CN103360652A - UV (ultraviolet)-resisting cable sheath material and method for preparing same - Google Patents
UV (ultraviolet)-resisting cable sheath material and method for preparing same Download PDFInfo
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- CN103360652A CN103360652A CN2013102533716A CN201310253371A CN103360652A CN 103360652 A CN103360652 A CN 103360652A CN 2013102533716 A CN2013102533716 A CN 2013102533716A CN 201310253371 A CN201310253371 A CN 201310253371A CN 103360652 A CN103360652 A CN 103360652A
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- 239000000463 material Substances 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title abstract description 3
- 239000000843 powder Substances 0.000 claims abstract description 28
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims abstract description 14
- -1 polypropylene Polymers 0.000 claims abstract description 13
- 229920001084 poly(chloroprene) Polymers 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004593 Epoxy Substances 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004743 Polypropylene Substances 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000006096 absorbing agent Substances 0.000 claims abstract description 7
- 229940037003 alum Drugs 0.000 claims abstract description 7
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000018660 ammonium molybdate Nutrition 0.000 claims abstract description 7
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 7
- 239000011651 chromium Substances 0.000 claims abstract description 7
- 239000010433 feldspar Substances 0.000 claims abstract description 7
- 239000011521 glass Substances 0.000 claims abstract description 7
- 235000019359 magnesium stearate Nutrition 0.000 claims abstract description 7
- 239000010445 mica Substances 0.000 claims abstract description 7
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 7
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001155 polypropylene Polymers 0.000 claims abstract description 7
- 102220040412 rs587778307 Human genes 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 4
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims abstract description 3
- 229940010552 ammonium molybdate Drugs 0.000 claims abstract description 3
- 239000011609 ammonium molybdate Substances 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 7
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 6
- HGQSXVKHVMGQRG-UHFFFAOYSA-N dioctyltin Chemical compound CCCCCCCC[Sn]CCCCCCCC HGQSXVKHVMGQRG-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 230000036571 hydration Effects 0.000 claims description 3
- 238000006703 hydration reaction Methods 0.000 claims description 3
- 230000000630 rising effect Effects 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 230000032683 aging Effects 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 2
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 abstract 1
- OKISUZLXOYGIFP-UHFFFAOYSA-N 4,4'-dichlorobenzophenone Chemical compound C1=CC(Cl)=CC=C1C(=O)C1=CC=C(Cl)C=C1 OKISUZLXOYGIFP-UHFFFAOYSA-N 0.000 abstract 1
- NPLAVDWQFWXSND-UHFFFAOYSA-N C(CCCCCCC)[Sn]CCCCCCCC.C(CS)(=O)OCCCCCC(C)C Chemical compound C(CCCCCCC)[Sn]CCCCCCCC.C(CS)(=O)OCCCCCC(C)C NPLAVDWQFWXSND-UHFFFAOYSA-N 0.000 abstract 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 abstract 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 abstract 1
- 230000006750 UV protection Effects 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
Abstract
The invention discloses an UV (ultraviolet)-resisting cable sheath material. The ultraviolet-resisting cable sheath material is characterized by being prepared from the following raw materials in parts by weight: 100-110 parts of neoprene M-40, 12-15 parts of polypropylene T30S, 8-10 parts of nano diatomite, 10-15 parts of feldspar powder, 5-7 parts of glass powder, 20-25 parts of mica powder, 5-6 parts of magnesium stearate, 4-5 parts of phthalate, 3-4 parts of epoxy tetrahydro dioctyl phthalate, 1-3 parts of alum powder, 2-3 parts of hydrated zinc borate, 1-2 parts of N-(beta-aminoethyl)-gamma-aminopropyl trimethoxysilane, 1-2 parts of diisopropyl naphthalene sulfonate, 0.3-0.6 part of aluminum isopropoxide, 1-2 parts of chromium boride, 1-2 parts of an antioxidant 168, 3-4 parts of anhydrous ethanol, 0.2-0.3 part of a UV absorber UV-9, 0.8-1 part of bis isooctyl thioglycolate di-n-octyltin, 0.8-1 part of ammonium molybdate trimolybdate and 0.6-1 part of a vulcanizing agent DCBP. The cable sheath material disclosed by the invention has good physical and mechanical properties and good UV resistance and can resist oil, heat, flame, sunlight, ozone, ageing, acids and alkalies. Because particles are added in the process of preparing the cable sheath material, the compatibility of the raw materials can be improved, and the tearing strength and the tensile strength of the cable sheath material can be further enhanced.
