CN107646838A - A kind of edible glue class pesticide spray assistant composition - Google Patents
A kind of edible glue class pesticide spray assistant composition Download PDFInfo
- Publication number
- CN107646838A CN107646838A CN201610597358.6A CN201610597358A CN107646838A CN 107646838 A CN107646838 A CN 107646838A CN 201610597358 A CN201610597358 A CN 201610597358A CN 107646838 A CN107646838 A CN 107646838A
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- China
- Prior art keywords
- composition
- spray
- agricultural chemicals
- spray adjuvantses
- adjuvantses
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/34—Nitriles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
Abstract
The present invention relates to a kind of preparation and application of pesticide spray assistant composition, the spray adjuvantses are mainly made up of natural edible glue (containing its raw material), have the characteristics of green, safe and harmless.The auxiliary agent is applied to all kinds of formulation agricultural chemicals, has the adhesion of enhancing decoction and wettability, increases agricultural chemicals spreading area, delay spray evaporation speed, reduce the effect of droplet drift, it is possible to increase pesticide control effect, reduces applications of pesticide cost.The auxiliary agent has wide range of applications, and can be used cooperatively with the various farm chemical ingredients such as herbicide, insecticide, bactericide and plant growth regulator.
Description
Technical field
The present invention relates to a kind of preparation and application of the pesticide spray assistant composition for coming from natural food material, the combination
Thing is applied to herbicide, insecticide, bactericide and plant growth regulator pesticide synergistic application, belongs to insecticides adjuvant technology neck
Domain.
Background technology
Agricultural chemicals in use always there is effective rate of utilization it is low the problem of.It is estimated that sprayed from spraying equipment
The agricultural chemicals gone only has 25%~50% can deposit on crop leaf, and the medicament less than 1% can be deposited on target pest, only
0.03% medicament really plays insecticidal action.Agricultural chemicals drift, volatilization and loss are the main reason for causing agricultural chemicals to lose, and are improved
Agricultural chemicals utilization rate it is necessary to reduce agricultural chemicals from spray tank into target transmittance process because drifting about, evaporating and blade face is lost in and brought
Loss, it is exactly to add spray adjuvantses in pesticide spray liquid to solve this problem most efficient method.Agricultural chemicals adds spray adjuvantses
Medical liquid surface tension can be reduced afterwards, extended droplet moisture preserving time, increased spreading area and resistance of rainwater washing against of the decoction on blade face
Ability, playing prevents float of mist droplet, enhancing plate-out ability, sorbefacient effect, promotes the new technologies such as accuracy pesticide applying, decrement dispenser
Popularization and application.
The most widely used pesticide spray auxiliary agent of existing market has nonionic surfactants, organic silicon, plant
Oils and mineral oils etc., but its applicability is restricted Shortcomings part by auxiliary agent physicochemical property.Nonionic surfactants
Auxiliary agent easily fails under high temperature, drought condition;Organic silicon auxiliary agent is only applicable to the scopes of pH 5~9, in meta-acid, meta-alkali solution
In degrade rapidly, and in hot environment using easily produce poisoning;Vegetable oil is with mineral oil due to immiscible, it is necessary to add with water
Emulsifying agent is prepared into emulsion and could used as spray adjuvantses.
The invention provides a kind of new pesticide synergistic technical scheme, the problem of existing spray adjuvantses are present is overcome.Should
Scheme can not only increase spreading area of the pesticide droplet on blade face, delay the evaporation rate of spray droplet, reduce droplet drift,
Drug effect is improved to play, and auxiliary agent is derived from natural food raw material, and green, the safe and environment-friendly advantage of product protrudes.
The content of the invention
The present invention provides a kind of one or more of mixtures by natural edible glue or its raw material, with food emulsifying agent, food
The agricultural chemicals synergist composition that preservative and water etc. are mixed is savored, said composition directly mixes with all kinds of formulation agricultural chemicals to be made
With by strengthening spray liquid adhesion and wetting action, reducing droplet evaporation capacity, increase medicinal liquid osmosis speed and infiltration capacity, reach
Extend pesticide efficacy release time, reduce Pesticide use amount, improve the purpose of pesticide efficacy.The present invention has a wide range of application
It is general, synergistic effect is respectively provided with to the class agricultural chemicals such as weeding, desinsection, sterilization and plant growth regulating.
