG C mixing 4 minutes, add again particle obtained above and feldspar powder, glass dust, mica powder, irgasfos 168, ultra-violet absorber UV-9, Imarcaptoacetate dioctyltin, be at 90 DEG C in temperature, mixing 4 minutes; Adding the each raw material of residue, is at 60 DEG C mixing 2 minutes in temperature again, and discharging is cooling obtains described uvioresistant cable jacket material.
Performance test:
Hot strength: 17.0MPa;
Elongation at break: 707%;
Oil resistivity: 100 DEG C × 75h of 20# machine oil, elongation at break conservation rate 72.7%, tensile strength conservation rate 77.9%;
Resistance to ozone: 25 DEG C, 25h, ozone concentration 0.024%, without cracking;
Ageing-resistant: 120 DEG C, 200h, tensile strength conservation rate 89.2%, elongation at break conservation rate 79.1%.
Claims (2)
1. a uvioresistant cable jacket material, it is characterized in that what it was made up of the raw material of following weight parts: neoprene M-40100-110, polypropylene T30S12-15, nano diatomite 8-10, feldspar powder 10-15, glass dust 5-7, mica powder 20-25, dolomol 5-6, phthalic acid ester 4-5, 4, 5-epoxy tetrahydro-2-ethylhexyl phthalate 3-4, alum powder 1-3, hydration zinc borate 2-3, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane 1-2, diisopropyl sodium naphthalene sulfonate 1-2, aluminium isopropoxide 0.3-0.6, chromium boride 1-2, irgasfos 168 1-2, absolute ethyl alcohol 3-4, ultra-violet absorber UV-90.2-0.3, Imarcaptoacetate dioctyltin 0.8-1, three ammonium molybdate 0.8-1, vulcanizing agent DCBP0.6-1.
2. the preparation method of a uvioresistant cable jacket material as claimed in claim 1, it is characterized in that comprising the following steps: above-mentioned aluminium isopropoxide is mixed with absolute ethyl alcohol, under normal temperature, fully stir, add nano diatomite, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane, at 60-70 DEG C, constant temperature stirs 20-30 minute, add alum powder, chromium boride, three ammonium molybdates, rising temperature is to 80-90 DEG C, insulation 1-2 hour, be cooled to normal temperature, add diisopropyl sodium naphthalene sulfonate, 700-900 rev/min is disperseed 10-13 minute, ball milling post-drying, sieve, obtain the particle of 2-3 μ m, by above-mentioned neoprene M-40 and polypropylene T30S, dolomol, phthalic acid ester, 4,5-epoxy tetrahydro-2-ethylhexyl phthalate is mixed to join in banbury, mixing 2-4 minute at 82-90 DEG C, add again particle obtained above and feldspar powder, glass dust, mica powder, irgasfos 168, ultra-violet absorber UV-9, Imarcaptoacetate dioctyltin, be at 85-90 DEG C in temperature, mixing 4-5 minute, adding the each raw material of residue, is mixing 2-3 minute at 55-60 DEG C in temperature again, and discharging is cooling obtains described uvioresistant cable jacket material.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310253371.6A CN103360652B (en) | 2013-06-21 | 2013-06-21 | A kind of uvioresistant cable jacket material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310253371.6A CN103360652B (en) | 2013-06-21 | 2013-06-21 | A kind of uvioresistant cable jacket material and preparation method thereof |
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| CN103360652A CN103360652A (en) | 2013-10-23 |
| CN103360652B true CN103360652B (en) | 2016-05-04 |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104140650B (en) * | 2014-07-17 | 2016-01-20 | 滁州优胜高分子材料有限公司 | A kind of fiber optic ribbon cable cable PBT material |
| CN104774378A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Stable polypropylene composite material for household electric appliances |
| JP2017066183A (en) * | 2015-09-28 | 2017-04-06 | 日立金属株式会社 | Chloroprene rubber composition and manufacturing method therefor, wire and cable and manufacturing method therefor, crosslinking method and storing method of chloroprene rubber composition |
| CN105504389A (en) * | 2016-01-29 | 2016-04-20 | 宁波远欣石化有限公司 | Environmental-friendly alumina sol modified rubber material and preparation method thereof |
| CN107474342A (en) * | 2017-08-31 | 2017-12-15 | 安徽华海特种电缆集团有限公司 | A kind of low smoke and zero halogen photovoltaic generation antiultraviolet CABLE MATERIALS and preparation method thereof |
| CN109705480A (en) * | 2018-12-31 | 2019-05-03 | 安徽天康(集团)股份有限公司 | A kind of fire prevention Plastic-sheathed Cable and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101173067A (en) * | 2007-10-31 | 2008-05-07 | 上海矿用电缆厂 | High-strength cold hardiness cable sheath rubber and technique of preparing the same thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04202246A (en) * | 1990-11-29 | 1992-07-23 | Furukawa Electric Co Ltd:The | Polychloroprene rubber composition |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101173067A (en) * | 2007-10-31 | 2008-05-07 | 上海矿用电缆厂 | High-strength cold hardiness cable sheath rubber and technique of preparing the same thereof |
Non-Patent Citations (1)
| Title |
|---|
| 耐热氯丁橡胶电缆护套配方研制;蒋峰;《世界橡胶工业》;20040630;第31卷(第6期);23-26 * |
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