Description
Technical field
The present invention relates generally to a kind of sheath material, relates in particular to a kind of uvioresistant cable jacket material and preparation method thereof.
Background technology
The over-all properties of chloroprene rubber is good, natural rubber and other synthetic rubber are all incomparable on a lot of performances, good physical and mechanical properties is arranged, oil resistant, heat-resisting, anti-combustion, anti-daylight, anti-ozone, ageing-resistant, acid and alkali-resistance, chemical-resistant reagent, therefore be used as widely cable jacket material, and CABLE MATERIALS is higher for the requirement of performance, to accept for a long time to be exposed to the sun, wind and rain, high temperature, low cold etc., corrosion-resistant for it, the performance requriements of the each side such as fire-retardant is all higher, therefore need a kind of new method to improve and strengthen the overall performance of chloroprene rubber, necessary for the development of cable cause.
Summary of the invention
The object of the invention just provides a kind of uvioresistant cable jacket material and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of uvioresistant cable jacket material, it is comprised of the raw material of following weight parts
Chloroprene rubber M-40 100-110, polypropylene T30S 12-15, nano diatomite 8-10, Feldspar Powder 10-15, glass powder 5-7, mica powder 20-25, Magnesium Stearate 5-6, phthalic ester 4-5, epoxy tetrahydro-2-ethylhexyl phthalate 3-4, alum powder 1-3, hydration zinc borate 2-3, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane 1-2, di-isopropyl sodium naphthalene sulfonate 1-2, aluminum isopropylate 0.3-0.6, chromium boride 1-2, irgasfos 168 1-2, dehydrated alcohol 3-4, UV light absorber UV-9 0.2-0.3, Imarcaptoacetate dioctyltin 0.8-1, three ammonium molybdate 0.8-1, vulcanizing agent DCBP0.6-1.
A kind of preparation method of uvioresistant cable jacket material may further comprise the steps:
Above-mentioned aluminum isopropylate is mixed with dehydrated alcohol, fully stir under the normal temperature, add nano diatomite, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane, stirred 20-30 minute at 60-70 ℃ of lower constant temperature, add alum powder, chromium boride, three ammonium molybdates, the rising temperature is incubated 1-2 hour to 80-90 ℃, be cooled to normal temperature, add the di-isopropyl sodium naphthalene sulfonate, 700-900 rev/min was disperseed the ball milling post-drying 10-13 minute, sieve, get the particle of 2-3 μ m; Above-mentioned chloroprene rubber M-40 and polypropylene T30S, Magnesium Stearate, phthalic ester, epoxy tetrahydro-2-ethylhexyl phthalate are mixed to join in the Banbury mixer, descended mixing 2-4 minute at 82-90 ℃, add again particle obtained above and Feldspar Powder, glass powder, mica powder, irgasfos 168, UV light absorber UV-9, Imarcaptoacetate dioctyltin, be under 85-90 ℃ in temperature, mixing 4-5 minute; Add each raw material of residue again, be 55-60 ℃ in temperature and descended mixing 2-3 minute, the discharging cooling namely gets described uvioresistant cable jacket material.
Advantage of the present invention is:
The cable jacket material that the present invention produces has good physical and mechanical properties, oil resistant, heat-resisting, anti-combustion, anti-daylight, anti-ozone, ageing-resistant, acid and alkali-resistance, anti-ultraviolet property excellence, by in preparation, adding particle of the present invention, strengthen the consistency of each stock yard, further strengthened tearing toughness, tensile strength.
Embodiment
Embodiment 1
A kind of uvioresistant cable jacket material, it is comprised of the raw material of following weight parts (kilogram)
Chloroprene rubber M-40 110, polypropylene T30S 15, nano diatomite 8, Feldspar Powder 15, glass powder 5, mica powder 25, Magnesium Stearate 6, phthalic ester 5, epoxy tetrahydro-2-ethylhexyl phthalate 4, alum powder 3, hydration zinc borate 3, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane 2, di-isopropyl sodium naphthalene sulfonate 2, aluminum isopropylate 0.6, chromium boride 1, irgasfos 168 1, dehydrated alcohol 4, UV light absorber UV-9 0.3, Imarcaptoacetate dioctyltin 0.8, three ammonium molybdates 0.8, vulcanizing agent DCBP0.6.