The present invention provides a kind of agricultural chemicals synergist composition to achieve the above object, and said composition is by 0.01%-20%
One or more natural edible glue (containing its raw material) combination structure costing formula basis, it is possible to additionally incorporate 1-40% food emulsification
Agent, 1%-10% food preservative and 50%-95% water.Natural edible glue (containing its raw material) is as thickening in the present invention
Agent, food emulsifying agent is as nonionic surface active agent.Natural edible glue or its raw material by the synergy with emulsifying agent,
Increase system viscosity is played, promotes decoction to make in target plant moistened surface spread and infiltration, increase hold-up, extension drug effect
With time and the effect of anti-rain drop erosion, additionally it is possible to regulate and control spray droplet size, reduce decoction and evaporate and avoid drifting about.The agricultural chemicals
Builder is added with the food preservative no less than 1%, and it is rotten to prevent that the edible glue in auxiliary agent from degrading.In agricultural production,
The synergistic composition is added in agricultural chemicals by a certain percentage, Pesticide use amount more than 30% can be reduced.
The present invention has advantages below:(1) synergistic effect is notable, the auxiliary agent can strengthen decoction plant surface wetting,
Adhesion and permeance property, retard evaporation speed, are greatly improved the utilization of pesticide active ingredient.(2) green safe, the auxiliary agent is whole
Food additives are used as raw material, there is good bioavilability and compatibility, avoid organosilicon and azone analog assistant from using
During existing allergy risk.(3) environmentally friendly, spray droplet size can be controlled in suitable scope by adding the auxiliary agent,
Poisoning and environmental pollution caused by avoiding agricultural chemicals drift.(4) have wide range of applications, accommodate and missible oil, suspending agent, wettable powder
The different formulations of pesticide buckets such as agent, suspension emulsion, microemulsion, aqueous emulsion, aqua are mixed to be used, especially with missible oil, microemulsion, suspension emulsion,
Aqueous emulsion, the mixing of aqua are better.(5) Pesticide use cost is saved, Pesticide use amount can be reduced using the auxiliary agent, especially
It is to subtract to apply high price agricultural chemicals remarkable in economical benefits.
Brief description of the drawings
Fig. 1 is the blade surface precipitation capacity that different content is formulated spray adjuvantses.
Fig. 2 is the blade surface precipitation capacity rate of recovery that different content is formulated spray adjuvantses.
Embodiment
The present invention is better understood by means of following embodiments, these embodiments are only used for illustrating the present invention, no
Limitation of the present invention should be interpreted.
A kind of preparation of pesticide spray auxiliary agent of embodiment 1
A kind of pesticide spray auxiliary agent is made up of by weight percentage following component:Xanthans 0.2%, sucrose fatty acid ester
20%, sorbic acid 2%, water 77.8%.
Exemplified by preparing 1 kilogram of pesticide spray auxiliary agent, specific preparation process is as follows:
The first step:778 grams of water are added in reactor, reactor is heated to 15-100 using 10 DEG C/min programming rate
DEG C, it is well mixed with being slowly added to 2 grams of xanthan rubber powders under 500-800rpm/min mechanical agitation speed conditions.
Second step:200 grams of sucrose fatty acid esters are added in reactor under the reaction temperature and mixed with xanthans
Uniformly.
3rd step:20 grams of sorbic acids are added into xanthans and sucrose-fatty lipoprotein mixture, continue to mix to
Room temperature is naturally cooled to after even to get product.
A kind of Herbicidal combinations of 2 spray adjuvantses containing synergy of embodiment
Xanthans 0.2g, sucrose fatty acid ester 20g, sorbic acid 2g, water 77.8g are taken, is prepared using the method for embodiment 1
100g spray adjuvantses, 5g spray adjuvantses and 16mL ammonium glyphosates (aqua) plus 1L water is taken to be mixed with to obtain Herbicidal combinations.
A kind of Pesticidal combination of 3 spray adjuvantses containing synergy of embodiment
Edible gelatin 5g, glyceryl monostearate 35g, benzoic acid 2g, water 58g are taken, is prepared using the method for embodiment 1
100g spray adjuvantses, 10g spray adjuvantses and 1.6mL effective cypermethrins (missible oil) plus 1L water is taken to be mixed with to obtain Insecticidal combinations
Thing.
A kind of bactericidal composition of 4 spray adjuvantses containing synergy of embodiment
Carragheen 1g, soybean lecithin 20g, citric acid 2g, water 77g are taken, 100g sprayings are prepared using the method for embodiment 1
Auxiliary agent, 50g spray adjuvantses and 1.6mL pyrazoles Fluoxastrobin (missible oil) plus 1L water is taken to be mixed with to obtain bactericidal composition.
A kind of bactericidal composition of 5 spray adjuvantses containing synergy of embodiment
Locust bean gum 2g, potato starch 20g, citric acid 2g, water 76g are taken, 100g sprayings are prepared using the method for embodiment 1
Auxiliary agent, 30g spray adjuvantses and 1g Fluoxastrobins (wettable powder) plus 1L water is taken to be mixed with to obtain bactericidal composition.
A kind of bactericidal composition of 6 spray adjuvantses containing synergy of embodiment
Xanthans and pectin mixture 10g, sorbitan fatty acid fat 35g, benzoic acid 2g, water 53g are taken, using embodiment
100g spray adjuvantses are prepared in 1 method, take 15g spray adjuvantses and 4mL Bravos (suspending agent) plus 1L water mixing system respectively to obtain
Bactericidal composition.
A kind of plant coutrol composition of 7 spray adjuvantses containing synergy of embodiment
Guar bean flour 12g, sucrose fatty acid ester 10g, benzoic acid 2g, water 76g are taken, is prepared using the method for embodiment 1
100g spray adjuvantses, 20g spray adjuvantses and 10mL cycocels (aqua) plus 1L water is taken to be mixed with to obtain plant coutrol composition.
The application method of agricultural chemicals synergist of the present invention is:The agricultural chemicals for preparing to use first is diluted to the medicine of required ratio
Liquid, then the builder is proportionally added into pesticide solution and stirred.
The mist droplet particle size measure of spread of embodiment 8
Decoction droplet using laser particle analyzer to formula spray adjuvantses described in addition different content percentage embodiment 2-7
Particle diameter distribution is determined, with D50 values (meso-position radius, representing that cumulative distribution percentage reaches particle size values corresponding when 50%)
It is compared for grain size characteristic index, as a result as shown in table 1.
Table 1. adds influence of the different content Percent Spray auxiliary agent to mist droplet particle size
After the as shown by data of table 1 adds spray adjuvantses of the present invention, pesticide droplet particle diameter significantly increases, and can promote decoction
Blade face is settled down to quickly, is advantageous to control drift.Mist droplet particle size size is suitable simultaneously, avoids because droplets particles are excessive, adhesive force
Loss is tumbled caused by difference.
The evaporation experiment of embodiment 9
By 100 μ l added with formula spray adjuvantses described in 5% (wt%) embodiment 2-7 and organosilicon, azone spray adjuvantses
And the pyrazoles Fluoxastrobin decoction dropwise addition for being not added with spray adjuvantses determines mass change of the decoction with time lengthening on slide
Value, as a result as shown in table 2.
The droplet of table 2. evaporates speed comparative experiments
The as shown by data of table 2 adds spray adjuvantses of the present invention compared with being not added with auxiliary agent, addition organosilicon and azone auxiliary agent
Decoction evaporation rate has obvious reduction, contributes to reduction decoction that evaporation occurs in spray process and scatters and disappears.
The sedimentation experiment of embodiment 10
By the pyrazoles Fluoxastrobin decoction added with formula spray adjuvantses described in different content percentage embodiment 4 in identical bar
The blade surface of fixed-area is quantitatively sprayed onto under part, it is phonetic using pyrazoles on LC-MS method measure blade face after naturally dry
The deposition of bacterium ester, using chromatographic peak area as decoction deposition size reduced parameter, as a result as shown in Figure 1.