A kind of preparation method of uvioresistant cable jacket material may further comprise the steps:
Above-mentioned aluminum isopropylate is mixed with dehydrated alcohol, fully stir under the normal temperature, add nano diatomite, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane, stirred 30 minutes at 70 ℃ of lower constant temperature, add alum powder, chromium boride, three ammonium molybdates, rising temperature to 90 ℃ is incubated 2 hours, be cooled to normal temperature, add the di-isopropyl sodium naphthalene sulfonate, 900 rev/mins were disperseed the ball milling post-drying 13 minutes, sieve, get the particle of 3 μ m; Above-mentioned chloroprene rubber M-40 and polypropylene T30S, Magnesium Stearate, phthalic ester, epoxy tetrahydro-2-ethylhexyl phthalate are mixed to join in the Banbury mixer, descended mixing 4 minutes at 90 ℃, add again particle obtained above and Feldspar Powder, glass powder, mica powder, irgasfos 168, UV light absorber UV-9, Imarcaptoacetate dioctyltin, be under 90 ℃ in temperature, mixing 4 minutes; Add each raw material of residue again, be 60 ℃ in temperature and descended mixing 2 minutes, the discharging cooling namely gets described uvioresistant cable jacket material.
Performance test:
Tensile strength: 17.0MPa;
Elongation at break: 707%;
Oil-proofness: 100 ℃ * 75h of 20# machine oil, elongation at break conservation rate 72.7%, tensile strength conservation rate 77.9%;
Anti-ozone: 25 ℃, 25h, ozone concn 0.024%, without cracking;
Ageing-resistant: 120 ℃, 200h, tensile strength conservation rate 89.2 %, elongation at break conservation rate 79.1%.
Claims (2)
1. uvioresistant cable jacket material is characterized in that what it was comprised of the raw material of following weight parts:
Chloroprene rubber M-40 100-110, polypropylene T30S 12-15, nano diatomite 8-10, Feldspar Powder 10-15, glass powder 5-7, mica powder 20-25, Magnesium Stearate 5-6, phthalic ester 4-5, epoxy tetrahydro-2-ethylhexyl phthalate 3-4, alum powder 1-3, hydration zinc borate 2-3, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane 1-2, di-isopropyl sodium naphthalene sulfonate 1-2, aluminum isopropylate 0.3-0.6, chromium boride 1-2, irgasfos 168 1-2, dehydrated alcohol 3-4, UV light absorber UV-9 0.2-0.3, Imarcaptoacetate dioctyltin 0.8-1, three ammonium molybdate 0.8-1, vulcanizing agent DCBP0.6-1.
2. the preparation method of a uvioresistant cable jacket material as claimed in claim 1 is characterized in that may further comprise the steps:
Above-mentioned aluminum isopropylate is mixed with dehydrated alcohol, fully stir under the normal temperature, add nano diatomite, N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane, stirred 20-30 minute at 60-70 ℃ of lower constant temperature, add alum powder, chromium boride, three ammonium molybdates, the rising temperature is incubated 1-2 hour to 80-90 ℃, be cooled to normal temperature, add the di-isopropyl sodium naphthalene sulfonate, 700-900 rev/min was disperseed the ball milling post-drying 10-13 minute, sieve, get the particle of 2-3 μ m; Above-mentioned chloroprene rubber M-40 and polypropylene T30S, Magnesium Stearate, phthalic ester, epoxy tetrahydro-2-ethylhexyl phthalate are mixed to join in the Banbury mixer, descended mixing 2-4 minute at 82-90 ℃, add again particle obtained above and Feldspar Powder, glass powder, mica powder, irgasfos 168, UV light absorber UV-9, Imarcaptoacetate dioctyltin, be under 85-90 ℃ in temperature, mixing 4-5 minute; Add each raw material of residue again, be 55-60 ℃ in temperature and descended mixing 2-3 minute, the discharging cooling namely gets described uvioresistant cable jacket material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310253371.6A CN103360652B (en) | 2013-06-21 | 2013-06-21 | A kind of uvioresistant cable jacket material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310253371.6A CN103360652B (en) | 2013-06-21 | 2013-06-21 | A kind of uvioresistant cable jacket material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103360652A true CN103360652A (en) | 2013-10-23 |