Fig. 1 as shown by data adds the pyrazoles Fluoxastrobin decoction deposition highest of 5% auxiliary agent of the present invention, than being not added with auxiliary agent pair
More than 30% is had more according to a group deposition, 20%-30% is had more than organosilicon and azone auxiliary agent control group deposition.
The antiscour of embodiment 11 is tested
By the pyrazoles Fluoxastrobin decoction added with formula spray adjuvantses described in different content percentage embodiment 4 in identical bar
The blade surface of fixed-area is quantitatively sprayed onto under part, after naturally dry, a half vane carries out deposition determination experiment, another
Half vane, to trickling, carries out antiscour experiment in its surface basis weight spray water, is surveyed after naturally dry using LC-MS method
The residual quantity of pyrazoles Fluoxastrobin on blade face is determined, by the ratio between pyrazoles Fluoxastrobin residual quantity chromatographic peak area and deposition chromatographic peak area
(rate of recovery) is used as auxiliary agent erosion resistibility reduced parameter, as a result as shown in Figure 2.
Fig. 2 as shown by data adds the pyrazoles Fluoxastrobin decoction rate of recovery highest of 5% auxiliary agent of the present invention, than being not added with auxiliary agent pair
More than 40% is had more according to a group rate of recovery, 10%-20% is had more than organosilicon and the azone auxiliary agent control group rate of recovery.Illustrate to use this
Invention spray adjuvantses have significant erosion resistibility.
The synergy spray adjuvantses application experiment of embodiment 12
Bravo bactericidal composition is prepared as described in embodiment 6, formulation rate is 20g/ mus, carries out preventing and treating powdery mildew of cucumber
Effect experiment.Control group:Organic silicon, azone, nonionic surfactants and plant oil auxiliary agent, experimental result such as table 3
It is shown.
Dispenser next day is observed, and obvious poisoning occur in the cucumber leaves of 5% benefit energy treatment region, are observed after 7 days and find that benefit can be located
The cucumber leaves 70%-80% of reason dries up, or even whole strain is dead.Other auxiliary agents do not have poisoning.In terms of prevention effect, use
The auxiliary agent of embodiment 6 improves 33.9% than not adding assistant, and 10.7-29.5% is improved than control group auxiliary agent.Pesticide spray of the present invention
The prevention effect of auxiliary agent is significantly better than non-adding assistant and addition conven-tional adjuvants.
Influence of the 3. different spray adjuvantses of table to pesticide control effect
Note:Investigate data and take 3 repetition laboratory mean values
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to most
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the skill of the present invention
Art scheme is modified or equivalent substitution, and without departing from the objective and scope of technical solution of the present invention, it all should cover in this hair
Among bright right.
Claims (13)
- A kind of 1. spray adjuvantses composition, it is characterised in that:Said composition is 0.01%-20% comprising mass percent (wt%) Natural edible glue, 1-40% food emulsifying agent, 1%-10% food preservative and 50%-95% water.
- 2. spray adjuvantses composition according to claim 1, it is characterised in that:The natural edible glue is:Sodium alginate, Agar, gelatin, pectin, xanthans, Arabic gum, furcellaran, bassora gum, locust bean gum, carragheen, gellan, gellan gum, melon That bean gum, konjaku glucomannan, curdlan, maltodextrin, linseed meal, oatmeal, beet pulp, konjaku flour, cluster bean One or more combinations in powder.
- 3. spray adjuvantses composition according to claim 1, the food emulsifying agent is sucrose fatty acid ester, glycerine list is hard One or more combinations in resin acid ester, sorbitan fatty acid fat, soybean lecithin, starch.
- 4. spray adjuvantses composition according to claim 1, the food preservative be sorbic acid, benzoic acid, citric acid, One or more combinations in dehydroactic acid.
- 5. a kind of agricultural chemicals synergist, including the spray adjuvantses composition described in claim 1.
- 6. agricultural chemicals synergist according to claim 5, it is characterised in that:The spray adjuvantses composition is applied to difference The formulations of pesticide, the formulations of pesticide include one kind in missible oil, wettable powder, microemulsion, suspension emulsion, aqueous emulsion and aqua More than.
- 7. agricultural chemicals synergist according to claim 5, it is characterised in that:The spray adjuvantses composition is applied to difference Farm chemical ingredients are prepared, and the farm chemical ingredients prepare the one kind included in herbicide, insecticide, bactericide, plant growth regulator More than.
- 8. the agricultural chemicals synergist according to claim 5 or 7, it is characterised in that:The spray adjuvantses composition is applied to When herbicide is prepared in processing, its mass percent (wt%) is 0.1%-10%.
- 9. the agricultural chemicals synergist according to claim 5 or 7, it is characterised in that:The spray adjuvantses composition is applied to When insecticide is prepared in processing, its mass percent (wt%) is 0.1%-10%.
- 10. the agricultural chemicals synergist according to claim 5 or 7, it is characterised in that:The spray adjuvantses composition is applied to When bactericide is prepared in processing, its mass percent (wt%) is 0.1%-10%.
- 11. the agricultural chemicals synergist according to claim 5 or 7, it is characterised in that:The spray adjuvantses composition is applied to When plant growth regulator is prepared in processing, its mass percent (wt%) is 0.1%-10%.
- 12. according to the agricultural chemicals synergist described in claim 5-7 any one, it is characterised in that:The spray adjuvantses combination The mass percent of thing is (wt%) 0.1%-8%.
- 13. the preparation method of the spray adjuvantses composition according to claim 1-4 any one, it is characterised in that the side Method comprises the following steps:Add water in reactor, reactor is heated to 15-100 DEG C, is stirred with 500-800rpm/min machinery Edible glue or its raw material, emulsifying agent, preservative are sequentially added under the conditions of mix rotating speed in proportion, it is natural after stirring and dissolving is well mixed Cooling.
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CN201610597358.6A CN107646838A (en) | 2016-07-26 | 2016-07-26 | A kind of edible glue class pesticide spray assistant composition |
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CN201610597358.6A CN107646838A (en) | 2016-07-26 | 2016-07-26 | A kind of edible glue class pesticide spray assistant composition |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109452271A (en) * | 2018-11-07 | 2019-03-12 | 四川省乐山市华莱利科技有限公司 | A kind of insecticides adjuvant composition of resistance of rainwater washing against and its application |
CN113180039A (en) * | 2021-05-06 | 2021-07-30 | 苏州嘉佑生物科技有限公司 | Special auxiliary agent for unmanned aerial vehicle plant protection and flying prevention and preparation method and application thereof |
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CN101637172A (en) * | 2009-06-12 | 2010-02-03 | 深圳诺普信农化股份有限公司 | Insecticidal/acaricidal composition having lufenuron and tebufenozide |
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2016
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DE2556656A1 (en) * | 1975-12-16 | 1977-06-30 | Tama Flex Sansho Inc | Additives for sprayable aq. agricultural compsns. - contain sorbitol, nonionic surfactant and hydrophobic oil, and give a stable, adherent aerosol |
CN101637172A (en) * | 2009-06-12 | 2010-02-03 | 深圳诺普信农化股份有限公司 | Insecticidal/acaricidal composition having lufenuron and tebufenozide |
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Title |
---|
王早骧: "《农药助剂》", 31 January 1997, 化学工业出版社 * |
石伶俐等: "喷雾助剂对三唑磷在水稻叶片上沉积量的影响", 《中国农业科学》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109452271A (en) * | 2018-11-07 | 2019-03-12 | 四川省乐山市华莱利科技有限公司 | A kind of insecticides adjuvant composition of resistance of rainwater washing against and its application |
CN113180039A (en) * | 2021-05-06 | 2021-07-30 | 苏州嘉佑生物科技有限公司 | Special auxiliary agent for unmanned aerial vehicle plant protection and flying prevention and preparation method and application thereof |
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