| CN103360652B CN103360652B (en) | 2016-05-04 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104140650A (en) * | 2014-07-17 | 2014-11-12 | 滁州优胜高分子材料有限公司 | Pbt material for optical fiber cable |
| CN104774378A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Stable polypropylene composite material for household electric appliances |
| CN105504389A (en) * | 2016-01-29 | 2016-04-20 | 宁波远欣石化有限公司 | Environmental-friendly alumina sol modified rubber material and preparation method thereof |
| JP2017066183A (en) * | 2015-09-28 | 2017-04-06 | 日立金属株式会社 | Chloroprene rubber composition and manufacturing method therefor, wire and cable and manufacturing method therefor, crosslinking method and storing method of chloroprene rubber composition |
| CN107474342A (en) * | 2017-08-31 | 2017-12-15 | 安徽华海特种电缆集团有限公司 | A kind of low smoke and zero halogen photovoltaic generation antiultraviolet CABLE MATERIALS and preparation method thereof |
| CN109705480A (en) * | 2018-12-31 | 2019-05-03 | 安徽天康(集团)股份有限公司 | A kind of fire prevention Plastic-sheathed Cable and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JPH04202246A (en) * | 1990-11-29 | 1992-07-23 | Furukawa Electric Co Ltd:The | Polychloroprene rubber composition |
| CN101173067A (en) * | 2007-10-31 | 2008-05-07 | 上海矿用电缆厂 | High-strength cold hardiness cable sheath rubber and technique of preparing the same thereof |
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2013
- 2013-06-21 CN CN201310253371.6A patent/CN103360652B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04202246A (en) * | 1990-11-29 | 1992-07-23 | Furukawa Electric Co Ltd:The | Polychloroprene rubber composition |
| CN101173067A (en) * | 2007-10-31 | 2008-05-07 | 上海矿用电缆厂 | High-strength cold hardiness cable sheath rubber and technique of preparing the same thereof |
Non-Patent Citations (1)
| Title |
|---|
| 蒋峰: "耐热氯丁橡胶电缆护套配方研制", 《世界橡胶工业》 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104140650A (en) * | 2014-07-17 | 2014-11-12 | 滁州优胜高分子材料有限公司 | Pbt material for optical fiber cable |
| CN104140650B (en) * | 2014-07-17 | 2016-01-20 | 滁州优胜高分子材料有限公司 | A kind of fiber optic ribbon cable cable PBT material |
| CN104774378A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Stable polypropylene composite material for household electric appliances |
| JP2017066183A (en) * | 2015-09-28 | 2017-04-06 | 日立金属株式会社 | Chloroprene rubber composition and manufacturing method therefor, wire and cable and manufacturing method therefor, crosslinking method and storing method of chloroprene rubber composition |
| CN105504389A (en) * | 2016-01-29 | 2016-04-20 | 宁波远欣石化有限公司 | Environmental-friendly alumina sol modified rubber material and preparation method thereof |
| CN107474342A (en) * | 2017-08-31 | 2017-12-15 | 安徽华海特种电缆集团有限公司 | A kind of low smoke and zero halogen photovoltaic generation antiultraviolet CABLE MATERIALS and preparation method thereof |
| CN109705480A (en) * | 2018-12-31 | 2019-05-03 | 安徽天康(集团)股份有限公司 | A kind of fire prevention Plastic-sheathed Cable and preparation method thereof |
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| Publication number | Publication date |
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| CN103360652B (en) | 2016-05-04 |
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Address after: 243102 Anhui city of Ma'anshan province Dangtu County Economic Development Zone Patentee after: ANHUI RONGJIU INTELLIGENT EQUIPMENT TECHNOLOGY CO.,LTD. Address before: 243102 Anhui city of Ma'anshan province Dangtu County Economic Development Zone Patentee before: ANHUI RONGJIU OPTICAL FIBER COMMUNICATION Co.,Ltd. |
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Effective date of registration: 20240228 Address after: No. 5825, Wujiangtai Village, Bazhou Town, Bazhou City, Langfang City, Hebei Province, 065700 Patentee after: Wu Lianqi Country or region after: China Address before: 413, Floor 4, Building B, Innovation Building, Linyi Hi tech Industrial Development Zone, Shandong Province, 276000 Patentee before: Linyi High tech Zone Jinlanling Labor Service Co.,Ltd. Country or region before: China |
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